• Geomechanics and Engineering
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• 제14권2호
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• pp.187-193
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• 2018

Water inrush through the destruction of water resisting rock mass structure was divided into direct water inrush, key block water inrush and splitting water inrush. In the direct water inrush, the Reynolds numbers has a significant effect on the distribution of the water flow and vortex occurred in the large Reynolds numbers. The permeability coefficient of the fracture is much larger than the rock, and the difference is between 104 and 107 times. The traditional theory and methods are not considering the effect of inertia force. In the position of the cross fracture, the distribution of water flow can only be linearly distributed according to the fracture opening degree. With the increase of Reynolds number, the relationship between water flow distribution and fracture opening is studied by Semtex.

• Bulletin of the Korean Chemical Society
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• 제22권12호
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• pp.1316-1322
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• 2001

Transition metal complexes of novel mono- and di-ferrocene-substituted porphyrins have been synthesized and characterized by structural and electrochemical methods. The X-ray structures of Mn(FPTTP)Cl and Mn(DFTTP)Cl showed the distorted square pyramidal coordination geometry with syn configuration of chloride and ferrocenyl substituents. The electrochemistry of ferrocene-substituted porphyrins and their metal complexes has been determined to elucidate the ${\pi}-conjugation$ effect of the porphyrin ring. The ferrocenyl group of H2FPTTP underwent a reversible one-electron transfer process at 0.30 V, indicating the good electron donating effect of the phorphyrin ring to the ferrocene substituent. The redox potential of the ferrocenyl subunit and porphyrin ring was affected by the central metal ions of the metalloporphyrins, that is, Zn(II) and Ni(II) made the oxidation of ferrocene much easier and Mn(III) made it harder. The ferrocene subunits of H2DFTTP interacted electrochemically with each other with peak splitting of 0.21 V. The strength of the electrochemical interactions between the two ferrocenyl substituents can be controlled by central metal ions of metalloporphyrins.

• Advances in concrete construction
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• 제5권5호
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• pp.481-492
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• 2017

The aim of this paper is to investigate the effect of quartz powder (Qp), quartz sand (Qs), and different water curing temperature on mechanical properties including 7, 14, 28-day compressive strength and 28-day splitting tensile strength of Ultra High Performance Concrete and also finding the correlation between these variables on mechanical properties of UHPC. The response surface methodology was monitored to show the influences of variables and their interactions on mechanical properties of UHPC, then, mathematical models in terms of coded variables were established by ANOVA. The offered models are valid for the variables between: quartz powder 0 to 20% of cement substitution by cement weight, quartz sand 0 to 50% of aggregate substitution by crushed limestone weight, and water curing temperature 25 to $95^{\circ}C$.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2022년도 봄 학술논문 발표대회
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• pp.184-185
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• 2022

This study researched the effect of graphene nanoribbons (0.05 wt%) on cement-based materials' mechanical and electrical properties. The results were compared with the ordinary Portland cement (OPC) paste and OPC paste with the same content of carbon nanotubes. The experiment results showed that after curing for 28 days, the compressive and splitting tensile strength of the sample with graphene nanoribbons were increased by 17.8% and 6.6% compared to OPC paste, and its reinforced effect for cement-based materials was superior to carbon nanotubes. Besides, due to the excellent electrical properties of graphene nanoribbons, the sample reinforced by graphene nanoribbons had a lower electrical resistivity (135.5 Ω·m) than OPC paste (418.5 Ω·m) and paste with carbon nanotubes (175.5 Ω·m). This proved the promising application of graphene nanoribbons on cement-based materials.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2020년도 가을 학술논문 발표대회
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• pp.27-28
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• 2020

In this paper, we investigated the performance of synthetic graphene oxide-functionalized carbon nanotubes (GF) to promote cement hydration and increase the mechanical properties of cement paste. The enhancement effect of GF on the various properties of cement paste was evaluated via the mechanical strength, X-ray diffraction, and heat of hydration of cement paste. The results clearly showed that GF incorporation into cement paste promotes the early hydration of cement paste, generates more hydration products, which results in the mechanical improvement of cement paste. The compressive and splitting tensile strength were increased by 32.17% and 17.31%, respectively, compared to ordinary Portland cement at 28 days of hydration.

• 콘크리트학회논문집
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• 제12권1호
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• pp.13-22
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• 2000

This paper describes the results obtained from 11 direct tension tests to explore the influence of concrete strength on tension stiffening behavior in reinforced concrete axial members. Three different concrete compressive strengths, 250, 650, and 900kgf/$\textrm{cm}^2$, were included as a main variable, while the ratio of cover thickness-to-rebar diameter was kept constant to be 2.62 to prevent from splitting cracking. As the results, it was appeared that, as higher concrete strength was used, less tension stiffening effect was resulted, and the residual deformation upon unloading was larger. In addition, the spacing between adjacent transverse cracks became smaller with higher concrete strength. The major cause for those results may be attributed to the fact that nonuniform bond stress concentration at both loaded ends and crack sections becomes severer as higher concrete is used, thereby local bond failure becomes more susceptible. From these findings, it would be said the increase in flexural stiffness resulting from using high-strength concrete will be much smaller than that predicted by the conventional knowledge. Finally, a factor accunting for concrete strength was introduced to take account for the effect of HSC on tension stiffening. This proposed equation predicts well the tension stiffening for the effect of HSC on tension stiffening. This proposed equation predicts well the tension stiffening behavior of these tests.

• 대한화학회지
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• 제21권1호
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• pp.23-31
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• 1977

Octahedral symmetry 를 지닌 리간드에 의한 영향 아래있는 하나의 d전자를 갖는 금속 착물을 대상으로, 결정장 분리계수 10Dq를 결정장이론에 의하여 이론적으로 계산하였다. 점전하 모형을 쓰되, Shull-Lowdin 함수를 사용하여 배치간 작용을 고려하고, Integral Hellmann-Feynman Theorem을 써서 고차섭동의 영향을 추출하였다. 고차섭동의 영향이 일차섭동의 약 $50{\%}$가 됨을 알았다. Octahedral potential에 의해 3d 함수의 각 성분의 변화가 없고, $E_g\;와\;T_{2g}$상태에서, 동경성분의 변화가 일정하므로 10Dq는 유일한 파라미터로 남을 것이라는 결론을 얻었다.

• 한국결정성장학회지
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• 제18권5호
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• pp.217-224
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• 2008

수평 전기로에서 $ZnIn_2Se_4$ 단결정을 합성하여 HWE(Hot Wall Epitaxy)방법으로 $ZnIn_2Se_4$ 단결정 박막을 반절연성 GaAs(100) 기판에 성장시켰다. $ZnIn_2Se_4$ 단결정 박막의 성장 조건을 증발원의 온도 $630^{\circ}C$, 기판의 온도 $400^{\circ}C$였고 성장 속도는 0.5 $\mu m/hr$였다. $ZnIn_2Se_4$ 단결정 박막의 결정성의 조사에서 10K에서 광발광(photoluminescence) 스펙트럼이 682.7nm ($1.816{\underline{1}}eV$)에서 exciton emission 스펙트럼이 가장 강하게 나타났으며, 또한 이중결정 X-선 요통곡선(DCRC)의 반폭치(FWHM)도 128 arcsec로 가장 작아 최적 성장 조건임을 알 수 있었다. Hall 효과는 van der Pauw 방법에 의해 측정되었으며, 온도에 의존하는 운반자 농노와 이동도는 293 K에서 각각 $9.41\times10^{16}/cm^{-3}$, $292cm^2/V{\cdot}s$였다. $ZnIn_2Se_4$/SI(Semi-Insulated) GaAs(100) 단결정 박막의 광흡수와 광전류 spectra를 293 K에서 10K까지 측정하였다. 광흡수 스펙트럼으로부터 band gap $E_g(T)$는 varshni공식에 따라 계산한 결과 $E_g(T)=1.8622\;eV-(5.23\times10^{-4}eV/K)T^2/(T+775.5K)$ 이었으며 광전류 스펙트럼으로부터 Hamilton matrix(Hopfield quasicubic mode)법으로 계산한 결과 crystal field splitting energy ${\Delta}cr$값이 182.7meV이며 spin-orbit energy ${\Delta} so$값은 42.6meV임을 확인하였다. 10 K일 때 광전류 봉우리들은 n= 1, 27일때 $A_{1}-$, $B_{1}-$와 $C_{27}-exciton$ 봉우리임을 알았다.

• 한국재료학회지
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• 제26권11호
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• pp.604-610
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• 2016

We report on the fabrication and characterization of a novel $Cu_2O/CuO$ heterojunction structure with CuO nanorods embedded in $Cu_2O$ thin film as an efficient photocathode for photoelectrochemical (PEC) solar water splitting. A CuO nanorod array was first prepared on an indium-tin-oxide-coated glass substrate via a seed-mediated hydrothermal synthesis method; then, a $Cu_2O$ thin film was electrodeposited onto the CuO nanorod array to form an oxide semiconductor heterostructure. The crystalline phases and morphologies of the heterojunction materials were examined using X-ray diffraction and scanning electron microscopy, as well as Raman scattering. The PEC properties of the fabricated $Cu_2O/CuO$ heterojunction photocathode were evaluated by photocurrent conversion efficiency measurements under white light illumination. From the observed PEC current density versus voltage (J-V) behavior, the $Cu_2O/CuO$ photocathode was found to exhibit negligible dark current and high photocurrent density, e.g. $-1.05mA/cm^2$ at -0.6 V vs. $Hg/HgCl_2$ in $1mM\;Na_2SO_4$ electrolyte, revealing the effective operation of the oxide heterostructure. The photocurrent conversion efficiency of the $Cu_2O/CuO$ photocathode was estimated to be 1.27% at -0.6 V vs. $Hg/HgCl_2$. Moreover, the PEC current density versus time (J-T) profile measured at -0.5 V vs. $Hg/HgCl_2$ on the $Cu_2O/CuO$ photocathode indicated a 3-fold increase in the photocurrent density compared to that of a simple $Cu_2O$ thin film photocathode. The improved PEC performance was attributed to a certain synergistic effect of the bilayer heterostructure on the light absorption and electron-hole recombination processes.

• 콘크리트학회논문집
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• 제22권2호
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• pp.179-186
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• 2010

철근과 콘크리트의 부착은 콘크리트와 철근의 일체거동에 의한 안전성 확보를 위해서도 필요하지만, 적정수준의 연성을 확보하여, 부재의 거동을 조절하기 위해서도 필요하다. 현재까지 반복하중 하에서의 부착응력-슬립관계에 대한 연구는 진행되어 왔으나, 철근 부식이 이루어진 경우의 반복하중 하에서의 부착응력-슬립관계에 대한 연구는 거의 없는 실정이다. 따라서 이 연구에서는 부식된 철근의 부착 실험을 통하여 단조하중과 반복하중 하에서의 부식률에 따른 부착응력-슬립 관계를 살펴보았다. 실험결과로부터 철근 부식은 할열 균열이 발생하기 전까지는 단조하중에서의 부착강도를 증가시키는 것을 확인하였다. 그리고 반복하중 횟수와 반복하중 하에서의 슬립 및 잔류슬립을 이중로그스케일로 도시한 결과, 철근 부식이 있는 경우에도 철근 부식이 없는 경우와 마찬가지로 선형 관계임을 확인하였다. 그리고 부식에 의한 균열이 발생하지 않는 한, 철근 부식이 반복하중 재하 이후의 부착강도 및 부착강도에서의 슬립 등 부착 특성에 영향을 미치지 않는 것도 알 수 있었다. 마지막으로, 철근 부식으로 인한 균열이후에서의 응력수준에 따른 피로수명은 급격히 감소하는 것을 확인하였다. 이 연구에서 제시하는 철근 부식을 고려한 반복하중 하에서의 부착응력-슬립의 관계는 철근콘크리트 구조물의 내구수명 예측 시 유용하게 사용될 수 있을 것으로 사료된다.