• Journal of Powder Materials
• /
• v.17 no.5
• /
• pp.379-384
• /
• 2010

In the present work, bismuth nanopowders with various particle size distributions were synthesized by controlling argon (Ar) gas flow rate and chamber pressure of a gas condensation (GC) apparatus. From the analyses of transmission electron microscopy (TEM) images and nitrogen gas adsorption results, it was found that as Ar gas flow rate increased, the specific surface area of bismuth increased and the average particles size decreased. On the other hand, as the chamber pressure increased, the specific surface area of bismuth decreased and the average particles size increased. The optimum gas flow rate and chamber pressure for the maximized electrochemical active surface area were determined to be 8 L/min and 50 torr, respectively. The bismuth nanopowders synthesized at the above condition exhibit 13.47 $m^2g^{-1}$ of specific surface area and 45.6 nm of average particles diameter.

• Carbon letters
• /
• v.4 no.4
• /
• pp.168-174
• /
• 2003

Silver nitrate ($AgNO_3$) powder was mixed into a reformed pitch precursor. Then, the silver-containing pitch was melt spun to form round and "C" shape fibers. A wire mesh was inserted prior to the nozzle to improve the spinnability of the silvercontaining precursor pitch. Silver particles in the carbon fibers (CFs) were detected by XRD and TEM. These tests showed that silver particles were uniformly distributed and the total amount of silver remained constant during stabilization and carbonization. Next, the silver-containing CFs were activated by steam diluted in nitrogen gas. Silver particles accelerated the activation rate, but the specific surface areas of the silver-containing ACFs were similar to those of non-silver containing ACFs at the same burn-off levels. The specific surface area of the C-shaped activated carbon fibers was larger than that of the round activated carbon fibers. The likely reason is that the surface area of a C-shaped CF is about two times larger than that of a round CF when equivalent cross-sectional areas are compared. A small amount of silver particles in the periphery of the CFs was removed during the activation, but the remainder of silver was stayed within the ACFs.

• Journal of the Society of Cosmetic Scientists of Korea
• /
• v.19 no.1
• /
• pp.85-107
• /
• 1993

The cosmetic fine powders were mixed with variation of mixing time(5) in the mixers (ribbon mixer, powder mixer, micropulverizer and fine impact mill). The powders were nixed with small amount of ferric oxide. as tracer. The mixed powders ere measured the particle size distribution, specific surface area and surface color with mixing time (s). The color variation, particle size distribution and specific surface area of the mixed powder exist a relationship with mining time(s) that can be expressed as mathematical equations to show the degree of the mixing of the powder mixture. The linear velocity of the impellar tip is the main factor contributing to he mixing efficiency of the mixers un this study. According to the linear velocity, he mixers used are devieded as convection mixing (ribbon mixer), sclera mixing powder mixer) and diffusion mixing (micropulverizer/fine impact mill).

• The Magazine of the Society of Air-Conditioning and Refrigerating Engineers of Korea
• /
• v.17 no.1
• /
• pp.74-82
• /
• 1988

A numerical analysis of the mathematical model for fluidized bed coal combustion has been performed. Based on the physical nature of the specific surface variation due to the decreasing of coal particle diameter according to the combustion process, the modified model which has been added the specific surface variation to the S.ENDRENYI and B.PALANCZ's mathematical model was established in this study. From the numerical analysis of these two models, it was found that the perfect combustion time is increasing largely at least 5 seconds in the modified model in comparison with that of the S.ENDRENYI and B.PALANCZ's model, and the bed temperature and the coal particle surface temperature during the main combustion period represent constant with time in the S.ENDRENYI and B.PALANCZ's model, on the other hand, these properties are decreasing linearly with time in the modified model.

• Journal of the Architectural Institute of Korea Structure & Construction
• /
• v.34 no.2
• /
• pp.49-56
• /
• 2018

The use of highly absorptive materials in cement-based materials is increasing for internal curing purpose. However, calculation of correct absorption capacity of such materials is not easy, which leads to change in the effective water-to-cement ratio of cement paste by either absorbing or releasing water. In this study, effective absorption capacity of a highly absorptive material was found using isothermal calorimetry. Moreover, the effect of specific surface area was investigated. It was found that the method was capable of finding effective water absorption capacity of activated carbon fiber. For the activated carbon fiber used in this research, the effect of specific surface area was negligible because the high BET surface area was due to micropores less than 1nm, which does not affect the rate of hydration curve. Thus, the effective absorption capacity of such materials can be found successfully using this method.

• Nuclear Engineering and Technology
• /
• v.3 no.1
• /
• pp.21-31
• /
• 1971

The part of the work of plastic deformation of metal goes into the changes in the total surface free energy. This contribution is dependent on the specific surface free energy, which is affected by the environment. Based on thermodynamical approach, volume constancy requirement and adsorption induced two distinct dislocation interaction mechanisms for strengthening or weakening of metals at surface, theoretical derivation has been made to show that the environmental contribution on the strain hardening, the stress and the energy required for plastic deformation can be expressed in terms of solid surface tension in vacuum (${\gamma}$$_{s}$), interfacial tension (${\gamma}$$_{se}$ ), surface dislocation density ($\rho$$_{s}$), internal dislocation density ($\rho$$_{i}$) and fraction of surface site uncoverage (f). On the basis of theoretical derivation, the various mechanical behaviours under different environments are predicted.d.d.

• Carbon letters
• /
• v.9 no.1
• /
• pp.23-27
• /
• 2008

The adsorption and reduction of Cr (VI) to Cr (III) by surface modified activated carbon (AC) in an aqueous solution was studied. The effects of surface modifications on the properties of the carbons were investigated by the analysis of specific surface area, carbon surface pH, acid/base surface values and functional groups. In order to understand the Cr(VI) adsorption and reduction ratio from Cr(VI) to Cr(III), the Cr adsorption capacity of AC was also measured and discussed by using inductively coupled plasma and UV spectrophotometer. The modifications bring about substantial variation in the chemical properties whereas the physical properties such as specific surface area, pore volume and pore size distribution nearly were not changed. Total Cr adsorption efficiency of as-received activated carbon (R-AC) and nitric acid treated activated carbon (N1-AC and N2-AC) were recorded on 98.2, 99.7 and 100%. Cr(III) reduction efficiency of R-AC increased largely from 0.4% to 28.3% compared to N1-AC and N2-AC.

• Journal of the Korean institute of surface engineering
• /
• v.47 no.1
• /
• pp.13-19
• /
• 2014

The various surface treated conditions of Fe-3.0%Ni-0.7%Cr-1.4%Mn-X steel such as as-received, ion nitriding, DLC coated, DLC coated after nitriding for 3 hrs and 6 hrs were investigated to evaluate the beneficial effect for plastic mold steel. Micro Vickers hardness tester was used to estimate nitriding depth from the hardness profile and to measure hardness on the surface. Elastic modulus and residual stress were measured by a nanoindentator. Scratch test and SP (small ball punch test) were utilized to assess the adhesive strength of DLC coating. The depth of nitriding layer was measured as $50{\mu}m$ for the condition of 3 hrs nitriding and $90{\mu}m$ for that of 6 hrs nitriding. Hardness, elastic modulus, residual stress of DLC coating were 20.37 GPa, 162.78 GPa and -1456 MPa respectively. Residual stress on the surface of DLC coating after nitriding could increase to -3914 MPa by introducing nitriding before DLC coating. During the 'Ball-On-Disc' test ${\gamma}^{\prime}$ particles pulled out from the surface of nitrized layer tend to enhance abrasive wear mode since the fraction of ${\gamma}^{\prime}$ (Fe4N) in ion-nitrized layer is known to increases with nitriding time. Thus the specific wear rate of the nitriding layer increased. Comparing with nitriding the specific wear rate in work piece disc as well as ball decreased prominently in DLC coating due to the remarkable reduction in friction coefficient.

• Proceedings of the Korea Concrete Institute Conference
• /
• 1999.10a
• /
• pp.81-84
• /
• 1999

In this study, the influence of specific surface area of cement, substitution ratio of gypsum anhydrite on the physical properties of concrete were investigated by measurements of slump, air content and compressive strength. The results showed that reducing the specific surface area of cement under 3200$\textrm{cm}^2$/g and using 20% of gypsum anhydrite were desirable to prevent the decrease in workability and strength of concrete in summer season.

• International Journal of Concrete Structures and Materials
• /
• v.7 no.4
• /
• pp.287-293
• /
• 2013

Strength and some durability properties of concrete containing rice husk ash (RHA) predominantly composed of amorphous silica at a specific surface of 235 $m^2/kg$ produced using a charcoal incinerator were determined. The maximum ordinary Portland cement (OPC) replacement with the RHA increased with increase in water/binder (w/b) ratio of the concrete mixes. The results show that 15 % OPC could be substituted by the RHAwithout strength loss at w/b ratio of 0.50. The split tensile strength generally increased with increase in RHA content for the mixes.