• 한국해양환경ㆍ에너지학회지
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• 제15권3호
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• pp.238-246
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• 2012

해양으로 유출된 유류는 다양한 풍화과정을 통해 환경에서 제거되며, 증발이 유출사고 초기에 가장 우세한 풍화과정이다. 본 연구에서는 허베이스피리트호 사고유 중 이란산 원유를 대상으로 실험실에서 표준화된 증발실험을 실시하여 시간에 따른 물리화학적 변화를 관찰하였다. 증발과정에 영향을 미치는 유막두께, 풍속 등의 변수를 제어하여 48시간까지 노출한 결과 $29.3{\pm}0.4%$의 재현성 있는 결과를 산출하였다(n=40, p<0.001). 미국해양대기청의 풍화모델인 ADIOS2를 이용하여 환경조건에서 증발을 시뮬레이션한 결과 29%의 증발율을 구할 수 있었으며, 본 실험과 일치하는 결과를 확인하였다. 증발율에 따른 원유의 조성변화를 분석한 결과 저분자량의 알칸과 PAHs가 제거되었으나, 바이오마커 화합물은 증발에 의한 영향을 받지 않는 보전적인 특성을 나타냈다. 바이오마커 중 $17{\alpha}(H)$, $21{\beta}(H)$-hopane을 이용한 풍화율 계산값은 48시간 최종 값이 24.4%로 물리적인 증발에 따른 양적변화와 유사한 결과를 보였다. 호판을 이용한 풍화율 계산값 비교결과 사고 초기 현장 표착유(1단계 풍화 28.9%)와 메소코즘 풍화 실험 5일차(26.5%)까지는 풍화과정이 주로 증발에 의한 것으로 확인되었다.

• 한국염색가공학회지
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• 제23권3호
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• pp.210-218
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• 2011

The structure of kapok fiber was characterized using FTIR and $^{13}C$-NMR spectrometers, elemental analyzer, x-ray diffractometer, SEM and IMT I-Solution ver 7.5. The kapok has a hollow tube shape and is composed of cellulose I with crystallinity of 47.95%. To develop novel oil-sorbent materials necessary to avoid the environmental pollution by spilled oil, the oil absorption capacity of various fibers such as kapok, polypropylene(PP), acryl, bamboo, cotton, rayon and wool fibers is compared in this study. The kapok fiber had the highest oil absorption capacity among the fibers and its water absorption capacity was the least. The kapok fiber selectively absorbed significant amounts of oils (43g/g of fiber for kerosene, 65g/g of fiber for soybean oil), which might be due to higher hydrophobicity of the kapok fiber, suggesting that kapok fiber may have high potential as excellent oil-absorbent materials.

• 한국해양환경ㆍ에너지학회지
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• 제3권3호
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• pp.58-65
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• 2000

해상 누유사고시의 방제대책은 오일펜스와 스키머를 사용하는 기계적 방법과 유화제를 사용하는 화학적 방법 그리고 현장에서 누출유를 소각하는 현장소각 방법으로 대별된다. 본 논고는 최근에 들어 관심이 집중되고 있는 해상누유 현장소각 기술에 대한 문헌 조사를 기초로 하여 작성된 것으로써, 해상누유 현장소각 기술의 특징, 역산, 현황, 장단점 그리고 실험적 연구 및 향후 적용가능성 등에 대하여 간략히 기술하였다.

• 한국항해항만학회:학술대회논문집
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• 한국항해항만학회 1998년도 추계학술대회논문집:21세기에 대비한 지능형 통합항만관리
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• pp.211-221
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• 1998

A digital image processing technique which is able to get the velocity vector distribution of a surface of the spilled oil in the ocean without contacting the flow itself. This technique is based upon the PIV(Particle Imaging Velocimetry) technique and its system mainly consists of a high sensitive camera, a CCD camera, an image grabber, and a host computer in which an image processing algorithm is adopted for velocity vector acquisition. For the acquisition of the advective velocity vector of floating matters on the ocean, a new multi-frame tracking algorithm is proposed, and for the acquisition of the diffusion velocity vector distribution of the spilt oil onto the water surface, a high sensitive gray-level cross-correlation algorithm is proposed.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2006년도 총회 및 춘계학술발표회
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• pp.424-427
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• 2006

Soil contamination with petroleum oil around a military army was investigated. It showed that soils of a riverside highland, an entrance of the military army, and nearby roads were contaminated with total petroleum hydrocarbons (TPH) released from the military army to the depth of approximately 2 m. The measured concentrations were as high as 15,277 mg/kg. A wide range of soil in the riverside highland was contaminated by the movement of oil to the surface soil, which occurred with the vertical movement of groundwater table caused by the change of river water level and groundwater level. Spilled petroleum oil components were released into Wonju Stream by the increase of hydraulic conductivity and the groundwater flow.

• 대한원격탐사학회:학술대회논문집
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• 대한원격탐사학회 2008년도 International Symposium on Remote Sensing
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• pp.368-368
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• 2008

Oil spills are a principal factor of the ocean pollution. The complicated problems involved in detecting oil spills are usually due to varying wind and sea surface condition such as ocean wave and current. The Hebei Spirit accident was happened in the west sea ($36^{\circ}$41'04" N, $126^{\circ}$03'12" E) near about 8 km distant from Tae-An, Korea on December 7, 2007. The aim of this work is to improve the detection and classification performance in order to define a more accurate training set and identifying the feature of oil spill region. This paper deals with an optimization technique for the detection and classification scheme using multi-frequency and multi-polarization SAR and optical image data sets of the oil spilled sea. The used image data are the ENVISAT ASAR WS and Radarsat-1 of C-band and ALOS PALSAR of L-band SAR data and KOMPSAT-2 optical images together with meteorological or oceanographic data. Both the theory and the experimental results obtained are discussed.

• 한국해양환경ㆍ에너지학회지
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• 제7권3호
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• pp.122-130
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• 2004

원유는 유기물질들이 오랜기간에 걸쳐 서로 다른 지질학적 조건하에서 화학적으로 형성된 유기화합물질이다. 석유는 원유와 정제유를 포함하는 개념이며 정제유는 원유산지별, 정제, 처리, 취급 및 보관과정에 따라 구별되는 특징을 가지고 있다. 유지문기법은 이러한 특성을 이용하여 해상유출유의 오염원을 밝히기 위한 감식ㆍ분석기법을 말한다. 주로 사용되는 기기분석은 기체크로마토그래프법(GC), 형광분광광도법(FL), 적외선분광광도법(IR)이며 이중에서 가장 많이 사용되는 기법은 기체크로마토그래프법이다. 기체크로마토그래프를 이용한 유지문기법은 기기의 높은 신뢰성과 우수한 분리능 및 재현성으로 인하여 활용성이 높은 분석장비이나 해상유출유의 감식의 경우 비교적 시간이 많이 소요되는 경향이 있다. 본 연구에서는 이러한 단점을 보완하고자 최근 개발 보급된 패스트 기체크로마토그래프(fast GC)를 이용하여 기존의 분석시간을 1/2로 단축하고 분리능을 향상 시킬수 있는 분석방법에 대해 연구하였다.

• 한국해양공학회지
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• 제19권4호
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• pp.35-41
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• 2005

There has been increasing offshore oil exploration, drilling, and production activities, as well as a huge amount of petroleum being transported by tankers and pipelines through the ocean and costal environment. Assessment must be made of the potential risk of damage resulting from the exploration, development and transportation activities. This is achieved through predictive impact evaluations of the fate of hypothetical or real oil spills. VVhen an oil spill occurs, planning and execution of cleanup measures also require the capability to forecast the short-term and long-term behavior of the spilled oil. A great amount of effort has been spent by government agencies, oil industries, and researchers over the past decade to develop more realistic models for oil spills. Numerous oil spill models have been developed and applied, most of which attempt to predict the oil spill fate and behavior. For an actual contingency planning, the oil fate and behavior model should be combined with an oil spill incident model, an environmental impact and risk model and a contingency planning model. The purpose of this review study is to give an overview of existing oil spill models that deal with the physical, chemical, biological, and socia-economical aspects of the incident, fate, and environmental impact of oil spills. After reviewing the existing models, future research needs are suggested. In the study, available oil spill models are separated into oil spill incident, oil spill fate and behavior, environmental impact and risk, and contingency planning models. The processes of the oil spill fate and behavior are reviewed in detail and the characteristics of existing oil spill fate and behavior models are examined and classified so that an ideal model may be identified. Finally, future research needs are discussed.

• 해양환경안전학회지
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• 제5권2호
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• pp.1-14
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• 1999

To find characteristics and areas of greater risk of oil spill at the coastal waters in Korea, some of risk factors were analyzed with historical data of oil spill and marine traffic. As a result, it is characterized that frequency of oil spill is increasing year by year and greatest percentage of spill source is fishing boat. It is proposed that the ports of Ulsan, Yeosu, Incheon and Pusan will be designated as primary area of risk as they have a higher risk of oil spills and its response authority is required to maintain appropriate regional response capability for prompt and effective response to a future spill incident. In addition, the regional response equipments at Ulsan are examined under a assumption of a medium size spill and it is found that the use of chemical dispersant can be an alternative when mechanical containment and recovery is not feasible in this area, and the existing response equipments may be appropriate to address that size of spill. However, the response authority is required to maintain more numbers of stronger boom for unsheltered waters and more quantity of concentrate dispersant to disperse all spilled oils on the water, furthermore the response authority should be prepared for a possible future catastrophic spill with sufficient equipments.

• 해양환경안전학회지
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• 제27권7호
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• pp.1116-1123
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• 2021

해수에 유출된 유류는 대기와 해수와의 접촉을 통해 다양한 풍화 과정(증발, 확산, 분산, 유화, 용해, 산화, 침전 및 생물분해 등)을 통해 물리·화학적 변화와 함께 생물학적 분해과정을 겪는다. 본 연구에서는 여러 가지 풍화작용 중 가장 즉각적이고 빠르며 오염물질의 질량에 가장 큰 영향을 미치는 인자라고 알려진 증발(evaporation)에 대한 영향을 확인해보고자 하였다. 휘발유, 등유, 경유를 대상으로 25 ℃(해수 연평균 온도)와 35℃(적도 부근 온도) 조건에서 유류의 휘발특성을 비교하였다. 이를 위해, 일정 기간마다 채취한 유류를 전처리하여 GC/MS 분석을 수행하고, 탄화수소의 변화량을 계산하여 비교하였다.