• Journal of the Korean Chemical Society
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• v.58 no.5
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• pp.437-444
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• 2014

The electrochemical corrosion and passivation of Co-RDE in borate buffer solution was studied by Potentiodynamic and electrochemical impedance spectroscopy. The mechanisms of both the active dissolution and passivation of cobalt and the hydrogen evolution in reduction reaction were hypothetically established while utilizing the Tafel slope, the rotation speed of Co-RDE, impedance data and the pH dependence of corrosion potential. Based on the EIS data, an equivalent circuit was suggested. In addition, the electrochemical parameters for specific anodic dissolution regions were carefully measured. An induction loop in Nyquist plot measured at the open-circuit potential was observed in the low frequency, and this could be attributed to the adsorption-desorption behavior in the corrosion process.

• Korea-Australia Rheology Journal
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• v.15 no.1
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• pp.9-17
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• 2003

The rheological behaviour of anatase $TiO_2$ with organic coating has been investigated extensively in this study. The yield stress was measured over a wide range of solids concentration and pH using stress-controlled and speed-controlled rheometers. The organic treatment leads to a shift of the isoelectric point (IEP) from around pH 5.5 to pH 2.4. A maximum yield stress occurs in the vicinity of the isoelectric point determined by electrokinetic measurements. The transition of rheological behaviour between elastic solid and viscous liquid is represented by a stress plateau in a plot of stress against strain. It is hypothesised that the slope of the stress plateau reflects the uniformity of the structure, and hence the distribution of bond strength. Altering the concentration and the surface chemistry can vary the bond strength and its distribution. therefore, resulting in different type of failure: "ductile-type" or "brittle-type". pH and volume fraction dependence of yield stress could be described quantitatively using existing models with reasonable agreement.easonable agreement.

• The Korean Journal of Ceramics
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• v.3 no.2
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• pp.73-81
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• 1997

In this paper, it is intended to present more reproducible and quantitative method for adhesion assemssement. In scratch test, micromechanical analysis on the stress state beneath the indenter was carried out considering the additional blister field. The interface adhesion was quantified as work of adhesion through Griffith energy approach on the basis of the analyzed stress state. The work of adhesion for DLC film/WC-Co substrate calculated through the proposed analysis shows the identical value regardless of distinctly different critical loads measured with the change of film thickness and scratching speed. On the other hand, uniaxial loading was imposed on DCL film/Al substrate, developing the transverse film cracks perpendicular to loading direction. Since this film cracking behavior depends on the relative magnitude of adhesion strength to film fracture strength, the quantification of adhesion strength was given a trial through the micromechanical analysis of adhesion-dependence of film cracking patterns. The interface shear strength can be quantified from the measurement of strain $\varepsilon$s and crack spacing $\lambda$ at the cessation of film cracking.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.27 no.1
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• pp.39-45
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• 2003

As the size of a combustor decreases to a MEMS scale, heat loss increases and becomes a dominant effect on the performance of the devices. Existing models, however, are not adequate to predict the heat transfer and combustion processes in such small scales. In the present study, a semi-empirical model to calculate heat loss from a micro combustor is described. The model derives heat transfer coefficients that best fits the heat loss characteristics of a micro combustor that is represented by transient pressure record after combustion is completed. From conservation of energy equation applied to the burned gas inside the combustor, a relationship between pressure and heat transfer is reduced. Two models for heat transfer coefficients were tested; a constant and first order polynomial of temperature with its coefficients determined from fitting with measurements. The model was tested on a problem of cooling process of burnt gas in a micro combustor and comparison with measurements showed good agreements. The heat transfer coefficients were used for combustion calculation in a micro vessel. The results showed the dependence of flame speed on the scale of the chamber through enhanced heat loss.

• Korean Journal of Remote Sensing
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• v.27 no.6
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• pp.729-741
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• 2011

Wind speeds have long been estimated from C-band VV-polarized SAR data by using the CMOD algorithms such as CMOD4, CMOD5, and CMOD_IFR2. Some SAR data with HH-polarization without any observations in VV-polarization mode should be converted to VV-polarized value in order to use the previous algorithms based on VV-polarized observation. To satisfy the necessity of polarization ratio (PR) for the conversion, we retrieved the conversion parameter from full-polarized SIR-C SAR image off the east coast of Korea. The polarization ratio for SIR-C SAR data was estimated to 0.47. To assess the accuracy of the polarization ratio coefficient, pseudo VV-polarized normalized radar cross section (NRCS) values were calculated and compared with the original VV-polarized ones. As a result, the estimated psudo values showed a good agreement with the original VV-polarized data with an root mean square error by 0.99 dB. We applied the psudo NRCS to the estimation of wind speeds based on the CMOD wind models. Comparison of the retrieved wind field with the ECMWF and NCEP/NCAR reanalysis wind data showed relatively small rms errors of 1.88 and 1.91 m/s, respectively. SIR-C HH-polarized SAR wind retrievals met the requirement of the scatterometer winds in overall. However, the polarization ratio coefficient revealed dependence on NRCS value, wind speed, and incident angle.

• Journal of Korea Multimedia Society
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• v.13 no.4
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• pp.496-503
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• 2010

Speech recognition system is developed of standalone, In case of a mobile terminal using that low recognition rate represent because of limitation of memory size and audio compression. This study suggest vocabulary recognition highest performance improvement system for separate acoustic search and lexical search. Acoustic search is carry out in mobile terminal, lexical search is carry out in server processing system. feature vector of speech signal extract using GMM a phoneme execution, recognition a phoneme list transmission server using Lexical Tree Search algorithm lexical search recognition execution. System performance as a result of represent vocabulary dependence recognition rate of 98.01%, vocabulary independence recognition rate of 97.71%, represent recognition speed of 1.58 second.

• Progress in Superconductivity
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• v.9 no.1
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• pp.119-125
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• 2007

We investigated recovery in $Au/YBa_2Cu_3O_7$ (YBCO) thin film meander lines on sapphire substrates. The meander lines were fabricated by patterning YBCO films coated with gold layers. The lines were subjected to simulated AC fault current and then small current was applied for recovery measurements. The samples were immersed in liquid nitrogen during the experiment. After the fault, the resistance decreased linearly, first slowly and then fast to zero. The initial slow decrease was due to the decrease of the meander line temperature, whereas the fast decrease was originated from the transition from the normal state to the superconducting state. The recovery speed depended on the size of samples, and was faster in the smaller samples during the whole period of recovery. The experimental results were analyzed quantitatively with the concept of heat transfer within the sample and to the surrounding liquid nitrogen. A heat balance equation was solved for the initial phase of recovery, and an expression for the time dependence of resistance was obtained. The result agreed with data well.

• Environmental Engineering Research
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• v.25 no.2
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• pp.147-162
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• 2020

The main objective of this study is to estimate the levels of pollution to which the community is presently exposed and to model the regimes of local air quality. Diurnal, daily, and monthly variations of NO, NO₂, SO₂, and O₃ were thoroughly investigated in three areas; namely, residential, industrial, and terminal in Ras Al-Khafji. There is obvious diurnal variation in the concentration of these pollutants that clearly follows the diurnal variation of atmospheric temperature and main anthropogenic and industrial activities. Correlation analysis showed that meteorological conditions play a vital role in shaping the pattern and transportation of air pollutants and photochemical processes affecting O₃ formation and destruction. Bivariate polar plots, an effective graphical tool that utilizes air pollutant concentrations' dependence on wind speed and wind direction, were used to identify prevailing emission sources. Non-buoyant ground-level sources like domestic heating and street transport emissions, various industrial stacks, and airport-related activities were considered dominant emission sources in observatory sites. This study offers valuable and detailed information on the status of air quality, which has considerable, quantifiable, and important public health benefits.

• Proceedings of the KSRS Conference
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• 2004.10a
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• pp.152-153
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• 2004

The growth rate of atmospheric $CO_2$ undergoes significant interannual variability, largely due to temporal variability of partitioning of $CO_2$ between terrestrial biosphere and ocean. In the present paper, as a follow-up to the work by Lee et al. [1], we estimated the year-to-year variability in net global air-sea $CO_2$ fluxes between 1982 and 2003 from observed changes in wind speed and estimated changes in ${\Delta}pCO_2$ Changes in $pCO_{25W}$ were inferred from global records of sea surface temperature (SST) anomalies and seasonally varying SST dependence of $pCO_{25W}$. The modeled interannual variability of $\pm0.2\;Pg\;C\;yr^{-1}\;(1{\sigma})$ from the present work is significantly smaller than the values deduced from atmospheric observations of $^{1.3}CO_2/CO_2$ in conjunction with different atmospheric transport models, but it is closer to the recent estimates inferred from a 3-D ocean biogeochemical model and atmospheric transport models constrained with extensive observations of atmospheric $CO_2$.

• Proceedings of the Materials Research Society of Korea Conference
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• 2011.05a
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• pp.28.2-28.2
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• 2011

Resistance random access memory (ReRAM) is a promising candidate for next-generation nonvolatile memory because of its advantageous qualities such as simple structure, superior scalability, fast switching speed, low-power operation, and nondestructive readout. We investigated the resistive switching behavior of tantalum oxide that has been widely used in dynamic random access memories (DRAM) in the present semiconductor industry. As a result, it possesses full compatibility with the entrenched complementary metal-oxide-semiconductor processes. According to previous studies, TiN is a good oxygen reservoir. The TiN top electrode possesses the specific properties to control and modulate oxygen ion reproductively, which results in excellent resistive switching characteristics. This study presents fully room temperature fabricated the TiN/$TaO_x$/Pt devices and their electrical properties for nonvolatile memory application. In addition, we investigated the TiN electrode dependence of the electrical properties in $TaO_x$ memory devices. The devices exhibited a low operation voltage of 0.6 V as well as good endurance up to $10^5$ cycles. Moreover, the benefits of high devise yield multilevel storage possibility make them promising in the next generation nonvolatile memory applications.