• 센서학회지
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• 제30권2호
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• pp.71-75
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• 2021

Recently, transition-metal-based hydroxide materials have attracted significant attention in various electrochemical applications owing to their low cost, high stability, and versatility in composition and morphology. Among these applications, transition-metal-based hydroxides have exhibited significant potential in supercapacitors owing to their multiple redox states that can considerably enhance the supercapacitance performance. In this study, nanostructured Ni-Mn double hydroxide is directly grown on a conductive substrate using an electrodeposition method. Ni-Mn double hydroxide exhibits excellent electrochemical charge-storage properties in a 1 M KOH electrolyte, such as a specific capacitance of 1364 Fg-1 at a current density of 1 mAcm-2 and a capacitance retention of 94% over 3000 charge-discharge cycles at a current density of 10 mAcm-2. The present work demonstrates a scalable, time-saving, and cost-effective approach for the preparation of Ni-Mn double hydroxide with potential application in high-charge-storage kinetics, which can also be extended for other transition-metal-based double hydroxides.

• 공업화학
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• 제33권5호
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• pp.523-531
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• 2022

A NiCo-metal organic framework (MOF) electrode, prepared using urea as a surfactant, was synthesized using a one-pot hydrothermal method. The addition of urea to the NiCo-MOF creates interstitial voids and an ultra-thin nanostructure in the NiCo-MOF, which improves its charge transfer performance. We obtained the optimal metal to surfactant ratio to achieve the best specific capacitance. The NiCo-MOF was employed as the working electrode material in a three-electrode system. Field emission scanning electron microscopy, X-ray diffraction, and Fourier-transform infrared spectroscopy were employed to characterize the microstructures and morphologies of the composites. Cyclic voltammetry, galvanostatic charge-discharge, and electrochemical impedance spectroscopy curves were employed to quantify the electrochemical properties of the electrodes in a 6 M KOH electrolyte.

• 로봇학회논문지
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• 제17권1호
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• pp.93-101
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• 2022

Bioheavy oil, which is expanding its range of use as an alternative fuel to reduce environmental pollutant emissions, has a lot of difficulty in combustion due to its low emission of pollutants such as nitrogen oxide (NOx) and sulfur oxide (SOx), while its low dissipation and high oxygen content in fuel. many studies have been conducted on change in characteristics by mixing rate combustion characteristics and combustion reactions, but there have been no specific and effective studies on the composition of control system, optimization of control, development of logic for mixing and burning, minimizing environmental pollutantants discharge. In this study, we intend to consider systemmatic and empirical considerations on the composition, logic development, solve the problem of manual switching of bioler master due to excessive oxygen content and tuning of the control system for optimal combustion of bioheavy oil.

• 전자통신동향분석
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• 제38권5호
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• pp.90-99
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• 2023

Recently, with the trend of information technology convergence and electrification, batteries are being widely used in fields such as industry, transportation, and specific applications. By 2030, the secondary battery market is expected to grow explosively by more than eight times compared with 2020 to $351.7 billion owing to the expanding adoption of electric vehicles. Depending on the electrochemical reactions in the electrode, a primary battery can only discharge through an irreversible reaction, while a secondary battery can be repeatedly charged and discharged using reversible reactions. According to the type of charge carrier ions, secondary batteries may be classified into those made of lithium, sodium, potassium, magnesium, and aluminum ions. We analyze the current status and technological issues of lithium-ion batteries, lithium-sulfur batteries, and solid-state batteries, which are representative examples of lithium secondary batteries. In addition, research trends in lithium secondary batteries are discussed.

• Journal of Periodontal and Implant Science
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• 제42권3호
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• pp.95-104
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• 2012

Purpose: The purpose of this study was to determine whether increasing the Ti6Al4V surface oxide negative charge through heat ($600^{\circ}C$) or radiofrequency plasma glow discharge (RFGD) pretreatment, with or without a subsequent coating with fibronectin, stimulated osteoblast gene marker expression in the MC3T3 osteoprogenitor cell line. Methods: Quantitative real-time polymerase chain reaction was used to measure changes over time in the mRNA levels for osteoblast gene markers, including alkaline phosphatase, bone sialoprotein, collagen type I (${\alpha}1$), osteocalcin, osteopontin and parathyroid hormone-related peptide (PTH-rP), and the osteoblast precursor genes Runx2 and osterix. Results: Osteoprogenitors began to differentiate earlier on disks that were pretreated with heat or RFGD. The pretreatments increased gene marker expression in the absence of a fibronectin coating. However, pretreatments increased osteoblast gene expression for fibronectin-coated disks more than uncoated disks, suggesting a surface oxide-mediated specific enhancement of fibronectin's bioactivity. Heat pretreatment had greater effects on the mRNA expression of genes for PTH-rP, alkaline phosphatase and osteocalcin while RFGD pretreatment had greater effects on osteopontin and bone sialoprotein gene expression. Conclusions: The results suggest that heat and RFGD pretreatments of the Ti6Al4V surface oxide stimulated osteoblast differentiation through an enhancement of (a) coated fibronectin's bioactivity and (b) the bioactivities of other serum or matrix proteins. The quantitative differences in the effects of the two pretreatments on osteoblast gene marker expression may have arisen from the unique physico-chemical characteristics of each resultant oxide surface. Therefore, engineering the Ti6Al4V surface oxide to become more negatively charged can be used to accelerate osteoblast differentiation through fibronectin-dependent and independent mechanisms.

• 대한안전경영과학회:학술대회논문집
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• 대한안전경영과학회 2010년도 추계학술대회
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• pp.63-80
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• 2010

This paper describes the development of various lighting equipment adapting Ultra Constant Discharge Lamp that has newly been on commercial supply in the market. Meeting the required conditions of lighting equipment, various types of UCD Lamp equipment with excellent performances could be successfully developed. In order to provide a guideline for the economical lighting product selection, the analyzed data comparison between Hi-pressure Sodium Lamp which has been the most popular lamp for street lighting and UCD Lamp is provided. The conclusions of the study are made as follows; (1) The performance measurement result of UCD Lamp shows excellent Luminous Efficacy as 108Lm/W, daylight-like Color Rendering Index as 90Ra, and the best operating temperature range as $-50^{\circ}C{\sim}+85^{\circ}C$. Comparing to the Hi-pressure Sodium Lamp, UCD could be evaluated as much superior products. (2) In an assembled status with the lighting fixture (Type STB형-60W), UCD Lamp was tested OK for one hour duration at the temperature range form $-50^{\circ}C$ to $+85^{\circ}C$ and the humidity of 98%. The operation at the extremely low temperature can be an excellent feature to enable the export to the cold temperature regions such as Northern Europe and Russia and the specific applications for defense systems and special industry. (3) As UCD Lamp is a genuine Korea made product following Energy-saving and Eco-friendly policy, it should be appreciated as one of the best $CO^2$ reduction Green product.

• 상하수도학회지
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• 제26권2호
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• pp.177-189
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• 2012

Sediment load deposited in sewers and manholes reduces not only the capacity of pipes but also the efficiency of the whole sewer system. This causes the inundations of the low places and overflows at manholes, Moreover, sulfides and bad odor can occur due to deposited sediment with organic loads in manholes. Movements of sediment load in manholes are complicated depending on manhole size, location, inside structure, sediment load type, and time. Therefore, it is necessary to understand the movements of sediment load in manholes by experiments. In this study, experiments were implemented by a square manhole with straight path to measure deposited sedimentation quantity. The experimental apparatus was consisted of a high water tank, an upstream tank, test pipes, a sediment supplier, a manhole, and a downstream tank to measure the experimental discharge. The quantity of deposited sediment load was measured by different conditions, such as the inflow condition of sediment(continuous and certain period), the amount of inflow sediment, discharge, and the type of sediment. Jumoonjin sand(S=2.63, D50=0.55mm), general sand(GS, S=2.65, D50=1.83mm) and anthracite (S=1.45, D50=0.80mm) were employed for the experiment. The velocities in inflow pipe were 0.45 m/s, 0.67 m/s, and 0.9 m/s. Sediment load movement and sedimentation quantity in manhole were influenced by many factors such as velocity, shear stress, viscosity, amount of sediment, sediment size, and specific gravity. Suggested regression equations can estimated the quantity of deposited sediment in the straight path square manholes. The connoted equations that were evaluated through the experimental study have velocity range from 0.45 to 0.9m/sec. The study results illustrates that appropriation of design velocity ragne between 1.0 and 2.0m/sec could implement to maintain and manage manholes.

• 한국물환경학회지
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• 제34권1호
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• pp.33-45
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• 2018

In this study, we discussed the application of Watershed model and Load Duration Curves (LDC) in Total Water Load Management System. The Flow Duration Curves (FDC) and the LDC were generated using the results of the daily HSPF model and analyzed on monthly or yearly flow duration variability, and non-point pollutant discharge loads by entire flow conditions. As a result of the calibration and verification of the HSPF model, both the flow and the water quality were appropriately simulated. The simulated values were used to generate the Flow Duration Curve and the Load Duration Curve, and then the excess rate by entire flow conditions was analyzed. The point and non-point pollutant discharge loads for entire flow conditions were calculated. It is possible to evaluate the variability of water quality in specific flow duration through the curves reflecting the flow duration variability and to confirm the characteristics of the pollutant source. For a more scientific Total Water Load Management System, it is necessary to switch from a current system to a system that can take into account the entire flow conditions. For this, the application of the watershed model and load duration curve is considered to be the best alternative.

• 한국세라믹학회지
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• 제43권2호
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• pp.121-125
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• 2006

[ $LiFePO_4$ ] is one of the promising materials for cathode material of secondary lithium batteries due to its high energy density, low cost, environmental friendliness and safety. $LiFePO_4$ was synthesized by the solid-state reaction method at 500 - 800°C. The crystal structure of $LiFePO_4$ was analyzed by X-ray powder diffraction. The samples synthesized at 600 and $700^{\circ}C$ showed a single phase of a olivine structure. The particle sizes were increased and the specific surface areas were decreased with heating temperatures. The electrochemical performance was investigated by coin cell test. The discharge capacities at 0.1 C-rate were 118 mAh/g and 112 mAh/g at $600^{\circ}C,\;700^{\circ}C$, respectively. In an attempt to improve the electrical conductivity of cathode materials, $LiFePO_4/graphite$ composite was prepared with various graphite contents. The electrical conductivity and discharge capacity were increased with increasing the graphite contents in composite samples. The rate capabilities at high current densities were also improved.

• 한국재료학회지
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• 제26권5호
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• pp.258-265
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• 2016

Fluorine-doped tin oxide (FTO) nanoparticles have been successfully synthesized using ultrasonic spray pyrolysis. The morphologies, crystal structures, chemical bonding states, and electrochemical properties of the nanoparticles are investigated. The FTO nanoparticles show uniform morphology and size distribution in the range of 6-10 nm. The FTO nanoparticles exhibit excellent electrochemical performance with high discharge specific capacity and good cycling stability ($620mAhg^{-1}$ capacity retention up to 50 cycles), as well as excellent high-rate performance ($250mAhg^{-1}$ at $700mAg^{-1}$) compared to that of commercial $SnO_2$. The improved electrochemical performance can be explained by two main effects. First, the excellent cycling stability with high discharge capacity is attributed to the nano-sized FTO particles, which are related to the increased electrochemical active area between the electrode and electrolyte. Second, the superb high-rate performance and the excellent cycling stability are ascribed to the increased electrical conductivity, which results from the introduction of fluorine doping in $SnO_2$. This noble electrode structure can provide powerful potential anode materials for high-performance lithiumion batteries.