• 제목/요약/키워드: stable cathode

Search Result 166, Processing Time 0.024 seconds

Stable Atmospheric Plasma Generation at a Low Voltage using a Microstructure Array (대기압 플라즈마 발생용 마이크로 전극 제작 및 저전압 동작 특성)

  • Han, Sung-Ho;Kim, Young-Min;Kim, Jae-Hyeok
    • The Transactions of The Korean Institute of Electrical Engineers
    • /
    • v.56 no.4
    • /
    • pp.773-776
    • /
    • 2007
  • A microstructure array has been proposed for micro plasma generation using electroplating and double exposed process. A stable atmospheric plasma has been generated at a low voltage by utilizing the micro electrode gap. Self-aligned microstructure can provide uniform electrode overlap with precisely controlled gap between the electrodes. The proposed structure allows for triode operation, which can expand the generated plasma over a large area by applying a lateral electric field. Electrical characteristics of the micro triode confirm the large numbers of the plasma ions are drifted to the secondary cathode by the lateral electrical field.

Evaluation of Durability for Al Alloy with Anodizing Condition (알루미늄 합금의 양극산화 조건에 따른 내구성 평가)

  • Lee, Seung-Jun;Han, Min-Su;Kim, Seong-Jong
    • Proceedings of the Korean Institute of Surface Engineering Conference
    • /
    • 2016.11a
    • /
    • pp.152-152
    • /
    • 2016
  • Anodizing is a technology to generate thicker and high-quality films than natural oxide films by treating metals via electrochemical methods. It is a technique to develop metals for various uses, and extensive research on the commercial use has been performed for a long time. Aluminum anodic oxide (AAO) is generate oxide films, whose sizes and characteristics depending on the types of electrolytes, voltages, temperatures and time. Electrochemical manufacturing method of nano structure is an efficient technology in terms of cost reduction, high productivity and complicated shapes, which receives the spotlight in diverse areas. The sulfuric acid was used as an anodizing electrolyte, controlling its temperature to $10^{\circ}C$. The anode was 5083 Al alloy with dimension of $5(t){\times}20{\times}20mm$ while the cathode was the platinum. The distance between the anode and the cathode was maintained at 3 cm. Agitation was introduced by magnetic stirrer at 300 rpm to prevent localized temperature rise that hinders stable growth of oxide layer. In order to observe surface characteristics with applied current density, the electrolyte temperature, concentration was maintained at constant condition for $10^{\circ}C$, 10 vol.%, respectively. To prevent hindrance of stable growth of oxide layer due to local temperature increase during the experiment, stirring was maintained at constant rate. In addition, using galvanostatic method, it was maintained at current density of $10{\sim}30mA/cm^2$ for 40 minutes. The cavitation experiment was carried out with an ultrasonic vibratory apparatus using piezo-electric effect with modified ASTM-G32. The peak-to-peak amplitude was $30{\mu}m$ and the distance between the horn tip and specimen was 1 mm. The specimen after the experiment was cleaned in an ultrasonic, dried in a vacuum oven for more than 24 hours, and weighed with an electric balance. The surface damage morphology was observed with 3D analysis microscope. As a result of the investigation, differences were observed surface hardness and anti-cavitation characteristics depending on the development of oxide film with applied current density.

  • PDF

Comparison of Metal Transfer Behavior in Electrodes for Shielded Metal Arc Welding

  • Xu, X.;Liu, S.;Bang, K.S.
    • International Journal of Korean Welding Society
    • /
    • v.4 no.1
    • /
    • pp.15-22
    • /
    • 2004
  • Metal transfer behavior of three shielded metal arc welding electrodes, AWS El1018, E6013 and E6010, were investigated through the characterization of size distribution of droplets and measurement of arc voltage signals. Of the three electrodes, Ell018 electrode showed the largest droplet size with the smallest amount of spatter, while E6010 electrode showed the smallest droplet size with the largest amount of spatter. Even though Ell0l8 electrode showed a good agreement between the frequencies of voltage drop in FFT processed voltage signals and the transfer rate of droplets, E6013 and E6010 electrodes showed weaker correlation because of their dominant explosive transfer behavior. The type of cathode used and electrode baking time also influenced the metal transfer behavior. Compared to bead-on-plate welding using steel plate as a cathode, welding on a water-cooled copper pipe showed less short-circuiting and higher melting rate in all electrodes because of higher arc potential and/or anode drop. When baked for a long time, E6010 electrode showed much more stable arc with less short-circuiting and explosion due to the loss of gas formation ingredients.

  • PDF

Effect of Fabrication Method of Anode on OCV in Enzyme Fuel Cells (효소연료전지의 Anode 제조조건이 OCV에 미치는 영향)

  • Kim, Young-Sook;Lee, Se-Hoon;Chu, Cheun-Ho;Na, Il-Chai;Lee, Ho;Park, Kwon-Pil
    • Korean Chemical Engineering Research
    • /
    • v.53 no.1
    • /
    • pp.6-10
    • /
    • 2015
  • Enzyme fuel cells were composed of enzyme anode and PEMFC cathode. Enzyme anodes was fabricated by compression of a mixture of graphite particle, glucose oxidase as a enzyme and ferrocene as a mediator, and then coated with Nafion ionomer. Open circuit voltage (OCV) were measured with variation of anode manufacture factors, to find optimum condition of enzyme anode. Optimum pressure was 9.0 MPar for enzyme anode pressing process. Highest OCV was obtained at 60% graphite composition in enzyme anode. Optimum glucose concentration was 1.7mol/l in anode substrate solution and enzyme activity of anode was stable for 7 days.

Carbon nanotube / silane hybride film for highly efficient field emitter

  • Jeong, Hae-Deuk;Kim, Ho-Young;Jeong, Hee-Jin;Han, Joong-Tark;Lee, Geon-Woong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2010.06a
    • /
    • pp.181-181
    • /
    • 2010
  • Few-walled carbon nanotubes (FWNTs)-based field emitters with long term stability are fabricated by using a spray method. Tetraethylorthosilicate (TEOS) sol as a binder was mixed with dispersed solution of FWNTs to enhance the adhesion of FWNTs on the cathode substrate. Due to the strong intermolecular interaction of TEOS to the functional groups attached on CNTs and substrate, CNTs are tightly adhered to the cathode electrode when heat treatment is performed at $150^{\circ}C$ for 1 hour, resulting in a stable electron emission of CNT emitters for long time. Excellent field emission characteristics were exhibited, with a large field enhancement factor and low turn-on voltage, comparable to those of CNT emitters fabricated by a screen printing of CNT paste. Therefore, FWNTs / TEOS hybrid films could be utilized as an alternative for the efficient and reliable field emitters.

  • PDF

Deposition of Functional Organic and Inorganic Layer on the Cathode for the Improved Electrochemical Performance of Li-S Battery

  • Sohn, Hiesang
    • Korean Chemical Engineering Research
    • /
    • v.55 no.4
    • /
    • pp.483-489
    • /
    • 2017
  • The loss of the sulfur cathode material through dissolution of the polysulfide into electrolyte causes a significant capacity reduction of the lithium-sulfur cell during the charge-discharge reaction, thereby debilitating the electrochemical performance of the cell. We addressed this problem by using a chemical and physical approach called reduction of polysulfide dissolution through direct coating functional inorganic (graphene oxide) or organic layer (polyethylene oxide) on electrode, since the deposition of external functional layer can chemically interact with polysulfide and physically prevent the leakage of lithium polysulfide out of the electrode. Through this approach, we obtained a composite electrode for a lithium-sulfur battery (sulfur: 60%) coated with uniform and thin external functional layers where the thin external layer was coated on the electrode by solution coating and drying by a subsequent heat treatment at low temperature (${\sim}80^{\circ}C$). The external functional layer, such as inorganic or organic layer, not only alleviates the dissolution of the polysulfide electrolyte during the charging/discharging through physical layer formation, but also makes a chemical interaction between the polysulfide and the functional layer. As-formed lithium-sulfur battery exhibits stable cycling electrochemical performance during charging and discharging at a reversible capacity of 700~1187 mAh/g at 0.1 C (1 C = 1675 mA/g) for 30 cycles or more.

Flow Actuation by DC Surface Discharge Plasma Actuator in Different Discharge Modes

  • Kim, Yeon-Sung;Shin, Jichul
    • International Journal of Aeronautical and Space Sciences
    • /
    • v.16 no.3
    • /
    • pp.339-346
    • /
    • 2015
  • Aerodynamic flow control phenomena were investigated with a low-current DC surface discharge plasma actuator. The plasma actuator was found to operate in three different discharge modes with similar discharge currents of about 1 mA or less. Stable continuous DC discharge without audible noise was obtained at higher ballast resistances and lower discharge currents. However, even with continuous DC power input, a low-frequency self-pulsed discharge was obtained at lower ballast resistances, and a high-frequency self-pulsed discharge was obtained at higher set-point currents and higher ballast resistances, both with audible noise. The Schlieren image reveals that the low-frequency self-pulsed mode produces a synthetic jet-like flow implying that a gas heating effect plays a role, even though the discharge current is small. The high-frequency self-pulsed mode produces pulsed jets in a tangent direction, and the continuous DC mode produces a steady straight pressure wave. Particle image velocimetry (PIV) images reveal that the induced flow field by the low-frequency self-pulsed mode has flow propagating in the radial direction and centered between the electrodes. The high-frequency self-pulsed mode and continuous DC mode produce flow from the anode to the cathode. The perturbed region downstream of the cathode is larger in the high-frequency self-pulsed mode with similar maximum speeds.

Electrical characteristics of lateral poly0silicon field emission triode using LOCOS process

  • Lee, Jae-Hoon;Lee, Myoung-Bok;Park, Dong-Il;Ham, Sung-Ho;Lee, Jong-Hyun;Lee, Jung-Hee
    • Journal of Korean Vacuum Science & Technology
    • /
    • v.3 no.1
    • /
    • pp.38-42
    • /
    • 1999
  • Using the LOCOS process, we have fabricated the lateral type polysilicon field emission triodes with poly-Si/oxide/Si structure and investigated their current-voltage characteristics for three biasing modes of operation. The fabricated devices exhibit excellent electrical performances such as a relatively low turn-on anode voltage of 14 V at VGC = 0V, a stable and high emission current of 92${\mu}$A/triode over 90 hours, a small gate leakage current of 0.23 ${\mu}$A/triode and an outstanding transconductance of 57${\mu}$S/5triodes at VGC = 5V and VAC = 26V. these superior electrical operation is believed to be due to a large field enhancement effect, which is related to the sharp cathode tips produced by the LOCOS process as well as the high aspect ratio (height /radius ) of the cathode tip end.

  • PDF

Electrochemical Properties of Li[Ni0.2Li0.2Mn0.6]O2 by Microwave-assisted Sol-gel Method

  • Park, Yong-Joon;Kim, Seuk-Buom
    • Transactions on Electrical and Electronic Materials
    • /
    • v.10 no.3
    • /
    • pp.102-105
    • /
    • 2009
  • $Li[Ni_{0.2}Li_{0.2}Mn_{0.6}]O_2$ cathode materials have been synthesized by a microwave-assisted sol-gel method. The structure and electrochemical properties of $Li[Ni_{0.2}Li_{0.2}Mn_{0.6}]O_2$ were studied by X-ray difftactometry (XRD), scanning electron microscopy (SEM) and charge-discharge cycler. The powder prepared by microwave assisted sol-gel method showed good crystallinity and well-defined facet shapes. The $Li[Ni_{0.2}Li_{0.2}Mn_{0.6}]O_2$ electrode delivered a high discharge capacity of 230 $mAhg^{-1}$ at the specific current of 40 $mAg^{-1}$ (0.2 C rate) in the voltage range of 2.0${\sim}$4.8 V. About 60 % of the discharge capacity measured at 0.2 Crate (140 $mAhg^{-1}$) was maintained at a 6 C (1200 $mAg^{-1}$)rate. The cyclic property was also stable and it did not deteriorated at a high Crate.

Performance Characteristics of Anode-Supported Tubular Solid Oxide Fuel Cell (연료극 지지체식 원통형 고체산화물 연료전지의 성능 특성)

  • Song Rak-Hyun;Song Keun-Suk
    • Korean Journal of Materials Research
    • /
    • v.14 no.5
    • /
    • pp.368-373
    • /
    • 2004
  • To improve the conventional cathode-supported tubular solid oxide fuel cell (SOFC) from the viewpoint of low cell power density, expensive fabrication process and high operation temperature, the anode-supported tubular solid oxide fuel cell was investigated. The anode tube of Ni-8mol% $Y_2$O$_3$-stabilized $ZrO_2$ (8YSZ) was manufactured by extrusion process, and, the electrolyte of 8YSZ and the multi-layered cathode of $LaSrMnO_3$(LSM)ILSM-YSZ composite/$LaSrCoFeO_3$ were coated on the surface of the anode tube by slurry dip coating process, subsequently. Their cell performances were examined under gases of humidified hydrogen with 3% water and air. In the thermal cycle condition of heating and cooling rates with $3.33^{\circ}C$/min, the anode-supported tubular cell showed an excellent resistance as compared with the electrolyte-supported planar cell. The optimum hydrogen flow rate was evaluated and the air preheating increased the cell performance due to the increased gas temperature inside the cell. In long-term stability test, the single cell indicated a stable performance of 300 mA/$\textrm{cm}^2$ at 0.85 V for 255 hr.