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Synthesis of Reduced Graphene-metal Hybrid Materials via Ion-exchange Method and its Characterization (이온교환법에 의한 환원 그래핀-금속 하이브리드 소재의 합성 및 특성)

  • Park, Aeri;Kim, Sumin;Kim, Hyun;Han, Jong Hun
    • Journal of the Microelectronics and Packaging Society
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    • v.27 no.4
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    • pp.25-37
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    • 2020
  • In this study, hybridization of graphene oxide and metal was carried out by the functional groups containing oxygen and thermal treatment for reduction in order to enhance the electrical conductivity and magnetic properties of graphene materials. Graphene-metal hybrid materials were synthesized using the oxygen-containing functional groups (-OH, -COOH and so on) on the surface of graphene oxide by replacing them with metal ions via ion exchange method as well as thermal reduction. The metals used in this study were Fe, Ag, Ni, Zn, and Fe/Ag, and it was confirmed that metal particles of uniform size were well dispersed on the graphene surface through SEM, TEM, and EDS. All of the metal particles on the graphene surface had an oxide-crystalline structure. To check the electrical properties, sheet resistance of the rGO-metal hybrid sample was measured on the PET film made by the dip-coating, and the specific resistance was calculated by measuring the thickness of the specimen through SEM. As a result, the specific resistance was in the range of 2.14×10-5 and 3.5×10-3 ohm/cm.

Experimental Evaluation of the Flexural Behavior of SY Permanent Steel Form for RC Beam and Girder (SY 비탈형 보 거푸집의 휨 거동에 대한 실험적 고찰)

  • Bae, Kyu-Woong;Boo, Yoon-Seob;Shin, Sang-Min
    • Journal of the Korea Institute of Building Construction
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    • v.22 no.1
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    • pp.11-21
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    • 2022
  • Currently, in the domestic construction industry, the free web method has been emerging as a potential solution to the shortage of skilled workers due to the prolonged COVID-19 crisis, as it helps in securing economic feasibility through shortening the construction period and reducing labor costs. To consider one part of the construction method, in this study, the bending behavior according to the load was evaluated for the SY slope-type beam formwork, which was manufactured at a factory, assembled with rebar, brought into the site, and then poured into the site. For the SY Beam standard cross-sectional shape, a cross-sectional dimensional width of 400mm and depth 600mm determined through structural modeling using the MIDAS GEN program were applied. A total of 6 specimens were made with a member length of 5,000mm, 5 specimens and one RC specimen in the comparison group were manufactured in real-size format using the thickness of the steel plate(0.8, 1.0, 1.2mm) as a variable, and bending experiments were performed. In the bending test, the steel plate deck showed high initial stiffness and maximum strength as it yielded, which showed that it sufficiently contributed to the flexural strength. It is judged that additional analysis and experimental studies for 1.05, 1.1, and 1.15mm are needed to derive the appropriate steel plate thickness and the method for calculating the tensile force contribution of the steel plate to secure the manufacturing, construction and economic feasibility of SY Beam in the future.

Evaluation of Serviceability and Flexural Performance for RC Hollow Slab by Hollow Ratio and Damping Ratio (중공율과 감쇠율을 이용한 RC 중공 슬래브의 사용성 및 휨성능 평가)

  • Jong Hoon Kim;Dong Baek Kim;Yong Gon Kim;Jae Won Lee;Jeong Ho Choi
    • Journal of the Society of Disaster Information
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    • v.18 no.4
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    • pp.930-935
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    • 2022
  • Purpose: The purpose of this study is to evaluate the stiffness reduction and damping ratio of reinforced concrete hollow slabs and to analyze their performance, and to study the effect of the damping effect of hollow bodies and the stiffness reduction on the serviceability of slabs. Method: Test specimen was made in a size of 0.6m*0.21m*3.6m to evaluate the vibration effect of the slab, and the hollow ratio was set in six steps from 0.0% to 30% to measure the change in rigidity and damping according to the change in the hollow ratio. Result: As the hollow ratio increases, rigidity decreases and the natural frequency decreases, but as the mass decreases, the natural frequency increases gradually. Since energy is hardly dissipated up to the hollow ratio of 20%, the hollow ratio should be reduced by 30%. Conclusion: It was found that the bending strength degradation of the slab with a hollow ratio of about 30% is minimized, but an appropriate natural frequency can be maintained, and a certain damping effect can be obtained.

Possibility of Using Landfill Coal Ash as CLSM Material for Emergency Restoration of Ground and Road Joint Parts (지반 및 도로 공동부의 긴급복구용 CLSM 재료로 매립 석탄저회 활용 가능성)

  • Jin-Man Kim;Sang-Chul Shin;Kyoung-Nam Min;Ha-Seog Kim
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.1
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    • pp.55-61
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    • 2023
  • This study aims to develop CLSM fill material for emergency restoration using landfill coal ash. As a result of examining physical properties such as particle size distribution and fines content of landfill coal ash, bottom ash, fly ash, and general soil were mixed, and SP was found to have a density of 2.03 and a residual particle pass rate of 7.8 %. CLSM materials that secure fluidity in unit quantities without using chemical admixtures such as glidants and water reducing agents have a high risk of material separation due to bleeding. As a result of this experiment, it was found that the bleeding ratio did not satisfy the standard in the case of the specimen with a large amount of fly ash and a lot of addition of mixing water. As a result of the compressive strength test, the strength development of 0.5 MPa or more for 4 hours was found to be satisfactory for the specimens using hemihydrate gypsum with a unit binder amount of 200 or more, and the remaining gypsum showed poor strength development. Although it is judged that landfill coal ash can be used as a CLSM material, it is necessary to identify and apply the physical and chemical characteristics of coal ash buried in the ash treatment plant of each power generation company.

Effect of Fines Content on the Cyclic Shear Characteristics of Sand-clay Mixtures (점토혼합모래의 반복전단특성에 대한 세립분 함유율의 영향)

  • Kim, Uk-Gie;Hyodo, Masayuki;Ahn, Tae-Bong
    • Journal of the Korean Geotechnical Society
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    • v.24 no.1
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    • pp.51-59
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    • 2008
  • In this study, cyclic shear characterics of sand-clay mixtures were analyzed. In order to perform cyclic triaxial tests on sand clay mixtures, natural clays with activity and silica sand were mixed variously to reproduce soils with wide range of grain size compositions. Test specimens with various fines contents were prepared by the moisture compaction and pre-consolidation methods, while paying attention to the void ratio expressed in terms of the sand structure and clay structures, and undrained cyclic shear tests were performed. In the test results, cyclic shear strength decreased with increasing of sand granular void ratio below 20% of fine contents. When the granular void ratio of the test specimen exceeded the maximum void ratio of the silica sand, the clay matrix dominated the soil structure, and soil structures were not influenced by compaction energy. It was observed that, the matrix structure of the coarse particles has great effect on the undrained cyclic shear strength characteristics for sand-clay mixtures, and therefore, it is more appropriate to pay more attention to the density of the sand structure, rather than to the fines content.

Structural and Electrical Properties of La0.7Sr0.3-xMgxMnO3 Ceramics with MgO Content (MgO 첨가에 따른 La0.7Sr0.3-xMgxMnO3 세라믹스의 구조적, 전기적 특성)

  • Hyun-Tae Kim;Jeong-Eun Lim;Byeong-Jun Park;Sam-Haeng Yi;Myung-Gyu Lee;Joo-Seok Park;Young-Gon Kim;Sung-Gap Lee
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.36 no.3
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    • pp.275-279
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    • 2023
  • La0.7Sr0.3-xMgxMnO3 (LSMMO) (x=0.05~0.20) specimens are fabricated by a solid phase sintering method, and the sintering temperature and time are 1,300℃ and 2 hours, respectively. The dependence of the crystalline structure according to the amount of Mg2+ contents is not observed, and all specimens show a polycrystalline rhombohedral crystal structure, the X-ray diffraction (110) peaks move to the high angle side with increasing the amount of Mg2+ contents. LSMMO specimens exhibit a granule-shaped microstructure with an average grain size of 1 ㎛ or less. Resistivity gradually decrease as the amount of Mg2+ contents increased. And in the La0.7Sr0.1Mg0.2MnO3 specimen, resistivity and B25/65-value are 36.7 Ω-cm and 394 K at room temperature, respectively. LSMMO specimens show a variable-range hopping (VRH) electrical conduction mechanism, and the negative temperature of coefficient of resistance (NTCR) is approximately 0.37~0.38%/℃.

A Study on Property Distribution of [011] Poled Mn:PIN-PMN-PT Single Crystals Grown by Bridgeman Method (Bridgeman 성장 [011] 분극 Mn:PIN-PMN-PT 압전단결정의 물성 분포 연구)

  • Soohyun Lim;Yub Je;Yohan Cho;Sang-Goo Lee;Hee-Seon Seo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.37 no.4
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    • pp.412-419
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    • 2024
  • Mn-doped Pb(In1/2Nb1/2)O3-Pb(Mg2/3Nb1/3)O3-PbTiO3 (Mn:PIN-PMN-PT) single crystals, which exhibit improved phase transition temperatures and coercive field properties compared to Pb(In1/2Nb1/2)O3-Pb(Mg2/3Nb1/3)O3-PbTiO3 (PIN-PMN-PT) single crystals, are expected to be utilized in high-power acoustic transducers. Bridgeman method, growing single crystals along the axial direction from melt, is most widely used method for single crystal growth with large size and high quality. However, single crystal boules grown by the Bridgeman method demonstrate a PT compositional variation, giving rise a distribution of crystal structure and material properties along the growing axis. To employ piezoelectric single crystals grown by the Bridgeman method for acoustic transducers, it is essential to investigate their overall property distribution. In this study, the compositional distribution and property variation of Mn:PIN-PMN-PT single crystals grown by the Bridgeman method was investigated. Measured compositional distribution of PT was from 29% to 32.5% in the Rhombohedral crystal region of the boule. Two types of specimen, [011]-poled Mn:PIN-PMN-29PT and Mn:PIN-PMN-32PT single crystals, were fabricated and tested to obtain full property variation at both ends of the Rhombohedral crystal region. The properties related to the 32 directional vibration mode and the properties related to high-power driving were measured to confirm the overall distribution of properties by composition.

An Experimental Study on the Evaluation of Shear Strength of Weathered Soil Containing Coarse Particles (굵은 입자가 포함된 풍화토의 전단강도 평가에 대한 실험연구)

  • Joon-Seok Kim
    • Journal of the Society of Disaster Information
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    • v.20 no.1
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    • pp.169-176
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    • 2024
  • Purpose: In this paper, an experimental study was conducted to analyze the difference in shear strength caused by the problem of excluding coarse particles due to the size of the test specimen in the direct shear test. Method: A large-scale direct shear test was conducted on three weathered soils containing coarse aggregates with a maximum diameter of 50mm. In addition, a small-scale direct shear test was performed using a sample with a maximum diameter of 5 mm, excluding coarse aggregates. Result: In the case of the small-scale direct shear test, compared to the results of the large-scale direct shear test containing large particles, the internal friction angle was about 2.3% smaller, and there was no significant difference. In terms of cohesion, compared to the large-scale direct shear test, the small-scale direct shear test derived about 80.3% smaller value, showing a relatively large difference. Conclusion: In the large-scale direct shear test, it was analyzed that the coarse particles had a greater impact on the cohesion than the internal friction angle. Therefore, granite weathered clay containing coarse particles is judged to have the same shear strength as the cohesive force that is not affected by vertical stress. In this study, it was analyzed that the small-scale direct shear test, which excludes the coarse particles that are commonly used, provides results on the safety side by excluding the effect of coarse particles.

US Features of the Parathyroid Glands: An Intraoperative Surgical Specimen Study (부갑상선의 초음파 소견: 수술 중 수술 검체 연구)

  • Wooyul Paik;Jong Cheol Lee;Byeong-Joo Noh;Dong Gyu Na
    • Journal of the Korean Society of Radiology
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    • v.84 no.3
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    • pp.596-605
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    • 2023
  • Purpose This study aimed to evaluate the US features of the parathyroid glands (PTGs) using surgical specimens of normal PTGs obtained during thyroid surgery. Materials and Methods This study included 34 normal PTGs from 17 consecutive patients who underwent thyroid surgery between December 2020 and March 2021. All normal PTGs were histologically confirmed by intraoperative frozen-section biopsy for autotransplantation. Surgically resected parathyroid specimens were scanned in sterile normal saline using high-resolution US prior to autotransplantation. The US features of echogenicity (hyperechogenicity or hypoechogenicity), echotexture (homogeneous or heterogeneous), size, and shape (ovoid or round) were retrospectively evaluated. The echogenicity of the three PTGs was compared with that of the thyroid parenchyma of the resected thyroid specimens in two patients. Results All PTGs showed hyperechogenicity similar to that of gauze soaked in normal saline. Homogeneous hyperechogenicity was observed in 32/34 (94.1%) patients, and the echogenicity of the three PTGs was hyperechoic compared with that of the thyroid parenchyma. The long diameter of the PTGs ranged from 5.1 mm to 9.8 mm (mean, 7.1 mm) and the shape of the PTGs was ovoid in 33/34 (97.1%) patients. Conclusion The echogenicity of normal PTG specimens was consistently hyperechoic, and the small ovoid homogeneously hyperechoic structure was a characteristic US feature of the PTGs.

Morbidity and Mortality After Laparoscopy-Assisted Distal Gastrectomy and Totally Laparoscopic Distal Gastrectomy to Treat Gastric Cancer: An Interim Report: A Phase III Multicenter, Prospective, Randomized Trial (The KLASS-07 Trial)

  • Han Hong Lee;Chang Min Lee;Moon-Soo Lee ;In Ho Jeong;Myoung Won Son;Chang Hyun Kim;Moon-Won Yoo;Sung Jin Oh;Young-Gil Son;Sung Il Choi;Mi Ran Jung;Sang Hyuk Seo;Shin-Hoo Park;Seong Ho Hwang;Jae-Seok Min;Sungsoo Park
    • Journal of Gastric Cancer
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    • v.24 no.3
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    • pp.257-266
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    • 2024
  • Purpose: We conducted a randomized prospective trial (KLASS-07 trial) to compare laparoscopy-assisted distal gastrectomy (LADG) and totally laparoscopic distal gastrectomy (TLDG) for gastric cancer. In this interim report, we describe short-term results in terms of morbidity and mortality. Methods and Methods: The sample size was 442 participants. At the time of the interim analysis, 314 patients were enrolled and randomized. After excluding patients who did not undergo planned surgeries, we performed a modified per-protocol analysis of 151 and 145 patients in the LADG and TLDG groups, respectively. Results: The baseline characteristics, including comorbidity status, did not differ between the LADG and TLDG groups. Blood loss was somewhat higher in the LADG group, but statistical significance was not attained (76.76±72.63 vs. 62.91±65.68 mL; P=0.087). Neither the required transfusion level nor the operation or reconstruction time differed between the 2 groups. The mini-laparotomy incision in the LADG group was significantly longer than the extended umbilical incision required for specimen removal in the TLDG group (4.79±0.82 vs. 3.89±0.83 cm; P<0.001). There were no between-group differences in the time to solid food intake, hospital stay, pain score, or complications within 30 days postoperatively. No mortality was observed in either group. Conclusions: Short-term morbidity and mortality rates did not differ between the LADG and TLDG groups. The KLASS-07 trial is currently underway.