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Use of Inner Ionomer Solution in Preparing Membrane-Electrode Assembly (MEA) for Fuel Cells and Its Characterization

  • Seo, Seok-Jun;Woo, Jung-Je;Yun, Sung-Hyun;Park, Jin-Soo;Moon, Seung-Hyeon
    • Korean Membrane Journal
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    • v.10 no.1
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    • pp.46-52
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    • 2008
  • Optimization of ionomer solution was conducted in order to improve the performance of MEAs in PEMPC. The interface between membrane and electrodes in MEAs is crucial region determining fuel cell performance as well as ORR reaction at cathode. Through the modification of Nafion ionomer content at the interface between membrane and electrodes, an optimal content was obtained with Nafion 115 membranes. Two times higher current density was obtained with the outer Nafion sprayed MEA compared with the non-sprayed one. In addition, the symmetrical impedance spectroscopy mode (SM) exhibited that the resistances of membrane area, proton hydration, and charge transfer decreased as the outer Nafion is sprayed. From the polarization curves and SM, the highest current density and the lowest resistance was obtained at the outer ionomer content of $0.15\;mg\;cm^{-2}$.

A Study for Rocket Exhaust Flow Cooling due to the Central Spray Type Water Injection (중앙 분사 방식 냉각수 투입에 의한 로켓 연소 후류 냉각에 관한 연구)

  • Kang, Sun-Il;Nam, Jung-Won;Huh, Hwan-Il
    • Aerospace Engineering and Technology
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    • v.12 no.1
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    • pp.163-172
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    • 2013
  • In this study, the cooling of rocket exhaust plume by sprayed water inside plume were investigated as varying of sprayed water mass, location, and method using computational fluid analysis. For Analyze rocket exhaust plume, a single species unreacted analysis model based on the chemically frozen analysis was used and the discrete particle model which was a kind of Euler-Lagrangian analysis model was used for simulate sprayed water inside plume. It was confirmed that the temperature of plume was reduced without cooling when water mass was two times of plume mass through analysis results.

Effect of Post-heat Treatment on Fatigue Strength of Thermally-Sprayed Stellite Alloy on Steel (스텔라이트 합금 용사 코팅의 피로 강도에 미치는 후열처리의 영향)

  • Oh Jeong Seong;Komotori Jun;Rhee Chang Kyu
    • Journal of Powder Materials
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    • v.12 no.2 s.49
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    • pp.106-111
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    • 2005
  • The effect of post-heat treatment on the coating characteristics and the fatigue strength of the gas flame thermally sprayed Stellite alloy coatings on $0.35\%$ carbon steel were investigated. The fatigue fracture surfaces of the heat treated samples were observed using SEM (Scanning Electron Microscopy). For as-sprayed samples, there was considerable scattering in the fatigue life due to the presence of the pores in the coating. After the post-heat treatment to improve the microstructural characteristics of the coating layer, the fatigue strength of the specimens was greatly improved, increasing with increasing the coating thickness. For the specimens with the 0.3mm and 0.5mm thick coating, the fatigue cracks originated in the substrate region just below the interface. On the contrary, for the specimens with the 1.0mm thick coating, they nucleated at the pore within the coating, and the fatigue strength was 2.6 times higher than that of the substrate due to the high fatigue resistance of the coating.

Effect of laser heat-treatment on microstructure and micro-hardness of HVOF-sprayed WC-CoCr coating

  • Zhang, Shi-Hong;Cho, Tong-Yul;Yoon, Jae-Hong;Fang, Wei;Joo, Yun-Kon;Song, Ki-Oh;Li, Ming-Xi
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2007.11a
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    • pp.138-139
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    • 2007
  • The microstructure and micro-hardness of high velocity oxygen fuel-sprayed (HVOF) WC-CoCr coatings are comparatively studied for both before and after laser heat-treatment (LT) of the coatings. The results indicate that compared to HVOF WC-CoCro coating, the laser treatment has eliminated the pores almost entirely providing a more homogeneous and densified microstructure. And the compact interface of the coating with substrate is achieved by laser treatment. The thickness of the coating has decreased from 300 ${\mu}m$ to 225 ${\mu}m$ As a result, the average porosity is five times higher in HVOF coating than in the coating by laser treatment. The laser treatment has produced a considerable increment in the hardness of the coating near surface whose average value increases from Hv0.2=1262.4 in the HVOF-sprayed coating to Hv0.2=1818.7 in the coatings treated with laser.

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Effect of Pesticide on Biological Traits of an Orb-web Spider, Trichonephila clavata Koch (Araneae: Araneidae) in Pinus densiflora Forests in Mt. Geumjeong, Korea (살충제 살포가 금정산 소나무림 내 무당거미(거미목 : 왕거미과)의 생물적 형질에 미치는 영향)

  • Jung, Jong-Kook;Kim, Junheon;Kim, Dongsoo;Jung, Chuleui
    • Korean journal of applied entomology
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    • v.59 no.3
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    • pp.209-215
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    • 2020
  • Debates over the ecological and public health impacts of aerial pesticide sprays are increasing. This is particularly true for controlling Monochamus beetles, which are vector insects of pinewood nematodes. In 2017, adult female orb-web spiders, Trichonephila clavata, were sampled from pine forests in Yangsan-si, Gyeongsangnam-do, Korea, where the aerial pesticide spray, fenitrothion or thiacloprid, was used for several decades. The biological traits of the spiders (body weight, body length, carapace width, and total hind leg length) were compared among treatment sites (no-spray, sprayed three times, and sprayed five times), and differences were observed. The body length, carapace width, and total hind leg length of the spiders in the sprayed areas were significantly shorter than in the no-spray area, but there were no differences between the area sprayed three or five times. These results indicate that repeated exposures to an aerial pesticide spray can alter morphological parameters, which influences population-level fitness. Future studies should monitor the spider long-term responses to pesticides (a direct effect) and prey availability (an indirect effect).

Laser Assisted Surface Alloying of Cast Iron with Thermal Sprayed Titanium Coatings (티타늄 용사피막을 이용한 주철의 레이저 표면합금화)

  • Park, Heung-Il;Kim, Sung-Gyoo;Lee, Byung-Woo
    • Journal of Korea Foundry Society
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    • v.17 no.4
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    • pp.393-401
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    • 1997
  • Commercial flake graphite cast iron substrate was coated with titanium powder by low pressure plasma spraying and was irradiated with a $CO_2$ laser to produce the wear resistant composite layer. From the experimental results of this study, it was possible to composite TiC particles on the surface layer by direct reaction between carbon existed in the cast iron matrix and titanium with thermal sprayed coating by remelting and alloying them using laser irradiation. The cooling rate of laser remelted cast iron substrate without titanium coating was about $1{\times}10^4$ K/s to $1{\times}10^5$ K/s in the order under the condition used in this study. The microstructure of alloyed layer consisted of three zones, that is, TiC particule crystallized zone (MHV $400{\sim}500$), the mixed zone of TiC particule+ledebulite (MHV $650{\sim}900$) and the ledebulite zone (MHV $500{\sim}700$). TiC particules were crystallized as a typical dendritic morphology. The secondary TiC dendrite arms were grown to the polygonized shape and were necking. And then the separated arms became cubic crystal of TiC at the slowly solidified zone. But in the rapidly solidified zone of fusion boundry, the fine granular TiC particules were grouped like grape.

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Development of a High Performance Extractor for the Effective Ingredient of Propolis (프로폴리스 유효성분의 고성능 추출기 개발)

  • Cho, Young Tae
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.16 no.3
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    • pp.107-112
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    • 2017
  • The purpose of this study was to develop an extractor to improve the effective ingredient of propolis. In order to improve the performance of conventional alcohol extraction at room temperature, a striking-type extractor used with a sprayed mist (alcohols, 95% alcohol) was developed for use at $40^{\circ}C$. Extraction of the effective ingredient of propolis was tested, and the resulting material was analyzed using a device. The extraction test of the mist spraying method indicated that the level of flavonoid was 1.56%, which is 1.5 times the 1.04% shown in existing data from a conventional stirred extractor. In addition, the extraction time can be reduced by half and the cost reduced by about 12.7% per year. It is confirmed that the extractor developed with a sprayed mist (alcohols, 95% alcohol) appears effective at the low temperature.

Control Efficacy of Environment-friendly Agricultural Materials against Alfalfa Weevil, Hypera postica Gyllenhal at Chinese Milk Vetch Field (자운영포장에서 알팔파바구미에 대한 친환경농자재의 방제효과)

  • Bae, Soondo;Mainali, Bishwo Prasad;Choi, Byeongryel;Yoon, Youngnam;Kim, Hyunju
    • The Korean Journal of Pesticide Science
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    • v.18 no.1
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    • pp.26-32
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    • 2014
  • This study was conducted to evaluate pest control efficacy of environment-friendly agricultural materials (EFAMs) according to their spray time and frequency against alfalfa weevil, Hypera postica Gyllenhal, at Chinese milk vetch field in Miryang, Korea. Larva, pupa and adult of H. postica occurred more in year 2010 than those in 2011, and the larval population peaked 5 days faster in year 2010 than on $10^{th}$ May in 2011. Control efficacies of EFAMS sprayed on various time and in several frequencies to H. postica during April in 2010 were 73.6%, 71.9% and 66.2% at single spray in early, middle and late April, respectively and ranged from 77.1% to 78.9% when sprayed twice. With three times spray the control efficacy averaged 87.2%. Control efficacies of EFAMs with a single application in early, middle and late April in 2011 were 57.9%, 66.8% and 65.2%, respectively and ranged from 73.7% to 76.8% when sprayed twice. Control efficacy averaged with 82.7% when EFAMs were sprayed for three times. Accordingly, control efficacy of EFAMs against was increased with increasing spray frequency. Among the tested, Ungsamee(R), Wangjoongwangeco(R) and Muchungjidae(R) with a single application showed relatively higher control efficacy with a 4 to 16% lower control rate than a chemical insecticide, etofenprox 20EC. Therefore, Ungsamee(R), Wangjoongwangeco(R) and Muchungjidae(R) can be effectively used for management of H. postica when sprayed at early April for high occurring population and middle April for low occurring population with a single spray.

Mode of Action of Streptomycin Resistance in the Citrus Canker Pathogen (Xanthomonas smithii subsp. citri) in Jeju Island

  • Hyun, Jae-Wook;Kim, Hyo-Jung;Yi, Pyoung-Ho;Hwang, Rok-Yeon;Park, Eun-Woo
    • The Plant Pathology Journal
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    • v.28 no.2
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    • pp.207-211
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    • 2012
  • It has been known that streptomycin resistance in bacteria can occur as a results of chromosomal mutation or through gene acquisition or both. Chromosomal mutations for resistances are point mutations in the rpsL gene, which alter ribosomal protein S12. Acquired resistance has occurred when an $Sm^R$ plasmid carrying transposon Tn5393 with tandem strA-strB gene is transferred by conjugation. A total of 686 isolates of Xanthomonas smithii subsp. citri causal agent of citrus canker disease were collected from 26 citrus orchards in Jeju Island in 2003 and 2004 seasons. Forty-nine of 111 isolates from streptomycin non-sprayed orchards in 2003 season were resistant to streptomycin. Of 107 isolates from orchards sprayed one time with streptomycin, 58 isolates were resistant, and 166 of 221 isolates from orchards sprayed two times with streptomycin were resistant. In 12 orchards sprayed three or more times with streptomycin, 219 of 247 isolates were resistant to streptomycin. Twenty-five isolates of X. smithii subsp. citri were surveyed to identify the mechanisms of streptomycin resistance in this study. Twenty-one of these 25 isolates were resistant to streptomycin, and it was proven by PCR assay that 18 of the 21 streptomycin resistant isolates have the strB gene. In sixteen of the 21 streptomycin resistant isolates, it was occurred a point mutation altered codon lysine (AAG)-41 of rpsL gene to arginine (AGG). The streptomycin-sensitive isolates easily acquired the resistance by mixed culture with resistant isolates. The strB gene was amplified from the isolates that acquired the resistance by mixed culture, and one isolate of them was also point-mutated in codon 41 of rpsL gene to be resistant. In this study, most of the streptomycin-resistant isolates of X. smithii sub sp. citri in Jeju island expressed the resistance by both chromosomal point mutation and gene acquisition, and the resistance was easily acquired through conjugation by culture mixed with streptomycin resistant and sensitive strains.

Drift and Distribution Properties of Pesticide Spray Solution Applied Aerially by manned-Helicopter (헬기를 이용한 항공살포 농약의 비산 및 분포 특성)

  • Jin, Yong-Duk;Lee, Hee-Dong;Park, Yeon-Ki;Kim, Jin-Bae;Kwon, Oh-Kyung
    • The Korean Journal of Pesticide Science
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    • v.12 no.4
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    • pp.351-356
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    • 2008
  • This study was carried out to assess adoptability and environment impacts of ultra low volume (ULV) pesticide spray solutions aerially sprayed by manned-helicopter. Uniformity of the deposited amount in paddy fields was uneven, showing $3.1{\sim}4.7$ times differences among surveyed sites. Drifting distance of aerially sprayed droplets from the target area was within 30 m in the wind direction and 20 m in the opposite direction. Most of the aerially sprayed pesticides were deposited in/on rice plants, while those in submerged paddy water and soil were relatively small. The degradation rate of the deposited pesticides was in the decreasing order of rice plants, paddy water and soil. Soil residues of pesticides in the aerially sprayed rice paddy fields after harvest ranged from non-detected to 0.201 mg/kg. However, no pesticides were detected in brown rice and rice straw. No phytotoxic symtoms were observed in rice plants and nearby non-target crops by the sprayed pesticides.