This experiment was carried out to evaluate biological availability of Ca and P in 4 different sources of tricalcium phosphate in young chicks. One hundred and twenty five-day-old male Single Comb White Leghorn chicks (10 treatments$\times$3replication$\times$4chicks) were used in trial 1 and 2, respectively, for 12 days of feeding period. Trial I was to evaluate the availability of phosphorus in the supplements, Standard purified diets were prepared to supply 0.07, 0.14 and 0.21%P using a mixture (1 : 1) of NaH$_2$PO$_4$ and KH$_2$PO$_4$ as the reference Phosphorus sources. Bone breaking strength of the tibia determeined by an Instron instrument appeared inadequate to be used as a criterion due to very high variations of the measurement within a treatment. Thus, tibia bone ash content was utilized as a criterion to evaluate th biological avilability of phosphorus in the supplements. The levels of the biological availability of the four different sources of dicalcium phoshate were 77.1, 91.0, 96.4 and 95.5%, respectively, and those of the three tricalcium phosphate sources were 94.1, 95.0 and 99.5% , respectively. Trial 2 was to determeine the levels of Ca biologically available in the supplements. Standard purified diets were made to supply 0.2, 0.3 and 0.4% Ca using CaCo$_3$ as the reference calcium source. When bone ash content was utilized as a criterion for the availability, the levels of calcium biologically available to the chicks were 78.3, 234.1, 87.6 and 244.5%, respectively, for the 4 different sources of dicalcium phosphate and 99.5, 84.0 and 101.5% , respectively, for the 3 different sources of tricalcium phosphate. The observation that two calcium sources appeared to be utilized with an unusual efficiency can hardly be explained at this moment. When they were revaluated on the basis of body weight gain, the availabilities of the four sources of dicalcium phosphate were 89.2, 58.2, 104.1 and 103.1% and of the three tricalcium phosphate were 112.6, 106.0 and 96.3% , respectively.
Prototype of $800{\ell}$ vacuum web coater (Vic Mama) consisting of ion source with low energy less than 250 eV for high speed surface modification and 4 magnetron sputter cathodes was designed and constructed. Its performance was evaluated through fabricating the adhesiveless flexible copper clad laminate (FCCL). Pumping speed was monitored in both upper noncoating zone pumped down by 2 turbo pumps with 2000 l/sec pumping speed and lower surface modification and sputter zone vacuumed by turbo pumps with 450 1/sec and 1300 1/sec pumping speed respectively. Ion current density, plasma density, and uniformity of ion beam current were measured using Faraday cup and the distribution of magnetic field and erosion efficiency of sputter target were also investigated. With the irradiation of ion beams on polyimide (Kapton-E, $38{\mu}m$) at different fluences, the change of wetting angle of the deionized water to polyimide surface and those of surface chemical bonding were analyzed by wetting anglometer and x-ray photoelectron spectroscopy. After investigating the deposition rate of Ni-Cr tie layer and Cu layer was investigated with the variations of roll speed and input power to sputter cathode. FCCL fabricated by sputter and electrodeposition method and characterized in terms of the peel strength, thermal and chemical stability.
Space-borne Earth observation technique is one of the most cost effective and rapidly advancing Earth science research tools today and the potential field and micro-wave radar applications have been leading the discipline. The traditional optical imaging systems including the well known Landsat, NOAA - AVHRR, SPOT, and IKONOS have steadily improved spatial imaging resolution but increasing cloud covers have the major deterrent. The new Earth observation satellites ENVISAT (launched on March 1 2002, specifically for Earth environment observation), ALOS (planned for launching in 2004 - 2005 period and ALOS stands for Advanced Land Observation Satellite), and RADARSAT-II (planned for launching in 2005) all have synthetic aperture radar (SAR) onboard, which all have partial or fully polarimetric imaging capabilities. These new types of polarimetric imaging radars with repeat orbit interferometric capabilities are opening up completely new possibilities in Earth system science research, in addition to the radar altimeter and scatterometer. The main advantage of a SAR system is the all weather imaging capability without Sun light and the newly developed interferometric capabilities, utilizing the phase information in SAR data further extends the observation capabilities of directional surface covers and neotectonic surface displacements. In addition, if one can utilize the newly available multiple frequency polarimetric information, the new generation of space-borne SAR systems is the future research tool for Earth observation and global environmental change monitoring. The potential field strength decreases as a function of the inverse square of the distance between the source and the observation point and geophysicists have traditionally been reluctant to make the potential field observation from any space-borne platforms. However, there have recently been a number of potential field missions such as ASTRID-2, Orsted, CHAMP, GRACE, GOCE. Of course these satellite sensors are most effective for low spatial resolution applications. For similar objects, AMPERE and NPOESS are being planned by the United States and France. The Earth science disciplines which utilize space-borne platforms most are the astronomy and atmospheric science. However in this talk we will focus our discussion on the solid Earth and physical oceanographic applications. The geodynamic applications actively being investigated from various space-borne platforms geological mapping, earthquake and volcano .elated tectonic deformation, generation of p.ecise digital elevation model (DEM), development of multi-temporal differential cross-track SAR interferometry, sea surface wind measurement, tidal flat geomorphology, sea surface wave dynamics, internal waves and high latitude cryogenics including sea ice problems.
Precipitation samples were collected at the GAW Stations in Anmyeon-do and Gosan for 10 years (2008-2017) to analyze pH, electrical conductivity and NH4+, Na+, K+, Mg2+, Ca2+, SO42-, NO3-, Cl-, and F- ions. From the analysis, the correlation between pH and rainfall, the composition of precipitation and comparison with other regions, and the results of neutralization characteristics by seasonal and pH were determined. In the comparison of ion balance and conductivity for the validation of analytical data, the correlation coefficients were within the range of 0.996~0.999, implying good linear relationship. The volume-weighted pH of the Anmyeon-do and Gosan areas were 4.7 and 4.9, respectively. The pH of the rainfall was affected by washout and rainout in both areas. The ionic strength of precipitation at Anmyeondo and Gosan were 0.42 ± 0.63 mM and 0.37 ± 0.75 mM, indicating about 27.6% and 35.3% of the total precipitation as per a pure precipitation criterion (10-4 M), respectively. The composition ratio of ionic species were 44.7% and 57.5% for marine sources (Na+, Mg2+, Cl-), 40.6% and 22.2% for the secondary inorganic components (NH4+, nss-SO42-, NO3-), and 5.6% and 4.0% for the soil source (nss-Ca2+), respectively. The neutralization factor of Anmyeon-do and Gosan were 0.43~0.65 and 0.34~0.48, and the neutralization factors of calcium carbonate were 0.15~0.34 and 0.25~0.30, respectively. Thus, both regions have the highest rate of neutralization caused by ammonia. As pH increased in Anmyeon-do and Gosan, change in calcium carbonate became greater than that in ammonia.
This study was carried out to investigate yearly change in the precipitation component and the source strength to acid precipitation at Iksan area from 1997 to 2003. The average ratio of acid precipitation was 70.0% in 1997, 56.3% in 1998 and 36.4% in 2003. On the other hand, it ranged from 6.9 to 19.2% when precipitation was less from 1999 to 2002. The average annual wet depositions of major ionic component in precipitation were calculated by multiplying equivalent concentration by precipitation. The order of major anion component in precipitation was ${SO_4}^{2-}>Cl^->{NO_3}^-$. On the other hand, the concentration of cation component were ${Ca_2}^+>Na^+>{NH_4}^+>{Mg_2}^+>K^+$ in order. The negative correlation was shown between pH and ionic component in precipitation except for ${Ca_2}^+\;and\;Na^+$. The correlation coefficient between pH and ${SO_4}^{2-}$ was highly significant as -0.508, which suggests that ${SO_4}^{2-}$ played important role in increasing the acidity of precipitation. Also the anions such as ${SO_4}^{2-}\;and\;{NO_3}^-$ were highly significant with cations such as ${Ca_2}^+,\;{Mg_2}^+,\;K^+,\;{NH_4}^+\;and\;Na^+$. As a result though pH was enable to use the acidity index of precipitation in somewhere, evaluating only pH in precipitation was insufficient as the index to establish corresponding strategy for acid rain.
Journal of Korean Society for Atmospheric Environment
/
v.25
no.6
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pp.523-538
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2009
Recently, there has been a keen demand for real-time automatic monitoring of VOCs not only in Korea but other developed countries. We carried out this study to evaluate and to optimize the performance of a continuous automatic monitoring system for hazardous VOCs (HVOCs) in the ambient atmosphere, using an on-line GC system. The online system normally consisted of a Nafion dryer prior to a cold trap of an automatic thermal desorption apparatus and a GC system equipped with two detectors, i.e. PID and ECD. Preliminary tests conducted to check out any contamination of the system revealed an evidence of significant artifact formation of benzene, and it was found that the Nafion dryer (even brand new one) is the source of the benzene artifact. Thus, all the subsequent experiments in this study was carried out inevitably by removing the Nafion dryer. The on-line GC method was investigated with a variety of QC/QA performance criteria such as repeatability, linearity, lower detection limits, and accuracy. In order to find out the best operating condition for the on-line GC system, three different types (in terms of adsorption strength) of cold trap combinations were tested, i.e. (i) Tenax-TA and Carbopack-B combination (weak and hydrophobic); (ii) Tenax-TA, Carbopack-X and Carboxen-1000 combination (strong and hydrophilic); and (iii) Tenax-TA and Carbopack-X combination (medium and hydrophobic/hydrophilic). The USEPA TO-17 manual method was selected as a reference method to evaluate the performance of the on-line method. A series of experiments revealed that the system performance was superior to others when a cold trap packed with hydrophilic adsorbents (Tenax-TA/Carbopack-X/Carboxen-1000 combination) was used and operated at $25^{\circ}C$. However, the system with a cold trap packed with a combination of Tenax-TA and Carbopack-X is more recommended for field applications since the carboxen-1000 adsorbent is too sensitive to water vapor, and hence the performance of the system might be very unstable to humid samples or during rainy days. Furthermore, the precision and accuracy criteria of the Tenax-TA/ Carbopack-X combination were generally compatible with the triple adsorbents cold trap. The continuous automatic monitoring method is, thus, considered very useful to real-time monitoring to understand the variations of VOCs concentrations in ambient air, as it adopts much simpler procedures in sampling, analysis, and data integration steps than manual monitoring methods. However, it should be noted that there is a high possibility of benzene artifacts formation through the Nafion dryer, which is often installed to remove water vapor in air samples before being adsorbed onto the cold trap. Therefore, if a Nafion dryer is used in any studies of monitoring VOCs, the benzene contamination should be carefully examined before carrying out obtaining the data.
Chang'a, Edwin Peter;Abdallh, Medani Eldow;Ahiwe, Emmanuel Uchenna;Mbaga, Said;Zhu, Ze Yuan;Fru-Nji, Fidelis;Iji, Paul Ade
Asian-Australasian Journal of Animal Sciences
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v.33
no.7
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pp.1126-1137
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2020
Objective: Pellet durability, particle size distribution, growth response, tibia bone characteristics and energy retention were measured to evaluate cassava as an alternative energy source to replace maize in broiler diets with or without Ronozyme (A+VP) enzyme composites. Methods: A total of 480 one-day broiler chicks were randomly assigned to 8 treatments in a 4×2 factorial arrangement. Four levels of cassava: (0%, 25%, 50%, 75%) and 2 levels of enzymes (0 and 500 g/tonne) were used. Each treatment was replicated six times, with ten birds per replicate. Results: The particle size distribution in the diets showed an increasing trend of small particles with increase in cassava level. Pellet durability decreased (p<0.05) with cassava inclusion. Feed intake was highest in birds fed diets with medium cassava level at 1 to 24 d and 1 to 35 d of age. The body weight gain of birds reduced (p<0.037) as cassava level increased, but it increased (p<0.017 when enzymes were added. The feed conversion ratio was high (p<0.05) when cassava level was increased, but it reduced (p<0.05) when enzymes were added. The dressing percentage (DP), and weight of drumsticks reduced (p<0.05) with increasing cassava level. Enzyme supplementation increased (p<0.05) DP, and weight of breast, thighs and drumsticks. Ash content, weight, length, width, and bone strength decreased (p<0.05) when cassava level was increased, however, they were increased with enzyme addition. The contents of Ca, K, and Zn were raised (p<0.001) with increasing cassava level. Enzyme inclusion increased (p<0.001) all mineral contents in tibia bones. Body fat and energy retained as fat decreased (p<0.001) as cassava level increased. Enzyme inclusion increased (p<0.05) body protein content and energy retained as protein. Conclusion: Although broiler performance was depressed by high levels of cassava inclusion, it was not affected by low levels, which further improved by enzyme supplementation.
KIM Gyu-Hyung;JEON You-Jin;BYUN Hee-Guk;LEE Yeon-Sook;LEE Eung-Ho;KIM Se-Kwon
Korean Journal of Fisheries and Aquatic Sciences
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v.31
no.2
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pp.149-159
/
1998
To utilize the oyster shell containing a lot of calcium, we investigated the bioavailability of calcium compounds from oyster shell. First, calcium oxide was prepared by burning of oyster shell at $1200^{\circ}C$. Its purity was approximately $98.5\%$. Calcium compounds, $CaCl_2$, and $CaHPO_4$, from the calcium oxide were prepared by chemical reaction. Effect on calcium absorption by the calcium compounds from oyster shell was improved using fish skin gelatin peptides.(FSGP), which was prepared by enzymatic hydrolysis of fish skin gelatin for 4hr with tuna pyloric caeca crude enzyme (TPCCE). in vitro experiment, calcium absorption by addition of FSGP in a mixture solution of calcium and phosphate was higher approximately $70\%$ than that by control. in vivo using calcium deficient rats, a group taken the diets with $3\%$ FSGP and $CaHPO_4$ was significantly improved amount of calcium and ash in femur and strength of femur. These results suggest that calcium compounds from oyster shell and FSGP could be used as an effective dietary calcium source.
Background: Published studies have reported relationships between X-ray repair cross-complementing group 1 (XRCC1) Arg399Gln polymorphism and lung cancer risk in Chinese population. However, the epidemiological results remained controversial. The objective of this study was to clarify the association of XRCC1 Arg399Gln polymorphism with lung cancer risk in the Chinese population. Materials and Methods: Systematic searches were performed through the database of Medline/Pubmed, Web of Science, Embase, CNKI and WanFang Medical Online. Odds ratios (ORs) with 95% confidence interval (95%CI) were calculated to estimate the strength of the association. Results: Overall, we observed an increased lung cancer risk among subjects carrying XRCC1 codon 399 Gln/Gln genotype (OR=1.36, 95%CI: 1.09-1.71) in the Chinese population on the basis of 19 studies with 5,416 cases and 5,782 controls. We did not observe any association between XRCC1 codon 399 Arg/Gln and Arg/Gln+Gln/Gln polymorphisms and lung cancer risk (OR=1.00, 95%CI: 0.92-1.08 and OR=1.05, 95%CI: 0.97-1.13, respectively). Limiting the analysis to studies with controls in agreement with Hardy-Weinberg equilibrium (HWE), we observed an increased lung cancer risk among subjects carrying XRCC1 codon 399 Gln/Gln genotype (OR=1.18, 95%CI: 1.01-1.38). When stratified by source of control, we observed an increased lung cancer risk among subjects carrying XRCC1 codon 399 Arg/Gln+Gln/Gln genotype on the basis of hospitalized patient-based controls (OR=1.21, 95%CI: 1.04-1.42) and among subjects carrying XRCC1 codon 399 Gln/Gln genotype on the basis of healthy subject-based controls (OR=1.22, 95%CI: 1.04-1.43). Conclusions: Our findings indicated that certain XRCC1 Arg399Gln variants might affect the susceptibility of lung cancer in Chinese population. Larger sample size studies are required to confirm our findings.
Journal of Korean Society of Occupational and Environmental Hygiene
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v.16
no.3
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pp.254-263
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2006
Manganese has a role as both toxic and essential in humans. Manganese is also an essential component in the welding because it increases the hardness and strength, prevents steel from cracking of welding part and acts as a deoxidizing agent to form a stable weld. In this study, manganese generation rate and its content was determined in flux cored arc welding on stainless steel. Domestic two products and foreign four products of flux cored wires were tested in the well designed fume generation chamber as a function of input power. Welding fume was measured by gravimetric method and metal manganese was determined by inductively coupled plasma-atomic emission spectrophotometer. The outer shell of the flux cored wire tube and inner flux were analyzed by scanning electron microscopy to determine their metal compositions. Manganese generation rate($FGR_{mn}$) was increased as the input power increased. It was 16.3 mg/min at the low input power, 38.1 mg/min at the optimal input power, and up to 55.4 mg/min at the high input power. This means that $FGR_{mn}$ is increased at the work place if welder raise the current and/or voltage for the high productivity. The slope coefficient of $FGR_{mn}$ was smaller than that of the generation rate of total fume(FGR). Also, the correlation coefficient of $FGR_{mn}$ was 0.65 whereas that of FGR is 0.91. $FGR_{mn}$ was equal or higher in the domestic products than that of the foreign products although FGR was similar. From the electron microscopic analytical data, we concluded that outer shell of the wire was composed mainly of iron, chromium, nickel and less than 1.2 % of manganese. There are many metal ingredients such as iron, silica, manganese, zirconium, titanium, nickel, potassium, and aluminum in the inner flux but they were not homogeneous. It was found that both $FGR_{mn}$ and content of manganese was higher and more varied in domestic flux cored wires than those of foreign products. To reduce worker exposure to fumes and hazardous component at the source, further research is needed to develop new welding filler materials that improve the quality of flux cored wire in respect to these points. Welder should keep in mind that the FGR, $FGR_{mn}$ and probably the generation rate of other hazardous metals were increased as the input power increase for the high productivity.
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