• Title/Summary/Keyword: specific discharge

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Electrochemical Characteristics of PFO pitch Anode prepared by Chemical Activation for Lithium Ion Battery (리튬이온전지용 화학적 활성화로 제조된 석유계 피치 음극소재의 전기화학적 특성)

  • Hwang, Jin Ung;Lee, Jong Dae
    • Korean Chemical Engineering Research
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    • v.55 no.3
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    • pp.307-312
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    • 2017
  • In this study, the electrochemical performance of surface modified carbon using the PFO (pyrolyzed fuel oil) was investigated by chemical activation with KOH and $K_2CO_3$. PFO was heat treated at $390{\sim}400^{\circ}C$ for 1~3h to prepared the pitch. Three carbon precursors (pitch) prepared by the thermal reaction were 3903 (at $390^{\circ}C$ for 3h), 4001(at $400^{\circ}C$ for 1h) and 4002 (at $400^{\circ}C$ for 2h). Also, the effect of chemical activation catalysts and mixing time on the development of porosity during carbonization was investigated. The prepared carbon was analyzed by BET and FE-SEM. It was shown that chemical activation with KOH could be successfully used to develop carbon with specific surface area ($3.12m^2/g$) and mean pore size (22 nm). The electrochemical characteristics of modified carbon as the anode were investigated by constant current charge/discharge, cyclic voltammetry and electrochemical impedance tests. The coin cell using pitch (4002) modified by KOH has better initial capacity (318 mAh/g) than that of other pitch coin cells. Also, this prepared carbon anode appeared a high initial efficiency of 80% and the retention rate capability of 2C/0.1 C was 92%. It is found that modified carbon anode showed improved cycling and rate capacity performance.

A Determination of the Maximum Potential Runoff of Small Rural Basins (소하천(小河川) 유역(流域)의 잠재유출량(潛在流出量) 결정(決定))

  • Yoon, Yong Nam;Hong, Chang Seon
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.2 no.1
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    • pp.53-62
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    • 1982
  • An effort of preliminary type has been made to develope a practical method for the waterway area determination of a drainage outlet in rural or agricultural areas. The Seoul meteorological station was selected as tile index station, and the maximum rainfalls-duration-frequency (R-D-F) relation of short-time intense rainfalls was first established. A frequency analysis of the daily rainfalls for the 75 stations selected throughout the country resulted the 50-year daily rainfall for each station. The rainfall factor, which is defined here as the ration of 50-year daily rainfalls of individual station and the index station, was determined for the 8 climatological regions divided in this study. Following the US SCS method the runoff number of a watershed was given based on the soil type, land-use pattern, and the surface treatment. With this runoff number and the R-D-F relationship the runoff factors for the index station were computed and hence a nomogram could be drawn which makes it possible to determine the runoff factor for a given rainfall number and a rainfall of specific duration and frequency. With this done, the potential runoff of a watershed for a given rainfall duration could be calculated, based on the unit hydrograph theory, by multiplying the rainfall factor, the runoff factor, and the drainage area of the watershed under consideration. Then, the maximum runoff potential was determined by varying the rainfall duration and finding out the duration which results the peak discharge of a gived return period.

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The analysis of the cultivation status of the upland crops in the paddy field using unmanned aerial vehicle

  • Park, Jin-Ki;Kwak, Kang-Su;Park, Jong-Hwa
    • Proceedings of the Korean Society of Crop Science Conference
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    • 2017.06a
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    • pp.352-352
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    • 2017
  • Recently, the South Korean government encourages the cultivation of upland crops in the paddy field to maintain an adequate level of rice production and then to balance the demand and supply of rice. This is mainly because the rice consumption per capita per year has continued to decline from 135 kg in 1979 to 61.9 kg in 2016, although the rice production was relatively stable. As a result, the rice overproduction became a big social problem. As a part of that, various upland crops such as soybean, maize, minor cereals and forage crops are planted in the paddy field 10 years ago. The cultivation of these crops may settle the problem of short supply and mass import of the crops to some extent. However, a systematic remote observation of upland crops in the paddy field is very scarce. This study investigated the cultivation status of upland crops and any changes of crop harvesting in the paddy field by using an unmanned aerial vehicle (UAV). Also, we analyzed the kind of upland crops and cultivation area in the paddy field by utilizing time series observation images. A fixed wing UAV is used for the investigation. This is because it is easy to use the flight operation and to control flight management software, and it can automatically cope with various emergency states such as a strong wind and battery discharge. The material of UAV is expanded polypropylene, which has an advantage of less equipment damage and risk during takeoff and landing. We acquired observed images in Buljeong-myeon, Goesan-gun, Chungcheongbuk-do, South Korea by using fixed wing UAV in 2015 and 2016. The total investigated area reaches 6,045 ha, and among them the agricultural area was 1,377 ha. For the next step, we created an orthoimage from all images taken using Pix 4D mapper program. According to the results of image analyses in 2015, the paddy field covered total 577 ha (75.9%) with crop plant. The cultivation area of beans, ginseng, maize, tobacco and peach was 256 ha (36.6%), 63 ha (9.2%), 37 ha (5.4%), 31 ha (4.5%) and 27 ha (3.8), respectively. And in 2016, the total covered area was 586 ha (77.1%), and it was comprised of 253 ha (35.5%), 88 ha (12.3%), 29 ha (4.1%), 22 ha (3.1%) and 32 ha (4.5%) in the same order. In this study, we focused on identifying the paddy field which was converted to the cultivation of upland crops by using UAV. And, it has been indicated that the cultivation area of rice decreased from 141 ha in 2015 to 127 ha in 2016, although that of ginseng increased by 25 ha. As a result, it is expected that a lot of paddy field could be replaced by high-income crops such as ginseng and fruit tree (peach) instead of relative low-income rice. More specific and widespread research on the remote sensing in the paddy field needs to be done.

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The Evaluation for Maximum Chl. a Site Observed in the Mid to Lower Nakdong River (낙동강 중${\cdot}$하류수역에서 클로로필 a 최대농도 출현지역 평가)

  • Shin, Sung-Kyo;Baek, Kyung-Hoon;Song, Mi-Koung
    • Korean Journal of Ecology and Environment
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    • v.35 no.1 s.97
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    • pp.21-27
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    • 2002
  • The frequent occurrence of excessive phytoplankton populations in the downstream Nakdong River has been an important water quality problem in recent years. The limnological survey of the Nakdong River was conducted from January 1997 to December 1999 on once or twice per month. A typical phenomenon of eutrophication appears with the persistent algal bloom due to high nutrients in the mid-lower part of the river. This study showed that the point at which Chl. a concentration reaches maximum was affected by the water temperature and the flow rate. For example, Chl. a concentration reached maximum after around 380, 240 and 120 hours which were estimated from the time of flow at low (${\le}10^{\circ}C$), mean ($10{\sim}20^{\circ}C$) and high (${\ge}20^{\circ}C$) water temperature conditions, respectively. It was estimated that increase coefficients of phytoplankton (Chl. a) on the water temperature are 0.201, 0.254 and $0.289\;day^{-1}$, on the contrary, decrease coefficients are -0.012, -0.128 and $-0.193\;day^{-1}$ in low, mean and high water temperature. Therefore, to prevent formation of Chl. a maximum concentration in the specific water resource, it is necessary to increase the discharge of dam as well as to decrease.

Combined Removal of n-heptane and CO using Plasma-catalytic Process (플라즈마/촉매 공정을 이용한 n-헵테인과 일산화탄소 동시제거)

  • Lee, Sang Baek;Jo, Jin Oh;Mok, Young Sun
    • Journal of the Korean Institute of Gas
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    • v.20 no.2
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    • pp.1-9
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    • 2016
  • Combined removal of n-heptane and carbon monoxide (CO) using a plasma-catalytic process was investigated. The performance of the plasma-catalytic process was compared with that of the catalyst-alone process to characterize the decomposition of n-heptane and CO with the operation parameters such as the type of catalyst, reaction temperature, and discharge power. From several sets of experiments, it was found that the decomposition efficiency of n-heptane mainly depended on the specific input energy rather than the reactor temperature, whereas the oxidation of CO on both the energy density and the reaction temperature. The results conducted over several metal oxide catalysts exhibited that the decomposition efficiency of n-heptane was in the order: $Pd/{\gamma}-Al_2O_3$ > $Ru/{\gamma}-Al_2O_3{\approx}Ag/{\gamma}-Al_2O_3$. Especially, $Pd/{\gamma}-Al_2O_3$ catalyst did hardly generate CO as a byproduct during the decomposition of n-heptane under an appropriate condition, revealing $CO_2$ selectivity of nearly 100%. The CO oxidation efficiency was largely affected by the type of catalyst ($Pd/{\gamma}-Al_2O_3$ > $Ru/{\gamma}-Al_2O_3$ > $Ag/{\gamma}-Al_2O_3$). At temperatures below $180^{\circ}C$, the plasma-catalytic process was more effective in the oxidation of CO, while above $180^{\circ}C$, the catalytic process resulted in slightly higher CO oxidation efficiency.

Regional frequency analysis using spatial data extension method : II .Flood frequency inference for ungaged watersheds (공간확장자료를 이용한 지역빈도분석 : II. 미계측 유역의 홍수빈도 추론)

  • Kim, Nam Won;Lee, Jeong Eun;Lee, Jeongwoo;Jung, Yong
    • Journal of Korea Water Resources Association
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    • v.49 no.5
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    • pp.451-458
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    • 2016
  • In order to infer regional flood frequency for ungauged watersheds, index flood method was applied for this study. To pursuit this given purpose, annual peak flood data for 22 watersheds located at the upstream of the Chungju Dam watershed were obtained from the spatial extension technique. The regionalization of mean annual flood was performed from extended flood data at 22 points. Based on the theory that flood discharge and watershed size follows the power law the regionalization generated the empirical relationship. These analyses were executed for the full size of the Chungju Dam watershed as one group and three different mid-size watersheds groups. From the results, the relationship between mean annual flood and watershed sizes follow the power law. We demonstrated that it is appropriate to use the relationship between specific flood discharges from the upper and lower watersheds in terms of estimating the floods for the ungaged watersheds. Therefore, not only the procedure of regional frequency analysis but also regionalizaion analaysis using finer discretization of the regions interest with respect to the regional frequency analyisis for the ungauged watersheds is important.

Determination of Model Parameters of Surface Cover Materials in Evaluation of Sediment Reduction and Its Effects at Watershed Scale using SWAT (토양유실 저감을 위한 지표피복 저감효과 변수 결정 및 SWAT 모형 유역단위 효과 분석)

  • Kum, Donghyuk;Jang, Chun Hwa;Shin, Min Hwan;Choi, Joong-Dae;Kim, Bomchul;Jeong, Gyo-Cheol;Won, Chul Hee;Lim, Kyoung Jae
    • Journal of Korean Society on Water Environment
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    • v.28 no.6
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    • pp.923-932
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    • 2012
  • The purpose of this study was to determine parameters of surface cover materials and evaluation the effects on runoff and sediment reductions with rice straw mat with PAM at watershed scale using the SWAT model. In this study, 1) regression equation of CN for rice straw mat + PAM using SCS curve number method was developed, 2) the USLE P factor, being able to reflect simulation of rice straw mat + PAM in the agricultural field, was estimated for various slope scenarios with VFSMOD-w. Then regression equation for CN and USLE P factor were used as input data in the SWAT model. Assuming rice straw mat + PAM is applied to radish and potato fields, occupying 24% of agricultural fields at the study watershed. Result of direct runoff without rice straw mat + PAM was $65,964,368\;m^3,$ with rice straw mat + PAM, direct runoff was $65,637,336\;m^3$, $327,031.8\;m^3$ reductions compared without it. Also, result of sediment without rice straw mat + PAM was 163,531 ton, with rice straw mat + PAM, sediment was 84,779 ton, 78,752 ton reduction compared without it. This analysis showed that about 48% sediment reductions would be expected with rice straw mat + PAM. As shown in this study, rice straw mat + PAM would be used as an efficient site-specific BMPs to reduce runoff and sediment discharge from field.

A Study of Adenovirus Pneumonia: Early Summer Outbreak in 1996 (1996년 초여름에 유행한 Adenovirus폐렴의 검토)

  • Kim, Chang Keun;Chung, Churl Young;Kim, Jung Suk;Lee, Hoan Jong
    • Pediatric Infection and Vaccine
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    • v.3 no.2
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    • pp.145-153
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    • 1996
  • The incidence of Adenovirus(AV) pneumonia in children is estimated at 8%. Long-term complications reported with type 7 include hyperleucent lung syndrome, bronchiolitis obliterans and may require several months to recover. We reviewed 8 case of AV pnemonia confirmed by AV culture and sero-diagnosis among selected 19 AV pneumonia suspicious cases who were admitted to the Sanggye Paik Hospital of Inje University due to clinical pneumonia from May to July 1996. From 19 children, nasal aspirates or trachial aspirates were collected: viral agents were detected by virus isolation and virus antigen was detected by indirect immunofluorescent staining. Serologic diagnosis for type-specific AV antibody was done by neutralisation test. The results are as follows: 1) Age of the patients ranged from 6 months to 47 months with a mean of $24{\pm}9$ months. 6 were male and 2 were female(M:F= 3:1). 2) Monthly distribution showed 4 cases on June, 2 cases on May and July, respectively. 3) The mean duration of admission was 20.4 days and mean duration of fever was 11.3 days 4) Peripheral leukocyte counts were elevated in 4 cases(50%) and findings of shift to left were showed in 4 cases(50%) and serum aminotransferase activities were elevated in 6 case(75%). 5) Radiologic findings include linear and streaky infiltration(1/8 cases), patchy and lobar consolidation (7/8 cases), pleural effusion(2/8 cases) and hyperleucency was seen in 3/8 cases at time of admission and increased to 6/8 cases on hospital discharge. 6) The AV serotypes were type 7, type 3, and type 1. 7) Oxygen supply was done in 4 cases(50%) and all 8 patients include 2 cases of type 7 treated with artificial ventilator were survived. In conclusion, the serotypes of AV pneumonia outbreaks in early summer of 1996 were type 7, 3, 1 and, as showed severe clinical course, continued follow up surveillance is necessary to the long term pulmonary complications.

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Assessment of Technology-Based Industrial Wastewater Effluent Limitations and Standards for the Application in Domestic Industries ( I ) : Case-study, Applying TBELs in US (처리기술에 근거한 산업폐수 배출허용기준 국내 적용성 연구( I ) : 미국 TBELs 적용사례 검토)

  • Kim, Kyeongjin;Son, Daehee;Her, Jin;Kim, Kwangin;Kwon, Osang;Yeom, Ictae
    • Journal of Korean Society on Water Environment
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    • v.26 no.1
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    • pp.1-9
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    • 2010
  • Technology-Based Effluent Limitations (TBELs) is a permit limits for a pollutant that is based on the capability of a treatment technology to reduce the pollutant to a certain concentration. Widely practiced for regulations of industrial wastewater in US, TBELs has been accepted as an effective means that can achieve balanced goals between complete elimination of pollutants discharge and economic feasibility for industries. The review of TBELs application in US and the applicability of TBELs to the domestic industry categories was given in three papers. In the first paper, the development and practices of TBELs in US were reviewed including case studies. The developments of TBELs in US in the four major categories, the metal products & machinery, the petroleum refining, the porcelain enameling and the meat & poultry products were reviewed. The applicability of TBELs to the domestic industrial categories was also assessed. In the second paper, the pollution loads analysis for domestic industrial wastewater was conducted based on risk assessment indicator using Toxic Weighting Factors (TWFs). This is an essential part to determine the priority of TBELs application for the domestic industrial categories. In the last paper, the application of TBELs to the domestic industries was demonstrated through a case-study for the pulp/paper/paperboard category. Direct application of TBELs of US into the Korean regulation system may not be desirable because the specific goals and the environment for the regulations for the two countries may not be identical. For example, unlike US, Korea does not adopt the individual permit system for pollution sources. However, among the unproductive and exhaustive controversies over the uniform regulations regardless of the industrial categories in Korea, the introduction of the principles of TBELs are inevitable and more extensive study for applications of TBELs optimized for Korean regulation system will be necessary.

Land-use Enhancement Benefit According to Flood Safety (치수안전도에 따른 토지이용의 편익 분석)

  • Lee, Jin Ouk;Kim, Hung Soo;Shim, Myung Pil;Choi, Seung An
    • Journal of Wetlands Research
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    • v.6 no.4
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    • pp.45-57
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    • 2004
  • This study analyzed the effect of land-use enhancement benefits with the flood safety which it is not quantified in the flood damage analysis, Korea. The land-use enhancement benefits mean the enhancement of land-use value according to the rise of flood safety of the protected area by the flood control projects and we performed the analysis of land-use enhancement benefits with the publicly announced land price which can objectively represent the land-use value of a specific area. We verified the statistical significance of the floating rate of land price according to the effects of flood control projects and the characteristics of a river through the analysis of variance. As a result of the verification, the increase of land-use value was represented by the net annual average floating rate of land price. The flood safety was classified as flood damage potential and flood prevention capacity. The flood damage potential was classified according to the rate of urbanization and flood prevention capacity was represented by the conditional annual non-exceedance probability obtained from the frequency analysis with uncertainty for the flood discharge. The study areas were small urban cities and we calculated the conditional annual non-exceedance probabilities of 200-year flood event for the levees constructed with the conditions of 10- and 50-year design frequency. The result was shown that the net annual average floating rate of land price would be raised nearly 5 times for 10%-increase of the conditional annual non-exceedance probability in small city areas.

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