• Membrane and Water Treatment
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• v.10 no.3
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• pp.223-229
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• 2019

Titania modified by 2-ethylimidazole (2-EI) (denoted as $2-EI-TiO_2$) demonstrated visible light photocatalytic activity for the degradation of organic compounds. $2-EI-TiO_2$ was a bright brown powder that exhibited similar crystallinity and morphology with the control $TiO_2$. A diffuse reflectance spectrum indicated that $2-EI-TiO_2$ absorbs visible light of all wavelengths. X-ray photoelectron spectroscopy (XPS) confirmed the cationic state of nitrogen species (e.g. Ti-O-N) on the surface of $2-EI-TiO_2$. Visible light-illuminated $2-EI-TiO_2$ degraded $10{\mu}M$ 4-chlorophenol (4-CP) by approximately 85% in 4 h. The photochemical activity of $2-EI-TiO_2$ was selective in targeting the organic compound. The repeated use of $2-EI-TiO_2$ decreased the photocatalytic activity for the 4-CP degradation. Experiments using radical scavengers and oxidant probes revealed that the oxidation by photogenerated holes is responsible for the degradation of organic compounds by illuminated $2-EI-TiO_2$ and the role of $^{\bullet}OH$ is negligible.

• Journal of the Semiconductor & Display Technology
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• v.22 no.1
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• pp.94-98
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• 2023

In the case of high-speed data transmission on high multilayer boards, signal coherence is a problem, especially due to the via hole, and a solution to improve return loss or insertion loss by applying a back drill to the via hole is being proposed. In this paper, Near-Field Electromagnetic measurements were made on a high multilayer board to determine how the presence or absence of back drill affects signal consistency. For this purpose, we used a signal generator, spectrum analyzer, and EMC scanner on a test board to determine if it is possible to distinguish between areas with and without back drill in the via holes of the stubs on the board. Also, we analyzed the measured value of S11, S21 and EMC etc. for how much it improves the signal attenuation of the stub with back drill. Through this, we knew that less electromagnetic waves are generated the stub via with back drill. At future research, we will analyze how much it improves the signal loss and electromagnetic waves due to the depth of back drill.

• Journal of The Korean Astronomical Society
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• v.46 no.3
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• pp.125-131
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• 2013

We present the relation between the genus in cosmology and the Betti numbers for excursion sets of three- and two-dimensional smooth Gaussian random fields, and numerically investigate the Betti numbers as a function of threshold level. Betti numbers are topological invariants of figures that can be used to distinguish topological spaces. In the case of the excursion sets of a three-dimensional field there are three possibly non-zero Betti numbers; ${\beta}_0$ is the number of connected regions, ${\beta}_1$ is the number of circular holes (i.e., complement of solid tori), and ${\beta}_2$ is the number of three-dimensional voids (i.e., complement of three-dimensional excursion regions). Their sum with alternating signs is the genus of the surface of excursion regions. It is found that each Betti number has a dominant contribution to the genus in a specific threshold range. ${\beta}_0$ dominates the high-threshold part of the genus curve measuring the abundance of high density regions (clusters). ${\beta}_1$ dominates the genus near the median thresholds which measures the topology of negatively curved iso-density surfaces, and ${\beta}_2$ corresponds to the low-threshold part measuring the void abundance. We average the Betti number curves (the Betti numbers as a function of the threshold level) over many realizations of Gaussian fields and find that both the amplitude and shape of the Betti number curves depend on the slope of the power spectrum n in such a way that their shape becomes broader and their amplitude drops less steeply than the genus as n decreases. This behaviour contrasts with the fact that the shape of the genus curve is fixed for all Gaussian fields regardless of the power spectrum. Even though the Gaussian Betti number curves should be calculated for each given power spectrum, we propose to use the Betti numbers for better specification of the topology of large scale structures in the universe.

• Publications of The Korean Astronomical Society
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• v.30 no.2
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• pp.559-563
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• 2015

Monitor of All-sky X-ray Image (MAXI) is a Japanese X-ray all-sky surveyer mounted on the International Space Station (ISS). It has been scanning the whole sky since 2009 during every 92-minute ISS rotation. X-ray transients are quickly found by the real-time nova-search program. As a result, MAXI has issued 133 Astronomer's Telegrams and 44 Gamma-ray burst Coordinated Networks so far. MAXI has discovered six new black holes (BH) in 4.5 years. Long-term behaviors of the MAXI BHs can be classified into two types by their outbursts; a fast-rise exponential-decay type and a fast-rise flat-top one. The slit camera is suitable for accumulating data over a long time. MAXI issued a 37-month catalog containing 500 sources above a ~0.6 mCrab detection limit at 4-10 keV in the region ${\mid}{b}{\mid}$ > $10^{\circ}$. The SSC instrument utilizing an X-ray CCD has detected diffuse soft X-rays extending over a large solid angle, such as the Cygnus super bubble. MAXI/SSC has also detcted a Ne emission line from the rapid soft X-ray nova MAXI J0158-744. The overall shapes of outbursts in Be X-ray binaries (BeXRB) are precisely observed with MAXI/GSC. BeXRB have two kinds of outbursts, a normal outburst and a giant one. The peak dates of the subsequent giant outbursts of A0535+26 repeated with a different period than the orbital one. The Be stellar disk is considered to either have a precession motion or a distorted shape. The long-term behaviors of low-mass X-ray binaries (LMXB) containing weakly magnetized neutron stars are investigated. Transient LMXBs (Aql X-1 and 4U 1608-52) repeated outbursts every 200-1000 days, which is understood by the limit-cycle of hydrogen ionization states in the outer accretion disk. A third state (very dim state) in Aql X-1 and 4U 1608-52 was interpreted as the propeller effect in the unified picture of LMXB. Cir X-1 is a peculiar source in the sense that its long-term behavior is not like typical LMXBs. The luminosity sometimes decreases suddenly at periastron. It might be explained by the stripping of the outer accretion disk by a clumpy stellar wind. MAXI observed 64 large flares from 22 active stars (RS CVns, dMe stars, Argol types, young stellar objects) over 4 years. The total energies are $10^{34}-10^{36}$ erg $s^{-1}$. Since MAXI can measure the spectrum (temperature and emission measure), we can estimate the size of the plasma and the magnetic fields. The size sometimes exceeds the size of the star. The magnetic field is in the range of 10-100 gauss, which is a typical value for solar flares.

• Journal of Communications and Networks
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• v.16 no.2
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• pp.227-237
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• 2014

Throughput scaling laws for two coexisting ad hoc networks with m primary users (PUs) and n secondary users (SUs) randomly distributed in an unit area have been widely studied. Early work showed that the secondary network performs as well as stand-alone networks, namely, the per-node throughput of the secondary networks is ${\Theta}(1/\sqrt{n{\log}n})$. In this paper, we show that by exploiting directional spectrum opportunities in secondary network, the throughput of secondary network can be improved. If the beamwidth of secondary transmitter (TX)'s main lobe is ${\delta}=o(1/{\log}n)$, SUs can achieve a per-node throughput of ${\Theta}(1/\sqrt{n{\log}n})$ for directional transmission and omni reception (DTOR), which is ${\Theta}({\log}n)$ times higher than the throughput with-out directional transmission. On the contrary, if ${\delta}={\omega}(1/{\log}n)$, the throughput gain of SUs is $2{\pi}/{\delta}$ for DTOR compared with the throughput without directional antennas. Similarly, we have derived the throughput for other cases of directional transmission. The connectivity is another critical metric to evaluate the performance of random ad hoc networks. The relation between the number of SUs n and the number of PUs m is assumed to be $n=m^{\beta}$. We show that with the HDP-VDP routing scheme, which is widely employed in the analysis of throughput scaling laws of ad hoc networks, the connectivity of a single SU can be guaranteed when ${\beta}$ > 1, and the connectivity of a single secondary path can be guaranteed when ${\beta}$ > 2. While circumventing routing can improve the connectivity of cognitive radio ad hoc network, we verify that the connectivity of a single SU as well as a single secondary path can be guaranteed when ${\beta}$ > 1. Thus, to achieve the connectivity of secondary networks, the density of SUs should be (asymptotically) bigger than that of PUs.

• Publications of The Korean Astronomical Society
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• v.15 no.spc2
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• pp.21-25
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• 2000

The ionosphere, the atmosphere of the earth ionized by solar radiations, has been strongly varied with solar activity. The ionosphere varies with the solar cycle, the seasons, the latitudes and during any given day. Radio wave propagation through or in the ionosphere is affected by ionospheric condition so that one needs to consider its effects on operating communication systems normally. For examples, sporadic E may form at any time. It occurs at altitudes between 90 to 140 km (in the E region), and may be spread over a large area or be confined to a small region. Sometimes the sporadic E layer works as a mirror so that the communication signal does not reach the receiver. And radiation from the Sun during large solar flares causes increased ionization in the D region which results in greater absorption of HF radio waves. This phenomenon is called short wave fade-outs. If the flare is large enough, the whole of the HF spectrum can be rendered unusable for a period of time. Due to events on the Sun, sometimes the Earth's magnetic field becomes disturbed. The geomagnetic field and the ionosphere are linked in complex ways and a disturbance in the geomagnetic field can often cause a disturbance in the F region of the ionosphere. An enhancement will not usually concern the HF communicator, but the depression may cause frequencies normally used for communication to be too high with the result that the wave penetrates the ionosphere. Ionospheric storms can occur throughout the solar cycle and are related to coronal mass ejections (CMEs) and coronal holes on the Sun. Except the above mentioned phenomena, there are a lot of things to affect the radio communication. Nowadays, radio technique for probing the terrestrial ionosphere has a tendency to use satellite system such as GPS. To get more accurate information about the variation of the ionospheric electron density, a TEC measurement system is necessary so RRL will operate the system in the near future.

• Proceedings of the Materials Research Society of Korea Conference
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• 2011.05a
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• pp.11.2-11.2
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• 2011

Polymer based organic photovoltaics have attracted a great deal of attention due to the potential cost-effectiveness of light-weight and flexible solar cells. However, most BHJ polymer solar cells are not thermally stable as subsequent exposure to heat drives further development of the morphology towards a state of macrophase separation in the micrometer scale. Here we would like to show three different approaches for developing new electroactive polymers to improve the thermal stability of the BHJ solar cells, which is a critical problem for the commercialization of these solar cells. For one of the examples, we report a new series of functionalized polythiophene (PT-x) copolymers for use in solution processed organic photovoltaics (OPVs). PT-x copolymers were synthesized from two different monomers, where the ratio of the monomers was carefully controlled to achieve a UV photo-crosslinkable layer while leaving the ${\pi}-{\pi}$ stacking feature of conjugated polymers unchanged. The crosslinking stabilizes PT-x/PCBM blend morphology preventing the macro phase separation between two components, which lead to OPVs with remarkably enhanced thermal stability. The drastic improvement in thermal stabilities is further characterized by microscopy as well as grazing incidence X-ray scattering (GIXS). In the second part of talk, we will discuss the use of block copolymers as active materials for WOLEDs in which phosphorescent emitter isolation can be achieved. We have exploited the use of triarylamine (TPA) oxadiazole (OXA) diblock copolymers (TPA-b-OXA), which have been used as host materials due to their high triplet energy and charge-transport properties enabling a balance of holes and electrons. Organization of phosphorescent domains in TPA-b-OXA block copolymers is demonstrated to yield dual emission for white electroluminescence. Our approach minimizes energy transfer between two colored species by site isolation through morphology control, allowing higher loading concentration of red emitters with improved device performance. Furthermore, by varying the molecular weight of TPA-b-OXA and the ratio of blue to red emitters, we have investigated the effect of domain spacing on the electroluminescence spectrum and device performance.

• Korean Journal of Materials Research
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• v.22 no.10
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• pp.504-507
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• 2012

Synthesis of RGO (reduced graphene oxide)-CdS composite material was performed through CBD (chemical bath deposition) method in which graphene oxide served as the support and Cadmium Sulfate Hydrate as the starting material. Graphene-based semiconductor photocatalysts have attracted extensive attention due to their usefulness for environmental and energy applications. The band gap (2.4 eV) of CdS corresponds well with the spectrum of sunlight because the crystalline phase, size, morphology, specic surface area and defects, etc., of CdS can affect its photocatalytic activity. The specific surface structure (morphology) of the photocatalyst can be effective for the suppression of recombination between photogenerated electrons and holes. Graphene (GN) has unique properties such as a high value of Young's modulus, large theoretical specific surface area, excellent thermal conductivity, high mobility of charge carriers, and good optical transmittance. These excellent properties make GN an ideal building block in nanocomposites. It can act as an excellent electron-acceptor/transport material. Therefore, the morphology, structural characterization and crystal structure were observed using various analytical tools, such as X-ray diffraction, scanning electron microscopy, transmission electron microscopy, and Raman spectroscopy. From this analysis, it is shown that CdS particles were well dispersed uniformly in the RGO sheet. Furthermore, the photocatalytic property of the resulting RGO-CdS composite is also discussed in relation to environmental applications such as the photocatalytic degradation of pollutants. It was found that the prepared RGO-CdS nanocomposites exhibited enhanced photocatalytic activity as compared with that of CdS nanoparticles. Therefore, better efficiency of photodegradation was found for water purification applications using RGO-CdS composite.

• Journal of Korea Entertainment Industry Association
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• v.14 no.3
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• pp.229-236
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• 2020

In this paper, the tone of Daegeum, one of the most representative wind instruments of our country, was analyzed. Daegeum is widely used as Jeongak Daegeum and Sanjo Daegeum, which are played in royal and wind music, and Sanjo Daegeum is mainly played in Sanjo, Sinawi and folk music. The reason why the two pieces of music are being played in different music genres is due to the improvement of the length of the pipe and the location of the finger holes, allowing the Sanjo Daegeum to perform faster than Jeongak Daegeum, apply various techniques, and make the choice of musical instruments harmonized with music by making the difference in tone. For timber analysis of Jeongak Daegeum and Sanjo Daegeum, the composition of the overtones was visually verified through Spectrogram and Spectrum Analizer, in which the results of recordings were recorded by playing octave low, flat, and octave high positions with the same power. From this, Jeongak Daegeum, which is rich in low-pitched sound, harmonizes with solemn music such as royal music, and Sanjo Daegeum, which has a relatively clear high-pitched sound, is well suited to bright music such as solo music.

• Nuclear Engineering and Technology
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• v.13 no.4
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• pp.264-276
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• 1981

A simulation procedure which can represent time-dependent nuclear characteristics of TRIGA Mark-III reactor is developed. CITATION, a multi-group diffusion-depletion program, has been utilized as calculational tool. The group structure employed in this study consists of 7 groups: -3-fast and 4-thermal-which is conventionally utilized in TRIGA type reactor analysis. Three-dimensional nuclear characteristics are synthesized by combining results from two-dimensional plane calculation and two-dimensional cylinder calculation, since direct three-dimensional approach is not yet possible. An effort ia made to develope a method which can extract effective zone and group dependent bucklings by neutron diffusion theory rather than conventional zone and/or group independent Ducklings by neutron transport theory, since neutron leakage is quite high for small core such as research reactors. It is turned out that the method developed in this study gives satisfactory results. The calculation is performed under assumptions that all control rods are fully withdrawn, that no samples are inserted in the irradiation holes and that the core is located in the center of the reactor pool. Burnup-dependent variation of core excess reactivity, time dependent change of Xe-135 poisoning and reactivity worth of rotary specimen rack are calculated and compared with operation records. Neutron flux and power distribution as well as neutron spectrum in each irradiation .facility are presented.