• Title/Summary/Keyword: stabilization process

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Effect of Phosphorous-Based Flame Retardants on the Weight, Diameter, and Thermal Stability after Stabilization Processes of Rayon Fibers for Carbon Fibers (탄소섬유용 레이온섬유의 안정화공정 후 중량, 직경 및 열안정성에 미치는 인계 난연제의 영향)

  • Yoon Sung Bong;Cho Donghwan;Park Jong Kyoo
    • Polymer(Korea)
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    • v.29 no.2
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    • pp.211-215
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    • 2005
  • Stabilization process is absolutely necessary to convert the precursor fibers into chemically, physically, thermally and structurally stable carbon fibers. Especially, it is critically important for rayon fibers experiencing severe weight loss and thermal shrinkage occurring at the stabilization stage below $400^{\circ}C$. The stabilization of rayon fibers strongly depends not only on stabilization temperature but also on heating rate, chemical pre-treatment, atmosphere, and so on. In the present study, the weight loss, fiber diameter change occurred in the furnace during the stabilization process for rayon fibers produced with various heating rates and in the absence and presence of phosphorous-based flame retardants and the thermal stability of the stabilized fibers were investigated. The result indicates that the weight, diameter and thermal stability of the rayon fibers are significantly affected by the type and amount of the flame retardant used. It is also suggested that the pre-treatment of rayon fibers with a concentration lower than $3\;vol\%$ of phosphoric acid is most desirable for further carbonization process of stabilized rayon fibers.

Phenanthrene으로 오염된 Kaolinite에 Electrokinetic-Fenton 기법 적용시 묽은 산의 주입에 따른 효과

  • 김정환;김기년;한상재;김수삼
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.04a
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    • pp.318-321
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    • 2003
  • This study explored the feasibility of applying Electrokinetic-Fenton process(EK-Fenton process) to remediation of contaminant sorbed on the soil possessed low-permeability. The addition of 0.01 N H$_2$SO$_4$ in the anode reservoir for the $H_2O$$_2$stabilization improved the stabilization of $H_2O$$_2$and the treatment effect of phenanthrene across the entire soil specimen. The use of $H_2O$$_2$and dilute acid as anode purging solution is a promising method treating of HOCs in low-permeability subsurface environments.

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A Study on the Stabilization/ Solidification Process Using Blast Furnace Slag (슬래그를 이용한 중금속 이온의 고정화)

  • 강성근;방완근;이승헌;김창은
    • Journal of the Korean Ceramic Society
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    • v.36 no.7
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    • pp.725-733
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    • 1999
  • It is a fundamental experiment to use blast-furnace slag in solidification/stabilization process. The compressive strength and leaching test of Pb and Cr doped samples were evaluated and the effects of heavy-metal ions on the hydration of slag was investigated. Sodium silicates(5wt%) was added as alkali-activator and the effects of replacing a part of slag with flyash or gypsum was also discussed. Pb ion was solidified by encapsulation of matrix. In of slag${\pm}$gypsum binder microstructure was densified by accelerating to form AFt/AFm phase and compressive strength was improved resulting in reducing leaching amount of Pb ion. Cr ion was solidified by substituting with Al ion in aluminate product. Slag+fly ash binder improved compressive strength and decreased leaching amount of Cr ion.

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Numerical Investigation of Ram Accelerator Flow Field in Expansion Tube (Expansion Tube 내의 램 가속기 유동장의 수치 연구)

  • 최정열;정인석;윤영빈
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 1997.04a
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    • pp.43-51
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    • 1997
  • Steady and unsteady numerical simulations are conducted for the experiments performed to investigate the ram accelerator flow field by using the expansion tube facility in Stanford University. Navier-Stokes equations for chemically reacting flows are analyzed by fully implicit and time accurate numerical methods with Jachimowski's detailed chemistry model for hydrogen-air combustion involving 9 species and 19 reaction steps. Although the steady state assumption shows a good agreement with the experimental schlieren and OH PLIF images for the case of $2H_2$+$O_2$+$17N_2$, it fails in reproducing the combustion region behind the shock intersection point shown in the case of $2H_2$+$O_2$+$12N_2$, mixture. Therefore, an unsteady numerical simulation is conducted for this case and the result shows all the detailed flow stabilization process. The experimental result is revealed to be an instantaneous result during the flow stabilization process. The combustion behind the shock intersection point is the result of a normal detonation formed by the intersection of strong oblique shocks that exist at early stage of the stabilization process. At final stage, the combustion region behind the shock intersection point disappears and the steady state result is retained. The time required for stabilization of the reacting flow in the model ram accelerator is found to be very long in comparison with the experimental test time.

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Studies on the Stabilization of Rayon Fabrics for Preparing Carbon Fabrics: 2. Fast Isothermal Stabilization Processes at High Temperature

  • Yoon, Sung-Bong;Cho, Chae-Wook;Cho, Dong-Hwan;Park, Jong-Kyoo;Lee, Jae-Yeol
    • Carbon letters
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    • v.9 no.4
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    • pp.308-315
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    • 2008
  • In the present study, fast isothermal stabilization processes for rayon precursor fabrics were performed at $350^{\circ}C$ and $400^{\circ}C$ within 3 minutes and the chemical and physical characteristics of the stabilized fabrics were investigated. In addition, rayon precursor fabrics were pre-treated with three different phosphorous-based flame retardants and then stabilized. The effect of flame retardants on the chemical composition, thermal shrinkage, weight change, thermal stability and XRD results was examined, comparing with those of the precursor fabrics. The result showed that the stabilization of rayon fabrics was most effective as the stabilization temperature was $350^{\circ}C$, the stabilization time was 3 min, and the pre-treatment with phosphoric acid of 1 vol%. The carbon contents of stabilized rayon fabrics were increased with increasing stabilization temperature and time, whereas the oxygen contents were decreased. Also, it is likely that the pre-treatment with phosphoric acid plays a role in retarding the change of chemical structure of rayon fabric. The XRD result was quite consistent with the result showing the effect of phosphoric acid on the chemical composition, thermal shrinkage and weight reduction of rayon fabric.

The Control of Inverted Pendulum for PID Controller (PID 제어기를 이용한 도립진자 제어)

  • 송해석;장갑부;노태정
    • 제어로봇시스템학회:학술대회논문집
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    • 2000.10a
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    • pp.124-124
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    • 2000
  • In this paper, The PID controller for stabilization of an inverted pendulum system is proposed. The PR control rule is very common in control systems. It is the basic tool for solving most process control problem. We consider the inverted pendulum system containing two PID controllers. The first controls the angle of the pendulum. The second is used to control the position of the cart. We can show stabilization of the PID controller through simulation of the inverted pendulum system.

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A Study on Determination of PID Coefficients by Deriving Temperature Stabilization Transfer Function and it's Simulation (온도 안정화 전달함수 도출 및 이의 시뮬레이션에 의한 PID 계수 결정에 관한 연구)

  • Eom, Jinseob
    • Journal of Sensor Science and Technology
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    • v.24 no.6
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    • pp.412-418
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    • 2015
  • In this paper, a new method for obtaining PID coefficients which are essential to a temperature stabilization process has been proposed. This method starts from measuring the open loop transfer function of the module, then the closed loop transfer function embodying PID control can be produced based on this. Finally, the simulations using a few PID coefficients and the performance analysis for those results provide the best PID coefficients which are effective in a fast setting to a target temperature, a less current needed, and less deviation from steady state. The measurement using the derived PID coefficients, $K_p=1.6$,$K_i=0.8$,$K_d=0.3$ showed $T_s=7.4[sec]$, %OS = 16, and stabilization within ${\pm}0.02[^{\circ}C]$ for several hours. In addition to light sources like SOA, the proposed method can be utilized for any device needs temperature stabilization.

Treatment, Disposal and Beneficial Use Option for Sewage Sludge (하수슬러지 처리기술 동향 및 최적화 처리방안)

  • Choe, Yong-Su
    • 수도
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    • v.24 no.5 s.86
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    • pp.29-44
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    • 1997
  • Sewage sludge produced in Korea was 1,275,800 tons (dewatered sludge cake) per year in 1996, which is 3,495 tons per day, 0.303% of 11,526,100 tons per day of sewage treated in 79 sewage treatment plants. Sludge production has been and will be increasing in accordance with construction of new facilities for sewage treatment. Most of the sludge is currently disposed by landfill and ocean dumping, but it is becoming difficult to find suitable sites for landfill, particularly in big cities such as Seoul. In addition, rapid increase of landfill cost is anticipated in a near future. Current trend for sludge disposal in advanced countries is land application. Over the past 10 to 20 years in the United States, sludge management practices have changed significantly, moving from disposal to beneficial use. They use biosolid for utilization instead of sludge for disposal. Under the Clean Water Act of 1972, amended in 1987 by Congress, the U.S. EPA was required to develop regulations for the use and disposal of sewage sludge. The EPA assessed the potential for pollutants in sewage sludge to affect public health and the environment through a number of different routes of exposure. The Agency also assessed the potential risk to human health through contamination of drinking water sources or surface water when sludge is disposed on land. The Final Rules were signed by the EPA Administrator and were published (Federal Register, 1993). These rules state that sewage sludge shall not be applied to land if the concentration of any pollutant in the sludge exceeds the ceiling concentration. In addition, the cumulative loading rate for each pollutant shall not exceed the cumulative pollutant loading rate nor should the concentration of each pollutant in the sludge exceed the monthly average concentration for the pollutant. The annual pollutant loading rate generally applies to applications of sewage sludge on agricultural lands. The most popular beneficial use of sewage sludge is land application. The sludge has to be stabilized for appling to land. One of the stabilization process for sewage sludge is lime stabilization process. The stabilization process is consisted of the stabilizing process and the drying process. Stabilization reactor can be a drum type reactor in which a crossed mixer is equipped. The additive agents are a very reactive mixture of calcium oxide and others. The stabilized sludge is dried in sun drier or rotary kiln.

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Studies on the Stabilization of Rayon Fabrics: 3. Effects of Long-Term Isothermal Stabilization at Low Temperatures and Chemical Pre-treatment (레이온직물의 안정화에 관한 연구: 3. 저온 장시간 등온 안정화 및 화학전처리 영향)

  • Cho, Chae Wook;Cho, Donghwan;Park, Jong Kyoo;Lee, Jae Yeol
    • Journal of Adhesion and Interface
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    • v.11 no.1
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    • pp.15-25
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    • 2010
  • In the present study, isothermal stabilization processes for rayon fabrics were performed at two relatively low temperatures $180^{\circ}C$ and $200^{\circ}C$ for a long period of time. The results of weight loss, dimensional shrinkage, X-ray diffraction and scanning electron microscopic observations studied with the rayon fabrics before and after the isothermal stabilization indicated that the chemical and physical changes of rayon precursor fibers proceeded continuously and slowly at the stabilization temperature below $200^{\circ}C$. And the pre-treatment with four different chemical compounds done prior to stabilization process influenced differently the characteristics of rayon fabrics. As a result, it was noticed that under the given stabilization conditions, $H_3PO_4$ and $Na_3PO_4$ played a role in catalyzing the stabilization reaction of rayon fabric whereas $NH_4Cl$ and $ZnCl_2$ played a role in delaying or retarding the reaction. $H_3PO_4$ showed the lowest percent weight loss of the fabric in the second stabilization conducted at $350^{\circ}C$. It was considered that phosphoric acid, which has a function of flame retardant, contributed to retarding somewhat the subsequent reaction even in the second stabilization step.

A Study on the Lime Stabilization of Livestock Waste (축산폐기물의 안정화 처리에 대한 연구)

  • Kim, Hyun-Chul;Choi, Yong-Su
    • Analytical Science and Technology
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    • v.8 no.1
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    • pp.91-99
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    • 1995
  • One of alternative conventional technologies used for treatment of livestock wastes is composting process, and recently some mechanical composting processes are being practiced. It is, however, recognized the composting process also has its own limitations such as longer time requirement, and difficulties to estimate the degree of decomposition, etc. The incomplete compost contains potentially harmful materials to crops and public health due to instabilized organic contents and pathogenic organisms. The purpose of this investigation is to develop an innovative system whereby anxious livestock wastes are thoroughly stabilized and disinfected. Thus the overall management scheme should meet the following requirements. 1. A system should be in a cost-effective and environmentally sound manner. 2. Sludges must be chemically stabilized and bacteriologically safe. 3. Odor-free by product should be applied to crop land. 4. Sludges are sources of fertilizer nutrients and/or soil amendments to enhance crop production. 5. And they can be used as potential pH adjusting agent of the acidified soils. Overall effectiveness of the developed system is experimentally tested to satisfy the preset criteria and requirements. Major experiments are divided into four categories: they are 1. chemical stability test, 2. optimal condition test of stabilization process, 3. bacteriological examination and disinfection tests, and 4. deodorization tests The stabilization process is consisted of the stabilizing reaction process and the drying process. Stabilized wastes is dried by both sun dryer and rotary dryer. It is shown that an additive dosage of about g/kg solid in wastes with a minimum of 5-minutes reaction would be necessary for effective stabilization reaction. The stabilization process is consisted of the stabilizing reaction process and drying process. Stabilized wastes are dried by both sun dryer and rotary dryer. It is shown that an additive dosage of about 300g/kg solid in wastes with a minimum of 5-minutes reaction would be necessary for effective stabilization reaction. In the stabilization reaction process, the pH of wastes is lowered from initial values of 12.3 to 8.6. High pH prevents odor production and kills pathogenic organisms. Organic matter contents in the stabilized wastes are about 50% and the sum of contents of fertilizer elements such as total nitrogen, $P_2O_5$ and $K_2O$ are about 5.3%. The livestock wastes that are stabilized chemically and hygienically can be used as a good soil conditioner and/or organic fertilizer.

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