• Mass Spectrometry Letters
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• 제1권1호
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• pp.9-12
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• 2010

Trimethylboroxine (TMB) is a six-membered ring compound containing Lewis acidic boron and Lewis basic oxygen atoms that can bind halide anion and alkali metal cation, respectively. We employed Fourier transform ion cyclotron resonance spectroscopy to study the gas-phase binding of $LiBrLi^+$ and $F^-(KF)_2$ to TMB. TMB forms association complexes with both $LiBrLi^+$ and $F^-(KF)_2$ at room temperature, providing direct evidence for the ditopic binding. Interestingly, the $TMB{\cdot}F^-(KF)_2$ anion complex is formed 33 times faster than the $TMB{\cdot}Li^+BrLi$ cation complex. To gain insight into the ditopic binding of an ion pair, we examined the structures and energetics of $TMB{\cdot}Li^+$, $TMB{\cdot}F^-$, $TMB{\cdot}LiF$ (the contact ion pair), and $Li^+{\cdot}TMB{\cdot}F^-$ (the separated ion pair) using Hartree-Fock and density functional theory. Theory suggests that $F^-$ binds more strongly to TMB than $Li^+$ and the contact ion-pair binding ($TMB{\cdot}LiF$) is more stable than the separated ion-pair binding ($Li^+{\cdot}TMB{\cdot}F^-$).

• 한국광학회지
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• 제6권4호
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• pp.296-301
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• 1995

광섬유격자와 단방향성 광섬유 loop mirror를 이용하여 단일모드로 발진하는 erbium첨가 광섬유레이저를 구성하였다. 이득매질인 erbium첨가 광섬유를 단방향성 loop내에 둠으로써 레이저광이 이득매질내에서 진행파를 이루도록 하고 loop 밖에서 반사 선폭이 0.2nm인 광섬유격자로 파장선택적 귀환시켜 주는 방식으로 공진기를 구성하였다. 수동형 광섬유 링공진기 형태의 광스펙트럼 분석기를 별도로 구성하여 광섬유레이저의 모드 스펙트럼을 관찰한 결과, 외부 온도변화로 인한 분 단위의 모드 튐을 제외하고는 대부분의 시간에 안정적인 단일모드 및 단일편광 상태의 특성을 나타냄을 확인할 수 있었다.

• 한국운동역학회지
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• 제14권1호
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• pp.41-50
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• 2004

The objective of the study is to analyze the myoelectrical activity involved in performing the Swallow movement, a D-level technique, in order to use it as the basic research data in helping train gymnasts in how to perform strength-related techniques. To this end, four national representative athletes who participated in the 2002 Busan Asian Games were selected. The results of the comparison analysis of the individual models are summarized as follows. 1) The results of the E.M.G analysis showed that during the Swallow movement, the myoelectrical activity was detected higher in pectorialis major muscle and bicep brachii muscle than in trapezius muscle and deltoid muscle. 2) The results of the E.M.G analysis showed that during the Swallow movement, the myoelectrical activity was measured high in triceps brachii muscle and palmaris longus muscle, while the myoelectrical activity was recorded low in latissimus dorsi muscle and rectus abdominis muscle. 3) In performing the Swallow in the rings, the mean average (%) was found high in the order of erector spinae, pectorialis major muscle, palmaris longus muscle, triceps brachii muscle, deltoid muscle, latissimus dorsi muscle, and trapezius muscle. All taken together, the athletes showed a difference in the distribution of the muscles during the performance of the Swallow. The muscle that showed a constant distribution among the athletes was pectoralis major muscle, which proves that for a stable performance, it is ideal to increase the myoelectrical activity in pectoralis major muscle.

• 유공압시스템학회논문집
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• 제1권2호
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• pp.8-14
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• 2004

Abstract: In the oil hydraulic piston pumps the clearance between the valve plate and cylinder block plays an important role for volumetric and overall efficiency. Thus, adequate lubricational fluid film is needed for the interface. In this study, fluid film thickness is measured by a gap sensor and a slip ring under operational conditions to observe the behavior of the lubrication mechanism in detail. To investigate the effect according to the valve plate types in view of the fluid film, three different types were designed. Leakage flow rate and shaft torque were also measured to clarify the effect according to the valve plate types. A broad range of experiments were conducted to provide reasonable data on the effect of fluid film. In this experiments two main parameters were found, of which the one is the discharge pressure and the other is valve plate geometry. As a result, we found that the spherical valve plate could get more stable fluid film thickness, maintain good efficiency for high pressure range than the other types.

• 제어로봇시스템학회논문지
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• 제22권11호
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• pp.888-894
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• 2016

This paper presents the kinematic and dynamic analysis of the robot arm for inspection and rescue operations. The inspection robot arm has Pitch-Pitch-Pitch-Yaw motion for an optimal and stable view of the camera installed at the end of the manipulator. The rescue operation robot arm has Yaw-Pitch-Pitch-Roll motion to handle heavy tools. Additionally, both robot arms are waterproof, as they use the triple-layer O-ring. Furthermore, the dynamic equation including the damping force due to the mechanical seal for waterproofness was derived by using the Newton-Euler method. A control system using the ARM processor was developed and introduced in this paper, and its performance was verified through experiments.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2004년도 춘계학술대회
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• pp.444-449
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• 2004

The design modification of bottom guide structures of the instrumented capsule, which is used for the irradiation test in the HANARO reactor, was required because of the trouble of the bottom guide arm's pin during irradiation. The previous structure with 3-pin arms was changed into the cone shape of one body. The specimens of the bottom end cap ring with three different sizes (${\Phi}68/70/72mm$) were designed and manufactured. The out-pile tests for the capsule with previous and new three bottom guide structures were performed in the one-channel flow test facilities. In order to evaluate the compatibility with HANARO and the structural integrity of the capsule, a loading/unloading, a pressure drop, a thermal performance, a vibration, and an endurance test were conducted. From out-pile test results, the capsule with the cone shape bottom guide structures was found to be more stable than the previous structure and the optimized size of the bottom guide structure selected was 70mm in diameter. It is expected that the new bottom guide structures will be applicable to all material and special capsules which will be designed and manufactured for the irradiation tests in the future.

• 약학회지
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• 제39권2호
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• pp.175-184
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• 1995

The interaction of omeprazole(OMP) with $\gamma$-cyclodextrin($\gamma$-CyD) was investigated by solubility study and the complexation was confirmed by means of UV/VIS spectrophotometer, circular dichroism, differential scanning calorimeter, and $^{1}$H nuclear magnetic resonance spectra. The stability, dissolution rate, and partition coefficient of the complex were measured. The results present that the benzimidazole moiety and a part of pyridine ring containing sulfur atom of OMP might be included into the cavity of $\gamma$-CyD and the formation type of inclusion complex appeared to be B$_{s}$. The stoichiometric ratio of OMP to $\gamma$-CyD in the complex was found to be 1:1 and the stability constant of the complex found to be 97.1 M$^{-1}$. And the dissolution rate of OMP was markedly increased by inclusion complex formation with $\gamma$-CyD, and so it was above 90% in 5 min. from solid complex. Oil to water partition coefficient of OMP-$\gamma$-CyD complex was 60, which is significantly higher than that of OMP itself, 36.4. The degradation rate constant of OMP were greater than OMP-$\gamma$-CyD complex in aqueous solutions of various pHs, and the half lives of OMP and OMP-$\gamma$-CyD at pH 9 were 279.2 and 509.9 days, respectively, showing that the complex was more stable than OMP, therefore it was thought that OMP was stabilized by inclusion formation with $\gamma$-CyD.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2017년도 제48회 춘계학술대회논문집
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• pp.517-520
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• 2017

본 논문은 추진기관 기밀체결부의 설계변수가 기밀조립부의 갭 거동과 오링의 기밀성능에 미치는 영향을 분석하고 효과적인 설계변수 설정 방안을 도출하였다. 체결부의 설계변수를 구성하는 요소로서 노즐 플랜지 두께, 체결볼트에 가하는 예비하중을 단계별로 변화하여 연소관 내압거동에 따른 기밀조립부 갭 벌어짐을 최소화하고 나아가서 기밀용 오링의 기밀성능을 효과적으로 유지할 수 있는 설계변수 조건을 평가함으로써 추진기관 연소관 노즐 기밀체결부의 효율적인 설계 방법론을 제시하였다.

• 폴리머
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• 제24권3호
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• pp.306-313
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• 2000

Stannous 2-ethylhexanoate와 2-hydroxyethyl methacrylate (HEMA)를 개시제로 사용하여 $\varepsilon$-caprolactone을 개환중합하여 polycaprolactone (PCL) 거대단량체를 합성하였다. 합성된 PCL 거대 단량체는 2,2,6,6-tetramethyl-1-piperidinyloxy (TEMPO)를 개시제로 사용하는 안정한 자유 라디칼 중합에 의해 스티렌과 공중합되었으며 그 결과 분자구조가 조절된 poly(styrene-g-caprolactone) (PS-g-PCL)이 얻어졌다. 얻어진 공중합체는 광산란 검출기가 장착된 GPC를 이용하여 분자량을 측정하였으며, $^1$H-NMR 분석을 통해 공중합체내의 PS/PCL 함량 비를 구하였다. 전체 분자량과 PCL 거대단량체의 분자량 그리고 공중합체내 PCL의 함량으로부터 사슬당 그라프트의 수를 계산하였다. DSC를 이용한 그라프트 공중합체의 열분석에서 PCL 결정의 흡열 피이크가 관찰되었으며, 이로부터 PS-g-PCL이 상분리되어 있음을 확인하였다.

• 폴리머
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• 제24권3호
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• pp.407-417
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• 2000

고분자 주쇄에 cyclobutane 또는 페닐과 방향족 술포닐옥시이미드 구조를 갖는 감광성 폴리이미드를 합성하여 광분해 특성에 있어서 고분자의 구조가 미치는 영향을 조사하였다. 폴리이미드는 N-히드록시와 염화 술포닐의 축중합에 의해 제조하였다. 합성된 폴리이미드는 25$0^{\circ}C$까지 열분해가 일어나지 않고 안정하였다. 254nm의 광조사에 따른 폴리이미드의 광분해는 분광학적 측정에 의해 N-O 결합의 절단 또는 이미드 moiety의 계열에 기인되는 것을 알 수 있었다. 본 연구의 폴리이미드는 포지티브형의 광분해성 고분자로의 활용이 가능한 것이 확인되었으며, 특히 pyromellitic diimide moiety를 함유하는 폴리이미드의 포지티브 화상은 높은 감도와 해상도를 나타내었다.