• Journal of Powder Materials
• /
• v.29 no.5
• /
• pp.411-417
• /
• 2022

Environmental issues such as global warming due to fossil fuel use are now major worldwide concerns, and interest in renewable and clean energy is growing. Of the various types of renewable energy, green hydrogen energy has recently attracted attention because of its eco-friendly and high-energy density. Electrochemical water splitting is considered a pollution-free means of producing clean hydrogen and oxygen and in large quantities. The development of non-noble electrocatalysts with low cost and high performance in water splitting has also attracted considerable attention. In this study, we successfully synthesized a NiCo₂O₄/NF electrode for an oxygen evolution reaction in alkaline water splitting using a hydrothermal method, which was followed by post-heat treatment. The effects of heat treatment on the electrochemical performance of the electrodes were evaluated under different heat-treatment conditions. The optimized NCO/NF-300 electrode showed an overpotential of 416 mV at a high current density of 50 mA/cm² and a low Tafel slope (49.06 mV dec^-1). It also showed excellent stability (due to the large surface area) and the lowest charge transfer resistance (12.59 Ω). The results suggested that our noble-metal free electrodes have great potential for use in developing alkaline electrolysis systems.

• Magazine of the Korean Society of Agricultural Engineers
• /
• v.26 no.1
• /
• pp.52-72
• /
• 1984

This study was performed to obtain the basic data which can be applied to the use of epoxy resin mortars. The data was based on the properties of epoxy resin mortars depending upon various mixing ratios to compare those of cement mortar. The resin which was used at this experiment was Epi-Bis type epoxy resin which is extensively being used as concrete structures. In the case of epoxy resin mortar, mixing ratios of resin to fine aggregate were 1: 2, 1: 4, 1: 6, 1: 8, 1:10, 1 :12 and 1:14, but the ratio of cement to fine aggregate in cement mortar was 1 : 2.5. The results obtained are summarized as follows; 1.When the mixing ratio was 1: 6, the highest density was 2.01 g/cm$^3$, being lower than 2.13 g/cm$^3$ of that of cement mortar. 2.According to the water absorption and water permeability test, the watertightness was shown very high at the mixing ratios of 1: 2, 1: 4 and 1: 6. But then the mixing ratio was less than 1 : 6, the watertightness considerably decreased. By this result, it was regarded that optimum mixing ratio of epoxy resin mortar for watertight structures should be richer mixing ratio than 1: 6. 3.The hardening shrinkage was large as the mixing ratio became leaner, but the values were remarkably small as compared with cement mortar. And the influence of dryness and moisture was exerted little at richer mixing ratio than 1: 6, but its effect was obvious at the lean mixing ratio, 1: 8, 1:10,1:12 and 1:14. It was confirmed that the optimum mixing ratio for concrete structures which would be influenced by the repeated dryness and moisture should be rich mixing ratio higher than 1: 6. 4.The compressive, bending and splitting tensile strenghs were observed very high, even the value at the mixing ratio of 1:14 was higher than that of cement mortar. It showed that epoxy resin mortar especially was to have high strength in bending and splitting tensile strength. Also, the initial strength within 24 hours gave rise to high value. Thus it was clear that epoxy resin was rapid hardening material. The multiple regression equations of strength were computed depending on a function of mixing ratios and curing times. 5.The elastic moduli derived from the compressive stress-strain curve were slightly smaller than the value of cement mortar, and the toughness of epoxy resin mortar was larger than that of cement mortar. 6.The impact resistance was strong compared with cement mortar at all mixing ratios. Especially, bending impact strength by the square pillar specimens was higher than the impact resistance of flat specimens or cylinderic specimens. 7.The Brinell hardness was relatively larger than that of cement mortar, but it gradually decreased with the decline of mixing ratio, and Brinell hardness at mixing ratio of 1 :14 was much the same as cement mortar. 8.The abrasion rate of epoxy resin mortar at all mixing ratio, when Losangeles abation testing machine revolved 500 times, was very low. Even mixing ratio of 1 :14 was no more than 31.41%, which was less than critical abrasion rate 40% of coarse aggregate for cement concrete. Consequently, the abrasion rate of epoxy resin mortar was superior to cement mortar, and the relation between abrasion rate and Brinell hardness was highly significant as exponential curve. 9.The highest bond strength of epoxy resin mortar was 12.9 kg/cm$^2$ at the mixing ratio of 1:2. The failure of bonded flat steel specimens occurred on the part of epoxy resin mortar at the mixing ratio of 1: 2 and 1: 4, and that of bonded cement concrete specimens was fond on the part of combained concrete at the mixing ratio of 1 : 2 ,1: 4 and 1: 6. It was confirmed that the optimum mixing ratio for bonding of steel plate, and of cement concrete should be rich mixing ratio above 1 : 4 and 1 : 6 respectively. 10.The variations of color tone by heating began to take place at about 60˚C, and the ultimate change occurred at 120˚C. The compressive, bending and splitting tensile strengths increased with rising temperature up to 80˚ C, but these rapidly decreased when temperature was above 800 C. Accordingly, it was evident that the resistance temperature of epoxy resin mortar was about 80˚C which was generally considered lower than that of the other concrete materials. But it is likely that there is no problem in epoxy resin mortar when used for unnecessary materials of high temperature resistance. The multiple regression equations of strength were computed depending on a function of mixing ratios and heating temperatures. 11.The susceptibility to chemical attack of cement mortar was easily affected by inorganic and organic acid. and that of epoxy resin mortar with mixing ratio of 1: 4 was of great resistance. On the other hand, when mixing ratio was lower than 1 : 8 epoxy resin mortar had very poor resistance, especially being poor resistant to organicacid. Therefore, for the structures requiring chemical resistance optimum mixing of epoxy resin mortar should be rich mixing ratio higher than 1: 4.

• Journal of the Korean Society for Aeronautical & Space Sciences
• /
• v.46 no.7
• /
• pp.535-541
• /
• 2018

In this study, wedge splitting tests were performed to evaluate fracture behavior of particle reinforced composite materials. Crack resistance was evaluated by using CTOD (crack tip opening displacement) and crack tip opening angle (CTOA). The particle reinforced composites were tested under various temperature ($-60^{\circ}C{\sim}50^{\circ}C$) and load speed (5~500mm/min). Also, digital image correlation method (DIC) was used to analyze the strain field at crack tip. Test results showed that the fracture energy increased with decreasing temperature and crack resistance increased with increasing load velocity.

• Membrane Journal
• /
• v.13 no.1
• /
• pp.54-63
• /
• 2003

The Preparation and electrochemical characterization of anion-exchange membranes containing pyridinium groups were performed. As a result, the pyridinium membranes showed good electrochemical properties, comparable to those of the commercial membranes, with electrical resistance of less than $3.0 {\Xi}cm^2$ in a 0.5 mol $dm^{-3}$ NaCl and high ionic permselectivity (the transport number of $Cl^-$ ions being 0.97). Moreover, water splitting in the membranes containing pyridinium group was about two or three order of magnitude lower than those in the commercial membranes (ｅ.ｇ. AM-1, Tokuyama Crop., Japan) at the same current density because the resonance effedt in the quaternary aromatic pyridinium group contributed to their molecular stability. In addition, the electrodialytic properties of the pyridinium membranes were evaluated in a semi-pilot scale.

• Advances in concrete construction
• /
• v.16 no.6
• /
• pp.277-290
• /
• 2023

In order to study the mechanical properties of basalt fiber reinforced ultra-fine fly ash concrete (BFUFARC), the effects of ultra-fine fly ash (UFA) content, basalt fiber content, basalt fiber length and water reducing agent content on the compressive strength, splitting tensile strength and flexural strength of the composite material were studied through experimental and theoretical analysis. Also, a scanning electron microscope (SEM) was employed to analyze the mesoscopic structure in the fracture surface of composite material specimens at magnifications of 500 and 3500. Besides, the energy release rate (G_c) and surface free energy (γ_s) of crack tip cracking on BFUFARC in different basalt fiber content were studied from the perspective of fracture mechanics. Further, the cracking resistance, reinforcement, and toughening mechanisms of basalt fibers on concrete substrate were revealed by surface free energy of BFUFARC. The experimental results indicated that basalt fiber content is the main influence factor on the splitting tensile strength of BFUFARC. In case that fiber content increased from 0 to 0.3%, the concrete surface free energy at the tip of single-sided crack showed a trend of increased at first and then decreased. The surface free energy reached at maximum, about 3.59 × 10^-5 MN/m. During the process of increasing fiber content from 0 to 0.1%, G_C-2_γS showed a gradually decreasing trend. As a result, an appropriate amount of basalt fiber can play a preventing cracking role by increasing the concrete surface free energy, further effectively improve the concrete splitting tensile performance.

• Korean Journal of Cleft Lip And Palate
• /
• v.4 no.2
• /
• pp.45-50
• /
• 2001

Recents reports have demonstrated that force and direction is important during mandibular distraction osteogenesis. The purpose of this study was to evaluate the resistant force of internal pterygoid muscles and inquire into relationship between internal pte'Ygoid muscles and cephalometric parameters. Eighty four patients with class III malocclusion underwent bilateral sgittal splitting of ramus with intraoral vertico-sagittal ramal osteotomy. A spring scale were used for measuring for resistence of internal pterygoid mescles after splitting of ramus. Skeletal-dental cephalometric analysis was made following statistic package was used for correlation between resistence and cephalometric parameters. The resistant force of right internal pterygoid muscle was greater than left muscle in Korean with class III malocclusion and the force had a linear regression relationship with facial depth (distance between nasion and gonion). The results suggested that facial depth has significant correlation of the resistance of internal pterygoid muscle (p<0.05).

• Advances in materials Research
• /
• v.8 no.2
• /
• pp.103-115
• /
• 2019

Polypropylene (PP) fibers for making fabric which is used for packing cement have a high strength and high tear resistance. Due to these excellent properties the present study investigates the effect of PP fibers on the mechanical strength of concrete. Mechanical strength parameters such as compressive strength, splitting tensile strength and flexural strength are evaluated. Structural integrity of concrete using Ultrasonic Pulse Velocity (UPV) was also studied. Concrete containing PP fibers in percentage of 0%, 0.15%, 0.25%, 0.5% and 0.75% was developed with a characteristic compressive strength of 25 MPa. Concrete cubes, cylinder and prismatic specimens were cast and tested. It was found that the UPV values recorded for all specimens were of the similar order. Test results indicated the used of PP fibers can significantly improve the flexural and splitting tensile strengths of concrete materials whereas it resulted a decreased in compressive strength. The relative increase in split tensile and flexural strength was optimum at a fiber dosage of 0.5% and a mild decreased were observed in 28 days compressive strength. The findings in this paper suggested that PP fibers deriving from these waste cement bags are a feasible fiber option for fiber-reinforced concrete productions.

• Steel and Composite Structures
• /
• v.48 no.2
• /
• pp.131-143
• /
• 2023

The CFRP bar was used to achieve more ductile and durable headed-stud shear connectors in composite components. Three series of push-out tests were firstly conducted, including specimens reinforced with pure steel fibers, steel and CFRP bars. The distributed stress was measured by the commercial PPP-BOTDA (Pre-Pump-Pulse Brillouin optical time domain analysis) optical fiber sensor with high spatial resolution. A series of numerical analyses using non-linear FE models were also made to study the shear force transfer mechanism and crack response based on the test results. Test results show that the CFRP bar increases the shear strength and stiffness of the large diameter headed-stud shear connection, and it has equivalent reinforcing effects on the stud shear capacity as the commonly used steel bar. The embedded CFRP bar can also largely improve the shear force transfer mechanism and decrease the tensile stress in the transverse direction. The parametric study shows that low content steel fibers could delay the crack initiation of slab around the large diameter stud, and the CFRP bar with normal elastic modulus and the standard reinforcement ratio has good resistance to splitting crack growth in headed stud shear connectors.

• Magazine of the Korean Society of Agricultural Engineers
• /
• v.29 no.4
• /
• pp.132-141
• /
• 1987

The objective of the study was to obtain the compressive the tensile and the fleniril strengthes, thermal resistance, chemical resistance and fire resistance of the reclaimed plastic corcrete in order to investigate the feasibility as a new construction material This reclaimed plastic concrete is a compositive material which is composed of sand and blend of 50% of LDPE(Low density polyethylene) and 50% of HDPE (High density polyethylene) which are inexpensive and easy to reclaim. The results obtained in the study are summarized as follows: 1. As the binder content ranging from 20 to 40 % increase, the compresie, the splitting tensile and the flexural strengthes were increased. The compressive strenzth of the specimen tested was the highest and flexural strength the next and tensile strength the lowest 2. The compressive, the tensile and flexural strengthes of specimens made of fine sand were higher than those of coarse sand. The compressive, the tensile and the flexural strengthes of specimens made of high pressure molding were higher than those of low pressure molding. 3.In comparison with different additives, the specimens with carbon black was excellent and B. H. T. good and ferric oxide poor for thermal resistance. 4. In relationship between the flexural strength with varying temperature from -23$^{\circ}C$ to 80$^{\circ}C$. The flexural strengthes were decreared as temperature increased at 25 %, 30 % and 35 % of binder contents, respectively. Especially at 60$^{\circ}C$, the flexural strength was significantly decreased. 5. The decrement of flexural strengthes and the weight losses after 7 days immersion in acid or alkali solutions were not significant. 6. Fire resistance of the reclaimed plastic concrete was not significantly influenced by the contents of sand. However, the fire resistance of the reclaimed plastic concrete was depend upon melting and ignition properties of the binder itself. Therefore. a proper selection of the binder and the fire retardant are recommended in arder to improve fire resistance of the reclaimed plastic concrete.

• KSCE Journal of Civil and Environmental Engineering Research
• /
• v.30 no.6A
• /
• pp.573-580
• /
• 2010

This paper presents the development of self-consolidating concrete (SCC) using lightweight aggregates. SCC using Lightweight aggregate properties have been evaluated in terms of flowability, segregation resistance and filling capacity of fresh concrete as per the standards of the Japanese Society of Civil Engineering (JSCE). The measurement of the mechanical properties of hardened SCC using lightweight aggregate, including compressive strength, splitting tensile strength, elastic moduli and density, as well as its dry shrinkage and carbonation properties were also carried out. The characteristics of SCC using lightweight aggregate at the fresh state showed that as the use of the lightweight aggregate, the flowability improves without exception of Mix No. 9 but the segregation resistance tends to decrease without exception of Mix No. 3, 4 and 5. The 28 days compressive strength of the SCC using lightweight aggregate was found to be 30 MPa or higher. The relationship between the compressive strength and the splitting tensile strength was found to be similar to the expression presented by CEB-FIP, and the relationship between the compressive strength and the elastic moduli was found to be similar to the expression suggested by ACI 318-08 which takes into consideration the density of concrete. The density of the SCC using lightweight aggregate decreased by up to 26% compared to that of the control SCC. Also, The dry shrinkage and carbonation depth of the SCC using lightweight aggregate increased compared to that of the control SCC.