• 제목/요약/키워드: spin-structure

검색결과 727건 처리시간 0.026초

졸겔 스핀 코팅에서 질산촉매가 티탄산연 박막의 물성에 미치는 영향 (The Effect of Nitric Acid Catalyst on the Properties of Lead Titanate Thin Films by Sol Gel Spin Coating)

  • 이전국;정형진;김종희
    • 한국세라믹학회지
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    • 제28권11호
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    • pp.859-864
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    • 1991
  • High quality lead titanate thin films were fabricated by spin coating on a silicon substrate. The resulting dried gel layers were uniform in thickness through 2$\times$2 $\textrm{cm}^2$ area, and polycrystalline perovskite structures developed almost crack free with a heat treatment above 50$0^{\circ}C$ in films with thickness above 360 nm. Metastable pyrochlore structures were observed in films with thickness of 160 nm when heat treated at 500 and $600^{\circ}C$, but these structure did not appear in films with thickness of 360 nm. The thickness dependence in crystal structure of films was studied. by varying the substrate condition and analyzing the interface between the film and substrate. In native oxide films on silicon stbstrates, amorphous dried gel layers were heterogeneously nucleated. Metastable cubic pyrochlore structure could be crystallized in amorphous native oxide.

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The LS$\rightarrow$HS Transition of Cobalt(III) in an Oxygen Lattice with the $K_2NiF_4$-Type Structure: Correlations with the Chemical Bonding Environment of the $(CoO_6)$ Octahedron Along the c-axis

  • Byeon, Song-Ho;Demazeau, Gerard
    • Bulletin of the Korean Chemical Society
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    • 제15권11호
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    • pp.949-953
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    • 1994
  • In oxides characterized by the $K_2NiF_4-type$ structure, the low-spin${\to}$high-spin transition of trivalent cobalt ion was studied in function of the nature of competing bonds in the perovskite-plane and along the c-axis. Using Slichter and Drickamer's model the calculated values of parameters characterizing such a transition are correlated with the covalency of competing bonds along the c-axis of the $K_2NiF_4$-structure and the local structural distortion of the $(CoO_6)$ octahedron.

Peierls Instability and Spin Ordering in Graphene

  • 김현중;조준형
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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    • pp.204-204
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    • 2012
  • Peierls instability and spin ordering of zigzag graphene nanoribbons (GNR) created on a fully hydrogenated graphene (graphane) are investigated as a function of their width using first-principles density-functional calculations within the generalized-gradient approximation. For the width containing a single zigzag C chain (N=1), we find the presence of a Peierls instability with a bond alternated structure. However, for width greater than N=1, the Peierls distortion is weakened or disappears because of the incommensurate feature of Fermi surface nesting due to the interaction of C chains. Instead, there exists the antiferromagnetic (AFM) spin ordering in which the edge states are ferromagnetically ordered but the two ferromagnetic (FM) edges are antiferromagnetically coupled with each other, showing that electron-lattice coupling and spin ordering in GNR are delicately competing at an extremely thin width of N=2. It is found that, as the width of GNR increases, the energy gain arising from spin ordering is enhanced, but the energy difference between the AFM and FM (where two edge states are ferromagnetically coupled with each other) orderings decreases.

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Spin coating 공정을 이용한 Polymethyl methacrylate (PMMA) 박막의 polymer gate dielectric layer로써의 특성평가 (Properties of Polymethyl methacrylate (PMMA) for Polymer Gate Dielectric Thin Films Prepared by Spin Coating)

  • 나문경;강동필;안명상;명인혜;강영택
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 춘계학술대회 논문집
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    • pp.29-32
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    • 2005
  • Poly (methyl methacrylate) (PMMA) is one of the promising representive of polymer gate dielectric for its high resistivity and sutible dielectric constant. PMMA (Mw=96700) films were prepared on p-Si by spin coating method. PMMA were coated compactively and flatly as observeed by AFM. MIS(Al/PMMA/p-Si) structure was made and capacitance-voltage (C-V) and current-voltage (I-V) measurements were done with PMMA films for different thermal treatment temperature. PMMA films were showed proper dielectric constant and breakdown voltage. Above the glass transition temperature PMMA films degraded. C-V measured at various frequencies, dielectric constant increased a little. The absence of hysteresis in the C-V characteristics, which eliminate the possibility of mobile charges in the PMMA films. The observed thermal stability, smooth surfaces, dielectric constant, I-V behavior implies PMMA formed by spin coating can be used as an efficient gate dielectric layer in OTFTs.

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Size and Aspect Ratio Effects on the Magnetic Properties of a Spin-Valve Multilayer by Computer Simulation

  • Lim, S.H.;Han, S.H.;Shin, K.H.;Kim, H.J.
    • Journal of Magnetics
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    • 제5권3호
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    • pp.90-98
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    • 2000
  • The change in the magnetic properties of a spin-valve multilayer with the structure IrMn (9 m)/CoFe (4 nm)/Cu (2.6 nm)/CoFe (2 nm)/NiEe (6 nm) is investigated as a function of the size and the aspect ratio. At a fixed aspect ratio (the length/width ratio) of 2, the magnetostatic interactions begin to affect the magnetic properties substantially at a spin-valve length of 5 $\mum$, and, at a length of 1 $\mum$, they become even more dominant. In the case of a fixed multilayer size (2.4 $\mum$) which is indicated by the sum of the length and the width, magnetization change occurs by continuous spin-reversal and M-H loops are characterized by no or very small hysteresis at aspect ratios smaller than unity, At aspect ratios greater than unity, magnetization change occurs by spin-flip resulting in squared hysteresis loops. A very large changes in the coercivity and the bias field is observed, and these results are explained by two separate contributions to the total magnetostatic interactions: the coercivity by the self-demagnetizing field and the bias field by the interlayer magnetostatic interaction field.

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위상절연체 소재 및 소자 기술 개발 동향 (Research Trend of Topological Insulator Materials and Devices)

  • 이우정;황태하;조대형;정용덕
    • 전자통신동향분석
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    • 제38권1호
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    • pp.17-25
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    • 2023
  • Topological insulators (TIs) emerge as one of the most fascinating and amazing material in physics and electronics. TIs intrinsically possess both gapless conducting surface and insulating internal properties, instead of being only one property such as conducting, semiconducting, and insulating. The conducting surface state of TIs is the consequence of band inversion induced by strong spin-orbit coupling. Combined with broken inversion symmetry, the surface electronic band structure consists of spin helical Dirac cone, which allows spin of carriers governed by the direction of its momentum, and prohibits backscattering of the carriers. It is called by topological surface states (TSS). In this paper, we investigated the TIs materials and their unique properties and denoted the fabrication method of TIs such as deposition and exfoliation techniques. Since it is hard to observe the TSS, we introduced several specialized analysis tools such as angle-resolved photoemission spectroscopy, spin-momentum locking, and weak antilocalization. Finally, we reviewed the various fields to utilize the unique properties of TIs and summarized research trends of their applications.

CoFe/Cu/NiFe Pseudo스핀밸브의 자기저항 특성 (The Giant Magnetoresistance Properties of CoFe/Cu/NiFe Pseudo Spin Valve)

  • 최원준;홍진표;김태송;김광윤
    • 한국자기학회지
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    • 제12권6호
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    • pp.212-217
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    • 2002
  • 비자성층을 사이에 둔 두 강자성층의 보자력 차이를 이용하여 거대자기저항특성을 나타내는 Ta/CoFe/Cu/NiFe/Ta 구조의 pseudo 스핀밸브를 DC 마그네트론 스퍼터링 방법으로 제조하였다. Ta/CoFe/Cu/NiFe/Ta 구조에서 CoFe층의 두께 변화에 따른 자화 특성 및 자기저항 특성을 조사하였으며, 이 구조에서 CoFe층의 두께가 60 $\AA$일 때 자기저항비는 3.82%이고 CoFe층과 NiFe층 사이의 보자력 차이는 27.4 Oe이다. Ta/CoFe/Cu/NiFe/Ta 구조를 갖는 pseudo 스핀밸브에서 CoFe층과 NiFe층의 보자력 차이는 CoFe층의 두께가 20 $\AA$에서 40 $\AA$까지 증가함에 따라 증가하였으며 40 $\AA$ 이상에서는 감소하였다. 이와 같은 결과는 박막의 결정성 및 포화 자기변형(λ$_{s}$)의 변화에 의한 것으로 판단된다. Cu층과 NiFe층 사이에 CoFe층을 삽입한 Ta/CoFe/Cu/NiFe/Ta 구조에서 삽입층인 CoFe층의 두께 변화에 따른 자화특성 및 자기저항 특성을 조사한 결과 CoFe두께가 10$\AA$시 자기저항비가 6.7 %이며. 삼층막 구조 보다 자기저항비가 약 1.5배 이상 증가함을 알 수 있었다.

Evidence of Spin Reorientation by Mössbauer Analysis

  • Myoung, Bo Ra;Kim, Sam Jin;Kim, Chul Sung
    • Journal of Magnetics
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    • 제19권2호
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    • pp.126-129
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    • 2014
  • We report the crystallographic and magnetic properties of $Ni_{0.3}Fe_{0.7}Ga_2S_4$ by means of X-ray diffractometer (XRD), a superconducting quantum interference device (SQUID) magnetometer, and a M$\ddot{o}$ssbauer spectroscopy. In particular, $Ni_{0.3}Fe_{0.7}Ga_2S_4$ was studied by M$\ddot{o}$ssbauer analysis for evidence of spin reorientation. The chalcogenide material $Ni_{0.3}Fe_{0.7}Ga_2S_4$ was fabricated by a direct reaction method. XRD analysis confirmed that $Ni_{0.3}Fe_{0.7}Ga_2S_4$ has a 2-dimension (2-D) triangular lattice structure, with space group P-3m1. The M$\ddot{o}$ssbauer spectra of $Ni_{0.3}Fe_{0.7}Ga_2S_4$ at spectra at various temperatures from 4.2 to 300 K showed that the spectrum at 4.2 K has a severely distorted 8-line shape, as spin liquid. Electric quadrupole splitting, $E_Q$ has anomalous two-points of temperature dependence of $E_Q$ curve as freezing temperature, $T_f=11K$, and N$\acute{e}$el temperature, $T_N=26K$. This suggests that there appears to be a slowly-fluctuating "spin gel" state between $T_f$ and $T_N$, caused by non-paramagnetic spin state below $T_N$. This comes from charge re-distribution due to spin-orientation above $T_f$, and $T_N$, due to the changing $E_Q$ at various temperatures. Isomer shift value ($0.7mm/s{\leq}{\delta}{\leq}0.9mm/s$) shows that the charge states are ferrous ($Fe^{2+}$), for all temperature range. The Debye temperature for the octahedral site was found to be ${\Theta}_D=260K$.

Ta/NiFe/Cu/Co Pseudo 스핀밸브 구조의 자기저항 효과 (Magnetoresistance Effect of Ta/NiFe/Cu/Co Pseudo Spin Valve Structure)

  • 주호완;최진협;최상대;이기암
    • 한국자기학회지
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    • 제14권1호
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    • pp.25-28
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    • 2004
  • Ta/NiFe/Cu/Co 구조의 Pseudo 스핀밸브 박막을 제작하여 NiFe, Cu, Co 각 층들의 두께변화에 따른 자기저항비(MR-ratio), 보자력, 자기 민감도(sensitivity), 반전자장(Switching Field)의 크기 등의 자기적 특성을 연구하였다. 각 층들의 두께를 변화시키면서 측정한 결과 Ta(4 nm)/NiFe(7.5 nm)/Cu(3 nm)/Co(5 nm)에서 최대 자기저항비 7.26 %를 얻을 수 있었다. 또한 각 층들의 독립적인 자화 과정을 통해 자기저항 특성을 조절할 수 있었다. 특히 Co의 두께를 변화시켜 자기저항비를 비교적 일정하게 유지하면서 보자력의 크기를 조절할 수 있음을 알게 되었다.

에피성장된 Fe/GaAs (001) 적층구조에서의 스핀 주입 및 검출 (Electrical spin injection and detection in epitaxially grown Fe/GaAs (001) hybrid structure)

  • 이태환;구현철;김경호;김형준;한석희;임상호
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 추계학술대회 논문집 Vol.21
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    • pp.357-357
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    • 2008
  • 에피성장된 Fe/GaAs 적층구조에서의 스핀 주입 실험을 하였다. Fe와 GaAs 사이에 Schottky tunnel barrier를 형성시키기 위하여 높게 도핑된 GaAs 층을 channel 층 위에 성장하였다. 스핀전달에 의한 chemical potential 차이만을 검출하기 위해서 전압 측정 단자 사이에 전류 흐름이 포함되지 않는 non-local 측정방법을 사용하였다. 그 결과 두 강자성 전극이 반평행한 구간에서 dip이 나타나는 것을 확인할 수 있었다.

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