• Title/Summary/Keyword: splitting effect

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Photocurrent study on the splitting of the valence band and growth of $Cdln_2Te_4$ single crystal by Bridgman method (Bridgman법에 의한 $Cdln_2Te_4$단결정의 성장과 가전자대 갈라짐에 대한 광전류 연구)

  • 홍광준;이관교;이봉주;박진성;신동찬
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.13 no.3
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    • pp.132-138
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    • 2003
  • A stoichiometric mixture for $CdIn_2Te_4$ single crystal was prepared from horizontal electric furnace. The $CdIn_2Te_4$ single crystal was grown in the three-stage vertical electric furnace by using Bridgman method. The $CdIn_2Te_4$ single crystal was evaluated to be tetragonal by the power method. The (001) growth plane of oriented $CdIn_2Te_4$ single crystal was confirmed from back-reflection Laue patterns. The carrier density and mobility of $CdIn_2Te_4$ single crystal measured with Hall effect by van der Pauw method are $8.61\times 1016 \textrm {cm}^{-3}$ and 242 $\textrm{cm}^2$/V.s at 293 K, respectively. The temperature dependence of the energy band gap of the $CdIn_2Te_4$ single crystal obtained from the absorption spectra was well described by the Varshni's relation, $1.4750ev - (7.69\times10^{-3})\; ev/k)\;T^2$/(T + 2147k).The crystal field and the spin-orbit splitting energies for the valence band of the $CdIn_2Te_4$ single crystal have been estimated to be 0.2704 eV and 0.1465 eV, respectively, by means of the photocurrent spectra and the Hopfield quasicubic model. These results indicate that the splitting of the $\Delta$so definitely exists in the $\Gamma_7$ states of the valence band of the $CdIn_2Te_4$ single crystal. The three photocurrent peaks observed at 10 K are ascribed to the $A_{1-} B_{1-}$ and Cl-exciton peaks for n = 1.

Effect of Spinal Cord Removal before or after Splitting and Washing on CNST Decontamination of Beef Carcasses

  • Lim, D.G.;Kim, D.H.;Lee, M.
    • Asian-Australasian Journal of Animal Sciences
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    • v.20 no.11
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    • pp.1770-1776
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    • 2007
  • Beef carcasses were examined to explore the effects of spinal cord removal and washing on central nervous system tissue (CNST) decontamination of the surface during the slaughtering process. A total of 15 carcasses were split by sawing centrally down the vertebral column and left sides of split carcasses were used for analysis. Samples were collected by swabbing the surface from 4 defined parts on the interior and 4 on the exterior of carcasses from the abattoir and analyzed using an ELISA-based test. The results showed that automatic and manual spray washing decreased CNST contamination, especially on the interior ventral parts of carcass surfaces (p<0.01), but did not decrease CNST on the interior dorsal parts. Increasing washing time to 60 s did not affect the reduction of CNST contamination. Samples following spinal cord removal prior to splitting showed lower calculated levels of "risk material" than the stated limit of detection (0.1%) of the ELISA kit on interior and exterior carcass parts (p<0.01). Therefore, spinal cord removal prior to splitting could be a very effective way to minimize CNST contamination of beef carcasses.

Splitting effect of photocurrent for $CdIn_2Te_4$ single crystal

  • You, Sang-Ha;Hong, Kwang-Joon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.84-85
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    • 2009
  • The single crystals of p-$CdIn_2Te_4$ were grown by the Bridgman method without the seed crystal. From photocurrent measurements, it was found that three peaks, A, B, and C, correspond to the intrinsic transition from the valence band states of $\Gamma_7(A)$, $\Gamma_6(B)$, and $\Gamma_7(C)$ to the conduction band state of $\Gamma_6$, respectively. The crystal field splitting and the spin orbit splitting were found to be 0.2360 and 0.1119 eV, respectively, from the photocurrent spectroscopy. The temperature dependence of the $CdIn_2Te_4$ band gap energy was given by the equation of $E_g(T)=E_g(0)$ - $(9.43\times10^{-3})T^2$/(2676+T). $E_g(0)$ was estimated to be 1.4750, 1.7110, and 1.8229 eV at the valence band states of A, B, and C, respectively. The band gap energy of $p-CdIn_2Te_4$ at room temperature was determined to be 1.2023 eV.

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Effect of silica fume on mechanical properties of concrete containing recycled asphalt pavement

  • Katkhuda, Hasan N.;Shatarat, Nasim K.;Hyari, Khaled H.
    • Structural Engineering and Mechanics
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    • v.62 no.3
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    • pp.357-364
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    • 2017
  • This paper presents the results of a study that investigated the improvement of the mechanical properties of coarse and fine recycled asphalt pavement (RAP) produced by adding silica fume (SF) with contents of 5%, 10%, and 15% by total weight of the cement. The coarse and fine natural aggregate (NA) were replaced by RAP with replacement ratio of 20%, 40% and 60% by the total weight of NA. In addition, SF was added to NA concrete mixes as a control for comparison. Twenty eight mixes were produced and tested for compressive, splitting tensile and flexural strength at the age of 28 days. The results show that the mechanical properties decrease with as the content of RAP increases. And the decrease in the compressive strength was more in the fine RAP mixes compared to the coarse RAP mixes, while the decrease in the splitting tensile and flexural strength was almost the same in both mixes. Furthermore, using SF enhances the mechanical properties of RAP mixes where the optimum content of SF was found to be 10%, and the mechanical properties enhancement of coarse RAP were better than fine RAP mixes. Accordingly, the RAP has the potential to be used in the concrete pavements or in other low strength construction applications in order to reduce the negative impact of RAP on the environment and human health.

Study on fracture characteristics of reinforced concrete wedge splitting tests

  • HU, Shaowei;XU, Aiqing;HU, Xin;YIN, Yangyang
    • Computers and Concrete
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    • v.18 no.3
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    • pp.337-354
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    • 2016
  • To study the influence on fracture properties of reinforced concrete wedge splitting test specimens by the addition of reinforcement, and the restriction of steel bars on crack propagation, 7 groups reinforced concrete specimens of different reinforcement position and 1 group plain concrete specimens with the same size factors were designed and constructed for the tests. Based on the double-K fracture criterion and tests, fracture toughness calculation model which was suitable for reinforced concrete wedge splitting tensile specimens has been obtained. The results show that: the value of initial craking load Pini and unstable fracture load Pun decreases gradually with the distance of reinforcement away from specimens's top. Compared with plain concrete specimens, addition of steel bar can reduce the value of initial fracture toughness KIini, but significantly increase the value of the critical effective crack length ac and unstable fracture toughness KIun. For tensional concrete member, the effect of anti-cracking by reinforcement was mainly acted after cracking, the best function of preventing fracture initiation was when the steel bar was placed in the middle of the crack, and when the reinforcement was across the crack and located away from crack tip, it plays the best role in inhibiting the extension of crack.

Effect of Curing Temperature and Aging on the mechanical Properties of Concrete (I) -Experimental Results and Analysis- (콘크리트의 재료역학적 성질에 대한 양생온도와 재령의 효과(I) -실험결과 및 분석을 중심으로-)

  • 한상훈;김진근;송영철
    • Journal of the Korea Concrete Institute
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    • v.12 no.6
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    • pp.23-34
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    • 2000
  • This paper reports the effects of curing temperature and aging on the strength and the modulus of elasticity. In oder to determine the strength and the modulus of elasticity with curing temperature and aging, experimental and analytical methods are adopted. The tests of 480 cylinders are carried out for type I, V and V with 15 percent replacement of fly ash cement concretes, which are cured at isothermal conditions of 10, 23, 35 and 5$0^{\circ}C$. and the concrete cylinders are tested at the ages of 1, 3, 7 and 28 days. According to the experimental results, the concrete subjected to high temperature at early ages attaines higher early-age compressive and splitting tensile strength but eventually attaines lower later-age compressive and splitting tensile strength. Even if modulus of elasticity has the same tendency, the variation of modulus of elasticity with curing temperature is smaller than that of compressive strength. Based on these experimental results, the relationships among compressive strength, modulus of elasticity and splitting tensile strength are proposed considering the effects of curing temperature, aging and cement type.

Effect of Reduced Graphene Oxide in Photoanode on Photoelectrochemical Performance in Water Splitting for Hydrogen Production (수소생산을 위한 물 분해용 광전극에 도입된 환원된 산화그래핀이 광전기화학성능에 미치는 영향)

  • YOON, SANGHYEOK;DING, JIN-RUI;KIM, KYO-SEON
    • Journal of Hydrogen and New Energy
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    • v.27 no.4
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    • pp.329-334
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    • 2016
  • Hydrogen is eco-friendly alternative energy source and the photoelectrochemical water splitting is believed to be one of the promising methods for hydrogen production. Many researchers have studied several potential photocatalysts to increase the photoelectochemical performance efficiency for hydrogen conversion. In this study, the GO (graphene oxide) was prepared by Tour's method and was dispersed in precursor solutions of $WO_3$ and $BiVO_4$. Those precursor solutions were spin-coated on FTO glass and several photocatalyst thin films of $WO_3$, $BiVO_4$ and $WO_3/BiVO_4$ were prepared by calcination. The morphologies of prepared photocatalyst thin films were measured by scanning electron microscope. The photoelectrochemical performances of photocatalyst thin films with rGO (reduced graphene oxide) and without rGO were analyzed systematically.

Push-out tests on stud shear connectors with constrained structure of steel-concrete composite beams

  • Qi, Jingjing;Xie, Zuwei;Cao, Hua;Huang, Zhi;Lv, Weirong;Shi, Weihua
    • Structural Engineering and Mechanics
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    • v.83 no.6
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    • pp.789-798
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    • 2022
  • The stud shear connector is the main force transfer member in the steel-concrete composite member, and the mechanical behavior is very complicated in the concrete. The concrete around the stud is subjected to the pry-out local pressure concentration of the stud, which can easily produce splitting mirco-cracks. In order to solve the problem of pry-out local splitting of stud shear connector, a kind of stud shear connector with constraint measure is proposed in this paper. Through the push-out test, the interface shear behavior of the new stud shear connector between steel and concrete flange plate was studied, and the difference between the new stud shear connector and the traditional stud connector was compared. The results show that the stud shear connector with constraint measure can effectively avoid the adverse effect of local pressure splitting by relying on its own constraint measure. The shear stiffness of the interface between steel and concrete flange plates is greatly improved, which provides a theoretical basis for the design of strong connection coefficient of steel-concrete composite structures.

Crystal field splitting energy for $CdGa_2Se_4$ epilayers obtained by photocurrent measurement (광전류 측정으로부터 얻어진 $CdGa_2Se_4$ 에피레이어의 결정장 갈라짐에 대한 에너지)

  • Hong, Kwang-Joon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.144-145
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    • 2009
  • Single crystal $CdGa_2Se_4$ layers were grown on a thoroughly etched semi-insulating GaAs(100) substrate at $420^{\circ}C$ with the hot wall epitaxy (HWE) system by evaporating the poly crystal source of $CdGa_2Se_4$ at $630\;^{\circ}C$. The crystalline structure of the single crystal thin films was investigated by the photoluminescence and double crystal X-ray diffraction (DCXD). The carrier density and mobility of single crystal $CdGa_2Se_4$ thin films measured with Hall effect by van der Pauw method are $8.27\;\times\;10^{17}\;cm^{-3}$, $345\;cm^2/V{\cdot}s$ at 293 K, respectively. The photocurrent and the absorption spectra of $CdGa_2Se_4$/SI(Semi-Insulated) GaAs(100) are measured ranging from 293 K to 10K. The temperature dependence of the energy band gap of the $CdGa_2Se_4$ obtained from the absorption spectra was well described by the Varshni's relation, $E_g$(T) = 2.6400 eV - ($7.721\;{\times}\;10^{-4}\;eV/K)T^2$/(T + 399 K). Using the photocurrent spectra and the Hopfield quasi cubic model, the crystal field energy(${\Delta}cr$) and the spin-orbit splitting energy(${\Delta}so$) for the valence band of the $CdGa_2Se_4$ have been estimated to be 106.5 meV and 418.9 meV at 10 K, respectively. The three photocurrent peaks observed at 10 K are ascribed to the $A_1$-, $B_1$-, and $C_{11}$-exciton peaks.

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RECONSTRUCTION OF SEVERE BUCCO-LINGUAL BONE RESORPTION AREA USING "RIDGE SPLITTING TECHNIQUE" (심한 협-설골 위축에서 치조골 수평 확장술을 이용한 골 재건)

  • Yeo, Duck-Sung;Lim, So-Yeon;Lee, Hyun-Jin;Ahn, Mi-Ra;Sohn, Dong-Seok
    • Maxillofacial Plastic and Reconstructive Surgery
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    • v.28 no.6
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    • pp.590-594
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    • 2006
  • Dental implant has become one of the important option for completely or partially edentulous patients, But it is challenging to reconstruct the severely atrophic ridge. Insufficient bone volume could restrict to place the wide and long implant and because of excessive interocclusal clearance, improper prosthetics could be produced. In this case bone augmentation for implant dentistry is necessary procedure to improve the insufficient bone volume. Therefore, bone augmentation or GBR is the most important procedure for successful implant placement and for ideal crown- root ratio. There are various bone augmentation techniques have been introduced recently; like block bone graft, distraction osteogenesis, inlay graft, onlay graft, etc.... In severe bucco-lingual resorption area, ridge splitting is the first choice of the treatment, because it provides a place for implantation and also has compaction effect. This technique may be indicated for sharp mandible and maxillary ridges in patients whose bone quantity is inadequate for primary stabilization. We report that the clinical experience of bone augmentation using ridge splitting technique in bucco-lingual bone resorption area.