• Title/Summary/Keyword: spherical rate

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Development and Analysis of the Highly Efficient Support System in a Liquid Hydrogen Vessel (액체수소 저장탱크용 고효율 지지 시스템 개발 및 해석)

  • Yun, Sang-Kook;Park, Dong-Heun
    • Journal of Advanced Marine Engineering and Technology
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    • v.31 no.4
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    • pp.363-369
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    • 2007
  • Probably the most significant heat transfer in the cryogenic liquid hydrogen storage tank from the atmosphere may occur through its support system. In this paper the efficient support system for the cryogenic storage vessel was newly developed and analysed. The support system was composed of a spherical ball as a supporter to reduce the contact area. which is located between two supporting SUS tubes inserted SUS and PTFE blocks. Numerical analyses for temperature distribution, and the thermal stress and strain of the support system were performed by the commercial codes FLUENT and ANSYS. The heat transfer rate of the supporter was evaluated by the thermal boundary potential method which can consider the variation of thermal conductivity with temperature. The results showed that the heat transfer rate through the developed supporter compared with the common SUS tube supporter was significantly reduced. The thermal stress and strain were obtained well below the limited values. It was found that the developed supporter can be one of the most efficient support systems for cryogenic liquid storage vessel.

Comparison of the Kinetic Behaviors of Fe2O3 Spherical Submicron Clusters and Fe2O3 Fine Powder Catalysts for CO Oxidation

  • Yoo, Seung-Gyun;Kim, Jin-Hoon;Kim, Un-Ho;Jung, Jin-Seung;Lee, Sung-Han
    • Bulletin of the Korean Chemical Society
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    • v.35 no.5
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    • pp.1379-1384
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    • 2014
  • ${\alpha}-Fe_2O_3$ spherical particles having an average diameter of ca. 420 nm and ${\alpha}-Fe_2O_3$ fine particles (< 10 ${\mu}m$ particle size) were prepared to examine as catalysts for CO oxidation. Kinetic studies on the catalytic reactions were performed in a flow reactor using an on-line gas chromatography system operated at 1 atm. The apparent activation energies and the partial orders with respect to CO and $O_2$ were determined from the rates of CO disappearance in the reaction stage showing a constant catalytic activity. In the temperature range of $150-275^{\circ}C$, the apparent activation energies were calculated to be 13.7 kcal/mol on the ${\alpha}-Fe_2O_3$ spherical submicron clusters and 15.0 kcal/mol on the ${\alpha}-Fe_2O_3$ fine powder. The Pco and $Po_2$ dependencies of rate were investigated at various partial pressures of CO and $O_2$ at $250^{\circ}C$. Zero-order kinetics were observed for $O_2$ on both the catalysts, but the reaction order for CO was observed as first-order on the ${\alpha}-Fe_2O_3$ fine powder and 0.75-order on the ${\alpha}-Fe_2O_3$ spherical submicron clusters. The catalytic processes including the inhibition process by $CO_2$ on the ${\alpha}-Fe_2O_3$ spherical submicron powder are discussed according to the kinetic results. The catalysts were characterized using XRD (X-ray powder diffraction), FE-SEM (field emission-scanning electron microscopy), HR-TEM (high resolution-transmission electron microscopy), and $N_2$ sorption measurements.

Spherical UO2 Kernel and TRISO Coated Particle Fabrication by GSP Method and CVD Technique (겔침전과 화학증착법에 의한 구형 UO2 입자와 TRISO 피복입자 제조)

  • Jeong, Kyung-Chai;Kim, Yeon-Ku;Oh, Seung-Chul;Cho, Moon-Sung
    • Journal of the Korean Ceramic Society
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    • v.47 no.6
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    • pp.590-597
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    • 2010
  • HTGR using a TRISO coated particles as nuclear raw fuel material can be used to produce clean hydrogen gas and process heat for a next-generation energy source. For these purposes, a TRISO coated particle was prepared with 3 pyro-carbon (buffer, IPyC, and OPyC) layers and 1 silicone carbide (SiC) layer using a CVD technique on a spherical $UO_2$ kernel surface as a fissile material. In this study, a spherical $UO_2$ particle was prepared using a modified sol-gel method with a vibrating nozzle system, and TRISO coating fabrication was carried out using a fluidized bed reactor with coating gases, such as acetylene, propylene, and methyltrichlorosilane (MTS). As the results of this study, a spherical $UO_2$ kernel with a sphericity of 1+0.06 was obtained, and the main process parameters in the $UO_2$ kernel preparation were the well-formed nature of the spherical ADU liquid droplets and the suitable temperature control in the thermal treatment of intermediate compounds in the ADU, $UO_3$, and $UO_2$ conversions. Also, the important parameters for the TRISO coating procedure were the coating temperature and feed rate of the feeding gas in the PyC layer coating, the coating temperature, and the volume fraction of the reactant and inert gases in the SiC deposition.

A Finite Element Galerkin High Order Filter for the Spherical Limited Area Model

  • Lee, Chung-Hui;Cheong, Hyeong-Bin;Kang, Hyun-Gyu
    • Journal of the Korean earth science society
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    • v.38 no.2
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    • pp.105-114
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    • 2017
  • Two dimensional finite element method with quadrilateral basis functions was applied to the spherical high order filter on the spherical surface limited area domain. The basis function consists of four shape functions which are defined on separate four grid boxes sharing the same gridpoint. With the basis functions, the first order derivative was expressed as an algebraic equation associated with nine point stencil. As the theory depicts, the convergence rate of the error for the spherical Laplacian operator was found to be fourth order, while it was the second order for the spherical Laplacian operator. The accuracy of the new high order filter was shown to be almost the same as those of Fourier finite element high order filter. The two-dimension finite element high order filter was incorporated in the weather research and forecasting (WRF) model as a hyper viscosity. The effect of the high order filter was compared with the built-in viscosity scheme of the WRF model. It was revealed that the high order filter performed better than the built in viscosity scheme did in providing a sharper cutoff of small scale disturbances without affecting the large scale field. Simulation of the tropical cyclone track and intensity with the high order filter showed a forecast performance comparable to the built in viscosity scheme. However, the predicted amount and spatial distribution of the rainfall for the simulation with the high order filter was closer to the observed values than the case of built in viscosity scheme.

Spherical and Aspherical RGP Lens Fitting to Epithelium and Endothelium of Rabbit's Cornea -Scanning Electron Microscopy (구면과 비구면 RGP 렌즈 장기 착용시 각막 상피, 내피에 미치는 영향-주사전자현미경적 관찰)

  • Kim, In-Suk;Ryu, Gun-Chang;Chae, Soo-Chul;Jeon, Chang-Jin
    • Applied Microscopy
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    • v.36 no.3
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    • pp.227-234
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    • 2006
  • To investigate the comparative effect of spherical and aspherical RGP lens were worn during 3 weeks on rabbit's cornea. Four white rabbits were worn right eyes with spherical lens and 4 white rabbits were worn right eyes with aspherical RGP lens. Left eyes were served as control. The rabbits were sacrificed at 3 weeks after fitting and observed morphological changes by scanning electron microscopy and also investigate proliferation rate of the corneal epithelium with RGP wearing. After spherical RGP lens wearing, the epithet layer damaged compared to aspherical lens. The superficial cell layer strip off seriously, cell size significantly changed abnormal. Both spherical and aspherical RGP lens fitting group showed so many bacteria and back surface of lens was found like a fern shape. The aspherical RGP lens original material type was some formal than spherical lens. We thought that these pattern was significantly altered with spherical lens by prohibited transmitter oxygen from atmosphere therefore the epithelium shape was changed. This suggested wearing the aspherical lens might be less physiologic than shperical lens fitting.

Synthesis of spherical SiO2 using scaled-up ultrasonic pyrolysis process (스케일-업 된 초음파 분무 열분해 공정을 이용한 구형 SiO2 분말 합성)

  • Kang, Woo-kyu;Lee, Ji-Hyeon;Kim, Jin-Ho;Hwang, Kwang-Taek;Jang, Gun-Eik
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.29 no.1
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    • pp.12-18
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    • 2019
  • The spherical $SiO_2$ powders were synthesized by the scaled-up ultrasonic pyrolysis (USP). The aqueous $SiO_2$ sol, which contained 20~30 nm $SiO_2$ particles, was used as a precursor for the scaled-up USP. The effects of the USP operating conditions and precursor conditions were systematically investigated, including reaction temperature, gas flow rate, and the concentration of $SiO_2$ sol on the morphologies of synthesized $SiO_2$ particles. the synthesized $SiO_2$ particle showed a pseudo-crystal phase, spherical morphology, and a smooth surface. The size of the spherical $SiO_2$ particle decreased as both reaction temperature increased and precursor concentration decreased. In addition, the synthesized $SiO_2$ particle size was increased by increasing the gas flow rate. Lastly, the scaled-up USP was compared with the lab-scale USP based on the same process conditions. Due to a short retention time in the reaction tube during the USP process, the $SiO_2$ particle synthesized via the lab-scale USP showed a larger particle size.

Development of Spherical Granule of Fermented Red Ginseng Extracts (발효홍삼농축액 구형과립 제조 기술 개발)

  • Shin, Myung-Gon
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.44 no.7
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    • pp.1064-1071
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    • 2015
  • Viscous fermented red ginseng extracts were dried and coated using a fluidized bed coater to increase convenience and consumer acceptance. The methods for making spherical granules of fermented red ginseng extracts with increasing convenience were established by using indigestible dextrin. Spherical granules of fermented red ginseng extracts with increasing convenience were made by mixing indigestible dextrin at 40% (40% IDD), 50% (50% IDD), and 60% (60% IDD) versus the soluble solid content of fermented red ginseng extracts. Spherical granules of fermented red ginseng extracts showed less angle of repose than powder of fermented red ginseng extracts. This means that spherical granules of fermented red ginseng extracts had good fluency with increased convenience. The more indigestible dextrin showed higher yields. Although 50% IDD showed less yield than 60% IDD, 50% IDD was the best mixing ratio for making spherical granules of fermented red ginseng extracts, as fermented red ginseng extracts is known as a healthy food. The optimized operation conditions of the fluidized bed coater for making 50% IDD were feeding rate 0.54 mL/min, atomization air pressure 2.15 bar, and product temperature $83.03^{\circ}C$.

Fluid film measurements on the spherical valve plate in oil hydraulic axial piston pumps

  • Kim, J.K.;Jung, J.Y.
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2002.10b
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    • pp.381-382
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    • 2002
  • The Fluid film between the valve plate and the cylinder block was measured by use of a gap sensor and the mercury-cell slip ring unit under real working conditions. During the operating periods, experiments with discharge pressure, revolution speed, and valve geometry was carried out for the fluid film on the valve plate. To investigate the effect of the valve shape, we designed two valve plates each having a different shape; the first valve plate was a plane valve plate. while the second valve plate was a spherical valve plate. It was noted that these two valve plates observed different aspects of the fluid film characteristics between the cylinder block and the valve plate. The leakage flow rate and the shan torque were also investigated in order to clarify the difference between these two types of valve plates. From the results of this study. we found that the spherical valve plate estimated good fluid film patterns and performance more than the other valve plate in oil hydraulic axial piston pumps.

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A NON-SPHERICAL MODEL FOR THE HOT OXYGEN CORONA OF MARS

  • KIM YONG HA;SON SUJEONG;YI YU;KIM JHOON
    • Journal of The Korean Astronomical Society
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    • v.34 no.1
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    • pp.25-29
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    • 2001
  • We have constructed a non-spherical model for the hot oxygen corona of Mars by including the effects of planetary rotation and diurnal variation of the Martian ionosphere. Exospheric oxygen densities are calculated by integrating ensemble of ballistic and escaping oxygen atoms from the exobase over the entire planet. The hot oxygen atoms are produced by dissociative recombination of $O^+_2$, the major ion in the Martian ionosphere. The densities of hot oxygen atoms at the exobase are estimated from electron densities which have been measured to vary with solar zenith angle. Our model shows that the density difference of hot oxygen atoms between noon and terminator is about two orders of magnitude near the exobase, but reduces abruptly around altitudes of 2000 km due to lateral transport. The diurnal variation of hot oxygen densities remains significant up to the altitude of 10000 km. The diurnal variation of the hot oxygen corona should thus be considered when the upcoming Nozomi measurements are analyzed. The non-spherical model of the hot oxy-gen corona may contribute to building sophisticate solar wind interaction models and thus result in more accurate escaping rate of oxygens from Mars.

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Preparation of Micro-spherical Activated Carbon with Meso-porous Structure for the Electrode Materials of Electric Double Layer Capacitor (전기이중층 캐패시터 전극용 meso-pore구조의 미소구형 활성탄소 제조)

  • Um, Eui-Heum;Lee, Chul-Tae
    • Applied Chemistry for Engineering
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    • v.20 no.4
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    • pp.396-401
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    • 2009
  • A micro-spherical activated carbon with meso-pore structure of 52~64% and particle diameter of $2{\sim}10{\mu}m$ was prepared for the improvement electrochemical performance of activated carbon as electrode material for electric double layer capacitor. Resorcinol-formaldehyde resin was used as a carbon source in this preparation. According to electrochemical analysis of EDLC using this activated a carbon with showing effects to reduce charge transfer resistance and to increase rate capability, it was found out that micro-spherical activated carbon could be a good method as well as a material for enhancing the performance of electric double layer capacitor.