• Analytical Science and Technology
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• v.11 no.5
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• pp.366-373
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• 1998

Polydentate Schiff base ligands, BSDT(1,9-bis(2-hydroxyphenyl)-2,5,8-triaza-1,8-nonadiene) having $N_3O_2$ atoms, BSTT(1,12-bis(2-hydroxyphenyl)-2,5,8,11-tetraaza-1,11-dodecadiene) having $N_4O_2$ atoms, BSTP(1,15-bis(2-hydroxyphenyl)-2,5,8,11,14-pentaaza-1,14-pentadodecadiene) having $N_5O_2$ atoms were synthesized. Protonation constants of these polydentate ligands were measured by potentiometry. Stability constants of the complexes between these ligands and the metal ions such as Cu(II), Ni(II) and Zn(II) were measured in DMSO by a polarographic method. It was observed that all metal(II) ions employed in this study formed 1:1 complexes with Schiff base ligands. Stability constants for the complex formation were in the order of Cu(II)>Ni(II)>Zn(II), and for the ligands were in the order of BSTP>BSTT>BSDT. There are due to the increase in the number of donor atoms. Both enthalpy and entropy changes were obtained in negative values. Exothermicity for the complex formation indicated tight binding between the ligands and metal ions. The negative entropy change would be related to the fact that solvent molecules are strongly interacting with the metal complexes.

• Korean Journal of Soil Science and Fertilizer
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• v.28 no.2
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• pp.114-122
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• 1995

Complexation experiment between humic acid and heavy metal cations was conducted to clear information on heavy metal adsorption by soil organic constituent. The absorbance of UV-visible light of humic acid-metal complexes increased with increasing wavelength, and the order of their absorbance was in the order of Zn->Cd->Cu- saturated humic acid. Carboxyl and phenolic OH groups participated in the complex formation between heavy metal cations and functional groups of humic acid, and the amounts complex was in the order of $Cu^{+{+}}$ > $Zn^{+{+}}$ $\geq$ $Cd^{+{+}}$. The stability constants of humic acid-metal complexes increased with increasing pH, and the order of first stability constants was $Zn^{+{+}}$ > $Cd^{+{+}}$ > $Cu^{+{+}}$, and those of second and overall stability constants were $Cu^{+{+}}$ > $Zn^{+{+}}$ > $Cd^{+{+}}$. With increasing pH, the average binding numbers betwen heavy metal cations and functional groups of humic acid increased the order of $Cu^{+{+}}$ > $Zn^{+{+}}$ > $Cd^{+{+}}$. It was postulated that two types of complexations between heavy metal cations and functional groups of humic acid. One was the reactions in which only carboxyl groups participated to form complexes, and the other was those in which both carboxyl and phenolic OH groups simultaneously participated.

• 한국생물공학회:학술대회논문집
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• 2003.04a
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• pp.445-449
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• 2003

As for the purpose, we first introduce an random mutation into wild-type gene to expand a mutation space, and then further recombine the mutant genes by staggered extension process PCR. As a result, we obtained the best clones 6-52 that showed a high activity and stability, from a round of error prone and staggered extension process PCR. The purified enzyme showed a similar pH stability to the wild-type enzyme and reveal a slightly high optimum pH at 12. In the optimum temperature, an identical dependency was also showed and a quite high stability in the thermal stability was obtained. Along with this, the enzyme was also stable at a reaction that supplement with a 15 % of ethanol as an additive. The addition of other solvents and surfactants did not improve the reaction and thus resulted in a similar profile to those of wild-type enzyme. The specific activity on the target compound rac-ketoprofen ethyl ester was calculated to be about 85, 000 unit, and the kinetic constants Km and Vmax were determined to be 0.2 mM and 90 mM/mg-protein/min respectively. The deduced amino acid alignment with the wild type enzyme revealed five mutations at L120P, I208V, T249A, D287H and T357A. Based on these observations, the site directed mutagenesis to delineate the mutagenic effect is under progress.

• Proceedings of the KSR Conference
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• 2008.11b
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• pp.1078-1083
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• 2008

In this paper, assessed are the stability of vehicle and track according to vertical support stiffness difference on the transition between conventional and zero-longitudinal resistance (ZLR) rail fastener on bridge. For this, the spring constants of rail fastener have been determined according to different load ranges - KTX load (with or without impact factor) and test load of EN standards - from results of laboratory test on rail pad, the stability analysis of vehicle and track has been performed according to numbers or installation length of ZLR fasteners using vertical vehicle-track coupled model to consider train-track interaction. The analysis results reveal that only the wheel load variation slightly exceed the limit value when 2 ZLR fasteners are used with spring constant determined within the EN test load range, but, in all other cases, all evaluation items are satisfied. Thus, it can be said that the stability of vehicle and track will not be degraded by ZLR fastener.

• Geomechanics and Engineering
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• v.24 no.5
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• pp.491-503
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• 2021

Shallow tunnels are vulnerable to earthquakes, and shallow ground is usually inhomogeneous. Based on the limit equilibrium method and variational principle, a solution for the seismic collapse mechanism of shallow tunnel in inhomogeneous ground is presented. And the finite difference method is employed to compare with the analytical solution. It shows that the analytical results are conservative when the horizontal and vertical stresses equal the static earth pressure and zero at vault section, respectively. The safety factor of shallow tunnel changes greatly during an earthquake. Hence, the cyclic loading characteristics should be considered to evaluate tunnel stability. And the curve sliding surface agrees with the numerical simulation and previous studies. To save time and ensure accuracy, the curve sliding surface with 2 undetermined constants is a good choice to analyze shallow tunnel stability. Parameter analysis demonstrates that the horizontal semiaxis, acceleration, ground cohesion and homogeneity affect tunnel stability greatly, and the horizontal semiaxis, vertical semiaxis, tunnel depth and ground homogeneity have obvious influence on tunnel sliding surface. It concludes that the most applicable approaches to enhance tunnel stability are reducing the horizontal semiaxis, strengthening cohesion and setting the tunnel into good ground.

• YAKHAK HOEJI
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• v.7 no.2_3
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• pp.51-54
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• 1963

In this experiment, it is found that the decomposition reaction of hexamine aqueous solution by heat is the pseudo first order reaction and the calculated decomposition velocity constants of Hexamine aqueous solution are 1.17 * $10^{-5}min.^{-1}(60{\deg}$ C), 1.99 * $10^{-5}min.^{-1}(70{\deg}$ C), 2.35 * $10^{-5}min.^{-1}(80{\deg}$ C), 6.63 * $10^{-5}min.^{-1}(100{\deg}$ C). In the result, the activation energy of decomposition reaction of hexamine aqueous solution is 12 $Cal.mole^{-1}$.

• Journal of applied mathematics & informatics
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• v.26 no.1_2
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• pp.365-374
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• 2008

We study a mathematical modeling for development of film negative and concentrate the bulk reaction problem. We prove nonnegativeness of developer, coupler and dye function in two dimensional case. Also we prove stability of our numerical scheme. Finally, we discuss numerical example which have specified constants.

• Kyungpook Mathematical Journal
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• v.50 no.4
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• pp.483-497
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• 2010

In this paper we study some qualitative behavior of the solutions of the difference equation $x_{n+1}=ax_n=\frac{bx_n}{cx_n-dx_{n-1}}$, n=0,1,$\ldots$, where the initial conditions x-1, x0 are arbitrary real numbers and a, b, c, d are positive constants with $cx_0-dx_{-1}\neq0$.

• Journal of Environmental Science International
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• v.5 no.6
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• pp.757-762
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• 1996

The removal effectiveness of various heavy metal ions in boron-rich containing plants has been studied by means of spectroscopic and pH methods. Treatment of the boron-rich containing sample which was collected from cherry and root of cabbage to heavy metal ions is resulted in that an excellent removal effect shows in the case of large ionic size of heavy metal. Stability constants are depended on the variation of pH.

• Proceedings of the KIEE Conference
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• 1997.07c
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• pp.1064-1066
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• 1997

This paper proposes an efficient algorithm of designing PSS and CSS. First, the stabilizer input variable is selected using the participation matrix. Secondly, the stabilizer constants are decided using first order eigenvalue sensitivity. The proposed method was validated to sample power system.