• Journal of the Korean Society for Marine Environment & Energy
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• v.15 no.3
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• pp.238-246
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• 2012

Once oil is spilled into marine environment, it experiences various weathering processes among which evaporation is the most dominant process in the initial stage of weathering. This study aimed to elucidate the effects of evaporation on the physicochemical properties of spilled oil using standardized laboratory experiments. Laboratory evaporation process was successfully reproduced using controlled rotary evaporation method. In case of Iranian Heavy crude (IHC), evaporation rate after 48 hours was $29.3{\pm}0.4%$ (n=40, p<0.001). Evaporation was simulated using ADIOS2 weathering model and the result was in agreement with laboratory experiment. Chemical composition changes of petroleum hydrocarbons including alkanes, polycyclic aromatic hydrocarbons (PAHs) and biomarkers by evaporation rate were also analyzed. As oil evaporated, low molecular weight alkanes and PAHs decreased, while biomakers showed conservative characteristics. Among biomarkers, $17{\alpha}(H)$, $21{\beta}(H)$-hopane was used for calculation of weathering rates, which matched with evaporative mass losses. Weathering rate calculation using hopane showed that stranded oils of weathering stage I (28.9%) and mesocosm oil weathering experiment till 5 days (26.5%) were mainly affected by evaporation process.

• Textile Coloration and Finishing
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• v.23 no.3
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• pp.210-218
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• 2011

The structure of kapok fiber was characterized using FTIR and $^{13}C$-NMR spectrometers, elemental analyzer, x-ray diffractometer, SEM and IMT I-Solution ver 7.5. The kapok has a hollow tube shape and is composed of cellulose I with crystallinity of 47.95%. To develop novel oil-sorbent materials necessary to avoid the environmental pollution by spilled oil, the oil absorption capacity of various fibers such as kapok, polypropylene(PP), acryl, bamboo, cotton, rayon and wool fibers is compared in this study. The kapok fiber had the highest oil absorption capacity among the fibers and its water absorption capacity was the least. The kapok fiber selectively absorbed significant amounts of oils (43g/g of fiber for kerosene, 65g/g of fiber for soybean oil), which might be due to higher hydrophobicity of the kapok fiber, suggesting that kapok fiber may have high potential as excellent oil-absorbent materials.

• Journal of the Korean Society for Marine Environment & Energy
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• v.3 no.3
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• pp.58-65
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• 2000

Responses to marine oil spills can be classified Into categories; 1) mechanical treatment using booms and skimmers, 2) chemical one utilizing dispersants, 3) controlled in-situ burning of spilled oils. In the present paper, characteristics, history, present issues, advantages and disadvanteges, and future applicability of in-situ burning technology which is nowadays winning much attention are summarized on the basis of a survey of related papers and other resources.

• Proceedings of the Korean Institute of Navigation and Port Research Conference
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• 1998.10a
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• pp.211-221
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• 1998

A digital image processing technique which is able to get the velocity vector distribution of a surface of the spilled oil in the ocean without contacting the flow itself. This technique is based upon the PIV(Particle Imaging Velocimetry) technique and its system mainly consists of a high sensitive camera, a CCD camera, an image grabber, and a host computer in which an image processing algorithm is adopted for velocity vector acquisition. For the acquisition of the advective velocity vector of floating matters on the ocean, a new multi-frame tracking algorithm is proposed, and for the acquisition of the diffusion velocity vector distribution of the spilt oil onto the water surface, a high sensitive gray-level cross-correlation algorithm is proposed.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2006.04a
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• pp.424-427
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• 2006

Soil contamination with petroleum oil around a military army was investigated. It showed that soils of a riverside highland, an entrance of the military army, and nearby roads were contaminated with total petroleum hydrocarbons (TPH) released from the military army to the depth of approximately 2 m. The measured concentrations were as high as 15,277 mg/kg. A wide range of soil in the riverside highland was contaminated by the movement of oil to the surface soil, which occurred with the vertical movement of groundwater table caused by the change of river water level and groundwater level. Spilled petroleum oil components were released into Wonju Stream by the increase of hydraulic conductivity and the groundwater flow.

• Proceedings of the KSRS Conference
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• 2008.10a
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• pp.368-368
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• 2008

Oil spills are a principal factor of the ocean pollution. The complicated problems involved in detecting oil spills are usually due to varying wind and sea surface condition such as ocean wave and current. The Hebei Spirit accident was happened in the west sea ($36^{\circ}$41'04" N, $126^{\circ}$03'12" E) near about 8 km distant from Tae-An, Korea on December 7, 2007. The aim of this work is to improve the detection and classification performance in order to define a more accurate training set and identifying the feature of oil spill region. This paper deals with an optimization technique for the detection and classification scheme using multi-frequency and multi-polarization SAR and optical image data sets of the oil spilled sea. The used image data are the ENVISAT ASAR WS and Radarsat-1 of C-band and ALOS PALSAR of L-band SAR data and KOMPSAT-2 optical images together with meteorological or oceanographic data. Both the theory and the experimental results obtained are discussed.

• Journal of the Korean Society for Marine Environment & Energy
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• v.7 no.3
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• pp.122-130
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• 2004

Crude oil is complex mixture of thousands of different organic compound formed from a variety of organic materials that are chemically converted under differing geological conditions over long periods of time. Also oil composition varies according to crude source, refining, processing, handling and storage. The oil fingerprint method is application of specific knowledge of petrochemicals and use of sophisticated analytical equipment and techniques to identify the source(s) of oil pollution. KNMPA currently utilizes three primary analytical techniques: Gas Chromatography (GC), Fluorescence Spectroscopy(FL) and Infrared Spectroscopy(IR). Of all these techniques, GC technique are most widely used. Gas Chromatography is used as a primary analytical method because high reliableness, high separating efficiency and repeatability, but it is timeconsumable. The study results of identification of waterborne spilled oil by Fast Gas Chromatograph method showed that analytical time is cut down to 30minutes in comparison with packed column method and chromatograms represent high resolution and high repeatability.

• Journal of Ocean Engineering and Technology
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• v.19 no.4 s.65
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• pp.35-41
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• 2005

There has been increasing offshore oil exploration, drilling, and production activities, as well as a huge amount of petroleum being transported by tankers and pipelines through the ocean and costal environment. Assessment must be made of the potential risk of damage resulting from the exploration, development and transportation activities. This is achieved through predictive impact evaluations of the fate of hypothetical or real oil spills. VVhen an oil spill occurs, planning and execution of cleanup measures also require the capability to forecast the short-term and long-term behavior of the spilled oil. A great amount of effort has been spent by government agencies, oil industries, and researchers over the past decade to develop more realistic models for oil spills. Numerous oil spill models have been developed and applied, most of which attempt to predict the oil spill fate and behavior. For an actual contingency planning, the oil fate and behavior model should be combined with an oil spill incident model, an environmental impact and risk model and a contingency planning model. The purpose of this review study is to give an overview of existing oil spill models that deal with the physical, chemical, biological, and socia-economical aspects of the incident, fate, and environmental impact of oil spills. After reviewing the existing models, future research needs are suggested. In the study, available oil spill models are separated into oil spill incident, oil spill fate and behavior, environmental impact and risk, and contingency planning models. The processes of the oil spill fate and behavior are reviewed in detail and the characteristics of existing oil spill fate and behavior models are examined and classified so that an ideal model may be identified. Finally, future research needs are discussed.

• Journal of the Korean Society of Marine Environment & Safety
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• v.5 no.2
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• pp.1-14
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• 1999

To find characteristics and areas of greater risk of oil spill at the coastal waters in Korea, some of risk factors were analyzed with historical data of oil spill and marine traffic. As a result, it is characterized that frequency of oil spill is increasing year by year and greatest percentage of spill source is fishing boat. It is proposed that the ports of Ulsan, Yeosu, Incheon and Pusan will be designated as primary area of risk as they have a higher risk of oil spills and its response authority is required to maintain appropriate regional response capability for prompt and effective response to a future spill incident. In addition, the regional response equipments at Ulsan are examined under a assumption of a medium size spill and it is found that the use of chemical dispersant can be an alternative when mechanical containment and recovery is not feasible in this area, and the existing response equipments may be appropriate to address that size of spill. However, the response authority is required to maintain more numbers of stronger boom for unsheltered waters and more quantity of concentrate dispersant to disperse all spilled oils on the water, furthermore the response authority should be prepared for a possible future catastrophic spill with sufficient equipments.

• Journal of the Korean Society of Marine Environment & Safety
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• v.27 no.7
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• pp.1116-1123
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• 2021

Oil spilled in seawater undergoes physical and chemical changes as well as biological degradation through various weathering processes, such as evaporation, diffusion, dispersion, emulsification, dissolution, oxidation, and sedimentation. Evaporation is one of the most immediate and prompt weathering processes, and it has the greatest influence on majority of pollutants. In this study, the evaporation characteristics of different oil samples were studied; the volatilization characteristics of gasoline, kerosene, and diesel were compared at average seawater (25 ℃) and near-equator (35 ℃) temperatures. The oil samples were pre-treated and then collected at regular intervals. Gas chromatography-mass spectrometry analysis was performed, and the changes in the amount of the hydrocarbons were calculated.