• Bulletin of the Korean Chemical Society
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• 제33권6호
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• pp.1934-1938
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• 2012

The reaction mechanism between cyclopropenylidene and formaldehyde has been systematically investigated employing the MP2/6-311+$G^*$ level of theory to better understand the cyclopropenylidene reactivity with carbonyl compound. Geometry optimization, vibrational analysis, and energy property for the involved stationary points on the potential energy surface have been calculated. Energies of all the species are further corrected by the CCSD(T)/6-311+$G^*$ single-point calculations. It was found that one important reaction intermediate (INTa) has been located firstly $via$ a transition state (TSa). After that, the common intermediate (INTb) for the two pathways (1) and (2) has been formed $via$ TSb. At last, two different products possessing three- and four-membered ring characters have been obtained through two possible reaction pathways. In the reaction pathway (1), a three-membered ring alkyne compound has been obtained. As for the reaction pathway (2), it is the formation of the four-membered ring conjugated diene compound. The energy barrier of the ratedetermining step of pathway (1) is lower than that of the pathway (2), and the ultima product of pathway (2) is more stable than that of the pathway (1).

• Tribology and Lubricants
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• 제16권3호
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• pp.157-165
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• 2000

A discharge free Electro-Rheological Squeeze Film Damper (ER-SFD) with predetermined-clearances at leakage ends can inherently eliminate electric discharge problems while still supplying stable leakage control. Test results show that the damping force of the slotted-ring ER-SFD is mainly affected by electric voltage, oil supply pressure, position of the damper and ratio of effective surface area of slotted-rings. As the supply voltage is larger, the amplitudes of both slotted ER-SFD and rotor are decreased at first and second critical speeds. The influence of the oil supply pressure and the effective surface area ratio was shown mainly near the first critical speed. The effective surface area ratio of slotted-rings influences the reduction of flexible rotor vibration. As a result, experimental results confirm that the slotted-ring ER-SFD satisfactorily controls the flexible rotor vibration, while eliminates the inherent electric discharge problems in conventional ER-SFDs.

• KSTLE International Journal
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• 제2권1호
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• pp.22-28
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• 2001

A resin bonded copper-graphite brush was investigated to evaluate the characteristics electrical signal transmission through a sliding contact as a function of the relative amount of graphite and copper in the brush. Particular attention was given to the correlation between electrical signal fluctuation and tribological properties in an electrical sliding contact system. A ring-on-block type tribotester was used for this experiment and the ring was made from pure copper. Results showed that a copper-graphite brush at a particular composition range exhibited the most stable frictional behavior with a minimum voltage drop. The amount of voltage drop at the friction interface was affected by the surface roughness, transfer film formation at the friction interface, and the real area of contact. Microscopic observations and the surface analysis showed a good agreement with the results from this experiment. The results also indicated that the electrical signal flunctuation was directly associated with the oscillation of the coefficient of friction during sliding by nanoscale variation of contacts at the friction interface.

• 한국정보통신학회:학술대회논문집
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• 한국정보통신학회 2015년도 춘계학술대회
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• pp.852-854
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• 2015

본 논문에서는 건물 통신환경 개선을 위한 건물 내벽의 실제적인 적용을 위해 제작과정이 단순하고 생산 단가가 저렴한 잉크젯 프린팅 방식을 이용하여 종이를 기반의 링 구조 주파수 선택 표면구조를 설계하고 제작하였다. 설계된 종이 기반 주파수 선택 표면구조는 X-대역에서 대역차단 특성과 우수한 입사각 안정성, 광대역 특성을 갖는다. 측정결과로부터 시뮬레이션 결과와 비교적 잘 일치하는 것을 확인하였다.

• Tribology and Lubricants
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• 제18권1호
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• pp.34-41
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• 2002

This paper presents the contact thermal behaviors of mechanical seals depending on the contacting face geometry. Using the finite element analysis, the temperature distribution, thermal distortion and leakage have been analyzed as functions of sealing gap and rotating speed of the seal ring shaft. The FE results indicate that the inclined contacting face may be more effective and stable based on the results of thermal characteristic analysis if the seal ring has been designed with a same thermal capacity between conventional rectangular sealing faces and inclined seating surface of seal rings.

• 한국광학회지
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• 제4권3호
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• pp.330-337
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• 1993

Erbium이 첨가된 광섬유를 이득 매질로 하여 광섬유 loop mirror가 포함된 '8' 자 형태의 고리형 광섬유 레이저를 구성하였다. Loop mirror내의 양방향으로 진행하는 두 광파간의 비선형적 위상차로 인하여 loop mirror의 투과율이 입사광 강도에 의존함으로써 수동형의 모드록킹이 가능하였으며, 외부 perturbation 이나 변조소자의 도움없이도 공진기내의 편광조절기만의 조절에 의해 모드록킹ㅇ르 시작시킬 수 있었다. 또한 모드록킹에 의한 펄스 출력 파형을 비선형 loop mirror의 투과특숭과 관련하여 고찰하여 보았다.

• Bulletin of the Korean Chemical Society
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• 제29권4호
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• pp.827-832
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• 2008

A new diarylethene compound with donor and acceptor substituent was synthesized from 2,3-bis(2-methylbenzo[b]thiophene-3-yl)hexafluorocyclopentene (BTF) over 5 steps. The donor-acceptor structured BTF compound (TBTFE) showed spectral change to a longer wavelength through photochromism with a high cyclization quantum yield (0.56). The 3,4-ethylenedioxythiophene (T) and carboethoxy (E) groups directly connected to BTF unit promoted electrical change accompanied with the photoisomerization of the BTF unit. Photo-induced electrical switching was achieved from a photocell containing TBTFE doped polymer film, which showed reversible and stable current change over repeated cycles by the alternative UV/Vis irradiation, as estimated by the I-V plot.

• 대한화학회지
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• 제22권4호
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• pp.195-201
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• 1978

니코틴과 그 양성자 부가물의 배치 및 형태를 분자궤도론으로 EHT와 CNDO/2방법을 써서 연구하였다. 가장 안정한 형태는 피롤리딘 고리가 $280^{\circ}$회전된 꼴임을 알았으며 이것을 콘쥬게이션, 정전기적 및 입체효과로서 설명하였다. 양성자의 부가는 피리딘 고리에 일어나며 일종의 ${\pi}$-착물이 형성됨을 알았다.

• Bulletin of the Korean Chemical Society
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• 제25권12호
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• pp.1911-1916
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• 2004

The conformational preference of tetrahomodioxacalix[4]arenes with three different para substituents on the phenolic ring has been investigated by using ab initio molecular orbital theory (RHF/6-31$G^{\ast}$) and density functional theory (B3LYP/6-31$G^{\ast}$). The stability order is predicted to be cone > C-1,2-alternate > partial cone > 1,3-alternate > COC-1,2-alternate. The distorted cone conformation is found to be most stable in a gas phase and the calculated results are in agreement with the reported $^1$H NMR and X-ray experimental observations. The substitution of methylene with dimethyleneoxa bridges increases the size of the annulus of the molecule, its conformational mobility, and the number of hydrogen bonding patterns. The thermodynamic stability and the conformational characteristics of tetrahomodioxacalix[4]arenes are discussed in regards of the number of phenolic hydrogen bonding patterns and the polarity of a molecule. The substituent effects on the para position of the phenolic ring are also introduced.

• E2M - 전기 전자와 첨단 소재
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• 제9권1호
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• pp.59-66
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• 1996

Polyimides containing cyclobutane ring in main chain is known to be thermally stable and able to be developed in organic solvents after photolysis with 254 nm UV light. This type of polyimides can be used as promising positive photoresist in VLSI fabrication process. In the current VLSI process, photoresist films are formed by spin coating. The film thickness is more than several hundred nano meters. It seems that there is room for improvement of film coating process by introducing Langmuir Blodgett technique. Thereby ultra thin film photoresist can be formed, and higher density of integration in VLSI be achieved. In the present work, depositing procedure of LB films of this polyimide was investigated. LB film thickness was measured by ellipsometry to evaluate deposited film status. Chemical imidization procedure was studied to avoid several problems in thermal imidization. The pattern of submicron dimension has successfully formed on LB film of 8nm thick, which found showing good contrast.