• Title/Summary/Keyword: specific discharge

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Electrochemical Performance of Activated Carbons/Mn3O4-Carbon Blacks for Supercapacitor Electrodes

  • Kim, Ki-Seok;Park, Soo-Jin
    • Bulletin of the Korean Chemical Society
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    • v.34 no.8
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    • pp.2343-2347
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    • 2013
  • In this work, manganese dioxide ($Mn_3O_4$)/carbon black (CB) composites (Mn-CBs) were prepared by an in situ coating method as electrical fillers and the effect of the Mn-CBs on the electrical performance of activated carbon (AC)-based electrodes was investigated. Structural features of Mn-CBs produced via in situ coating using a $KMnO_4$ solution were confirmed by XRD and TEM images. The electrical performances, including cv curves, charge-discharge behaviors, and specific capacitance of the ACs/Mn-CBs, were determined by cyclic voltammograms. It was found that the composites of $Mn_3O_4$ and CBs were successfully formed by in situ coating method. ACs/Mn-CBs showed higher electrical performance than that of AC electrodes fabricated with conventional CBs due to the pesudocapacitance reaction of manganese oxides in the aqueous electrolyte. Consequently, it is anticipated that the incorporation of $Mn_3O_4$ into CBs could facilitate the utilization of CBs as electrical filler, leading to enhanced electrochemical performance of AC electrodes for supercapacitors.

Fabrication and Output Characteristics of Compact Capacitor Transfer XeCl Laser (용량이행영 소형 XeCl레이저 제작 및 출력특성)

  • 김동환
    • Korean Journal of Optics and Photonics
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    • v.4 no.1
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    • pp.57-65
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    • 1993
  • Small XeCl laser of charge transfer discharge excitation was fabricated and output charateristics were investigated according to gas mixture ratio. Beam cross section of 2.7cm${\times}$1.5cm was obtained by constructing excimer laser which preionization is operated automatically and which has chang profile electrode. According to the component gas mixture ratio, the condition of maximum output energy, efficiency were investigated. The maximum energy, efficiency and specific energy were obtained 230 mJ, 1.6% and 1.1 J/l, respectively. The long pulse effect is observed by constructing low peaking to main capacitance ratio of 1:3.

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A Study for Developing the Thermal Dehydrator (고효율 열 탈수장치 개발에 관한 연구)

  • Lee, Jung-Eun
    • 유체기계공업학회:학술대회논문집
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    • 2003.12a
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    • pp.278-283
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    • 2003
  • A generation rate of sludge in Korea had increased dramatically about 200 % for a decade. A requirement for high efficiency dewatering system being possible to produce the low water content cake have suggested due to the appearanceof commercial and social problems about handling of dewatered cake. The conventional dewatering system with mechanical compression device was not suitable to produce the low water content cake and didn'tcope with lots of requirements. Therefore, this paper was to develop the high efficient filter press with the compressive and heating forces through the heating plate to be built between membrane filter plates. It is possible to produce the low water content cake and improve the dewatering rate, so this equipment positively coped with several types of problems related to the sludge dewatering. The plate heated by heat transfer materials such as steam, hot water and thermo-oil made the sludge make the residual moisture within the cake to discharge easilyand to improve the dewatering efficiency of equipment. The pilot scale experiment with 500kg of cake production showed that the dewatering efficiency determined by the final water content and dewatering velocity was improved 30% more than the conventional dewatering equipment.

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Performance Optimization of High Specific Speed Pump-Turbines by Means of Numerical Flow Simulation (CFD) and Model Testing

  • Kerschberger, Peter;Gehrer, Arno
    • International Journal of Fluid Machinery and Systems
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    • v.3 no.4
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    • pp.352-359
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    • 2010
  • In recent years, the market has shown increasing interest in pump-turbines. The prompt availability of pumped storage plants and the benefits to the power system achieved by peak lopping, providing reserve capacity, and rapid response in frequency control are providing a growing advantage. In this context, there is a need to develop pumpturbines that can reliably withstand dynamic operation modes, fast changes of discharge rate by adjusting the variable diffuser vanes, as well as fast changes from pumping to turbine operation. In the first part of the present study, various flow patterns linked to operation of a pump-turbine system are discussed. In this context, pump and turbine modes are presented separately and different load cases are shown in each operating mode. In order to create modern, competitive pump-turbine designs, this study further explains what design challenges should be considered in defining the geometry of a pump-turbine impeller. The second part of the paper describes an innovative, staggered approach to impeller development, applied to a low head pump-turbine project. The first level of the process consists of optimization strategies based on evolutionary algorithms together with 3D in-viscid flow analysis. In the next stage, the hydraulic behavior of both pump mode and turbine mode is evaluated by solving the full 3D Navier-Stokes equations in combination with a robust turbulence model. Finally, the progress in hydraulic design is demonstrated by model test results that show a significant improvement in hydraulic performance compared to an existing reference design.

Development of a Headlamp Testing System for Automobile Headlamp Beam Pattern Recognition (차량의 헤드램프 빔 패턴 인식을 위한 헤드램프 검사 시스템 개발)

  • Kim, Junghoon;Cho, Chiwoon
    • Transactions of the Korean Society of Automotive Engineers
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    • v.22 no.7
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    • pp.23-30
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    • 2014
  • "Cut off line" in automotive passing beam has very important safety function because it serves for headlamp aiming. Headlights that are aimed incorrectly will not only perform poorly but also offend oncoming traffic. In addition, an objective definition of cut off line in low beam is necessary, since a requirement for correct aiming of the beams is specified within all the existing regulations. Accordingly, headlight regulations are requirements that automobiles must satisfy in order to be sold in a particular country. In this study, a more advanced recognition method for the cut off lines of the various headlamps commonly used in Europe, North America, and domestic is suggested and a headlamp testing system is developed to adjust the beam to the country-specific regulation. This system uses image processing technology to detect the cut off lines in the beam patterns of halogen headlamps, high-intensity discharge headlamps, and light-emitting diode headlamps as well.

Preparation and Characteristics of Li4Ti5O12 Anode Material for Hybrid Supercapacitor

  • Lee, Byung-Gwan;Yoon, Jung-Rag
    • Journal of Electrical Engineering and Technology
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    • v.7 no.2
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    • pp.207-211
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    • 2012
  • Spinel-$Li_4Ti_5O_{12}$ was successfully synthesized by a solid-phase method at 800, 850, and $900^{\circ}C$ according to the $Li_4Ti_5O_{12}$ cubic spinel phase structure. To achieve higher EDLC energy density with the $Li_4Ti_5O_{12}$, the negative electrode of the hybrid supercapacitor was studied in this work. The electrochemical performances of the hybrid supercapacitor and EDLC were characterized by constant current discharge curves, c-rate, and cycle performance testing. The capacitance (1st cycle) of the hybrid supercapacitor and EDLC was 209 and 109 F, respectively, which is higher than EDLC. The capacitance of the hybrid supercapacitor decreases from 209 F to 101 F after 20 cycles when discharged at several specific current densities ranging from 1 to 10 A. In contrast, capacitance of the EDLC hardly decreases after 20 cycles. Results show that hybrid supercapacitor benefits from the high rate capability of supercapacitor and high capacity of the battery. Findings also prove that the hybrid supercapacitor is an energy storage device where the supercapacitor and the Li ion secondary battery coexist in one cell system.

A development of the Hybrid Sensor for the detection of the High Frequency Partial Discharge(HFPD) (고주파 부분방전(HFPD)측정용 하이브리드 센서 개발에 관한 연구)

  • Kim, J.H.;Koo, J.Y.;Kim, J.T.
    • Proceedings of the KIEE Conference
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    • 2002.11a
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    • pp.173-175
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    • 2002
  • In general, CT and Shunt have been traditionally used as a sensor for detecting the partial discharges in order to diagnose the present insulation state of the electric power apparatus. The former is very convenient for the practical application since it is not only non-contact method but its frequency bandwidth and resonance frequency could be designed for its specific application. However, it has been proved to have poor linearity and low sensitivity. For the latter, even though it is an ideal sensor, noise from the power source and the ground could flow into the system. Furthermore, the surge current could be easily come into the measuring systems giving rise to a severe breakdown. In this respect, a hybrid sensor has been designed and fabricated in order to overcome the shortcoming of these two types of sensors. For this purpose, the experimental comparison with commercialized products has been also carried out. In this concept of the hybrid sensor, two different impedances could provide the passage of the signals. In this way, the discrimination of the noise could be accomplished very effectively with high ratio of signal over noise(S/N) under the little influence from the external noises and the breakdown.

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The Effect of Particle Size Distribution of the Nongraphitic Carbon on the Performance of Negative Carbon Electrode in Lithium Ion Secondary Battery (무정형 탄소의 입도분포에 따른 리튬이온이차전지의 탄소부극 특성)

  • Kim, Hyun-Joong;Lee, Chul-Tae
    • Applied Chemistry for Engineering
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    • v.9 no.5
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    • pp.781-785
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    • 1998
  • Material and electrochemical characteristics of petroleum coke of the nongraphitic carbon prepated with attrition milling for 6~48 hours and heat-treatment at $700^{\circ}C$ for 1 hour was investigated. The milling condition affects the particle size distribution, BET specific surface area and interlayer distance of petroleum cokes. Carbon electrode with petroleum cokes prepared at the milling time of 12~24 hours and having average particle size of $6{\sim}8{\mu}m$ showed best electrochemical characteristics form the investigation of cyclic voltammogram and charge-discharge characteristics.

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A Study on Specific Discharge Estimation in Urban Watershed (도시유역의 비유량 산정에 대한 연구)

  • Son, Hui Won;Park, Kyung Mi;Kim, Jong Seok;Moon, Young Il
    • Proceedings of the Korea Water Resources Association Conference
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    • 2015.05a
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    • pp.511-511
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    • 2015
  • 국가적 측면에서 수자원의 효율적 관리는 국민의 안전 등 중요한 요소이며, 이를 위하여 수자원 장기 계획을 필요로 한다. 설계홍수량의 적정성 판단 및 첨두홍수량의 파악은 수자원 계획에 꼭 필요한 요소이다. 이를 산정하기 방법으로는 "설계홍수 추정 지침서(1993, 국토교통부)"에서 제시한 비유량법을 활용한 추정공식을 제시한 바 있다. 하지만, 기존에 제시된 비유량 산정 공식의 경우 유역면적 하나만을 매개변수로 하는 회귀식이기 때문에 급변하고 있는 강우 패턴 등의 반영이 어려울 것으로 판단되었으며, 특히 도시화 및 기후변화의 영향으로 인한 불투수면적의 증가와 집중호우 등의 극치수문사상이 발생됨에 따라 기존의 비유량법에 의해 첨두홍수량을 추정할 경우 많은 차이가 있을 것으로 예상된다. 또한, 하천기본계획 및 소하천정비종합계획 등 대부분의 하천관련 정비계획에서는 단위도법에 의해 산정된 홍수량을 계획홍수량으로 결정하고 있으며 비유량법에 의한 첨두홍수량은 계획홍수량의 적정성 검증 정도로만 활용하고 있으며 신뢰성에 의문이 제기되고 있는 실정이다. 따라서 도시유역을 대상으로 최근 수립된 하천기본계획 등의 계획홍수량 자료를 수집하고, 기존 비유량공식을 적용한 결과를 비교 검토하여 비유량 적용의 적정성을 판단하며 개선방안을 모색하고자 한다.

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The Electrochemical Properties of SnO2 as Cathodes for Lithium Air Batteries

  • Lee, Yoon-Ho;Park, Heai-Ku
    • Journal of the Korean Electrochemical Society
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    • v.22 no.4
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    • pp.164-171
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    • 2019
  • Nano-sized $SnO_2$ powders were synthesized via a solvent thermal reaction using $SnClO_4$, NaOH, and ethylene glycol at $150^{\circ}C$. TGA, SEM, FT-IR, XRD, and Potentiostat/Galvanostat were employed to investigate the chemical and electrochemical characteristics of the synthesized $SnO_2$. The structure of $SnO_2$ was amorphous, and when heat treated at $500^{\circ}C$, it was transformed into a crystalline structure. The morphology obtained by SEM micrographs of the as-synthesized $SnO_2$ showed powder features that had diameters ranging 100 to 200 nm. The electrochemical performance of the crystalline $SnO_2$ as a Li-air battery cathode was better than that of the amorphous $SnO_2$. The specific capacity of the crystalline $SnO_2$ was at least 350 mAh/g at 10 mA/g discharge rate. However, there was some capacity loss of all the cells during the consecutive cycles. Keywords : Lithium-Air Battery.