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  • Title/Summary/Keyword: spinel structure

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Effects of heat treatment and substrates on luminescent characteristics of ZnGa_O_4:Mn thin film phosphor (열처리조건과 기판이 ZnGa_O_4:Mn 박막 형광체의 발광특성에 미치는 영향)

  • Chung, Sung-Mook;Kim, Young-Jin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.05a
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    • pp.181-184
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    • 2004
  • The green emitting phosphor, ZnGa2O4:Mn thin film with spinel structure were deposited by rf magnetron sputtering. Thin film phosphors were heat-treated in nitrogen, vacuum and air atmosphere, respectively. The effects of the substrates, heat-treatment conditions and the sputtering parameters were investigated. The growing behavior and luminescent properties of thin films depend on the crystallinity of the substrates. The Ga/Zn atomic ratios and luminescent characteristics were dependent on the annealing conditions.

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Synthesis and Electrochemical Characteristics of Li0.7[Ni0.05Mn0.95]O2 as a Positive Material for Rechargeable Lithium Batteries

  • Shin, Sun-Sik;Kim, Dong-Won;Sun, Yang-Kook
    • Bulletin of the Korean Chemical Society
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    • v.23 no.5
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    • pp.679-682
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    • 2002
  • Layered Na0.7[Ni0.05Mn0.95]O2 compounds have been synthesized by a sol-gel method, using glycolic acid as a chelating agent. Na0.7[Ni0.05Mn0.95]O2 precursors w ere used to prepare layered lithium manganese oxides by ion exchange for Na by Li, using LiBr in hexanol. Powder X-ray diffraction shows the layered Na0.7[Ni0.05Mn0.95]O2 has an O3 type structure, which exhibits a large reversible capacity of approximately 190 mA h g-1 in the 2.4-4.5 V range. Na0.7[Ni0.05Mn0.95]O2 powders undergo transformation to spinel during cycling.

Growing and Luminous Characterization of ZnGa2O4:Mn Thin Film Deposited by RF Magnetron Sputtering (RF 스퍼터링 방법에 의한 ZnGa2O4:Mn 박막의 성장거동과 발광특성)

  • 정승묵;김영진
    • Journal of the Korean Ceramic Society
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    • v.40 no.7
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    • pp.652-656
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    • 2003
  • The green emitting phosphor, BnGa2O4:Mn thin films with spinel structure were deposited by rf magnetron sputtering at various Ar/O2 ratios. Thin film phosphors were heat-treated in air and N2+vacuum atmosphere, respectively. Effects of Ar/O2 ratios and annealing conditions on the structural and photoluminescence (PL) and cathodeluminescence (CL) properties were investigated. Luminous properties were more improved by inhibiting the films from contacting with oxygen during heat treatment.

Making sung lass lens by using ferrite plating and the effect of cutting off ultraviolet (페라이트 도금법에 의한 선글라스 렌즈의 제작과 자외선 차단효과)

  • Ha, T.W.;Cha, J.W.
    • Journal of Korean Ophthalmic Optics Society
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    • v.7 no.1
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    • pp.35-38
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    • 2002
  • Ferrite thin film with glass substrate was prepared by ferrite plating method in order to make sunglass which cut off ultraviolet and electromagnetic field. It has single phase of polycrystalline spinel structure and has gloss like as mirror and has hardness without scratch by scraping with nail. The transmittance of ferrite thin film is lowered near 400nm manifestly, which shows that the ferrite thin film was cut off ultraviolet successfully. Therefore, the sunglass with ferrite plating is use of cut of ultraviolet and electromagnetic field.

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Properties of Co-Ferrite Nanoparticles Synthesized by Thermal Decomposition Method

  • Oh, Young-Woo;Liu, J.P.
    • Journal of Magnetics
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    • v.11 no.3
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    • pp.123-125
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    • 2006
  • Co-ferrite nanoparticles have been synthesized by the decomposition of iron(III) acetylacetonate, Fe(acac)3 and Co acetylacetonate, Co(acac)2 in benzyl/phenyl ether in the presence of oleic acid and oleyl amine at the refluxing temperature of 295C/265C for 30 min. before cooling to room temperature. Particle diameter detected by PSA can be turned from 4 nm to 20 nm by seed-mediated growth and reaction conditions. Structural and magnetic characterization of Co-ferrite were measured by use of HRTEM, SAED (selected area electron diffraction), XRD and SQUID. The as-synthesized Co-ferrite nanoparticles have a cubic spinel structure and coercivity of 20 nm $CoFe_{2}O_{4} nanoparticles reached 1 kOe at room temperature and 18 kOe at 10 K.

The PTCR Effect of Semiconducting Zn-Ti-Ni-O Ceramics (Zn-Ti-Ni-O 반도성 세라믹스의 PTCR 현상)

  • Ko, Il-Young;Choi, Seung-Chul;Kim, Hwan
    • Journal of the Korean Ceramic Society
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    • v.30 no.8
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    • pp.609-614
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    • 1993
  • Semiconducting Zn-Ti-Ni-O and Zn-Ti-O system were investigated. The specimens sintered at the temperature between 1250C and 1450C exhibited PTCR effect between -50C and 350C with resistivity ration exceeding three decades. Semiconducting Zn-Ti-Ni-O is consisted of two phases, one is n-type ZnO and the other is p-type spinel structure. The mechanism of PTCR effect was explained in relation to the piezoelectric property of ZnO and the residual stress caused by thermal expansion difference between two phases during cooling process.

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Superparamagnetic Gd- and Mn-substituted Magnetite Fluids Applied as MRI Contrast Agents

  • Kim, Jong-Hee;Lee, Chang-Hyun;Lee, Sang-Kuk
    • Bulletin of the Korean Chemical Society
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    • v.30 no.6
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    • pp.1305-1308
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    • 2009
  • The experimental particle samples included (Mn0.1Fe0.9)O-Fe2O3 and FeO-(Gd0.1Fe0.9)2O3 with Mn2+andGd3+ substitutions in inverse spinel Fe3O4. A lecithin surfactant was adsorbed onto the magnetic particles by ultrasonication. The samples prepared showed excellent dispersibility at the mean size of 13 nm; their saturation magnetization values were 63 emu/g for the bare and Mn-substituted magnetites, and 56 emu/g for the Gd-substituted magnetite. The crystal structure of the substituted magnetites was very similar to that of the bare magnetite, due to a small amount of 0.1 mole fraction substituted in synthesizing the magnetite. The magnetite fluids, according to T2-weighted MR images, effectively diminished the signal intensity in the liver and spleen of Sprague-Dawley rats.

HEISENBERG GROUPS - A UNIFYING STRUCTURE OF SIGNAL THEORY, HOLOGRAPHY AND QUANTUM INFORMATION THEORY

  • Binz, Ernst;Pods, Sonja;Schempp, Walter
    • Journal of applied mathematics & informatics
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    • v.11 no.1_2
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    • pp.1-57
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    • 2003
  • Vector fields in three-space admit bundles of internal variables such as a Heisenberg algebra bundle. Information transmission along field lines of vector fields is described by a wave linked to the Schrodinger representation in the realm of time-frequency analysis. The preservation of local information causes geometric optics and a quantization scheme. A natural circle bundle models quantum information visualized by holographic methods. Features of this setting are applied to magnetic resonance imaging.

Liquid Phase Deposition of Transition Metal Ferrite Thin Films: Synthesis and Magnetic Properties

  • Caruntu Gabriel;O'Connor Charles J.
    • Journal of the Korean Ceramic Society
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    • v.43 no.11 s.294
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    • pp.703-709
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    • 2006
  • We report on the synthesis of highly uniform, single phase zinc and cobalt thin films prepared by the Liquid Phase Deposition (LPD) method. X-Ray diffraction, TGA and EDX measurements support the assumption that the as deposited films are constituted by a mixture of crystallized FeOOH and amorphous M(OH)2 (M=Co, Zn) which is converted upon heat treatment in air at 600?C into the corresponding zinc ferrites. The films with adjustable chemical compositions are identified with a crystal structure as spinel-type and present a spherical or rod-like microstructure, depending on the both the nature and concentration of the divalent transition metal ions. Zinc ferrite thin films present a superparamagnetic behavior above blocking temperatures which decrease with increasing the Zn content and are ferromagnetic at 5 K with coercivities ranging between 797.8 and 948.5 Oe, whereas the cobalt ferrite films are ferromagnetic at room temperature with magnetic characteristics strongly dependent on the chemical composition.

Abnormal Grain Growth Mechanism of Calcium Hexaluminate Phase

  • Song, Jun-Ho;Jo, Young-Jin;Bang, Hee-Gon;Park, Sang-Yeup
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.525-526
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    • 2006
  • Calcium-hexaluminate phase (CA6) is known to be effective for the crack shielding due to the spinel block crystal structure. In this study, we focused to the control of CA6 morphology for good damage tolerance behavior in alumina and zirconia/calcium-hexaluminate (CA6) composites. Calcium-hexaluminate (CA6) composites were prepared from zirconia, alumina and calcium carbornate powders. Calcium-hexaluminate (CA6) phase was obtained by the solid reaction through the formation of intermediate phase (CA2). CA6 phase showed the column type abnormal grain grown behavior composed of small blocks. Due to the typical microstructure of CA6, alumina and zirconia/calcium-hexaluminate composites provide a well controlled crack propagation behavior.

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