• 대한화학회지
• /
• 제20권5호
• /
• pp.364-373
• /
• 1976

多原子分子內의 內部廻轉子上에 있는 磁氣核은 分子의 全體廻轉으로 因하여 생기는 磁氣場뿐만 아니라 內部廻轉에 基因하는 磁氣場과도 相互作用할 수 있다. 이 論文에서는 多原子分子內의 內部廻轉子上에 있는 核스핀에 對한 스핀-廻轉相互作用 Hamiltonian을 誘導하였다. 誘導된 Hamiltonian은 스핀과 全體廻轉間의 相互作用을 나타내는 部分 및 스핀과 內部廻轉間의 相互作用을 나타내는 部分과의 合으로 이루어져 있음을 밝혔다. 스핀-廻轉相互作用 tensor와 磁氣的 가리움效果 間의 關係도 또한 調査하였다.

• Bulletin of the Korean Chemical Society
• /
• 제4권1호
• /
• pp.48-54
• /
• 1983

A magnetic nucleus located on an internal rotor can interact with magnetic fields arising from end-over-end molecular rotation as well as internal rotation. In this paper the expressions for spin-rotational relaxation times, $T_{1.SR}\;and\;T_{2.SR}$, are derived for such nucleus with the anisotropy of molecular rotation explicitly taken into consideration. The derived expressions are shown to be composed of two parts, the contribution from spin-overall-rotation coupling and that from spin-internal-rotation coupling. Some remarks on the use of derived expressions are also provided.

• Journal of Magnetics
• /
• 제16권1호
• /
• pp.23-26
• /
• 2011

The effects of titanium ions on the crystallographic and spin-rotation transitions in iron sulfide have been examined by M$\"{o}$ssbauer spectroscopy in the temperature range of 78 to 600 K. It is noted that the titanium impurity of $Ti_{0.02}Fe_{0.98}S$ affects both the crystallographic and spin-rotation transitions of the iron sulfide. 2% impurity of $Ti^{2+}$ in FeS causes the increase in the difference between the spin rotation and ${\alpha}$ transition temperature by as much as 10 K compared with that for FeS. Both 1c and 2c structures coexist in the range between the ${\alpha}$ transition temperature and approximately 26 K, with a smaller hyperfine field corresponding to the 1c structure. The spin-rotation temperature for $Ti_{0.02}Fe_{0.98}S$ was measured to be 365 K, which is 10 K lower than the ${\alpha}$ transition temperature. By the 2% impurity of $Ti^{2+}$ in FeS the N$\'{e}$el temperature appreciably is not affected.

• 한국자기공명학회논문지
• /
• 제2권1호
• /
• pp.66-83
• /
• 1998

Study on spin-rotation relaxation of nuclear spins located on a methyl group can reveal valuable dynamic information related to the internal rotation of methyl group itself. Toward this end we have measured methyl carbon-13 spin-rotation of methyl group itself. Toward this end we have measured methyl carbon-13 spin-rotational relaxation rate in toluene and 2-chloro-p-xylene over the temperature range of 179-363K. To interpret the temperature dependence of measured spin-rotational relaxation rate we have revised the temperature dependence of measured spin-rotational relaxation rate we have revised the expression derived thus far by other authors and reproduced experimental data on the basis of the newly derived expression. The results confirmed that our expression leads to better agreement with experimental data than the previous one over observed temperature range, especially at high temperature.

• 천문학회보
• /
• 제37권2호
• /
• pp.159.1-159.1
• /
• 2012

From the most recent dataset of the earth's spin rotation, we separate different frequency components of its perturbation and analyze their characteristics. Both changes of the earth's spin and pole position are considered.

• 대한기계학회:학술대회논문집
• /
• 대한기계학회 2001년도 춘계학술대회논문집E
• /
• pp.456-462
• /
• 2001

Comprehensive numerical computations are made of a homogenous spin-up in a cylindrical cavity with a time-dependent rotation rate. Numerical solutions are acquired to the governing axisymmetric cylindrical Navier-Stokes equation. A rotation rate formula is ${\Omega}_f={\Omega}_i+{\Delta}{\Omega}(1-{\exp}(-t/t_c))$. If $t_c$ is large, it implies that a rotation change rate is small. The Ekman number, E, is set to $10^{-4}$ and the aspect ratio, R/H, fixed to I. For a linear spin-up(${\epsilon}<<$), the major contributor to spin-up in the interior is not viscous-diffusion term but inviscid term, especially Coriolis term, though $t_c$ is very large. The viscous-diffusion term only works near sidewall. But for spin-up from rest, when $t_c$ is very large, viscous-diffusion term affects interior area as well as sidewall, initially. So azimuthal velocity of interior for large $t_c$ appears faster than that of interior for relatively small $t_c$. However, the viscous-diffusion term of interior decreases as time increases. Instead, inviscid term appears in the interior.

• 한국섬유공학회:학술대회논문집
• /
• 한국섬유공학회 1990년도 제2차 학술발표초록집
• /
• pp.67-67
• /
• 1990

Three non-ionic and two anioinic spin probes, differing in size and substituent, were synthesized. Their mobility in dried nylon 6 film was investicated by the spin probe technique using electron spin resonance spectrometer. When the size of a spin probe was large and the interaction between the probe molecules and polymer chains existed, the mobility of spin probes decreased. From Arrhenius plots of rotational correlation time, one discontinuity point ($T_d$) was determined. The activation energies for rotation below and above $T_d$ were discussed in terms of the mode of probe rotation. Three spin probes could be viewed as azo dyes having a built-in nitroxide radical. Photolysis of them in dimethylformamide and in nylon 6 film was performed by exposure to 254 nm UV light in the presence of air. It was found that dyes having a built-in nitroxide radical showed better photostability than dyes derived from ${\bata}-naphthol$..

• 대한기계학회논문집
• /
• 제19권3호
• /
• pp.771-783
• /
• 1995

A simplified model for the so-called ACRT(accelerated crucible rotation technique) Bridgman crystal growth was considered in order to investigate the principal effects of the periodic variation of angular velocity. Numerical solutions were obtained for Ro=0.5, Ra=4.236*10$_{6}$ and E=2.176*10$^{-3}$ . The effects of spin-up process combined with natural convection was investigated as a preliminary study. The spin-up time scale for the present problem was a little larger than that observed for homogeneous spin-up problems. Numerical results reveal that over a time scale of (H$^{2}$/.nu..omega.$_{f}$)$^{1}$2/ the forced convection due to the formation of Ekman layer predominates. When the state of rigid body rotation is attained, natural convection due to buoyancy emerges as the main driving force and them the steady-state is approached asymptotically. Based on our preliminary results with simple spin-up, several fundamental features associated with variation of rotation speed are successfully identified. When a periodic variation of angular velocity was imposed, the system response was also periodic. Due to effect of mixing, the heat transfer was enlarged. From the analysis of time-averaged Nusselt number along the bottom surface the effect of a periodic variation of angular velocity on the interface location could be indirectly identified.d.

• 한국정밀공학회지
• /
• 제22권6호
• /
• pp.144-151
• /
• 2005

Spin coater is regarded as a major module rotating at high speed to be used build up polymer resin thin film layer fur bonding process of GaAs wafer. This module is consisted of spin unit for spreading uniformly, align device, resin spreading nozzle and et. al. Specially, spin unit which is a component of module can cause to vibrate and finally affect to the uniformity of polymer resin film layer. For the stability prediction of rotation velocity and uniformity of polymer resin film layer, it is very important to understand the dynamic characteristics of assembled spin coater module and the dynamic response mode resulted from rotation behavior of spin chuck. In this paper, stress concentration mode and the deformed shape of spin chuck generated due to angular acceleration process are presented using analytical method for evaluation of structural safety according to the revolution speed variation of spin unit. And also, deformation form of GaAs wafer due to dynamic behavior of spin chuck is presented fur the comparison of former simulated results.

• 대한기계학회논문집B
• /
• 제25권3호
• /
• pp.339-346
• /
• 2001

The impulsive spin-up flow in a shallow rectangular container is analyzed numerically by quasi 3-D unsteady laminar flow. In the non-inertia coordinates, the flow is generated by the virtual forces as Coriolis force, etc.. After the boundary layers grow up near sidewalls, primary vortexes separate from the sidewalls. As the Reynolds number increases, the subsidiary vortexes take place in the boundary layer. The rigid body rotation is started from the inner region and propagated to the outer region, finally all the fluid reaches the rigid body rotation. According to the Reynolds number and the aspect ratio, the development of vortex pattern is symmetric or asymmetric.