• 한국분말재료학회지
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• 제17권5호
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• pp.379-384
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• 2010

In the present work, bismuth nanopowders with various particle size distributions were synthesized by controlling argon (Ar) gas flow rate and chamber pressure of a gas condensation (GC) apparatus. From the analyses of transmission electron microscopy (TEM) images and nitrogen gas adsorption results, it was found that as Ar gas flow rate increased, the specific surface area of bismuth increased and the average particles size decreased. On the other hand, as the chamber pressure increased, the specific surface area of bismuth decreased and the average particles size increased. The optimum gas flow rate and chamber pressure for the maximized electrochemical active surface area were determined to be 8 L/min and 50 torr, respectively. The bismuth nanopowders synthesized at the above condition exhibit 13.47 $m^2g^{-1}$ of specific surface area and 45.6 nm of average particles diameter.

• Carbon letters
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• 제4권4호
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• pp.168-174
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• 2003

Silver nitrate ($AgNO_3$) powder was mixed into a reformed pitch precursor. Then, the silver-containing pitch was melt spun to form round and "C" shape fibers. A wire mesh was inserted prior to the nozzle to improve the spinnability of the silvercontaining precursor pitch. Silver particles in the carbon fibers (CFs) were detected by XRD and TEM. These tests showed that silver particles were uniformly distributed and the total amount of silver remained constant during stabilization and carbonization. Next, the silver-containing CFs were activated by steam diluted in nitrogen gas. Silver particles accelerated the activation rate, but the specific surface areas of the silver-containing ACFs were similar to those of non-silver containing ACFs at the same burn-off levels. The specific surface area of the C-shaped activated carbon fibers was larger than that of the round activated carbon fibers. The likely reason is that the surface area of a C-shaped CF is about two times larger than that of a round CF when equivalent cross-sectional areas are compared. A small amount of silver particles in the periphery of the CFs was removed during the activation, but the remainder of silver was stayed within the ACFs.

• 대한화장품학회지
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• 제19권1호
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• pp.85-107
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• 1993

화장품에 사용되는 미분체의 혼합특성을 알기 위하여 화장품용 미분체 혼합기인 ribbon mixer, powder mixer micropulverizer, fine impact mill에 미립자, 구상 및 판상의 형태를 가진 bulk powders를 혼합시간을 변화 시키면서 혼합하는 실험을 하였다. 혼합분체의 혼합정도를 평가하기 위하여 산화철을 tracer로 사용하였으며, 원료 및 혼합물의 particle size distribution, specific surface area, density 및 표면색상을 측정하였다. 미분체 혼합물의 혼합시간과 표면색상변화, 입도분포 및 비표면적과의 사이에 대수적 1차 상관관계가 성립되었고, 색상의 변화로부터 혼합정도를 평가할 수 있는 간단한 식을 도출하였다. 사용된 혼합기에 대해 혼합기구별 modelling과 혼합에 따른 입도 분포 및 비표면적의 변화로부터 혼합기 impellar tip에서의 linear velocity별 혼합기는 대류혼합, 전단혼합 및 확산혼합으로 분류되었다.

• 대한설비공학회지:설비저널
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• 제17권1호
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• pp.74-82
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• 1988

A numerical analysis of the mathematical model for fluidized bed coal combustion has been performed. Based on the physical nature of the specific surface variation due to the decreasing of coal particle diameter according to the combustion process, the modified model which has been added the specific surface variation to the S.ENDRENYI and B.PALANCZ's mathematical model was established in this study. From the numerical analysis of these two models, it was found that the perfect combustion time is increasing largely at least 5 seconds in the modified model in comparison with that of the S.ENDRENYI and B.PALANCZ's model, and the bed temperature and the coal particle surface temperature during the main combustion period represent constant with time in the S.ENDRENYI and B.PALANCZ's model, on the other hand, these properties are decreasing linearly with time in the modified model.

• 대한건축학회논문집:구조계
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• 제34권2호
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• pp.49-56
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• 2018

The use of highly absorptive materials in cement-based materials is increasing for internal curing purpose. However, calculation of correct absorption capacity of such materials is not easy, which leads to change in the effective water-to-cement ratio of cement paste by either absorbing or releasing water. In this study, effective absorption capacity of a highly absorptive material was found using isothermal calorimetry. Moreover, the effect of specific surface area was investigated. It was found that the method was capable of finding effective water absorption capacity of activated carbon fiber. For the activated carbon fiber used in this research, the effect of specific surface area was negligible because the high BET surface area was due to micropores less than 1nm, which does not affect the rate of hydration curve. Thus, the effective absorption capacity of such materials can be found successfully using this method.

• Nuclear Engineering and Technology
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• 제3권1호
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• pp.21-31
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• 1971

금속의 소성변형에 필요한 일의 일부는 전표면자유에너지 (Total Surface Free Energy)의 변화에 소모된다. 전표면자유에너지 변화는 비표면 자유에너지 (Specific Surface Free Energy)에 의해 변화하며 비표면자유에너지는 분위기에 따라 달라 진다. 열역학적규명, 체적불변율과 흡착으로 인한 두 개의 판이하게 다른 강화 혹은 약화를 초래하는 전위(Dislocation) 상호작용기구를 기반으로 금속의 소성변형으로 인한 가공경화, 응력 및 에너지에 미치는 분위기의 영향을 이론식으로 도출했다. 이론식은 진공중금속표면장력 (${\gamma}$$_{s}$), 개면장력 (${\gamma}$$_{se}$ ), 포면전위밀도($\rho$$_{s}$), 내부전위 밀도($\rho$$_{i}$)와 표면노출율(f)의 함수로 표시할 수 있었다. 이론식을 이용하여 각기 다른 분위기내에서의 금속의 기계특성을 예측 비교해봤다.다.다.

• Carbon letters
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• 제9권1호
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• pp.23-27
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• 2008

The adsorption and reduction of Cr (VI) to Cr (III) by surface modified activated carbon (AC) in an aqueous solution was studied. The effects of surface modifications on the properties of the carbons were investigated by the analysis of specific surface area, carbon surface pH, acid/base surface values and functional groups. In order to understand the Cr(VI) adsorption and reduction ratio from Cr(VI) to Cr(III), the Cr adsorption capacity of AC was also measured and discussed by using inductively coupled plasma and UV spectrophotometer. The modifications bring about substantial variation in the chemical properties whereas the physical properties such as specific surface area, pore volume and pore size distribution nearly were not changed. Total Cr adsorption efficiency of as-received activated carbon (R-AC) and nitric acid treated activated carbon (N1-AC and N2-AC) were recorded on 98.2, 99.7 and 100%. Cr(III) reduction efficiency of R-AC increased largely from 0.4% to 28.3% compared to N1-AC and N2-AC.

• 한국표면공학회지
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• 제47권1호
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• pp.13-19
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• 2014

The various surface treated conditions of Fe-3.0%Ni-0.7%Cr-1.4%Mn-X steel such as as-received, ion nitriding, DLC coated, DLC coated after nitriding for 3 hrs and 6 hrs were investigated to evaluate the beneficial effect for plastic mold steel. Micro Vickers hardness tester was used to estimate nitriding depth from the hardness profile and to measure hardness on the surface. Elastic modulus and residual stress were measured by a nanoindentator. Scratch test and SP (small ball punch test) were utilized to assess the adhesive strength of DLC coating. The depth of nitriding layer was measured as $50{\mu}m$ for the condition of 3 hrs nitriding and $90{\mu}m$ for that of 6 hrs nitriding. Hardness, elastic modulus, residual stress of DLC coating were 20.37 GPa, 162.78 GPa and -1456 MPa respectively. Residual stress on the surface of DLC coating after nitriding could increase to -3914 MPa by introducing nitriding before DLC coating. During the 'Ball-On-Disc' test ${\gamma}^{\prime}$ particles pulled out from the surface of nitrized layer tend to enhance abrasive wear mode since the fraction of ${\gamma}^{\prime}$ (Fe4N) in ion-nitrized layer is known to increases with nitriding time. Thus the specific wear rate of the nitriding layer increased. Comparing with nitriding the specific wear rate in work piece disc as well as ball decreased prominently in DLC coating due to the remarkable reduction in friction coefficient.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1999년도 학회창립 10주년 기념 1999년도 가을 학술발표회 논문집
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• pp.81-84
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• 1999

In this study, the influence of specific surface area of cement, substitution ratio of gypsum anhydrite on the physical properties of concrete were investigated by measurements of slump, air content and compressive strength. The results showed that reducing the specific surface area of cement under 3200$\textrm{cm}^2$/g and using 20% of gypsum anhydrite were desirable to prevent the decrease in workability and strength of concrete in summer season.

• International Journal of Concrete Structures and Materials
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• 제7권4호
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• pp.287-293
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• 2013

Strength and some durability properties of concrete containing rice husk ash (RHA) predominantly composed of amorphous silica at a specific surface of 235 $m^2/kg$ produced using a charcoal incinerator were determined. The maximum ordinary Portland cement (OPC) replacement with the RHA increased with increase in water/binder (w/b) ratio of the concrete mixes. The results show that 15 % OPC could be substituted by the RHAwithout strength loss at w/b ratio of 0.50. The split tensile strength generally increased with increase in RHA content for the mixes.