• Title/Summary/Keyword: stabilizing agent

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Development of Stabilizing Agent for Double Base Propellant Rocket Motor (복기 추진제 로켓 모타 연소 안정제 개발)

  • 손원경;최성한;이원복
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 1994.04a
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    • pp.23-26
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    • 1994
  • 130mm D.B. 추진기관의 고온 시험에서 나타난 극심한 이상 연소 현상을 해결하기 위해 미세한 고체 입자들을 연소 가스에 분산시켜 불안정 연소를 억제하는 particulate damping 효과를 연구하였다. 고체 입자로서 효과적인 것으로 알려진 $K_2$$SO_4$. ZrC, Graphite를 CTPB, HTPB 고분자 물질에 충진시켜 epoxide, isocyanate 반응기와 가교 반응을 일으킴으로써 고무상의 탄성체 성질을 갖게 하는 $K_2$$SO_4$/CTPB, ZrC/Graphite/HTPB, ZrC/Graphite/AP/HTPB, ZrC/AP/HTPB 조성의 연소 안정제를 개발하였다. 이 연소 안정제는 외경 17mm, 길이 1000mm의 안정봉 형태로 제작하여 모타의 중심 cavity에 조립한 후 지상 연소 시험을 통하여 성능을 확인하였다. 시험 결과, 조성에 AP를 포함시켜 연소 안정제에 일정한 연소 속도를 부여하여 추진제 grain 연소 동안 고체 입자를 연소 가스에 분산되게 설계한 ZrC/Graphite/AP/HTPB, ZrC/AP/HTPB 조성의 연소 안정제가 불안정 연소 억제에 효과적인 것으로 나타났다.

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Development of Functional Microsphere( II ) - Surface Modification and Properties of EVA Microsphere - (기능성 microsphere의 개발(II) - EVA Microsphere의 표면개질과 특성 -)

  • Kim Hea-In;Park Heung-Sup;Park Soo-Min
    • Textile Coloration and Finishing
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    • v.17 no.3 s.82
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    • pp.26-33
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    • 2005
  • EVA microsphere was prepared by a thermally induced phase separation. EVAL microsphere was made by a saponification on sheath of EVA microsphere. And microcapsule with EVA core-PU shell structure was synthesized by interfacial polymerization using diisocyanates with PEG in gelatin aqueous solution as the stabilizing agent. The effects of chemical structure of diisocyanate on the average particle size and distribution, morphology, color strength and friction fastness of core-shell particles were investigated to design microcapsule. The friction fastness of the fabrics printed with EVA core-PU shell microcapsules had the 4-5 grade.

Preparation of Polystyrene particles based on interfacial stability of suspension polymerization (현탁중합의 계면안정에 따른 폴리스티렌 입자 제조)

  • 이진호;이상남;박문수;김은경;문명준
    • Journal of the Korean Graphic Arts Communication Society
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    • v.20 no.1
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    • pp.65-78
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    • 2002
  • The suspension polymerization of styrene was carried out to obtain the narrow-size distribution of particle by using poly(vinyl alcohol) (PVA) as suspension stabilizer according to the degree of hydrolysis and the molecular weight. The stabilizing properties of suspension are also dependent on the interfacial tension of aqueous solution when PVA is added. When the polymerization process was carried out with low hydrolyzed PVA, it gave single, well-defined particles, while high hydrolyzed PVA gave clusters. The size of particle produced in this study ranged between 5${\mu}{\textrm}{m}$ and 10${\mu}{\textrm}{m}$. The suspending agent, PVA, influences on the drop size and drop stability, When the molecular weight of PVA is increased, the drop size decreases and the drops become more stable toward coalescence. An increase in the PVA concentration decreases the mean drop size and narrows the drop size distribution.

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Effect of cement stabilization on geotechnical properties of sandy soils

  • Shooshpasha, Issa;Shirvani, Reza Alijani
    • Geomechanics and Engineering
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    • v.8 no.1
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    • pp.17-31
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    • 2015
  • An experimental program was performed to study the effects of cement stabilization on the geotechnical characteristics of sandy soils. Stabilizing agent included lime Portland cement, and was added in percentages of 2.5, 5 and 7.5% by dry weight of the soils. An analysis of the mechanical behavior of the soil is performed from the interpretation of results from unconfined compression tests and direct shear tests. Cylindrical and cube samples were prepared at optimum moisture content and maximum dry unit weight for unconfined compression and direct shear tests, respectively. Samples were cured for 7, 14 and 28 days after which they were tested. Based on the experimental investigations, the utilization of cemented specimens increased strength parameters, reduced displacement at failure, and changed soil behavior to a noticeable brittle behavior.

TOXICITY TESTS OF A NOVEL SOLUBILIZER FOR PACLITAXEL IN MALE BEAGLE DOGS

  • Kim, Yeo-Woon;Min, Kyung-Nan;Syrie Pang;Song, Hae-Won;Lee, Min-Jae;Lee, Mi-Suk;Kim, Jong-Jae;Sheen, Yhun-Yhong
    • Proceedings of the Korean Society of Toxicology Conference
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    • 2002.05a
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    • pp.117-117
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    • 2002
  • Paclitaxel isolated from the pacific yew tree, Taxus brevifolia, is microtuble-stabilizing agent that has a promising anticancer activity against a wide variety of tumors such as ovarian, breast and lung cancers. Because of its poor water solubility, paclitaxel is currently formulated in a mixture of polyoxyethyleneglycerol triricinoleate 35 (Cremophor EL) and dehydrated ethanol USP (1:1 v/v).(omitted)

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Reversible Addition-Fragmentation Chain Transfer (RAFT) Bulk Polymerization of Styrene: Effect of R-Group Structures of Carboxyl Acid Group Functionalized RAFT Agents

  • Lee Jung Min;Kim Ok Hyung;Shim Sang Eun;Lee Byung H.;Choe Soonja
    • Macromolecular Research
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    • v.13 no.3
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    • pp.236-242
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    • 2005
  • Three dithioester-derived carboxyl acid functionalized RAFT(reversible addition-fragmentation chain transfer) agents, viz. acetic acid dithiobenzoate, butanoic acid dithiobenzoate and 4-toluic acid dithiobenzoate, were used in the RAFT bulk polymerization of styrene, in order to study the effects of the R-group structure on the living nature of the polymerization. By conducting the polymerization with various concentrations of the RAFT agents and at different temperatures, it was found that the R-group structure of the RAFT agents plays an important role in the RAFT polymerization; the bulky structure and radical stabilizing property of the R-group enhances the living nature of the polymerization and allows the polymerization characteristics to be well controlled.

Effect of Dispersion Technique on Heat Transfer Properties of Transformer Oil with Nanoparticles (변압기 나노절연유의 열전달특성에 미치는 분산기술의 영향)

  • Song, Hyun-Woo;Choi, Cheol;Oh, Je-Myung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.11a
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    • pp.151-152
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    • 2005
  • Both $Al_2O_3$ and AlN nanopowders with diameters from ${\mu}m$ to mm were bead-milled and surface-modified by stabilizing agent. The size of bead-milled nanoparticles compared with the primary powder was effectively decreased and was dependent on milling time and bead size. The results of dispersion stability analysis indicated that chemical bonding between nanoparticles and surfactant is more effective than chemical adsorption to prepare the stable transformer oils containing nanoparticles. In this study, the thermal conductivity of the transformer oils containing nanoparticles was measured by transient hot-wire and laser flash methods.

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Revelation of the Susceptibility of Microcapsule by the Control of Polymer Structure (II) -Preparation of polyurethane microcapsules with different chemical structures- (고분자구조제어에 의한 microcapsule의 감성기능발현(II) -화학구조에 따른 polyurethane microcapsule의 특성-)

  • Hong, Ki-Jeong;Park, Soo-Min
    • Textile Coloration and Finishing
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    • v.9 no.5
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    • pp.63-74
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    • 1997
  • Polyurethane microcapsules were synthesized by interfacial polymerization in an aqueous poly(ethylene glycol) dispersion with ethylenediamine as chain extender of toluene diisocyanate in perfume oil using poly(vinyl alcohol) as the stabilizing agent. The effect of chemical structure on the average particle size and distributions, morphologies, and thermal properties to design microcapsules for the sustained release system was investigated. It came to be known that polyurethane microcapsules with ethylene diamine as chain extender had a rounder, more permeable and controlled release membranes. And the release test of polyurethane microcapsules with different soft segment content was done to certify the effect of long methylene chain. According to the higher molecular weight of polyether polyol, the release rate of microencapsulated disperse dye molecular was faster.

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Revelation of the Susceptivility of Microcapsule by the Control of Polymer Structure (I) -preparation of polyurethane microcapsules- (고분자구조제어에 의한 microcapsule의 감성기능발현(I) -polyurethane microcapsule의 제조와 그 특성-)

  • Hong, Ki Jeong;Park, Soo Min
    • Textile Coloration and Finishing
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    • v.9 no.5
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    • pp.52-62
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    • 1997
  • Abstract Polyurethanes have been designed and fabricated into membranes with unique separation properties. Moreover, polyurethane microcapsules also have been reported actively as controlled release materials for their excellent blood compatibility, tensile strength and permeability. In this study, polyurethane microcapsules were synthesized by interfacial polymerization in an aqueous poly(ethylene glycol) dispersion of toluene diisocyanate in perfume oil using poly(vinyl alcohol) as the stabilizing agent. The effect of a few important process conditions on the average particle size and distributions, morphologies, and thermal properties to design microcapsules for the sustained release system was investigated.

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Effects of Stellate Ganglion Block for the Treatment of Bronchial Asthmatic Patients -3 cases report- (기관지 천식 환자의 치료에 성상신경절 차단 효과 -3예 보고-)

  • Suh, Jae-Hyun
    • The Korean Journal of Pain
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    • v.8 no.2
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    • pp.331-335
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    • 1995
  • Asthma is a disease of the airways that is characterized by increased responsiveness of the tracheobronchial tree to a multiplicity of stimuli. A number of causes have been postulated for the increased airway reactivity of asthma is conservative as beta-adrenergic agonist, methylxanthines, glucocorticoids, anticholinergics and mast cell stabilizing agent. Stellate ganglion block for the treatment of bronchial asthma has its controversies. Stellate ganglion block was performed for the treatment of 3 patients with bronchial asthma. After stellate ganglion blocks, dyspnea, coughing and wheezing was markedly reduced. Lung function test improved with 1 st case. Two asthma cases were able to discontinue medication for asthma. No severe aggrevation of bronchial symptoms were noted after stellate ganglion blocks. It suggested that stellate ganglion block can be safely performed on bronchial asthmatic patients.

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