• Journal of Korean Society of Environmental Engineers
• /
• v.32 no.10
• /
• pp.965-972
• /
• 2010

The objective of this research was to evaluate for the changes of pore structures and adsorption capacities due to the increase the numbers of reactivation. The reactivated GAC had experienced three cycles of water treatment and thermal reactivation. The pore size distributions of virgin and reactivated GACs were very different. The virgin GAC was mostly microporous (< $15\;{\AA}$), with less mesopores ($20{\sim}100\;{\AA}$). The reactivated GACs was mostly mesoporous ($20{\sim}100\;{\AA}$), with less micropores (< $15\;{\AA}$). The specific surface area and total pore volume were reduced as the number of reactivation increased. The maximum adsorption capacity (X/M) of virgin GAC ($964.6\;{\mu}g/g$) for $CHCl_3$ was 2~3 times larger than 1st~3rd reactivated GAC ($255.6{\sim}399.5\;{\mu}g/g$). The maximum adsorption capacity (X/M) of virgin GAC (19.5 mg/g) for DOC (dissolved organic carbon) was equal to that of 1st~3rd reactivated GAC (18.0~18.7 mg/g).

• Journal of Korean Society of Environmental Engineers
• /
• v.35 no.2
• /
• pp.131-136
• /
• 2013

The aim of this study was to investigate the removal of fluoride using thermally treated pyrophyllite as adsorbent. Sorption experiments were conducted under batch conditions to examine the effects of adsorbent dose, reaction time, initial fluoride concentration and solution pH on fluoride removal. In the experiments, the pyrophyllite thermally treated at different temperatures [untreated (P-U), $400^{\circ}C$ (P-400), $600^{\circ}C$ (P-600)] were used. Results showed that the adsorption capacity was in the order of P-400 > P-U > P-600. The XRD analysis indicated that both P-U and P-400 were composed of quartz, dickite and pyrophyllite while P-600 was quartz. The BET analysis showed that the specific surface area was in the order of P-600 > P-400 > P-U. Kinetic data showed that fluoride sorption to P-400 arrived at equilibrium around 24 h. Equilibrium test demonstrated that the maximum sorption capacity of P-400 was 0.957 mg/g. In addition, fluoride removal by P-400 was not sensitive to solution pH between 4 and 10. However, fluoride removal decreased considerably at highly acidic (pH < 4) and alkaline (pH > 10) conditions. This study demonstrates that pyrophyllite could be used as a low-cost adsorbent for fluoride removal from aqueous solution.

• Economic and Environmental Geology
• /
• v.44 no.6
• /
• pp.513-523
• /
• 2011

We estimated geothermal power generation potential in Korea through Enhanced Geothermal System (EGS) technology following the recently proposed protocol which was endorsed by international organizations. Input thermal and physical data for estimation are density, specific heat and thermal conductivity measurements from 1,516 outcrop samples, 180 heat production, 352 heat flow, and 52 mean surface temperature data. Inland area was digitized into 34,742 grids of $1'{\times}1'$ size and temperature distribution and available heat were calculated for 1 km depth interval from 3 km down to 10 km. Thus estimated theoretical potential reached 6,975 GW which is 92 times total generation capacity of Korea in 2010. Technical potential down to 6.5 km and considering land accessibility, thermal recovery ratio of 0.14 and temperature drawdown factor of $10^{\circ}C$ was 19.6 GW. If we disregard temperature drawdown factor, which can be considered in estimating economic potential, the technical potential increases up to 56 GW.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.15 no.5
• /
• pp.2844-2858
• /
• 2014

The society experiencing the industrialization and urbanization has got over the socio-demographic change. these changes make the number of the population around the world, and this phenomenon is flowing into the whole country. Korea has became a Aging Society since 2000 and will be turned into the aged society by the 2018. therefore, the importance of preparing elderly living life such as silver town is getting emphasized. the purpose of this study is aimed at analyzing the decision elements of the preliminary demanders' intention who selecting Elderly Housing. Based on this study, it was broken down by the type much more. Binary Logistic Regression Analysis of Factors affecting the Elderly housing choices were subdivided. Through this process, improvement and the implications of this study was derived. this study deducts 3 kinds of implications. First, the preference for the development of elderly housing are different with each type of characteristics. Second, the indicators along with the individual characteristics account for the most part of the surface. so the specific investigation for the demand must be required to check the indicators. Third, when it comes to development of urban elderly housing, it requires to have a part of a local government plans securing the land. Fourth, when it comes to development of suburb elderly housing, it is required to arrange the living environment around the suburbs to let user classes living in Gyeonggi-do flow into elderly housing and live their new-life in the suburbs. Finally, when it comes to development of rural elderly housing, a variety of production, leisure and other programs should be made and put into there.

• Resources Recycling
• /
• v.4 no.1
• /
• pp.12-19
• /
• 1995

This study was carried out to remove the iron and impurities usmg hydrocyclone and HGMS for recycling of sludge from the granite stone cutting and polishing industrγ in the basic of chemi떠1 analysis and minerallogical investigation. This sludge consist of 70.9% $SiO_2$ 13.6% $Al_2O_3$ and It also contained 2.52% of $Fe_2O_7$ and 0.29% of $TiO_2$, as a main impurities to decrease the whiteness. As the result of hydrocyclone experiment, It was very good condition that are 100~150 g/l of sludge amount, 2.0~ 2.5 mm of underflow nozzle size, and 1.2~1.6 kg/$\textrm{cm}^2$ of pressure for 85% sludge product with the $-37{\mu}\textrm{m}$ size. $Fe_2O_3$ and $TiO_2$, contents by treatment of HGMS were decreased with 0.65% and 0.07% each at 10,000 gauss of magnetic field strength, and addih$\upsilon$n of Sodium tripolyphosphate as a dispersant was effected to get low grade F Fe,Ol and TiO, concentrate. PhYSIcal properties of this stone sludge product were showed 58.5% of whiteness, 1 13.4% of firing shrinkage and 3.0812 $\textrm{m}^2$/g of specific surface area.

• Resources Recycling
• /
• v.28 no.5
• /
• pp.74-79
• /
• 2019

The effects of equivalent of iron powder, particle size, agitation speed on the removal efficiency of copper ion were investigated by adding iron powder as cementation agents to simulated mine drainage solution with 117.15 mg/L Cu ion. The 50 % of Cu was removed at 90 min with 2 equivalent of iron powder while more than 99 % of Cu was removed at 60 min with 16 equivalent at 200 rpm and $20^{\circ}C$. The removal efficiencies of Cu ion were not different using 2 equivalent of $48{\mu}m$ and $150{\mu}m$ iron powder, and the removal efficiency increased rapidly with increasing the agitation speed to more than 400 rpm. This lower removal efficiency resulted from agglomeration of iron powder observed by SEM, which could reduce the effective specific surface area. More than 99 % of copper ion was removed using 2 equivalent of $48{\mu}m$ iron powder at 60 min, 600 rpm and $20^{\circ}C$.

• Journal of the Korean Magnetics Society
• /
• v.5 no.6
• /
• pp.928-936
• /
• 1995

In this research, the processing control of NiCuZn Ferrite has been developed. The mixing and the size reduction of raw materials have been proceeded. In order to produce NiCuZn Ferrite, highly concentrated slurry with fixed ratio and wet ball milling were used. First, the dispersion behavior of raw mixture at the region of pH4~pH11 has been studied. Using wet ball milling operation, the best conditions of mixing and size reduction have been determined. Further more, the most suitable conditions, such as, dispersant kind, dispersant amount, milling time, and slurry concentration have been studied. The poly acrylic ammonium salt (PAN) was chosen as a suitable dispersant to have effective dispersion in basic region. The slurry of raw mixture without dispersant, showed high viscosity and poor grindability. As 0.7 wt% of PAN was added, the concentrated slurry (up to 55 vol%) was possible, and showed well grindability. After 18 h ball milling of 30 vol% of mixture slurry with 0.7 wt% of PAN, the average particle size and specific surface area of raw mixture were $0.54\mu\textrm{m}$ and $12.92m^{2}/cc$, respectively. The ball milled raw mixture, calcined at $700^{\circ}C$ for 3h, was totally changed into NiCuZn Ferrite with spinel phase.

• Korean Chemical Engineering Research
• /
• v.57 no.6
• /
• pp.861-867
• /
• 2019

$Li_4Ti_5O_{12}$ is a promising next-generation anode material for lithium-ion batteries due to excellent cycle life, low irreversible capacity, and little volume expansion during charge-discharge process. However, it has poor charge capacity at high current density due to its low electrical conductivity. To improve this weakness, porous $Li_4Ti_5O_{12}$ was synthesized by sol-gel method with P123 as chelating agent. The physical characteristics of as-prepared sample was investigated by XRD, SEM, and BET analysis, and electrochemical properties were characterized by cycle performance test, cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS). $Li_4Ti_5O_{12}$ synthesized by 0.01mol ratio of P123/Ti showed most unified particle size, high specific surface area, and relatively high porosity. EIS analysis showed that depressed semicircle size was remarkably reduced, which suggested resistance value in electrode was decreased. Capacity in rate performance showed 178 mAh/g at 0.2C, 170 mAh/g at 0.5C, 110 mA/h at 5C, and 90 mAh/g at 10C. Capacity retention also showed 99% after rate performance.

• Applied Chemistry for Engineering
• /
• v.32 no.6
• /
• pp.599-606
• /
• 2021

In this study, an experiment and a reaction characteristic study were conducted to enhance the reaction activity of V₂O₅/WO₃/TiO₂ at 300 ℃ or less by adding selenium to the support, in a selective catalytic reduction method using ammonia as a reducing agent to remove nitrogen oxides. Se-TiO₂ and TiO₂ were synthesized using the sol-gel method, and used as a support when preparing V₂O₅/WO₃/TiO₂ and V₂O₅/WO₃/Se-TiO₂ catalysts. The reaction activity of our catalyst was compared with that of a commercial catalyst. The denitration efficiency of the catalyst using TiO₂ prepared by the sol-gel method was lower than that of the catalyst prepared using commercial TiO₂, but was improved by the addition of selenium. Thus, the effect of selenium addition on the catalyst structure was analyzed using BET, XRD, Raman, H₂-TPR, and FT-IR measurements and the effect of the increase in specific surface area by selenium addition and the formation of monomer and complex vanadium species on reaction characteristics were confirmed.

• Applied Chemistry for Engineering
• /
• v.32 no.5
• /
• pp.524-531
• /
• 2021

Depending on the type and amount of acid used as a modulator in the manufacturing process, the structural properties of UiO-66 can be modified and the adsorbability of chemical warfare agents can be enhanced. In this study, several acids as a modulator were used to synthesize UiO-66. Their properties were analyzed with FT-IR, XRD, titrator, and adsorption isotherms using chemical warfare agent simulant, DIMP. The UiO-66, structurally damaged by hydrochloric acid as a modulator, showed lower crystallinity and DIMP adsorption capacity and also smaller specific surface area and volume of voids compared to those of UiO-66, which was manufactured using acetic acid, and formic acid as a modulator. Additionally, UiO-66 which was synthesized by adding formic acid and hydrochloric acid as a modulator, showed the highest DIMP adsorption capacity and is likely to be used as an adsorbent for chemical warfare agent in the future.