• Title/Summary/Keyword: splitting resistance

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Photocatalytic and photoelectrocatalytic properties of anodic titanium dioxide nanotubes based on anodizing conditions (양극산화 조건에 따른 이산화티타늄 나노튜브의 광촉매 및 광전기화학적 특성)

  • Yeonjin Kim;Rin Jung;Jaewon Lee;JeongEun Yoo;Kiyoung Lee
    • Journal of the Korean institute of surface engineering
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    • v.56 no.2
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    • pp.137-146
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    • 2023
  • Nanosized TiO2 has been widely investigated in photoelectrochemical or photocatalytic applications due to their intrinsic properties such as suitable band position, high photocorrosion resistance, and surface area. In this study, to achieve the high efficiency in photoelectrochemical and photocatalytic performance, TiO2 nanotubular structures were formed by anodization at various temperatures and times. The morphological and crystal structure of the anodized TiO2 nanotubes (NTs) were characterized by scanning electron microscope (SEM) and X-ray diffraction (XRD). The photoelectrochemical (PEC) properties and incident photon-to-current conversion efficiency (IPCE) of the TiO2 NTs were studied with different lengths and morphologies. From the detailed investigations, the optimum thickness of TiO2 nanotubes was 3 ㎛. Moreover, we found that the optimum photocatalytic pollutant removal efficiency of TiO2 nanotubes for photodegradation of Rhodamine B (RhB) under simulated solar light was 5.34 ㎛ of tube length.

The Fractural-Mechanical Properties and Durability of Lightweight Concrete Using the Synthetic Lightweight Aggregate (합성경량골재(SLA)를 사용한 경량콘크리트의 파괴, 역학적 특성 및 내구성)

  • Jo Byung-Wan;Park Seung-Kook;Park Jong-Bin;Daniel C. Jansen
    • Journal of the Korea Concrete Institute
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    • v.17 no.1 s.85
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    • pp.19-25
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    • 2005
  • Recycling of waste materials in the construction Industry is a useful method that can cope with an environment restriction of every country. In this study, synthetic lightweight aggregates are manufactured with recycled plastic and fly ash with 12 percent carbon. Nominal maximum-size aggregates of 9.5 mm were produced with fly ash contents of 0, 35, and $80\%$ by the total mass of the aggregate. An expanded clay lightweight aggregate and a normal-weight aggregate were used as comparison. Gradation, density, and absorption capacity are reported for the aggregates. Five batches of concrete were made with the different coarse aggregate types. Mechanical properties of the concrete were determined including density, compressive strength, elastic modulus, splitting tensile strength, fracture toughness, and fracture energy. Salt-scaling resistance, a concrete durability property, was also examined. Compressive and tensile strengths were lower for the synthetic aggregates; however, comparable fracture properties were obtained. Relatively low compressive modulus of elasticity was found for concretes with the synthetic lightweight aggregate, although high ductility was also obtained. As nv ash content of the synthetic lightweight aggregate increased, all properties of the concrete were improved. Excellent salt-scaling resistance was obtained with the synthetic lightweight aggregate containing 80 percent fly ash.

Tension Lap Splice Length in High-Strength Concrete Flexural Members (고강도 콘크리트 휨부재의 인장 겹침이음길이에 관한 연구)

  • Lee, Gi-Yeol;Kim, Woo;Lee, Hwa-Min
    • Journal of the Korea Concrete Institute
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    • v.21 no.6
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    • pp.753-761
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    • 2009
  • This paper presents the test results of total 24 beam-end specimens to investigate the effect of high-strength concrete and cover thickness on the development resistance capacity in tensile lap splice length regions. Based on bond characteristics that an increase in concrete strength results in higher bond stress and shortening of the transfer length, cracking behavior that thin cover thickness induced a splitting crack easily and brittle crack propagation, current design code that development length provisions as uniform bond stress assumption was investigated apply as it. The results showed that as higher strength concrete was employed, not only development resistance capacity was influenced by cover thickness, but also more sufficient safety factor reserved shorter than the lap splice length provision in current design code. From experimental research results, high-strength concrete development length was not inverse ratio of $\sqrt{f_{ck}}$ but directly inverse of $f_{ck}$, and it is also said that there is a certain limit length of the embedded steel over which the assumption of uniform bond stress distribution is valid specially for high-strength concrete not having a same embed length such as normal-strength concrete in current design criteria hypothesis.

MnO2 co-catalyst effect on Photoelectrochemical Properties of GaN Photoelectrode (MnO2 조촉매가 코팅된 GaN 광전극의 광전기화학적 특성)

  • Kim, Haseong;Bae, Hyojung;Kang, Sung-Ju;Ha, Jun-Seok
    • Journal of the Microelectronics and Packaging Society
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    • v.23 no.4
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    • pp.113-117
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    • 2016
  • Recently, hydrogen is regarded as important energy in the future, because it is clean and renewable. The photoelectrochemical (PEC) system, which produce hydrogen using water splitting by solar energy, is one of the most promising energy systems because it has abundant energy sources and good theoretical efficiency. GaN has recently been regarded as suitable photoelectrode that could be used to split water to generate hydrogen without extra bias because its band edge position include water redox potential ($V_{redox}=1.23$ vs. SHE). GaN also shows considerable corrosion resistance in aqueous solutions and it is possible to control its properties, such as structure, band gap, and catalyst characteristics, in order to improve solar energy conversion efficiency. But, even if the band edge position of GaN make PEC reaction facilitate without bias, the overpotential of oxygen evolution reaction could reduce the efficiency of system. One of the ways to decrease overpotential is introduction of co-catalyst on photoelectrode. In this paper, we will investigate the effect of manganese dioxide ($MnO_2$) as a co-catalyst. $MnO_2$ particles were dispersed on GaN photoelectrode by spincoater and analyzed properties of the PEC system using potentiostat (PARSTAT4000). After coating $MnO_2$, the flat-band potential ($V_{fb}$) and the onset voltage ($V_{onset}$) were moved negatively by 0.195 V and 0.116 V, respectively. The photocurrent density increased on $MnO_2$ coated sample and time dependence was also improved. These results showed $MnO_2$ has an effect as a co-catalyst and it would enhance the efficiency of overall PEC system.

Mechanical Properties of Alkali-Activated Slag-Based Concrete Using Lightweight Aggregates (경량골재를 사용한 알칼리 활성 슬래그 콘크리트의 역학적 특성)

  • Yang, Keun-Hyeok;Oh, Seung-Jin;Song, Jin-Gyu
    • Journal of the Korea Concrete Institute
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    • v.20 no.3
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    • pp.405-412
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    • 2008
  • Six alkali-activated (AA) concrete mixes were tested to explore the significance and limitations of developing an environmental friendly concrete. Ground granulated blast-furnace slag and powder typed sodium silicate were selected as source material and an alkaline activator, respectively. The main parameter investigated was the replacement level of lightweight fine aggregate to the natural sand. Workability and mechanical properties of lightweight AA concrete were measured: the variation of slump with time, the rate of compressive strength development, the splitting tensile strength, the moduli of rupture and elasticity, the stress-strain relationship, the bond resistance and shrinkage strain. Test results showed that the compressive strength of lightweight AA concrete sharply decreased when the replacement level of lightweight fine aggregate exceeded 30%. In particular, the increase in the discontinuous grading of lightweight aggregate resulted in the deterioration of the mechanical properties of concrete tested. The measured properties of lightweight AA concrete were also compared, wherever possible, with the results obtained from the design equations specified in ACI 318-05 or EC 2, depending on the relevance, and the results predicted from the empirical equations proposed by Slate et al. for lightweight ordinary Portland cement concrete. The stress-strain curves of different concrete were compared with predictions obtained from the mathematical model proposed by Tasnimi. The measured mechanical properties of lightweight AA concrete generally showed little agreement with the predictions obtained from these equations.

The Properties of Durability and Strength of Fiber-Reinforced Polymer-Modified Mortars Using Eco-Friendly UM Resin (친환경 UM수지를 사용한 섬유보강 폴리머 시멘트 모르타르의 내구성 및 강도 특성)

  • Kwon, Min-Ho;Seo, Hyun-Su;Lim, Jeong-Hee;Kim, Jin-Sup
    • Journal of the Korea Concrete Institute
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    • v.25 no.3
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    • pp.313-320
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    • 2013
  • In this study, performance of fiber-reinforced polymer-modified mortar was studied for the development of eco-friendly materials for high performance repair and reinforcement. The general cement mortar and eco-friendly UM resin was mixed with a certain percentage for increased durability. To increase the strength of the polymer-modified mortar, PVA fiber, steel fiber and hybrid fiber were added at a constant rate. Hybrid fiber is contains the same percentage of PVA fiber and steel fiber. In order to determine the strength properties of fiber-reinforced polymer-modified mortar, the compressive strength test, the splitting tensile strength test and the flexural strength test were performed. And, in order to determine the durability properties of fiber-reinforced polymer-modified mortar, water absorption test and chemical resistance test were performed. From the experimental results, polymer-modified mortar using UM resin was improved durability. And the tensile strength and flexural strength increased, which were the vulnerability of fiber reinforced polymer-modified mortar. From this study, fiber-reinforced polymer-modified mortar using eco-friendly UM resin can be used to repair and reinforcement for the external exposure of concrete structures to improve the durability.

An Effective Mitigation Method on the EMI Effects by Splitting of a Return Current Plane (귀환 전류 평면의 분할에 기인하는 복사 방출 영향의 효과적인 대책 방법)

  • Jung, Ki-Bum;Jun, Chang-Han;Chung, Yeon-Choon
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.19 no.3
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    • pp.376-383
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    • 2008
  • Generally a return current plane(RCP) of high speed digital and analog part is partitioned. This is achieved in order to decrease the noise interference between subsystem in PCBs(Printed Circuit Boards). However, when the connected signal line exists between each subsystem, this partition will cause unwanted effects. In a EMI(Electromagnetic Interference) point of view, the partition of the return current plane becomes a primary factor to increase the radiated emission. Component bridge(CB) is used for the way of maintaining radiated emission, still specific user's guide doesn't give sufficient principle. In a view point of EMI, design principle of multi-CB using method will be analyzed by measurement. And design principle of noise mitigation will be provided. Generally interval of multi-CB is ${\lambda}/20$ ferrite bead. In this study, When multi-CB connection is applied, design principle of ferrite bead and chip resistor is proved by measurement. Multi-connected chip resistance$(0{\Omega})$ is proved to be more effective design method in the point of EMI.

An Effective Mitigation Method on the Signal-Integrity Effects by Splitting of a Return Current Plane (귀환 전류 평면의 분할에 기인하는 신호 무결성의 효과적인 대책 방법)

  • Jung, Ki-Bum;Jun, Chang-Han;Chung, Yeon-Choon
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.19 no.3
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    • pp.366-375
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    • 2008
  • Generally a return current plane(RCP) of high speed digital and analog part is partitioned. This is achieved in order to decrease the noise interference between subsystem in PCBs(Printed Circuit Boards). However, when the connected signal line exists between each sub system, this partition will cause unwanted effects. In a circuital point of view, RCP partition has a bad influence upon signal integrity. In a EMI(Electromagnetic Interference) point of view, the partition of the return current plane becomes a primary factor to increase the radiated emission. Component bridge(CB) is usecl for the way of maintaining signal integrity, still specific user's guide doesn't give sufficient principle. In a view point of signal integrity, design principle of multi-CB using method will be analyzed by measurement and simulation. And design principle of noise mitigation will be provided. Generally interval of CB is ${\lambda}/20$ ferrite bead. In this study. When multi-CB connection is applied, design principle of ferrite bead and chip resistor is proved by measurement and simulation. Multi-connected chip resistance$(0{\Omega})$ is proved to be more effective design method in the point of signal integrity.

An Experimental Study on the High Strength Lightweight Self-Compacting Concrete (고강도경량 자기충전콘크리트에 관한 실험적 연구)

  • Choi Yun-Wang;Kim Yong-Jic;Moon Han-Young
    • Journal of the Korea Concrete Institute
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    • v.17 no.6 s.90
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    • pp.923-930
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    • 2005
  • This paper was to evaluate the high strength lightweight self-compacting concrete(HLSCC) manufactured by Nan-Su, which main factor, Packing Factor(PF) for mixing design, has been modified and improved. We have examined HLSCC performance at its fresh condition as well as its mechanical properties at the hardened condition. The evaluation of HLSCC fluidity has been conducted per the standard of second class rating of JSCE, by three categories of flowability(slump-flow), segregation resistance ability(time required to reach 500mm of slump-flow and time required to flow through V-funnel) and filling ability(U-box test) of fresh concrete. The compressive strength of HLSSC at 28 days has come out to more than 30MPa in all mixes. The relationship between the compressive strength-splitting tensile strength and compressive strength-modulus of elasticity of HLSSC were similar those of typical lightweight concrete. Compressive strength and dry density of HLSCC at 28 days from the multiple regression analysis resulted as $f_c=-0.16LC-0.008LS+50.05(R=0.83)\;and\;f_d=-3.598LC-2.244LS+2,310(R=0.99)$, respectively.

Studies on the Effect of Fiber Reinforcing upon Mechanical Properties of Concrete and Crack Mode of Reinforoed Concrete (섬유보강이 콘크리트의 역학적 특성과 철근콘크리트의 균열성상에 미치는 영향에 관한 연구)

  • 박승범
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.20 no.2
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    • pp.4645-4687
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    • 1978
  • This study was attempted to investigate the mechanical properties of concrete and crack control effects of reinforced concrete with steel and glass fiber. The experimental program includes tests on the properties of fresh concrete containing fibers, compressive strength, tensile strength, flexural strength, Young's modulus, Shrinkage and deformation of steel or glass fiber reinforced concrete. Also this study was carried out to investigate the effect of steel or glass fiber to retard the development in reinforced concrete subject to uniaxial tension and thus facilitate the use of steels of higher strength. The major conclusions that can be drawn from the studies are as follows: 1. The effect of the fibers in various mixes on fresh concrete confirmed that fibers do have a significant effect on the properties of fresh concrete, bringing much more stable and exhibiting a signiflcant reduction in surface bleeding, and that the cohesion is greatly improved and the internal resistance increases with fiber concentration. But the addition of an excess contents and length of fibers brings about the reduction of workability. 2. With the addition of steel fibers(1.5% Vol.) to concrete, the compressive strength as compared with plain concrete showed a very slight increase, but excess addition, over 1.5% Vol. of steel and glass fiber reduced its strength. 3. Splitting tensile strength of fiber reinforced concrete showed a significant increase tendency, as compared with plain concrete. In case of containing steel fiber (2.5%, 30mm), it showed that the maximum increase rate of 1.48 times as much rate, and in case of containing glass fiber (2.5%, 30mm), the increase rate of strength was 1.25 times as much rate. 4. Flexural strength of fiber reinforced concrete showed a significant tendency, as compared with plain concrete. Containing steel fiber (2.5%, 30mm) showed the maximum increase rate of 1.64 times as much rate and containing glass fiber (2.5%, 30mm) showed the increase rate of strength of 1.32 times as much rate, and in general, the 30mm length brougth the best results. 5. The strength ratio ($\sigma$b/$\sigma$c and $\sigma$t/$\sigma$c) increased, when steel fiber's average spacing was up to 3.05mm, but decreased when beyond 3.05mm, and it was confirmed that tensile or flexural strengths of steel fiber reinforced concrete are apparently governed by fiber's average spacing. 6. The compressive strain of fiber reinforced concrete showed a significant increasing tendency as the fiber was added, but Young's modulus. with the addition of steel and glass fibers, showed a slight decrease tendency. And according to the increase of flexural strength, a considerable increase was seen in toughness. 7. With the addition of fiber's the shrinkage of concrete was significantly decreased, in both case of adding steel fibers 12.5%, 30mm, and showed a significant decrease ratio, in average 30.4% and 36.7%, as compared with plain concrete. 8. With the increase of fiber volume fraction and length, the gained stress in reinforcing bar in concrete specimens increased in all crack widths, but at different rates, with the decrease of fiber diameter, the stress showed a considerable increasing tendency. And the duoform steel fibers showed the greatest improvement, as compared with the other types tested. 9. The influence of fiber dimensions in order of significanse on the machanical properties of concrete and the crack control of reinforced concrete was explained as follows: content, length, aspect ratio and dimeter.

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