• 한국광물학회:학술대회논문집
• /
• 한국광물학회.한국암석학회 2001년도 공동학술발표회 논문집
• /
• pp.40-40
• /
• 2001

The sorption behavior of Cs(I), Sr(II), and U(VI) on representative single minerals(oxide and clay) and rocks were comparatively studied by using batch type sorption experiment. The effects of pH, ionic strength and the sorption mechanism were also discussed. It was found that mineral structure played as a main factor governing the sorption characteristics of Cs(I), Sr(II). The sorption of Cs(I) and Sr(II) on minerals showed ionic strength-dependency, which is a indirect sign of weak binding between metal cation and mineral surfaces. However, the sorption behavior of U(VI) was quite different compared with that of Cs(I), and Sr(II). Fe-oxide minerals showed strong tendency for U(VI) sorption, dominating the sorption in the composite/mixture systems. The surface characteristics which arise from mineral structure, and the affinity of metal ions to the sorption sites of minerals are the key to understand the role of minerals in the radionuclide sorption.

• 한국환경과학회지
• /
• 제11권9호
• /
• pp.961-969
• /
• 2002

This study was performed : 1) to establish the experimental analysis conditions for the sorption and desorption of toxic organic contaminants to/from the activated sludge, sediment, and clay, and 2) to determine the sorption and desorption equilibrium coefficients of some representative halogenated aliphatic compounds. Through the preliminary sorption test using Azo dye, a setting of quantitative experimental conditions to determine the sorption and desorption characteristics was decided as follows; equilibration time of 180 minutes, centrifuge for 15 minutes at 5000$\times$g, and 500mg/$\ell$ of TOC concentration. The sorption and desorption characteristics of halogenated aliphatic compounds onto activated sludge, sediment and clay could be described very well using the Freundlich isotherm. The preference of the average sorption capacity of the overall compounds showed in the sequence sediment 0.26mg/g, clay 0.23mg/g, and activated sludge 0.11 mg/g. The desorption rate of the sorbed compounds onto activated sludge, sediment and clay was approximately 89.8%, 35.3%, and 66.4%, respectively.

• 설비공학논문집
• /
• 제16권2호
• /
• pp.167-174
• /
• 2004

A sorption cool pad brings cooling effect without any pre-cooling, nor any external energy supply. It uses evaporative cooling effect stimulated by the desiccative sorption. In this paper, heat and mass transfer in the sorption cool pad are investigated theoretically. The evaporative cooling process caused by the desiccant is modeled and analyzed considering the sorption characteristics of the desiccant. Two nondimensional parameters are found to dominate the cooling process： one is related to the psychrometric characteristics and the other is to the sorption capacity of the desiccant. The former decides the time to reach the lowest temperature and the later controls the time duration of the cooling effect being sustained.

• 한국환경농학회지
• /
• 제41권4호
• /
• pp.276-281
• /
• 2022

BACKGROUND: Plastics that are used in our daily lives largely end up in the environment. In agricultural environments, plastic wastes and microplastics can be found due to the uses and improper management of plastic products (e.g., vinyl greenhouses and mulching vinyl). Microplastics can also interact with contaminants in the agricultural environment. Therefore, this study was set to investigate the sorption characteristics of tetracycline, one of widely used antibiotics, on microplastics. METHODS AND RESULTS: The sorption tests were carried out with the tetracycline solutions (0-30 mg L^-1) and microplastic films prepared from low density polyethylene (LDPE) and polyvinyl chloride (PVC). The residual tetracycline concentrations were analyzed and fitted to the Freundlich and Langmuir isotherm models. The tetracycline sorption patterns on LDPE and PVC films were described better with the Freundlich isotherm model than the Langmuir isotherm model. The isotherm model parameters suggested that the maximum sorption amount of tetracyline was greater for PVC, while the sorption affinity was greater for LDPE. CONCLUSION(S): Different types of microplastics can have different sorption characteristics of tetracycline. Therefore, there is a need for continuous research on the interaction of various types and shapes of microplastics and contaminants in the environment.

• 농업과학연구
• /
• 제23권2호
• /
• pp.250-260
• /
• 1996

Observed results of the adsorption between two competing anions for the shared sorption sites represent that the adsorption phenomena may depends on the characteristics of anion and available sorption sites in a given conditions. In binary systems, adsorption of one species can significantly influence the fate of the other anion, resulting in control of the extent of solute-adsorbate distributions throughout soil profile. And the proton-donation mechanisms by organic anions having a carboxyl as a functional group can also influence the adsorption of inorganic anions onto the hydroxylated sites of Fe and Al oxides. However, study of competitive adsorption of specifically adsorbed anions illustrates some of difficulties which arise in interpretation of reactions at oxide/aqueous solution interfaces. At least two factors prevented a simple analysis of reactions. First, at any pH value the maximum amount of adsorbate taken up at the surface depends on the identity of the anion. Second, it was necessary to postulate the sorption sites where the anion can be adsorbed. Hence, anions having non-specific adsorption characteristics are less capable for sorption sites, compared to those of specific adsorption characteristics, even though competition complies both ordinary and electrostatic interactions for sorption sites. Therefore, competition among chemical species in soil matrix can be of major significance in determining the effective mobility of any reactive anions with sorption sites.

• 한국환경농학회지
• /
• 제42권3호
• /
• pp.184-192
• /
• 2023

Microplastics are generated by the breakdown of plastic wastes in agricultural soil and residual pesticides in agricultural soil can adsorb on microplastics. In this study, the sorption characteristics of procymidone (PCM) and one of its metabolites, 3,5-dichloroaniline (DCA), on low-density polyethylene (LDPE) and polyvinyl chloride (PVC) microplastics were investigated. The sorption and desorption tests were carried out for 72 h using LDPE or PVC microplastic films to study the sorption isotherms of PCM and DCA and kinetics for sorption and desorption of PCM. The results show that the sorption data of PCM and DCA were better described by the Freundlich isotherm model (R²=0.7568-0.9915) than the Langmuir isotherm model (R²=0.0545-0.5889). The sorption potential of PVC for both PCM and DCA was greater than that of LDPE. The sorption data of PCM on PVC and LDPE were fitted better to the pseudo-second-order kinetic model than the pseudo-first-order kinetic model. The PCM sorption on LDPE was about three times faster than that on PVC. Both microplastic films released the sorbed PCM back to water, and more PCM was released from PVC than LDPE, but the desorption rate was faster with LDPE than PVC. Overall, the results show that different microplastics have different sorption characteristics for different chemicals. Also, the sorbed chemicals can be released back to environment suggesting the potential of contaminant spread by microplastics. Thus, the management practices of microplastics in agricultural soil need to consider their interaction with the chemical contaminants in soil.

• Nuclear Engineering and Technology
• /
• 제29권5호
• /
• pp.393-398
• /
• 1997

Batch sorption experiments were carried out to investigate the sorption characteristics of $^{90}$ Sr onto domestic granite(HG) and tuff(TF) samples. The effect of three independent variables ([Sr], Vo1/Wt], [pH]) on the sorption was investigated. (Sr) played as the most significant variable for the $^{90}$ S $r^{2+}$ sorption onto HG, whereas [pH] had the greatest effect among three variables onto TF. Tuff shooed much greater sorption than granite, which ues accounted for their differences in mineralogical properties. The selectivity of $^{90}$ Sr was much lower than that of $^{l37}$Cs.s.s.

• Nuclear Engineering and Technology
• /
• 제27권1호
• /
• pp.25-32
• /
• 1995

저준위 방사성 폐기물의 대표핵종인 Cs의 국내 대표 암반구성 물질인 화강암과 응회암에의 흡착특성을 조사하기 위해 회분식 흡착실험을 수행하였다. 반응표면분석법을 이용하여 ［Cs］, ［Vol/Wt］, ［pH］의 독립변수가 흡착에 미치는 영향을 정량적으로 평가하였다. 결과, 초기 세슘이온의 농도가 가장 중요한 변수로 나타났다. Cs의 흡착능의 pH 의존성은 미약한 것으로 나타났다. 핵종의 응회암에의 흡착량이 화강암보다 더 많았다. 이들 핵종흡착의 낮은 pH 비의존성을 매질의 전기적 표면특성과 핵종의 수용액상 특성으로 설명하였다. 핵종간과 매질간의 흡착능 비교는 물구조 변환론으로 설명하였다.

• 한국지하수토양환경학회:학술대회논문집
• /
• 한국지하수토양환경학회 2001년도 총회 및 춘계학술발표회
• /
• pp.26-29
• /
• 2001

Sorption/desorption Study was conducted to determine desorption-resistance hydrophobic organic compounds in natural soils with low organic carbon content. Sorption/desorption characteristics of chlorobenzene and phenanthrene for both PPI (Petro Processors, Inc. Superfund site) and BM (Bayou Manchac), soils were investigated. Desorption was biphasic including reversible and desorption-resistant compartments. The biphasic sorption parameters indicated the presence of appreciable size of desorption-resistant phase in these soils. A finite maximum capacity of desorption-resistant fraction (equation omitted) was observed after several desorption steps. The apparent organic carbon based Partition coefficient, K(equation omitted) was 10$^{4.92{\pm}0.27}$ for PPI soil and 10$^{4.92{\pm}0.27}$ for BM soil, respectively. The difference in K(equation omitted) was attributed to different characteristics in soil organic matter. The results suggest that desorption-resistance should be considered in remediation and risk assessments in natural soils and sediments.

• 한국지반환경공학회 논문집
• /
• 제2권1호
• /
• pp.103-114
• /
• 2001

본 연구에서는 근래에 퇴적된 습지토양의 유기물질에 느린 흡착부분이 존재하는지 살펴보기 위해 흡착실험을 행하였다. 최근 퇴적된 민물 습지토양에서의 소수성 유기화합물 (chlorobenzene and phenanthrene)의 흡착 특성을 회분식 흡착법을 사용하여 결정하였다. 유기물질의 나이의 상대 척도로서 산소/탄소 원소비 등을 포함한 여러 방법으로서 평가하였다. 토양의 나이가 유기화합물의 습지토양에서의 흡착에 차이를 유발하는지에 대해 조사하기 위하여 습지 토양의 표층부(상층부 0-2cm, 5년 미만)과 하층부(below 10cm, 20년 이상)에 대한 느린 흡착 특성을 상대적으로 오래된 PPI(Petro Processors, Inc. Superfund site), BM(Bayou Manchac) 토양과 비교하였다. 느린 흡착모델 변수의 비선형성(KF와 N)의 증가로서 느린 흡착부분이 존재함을 알 수 있었다. 느린 흡착모델의 분석결과 상당한 크기의 느린 흡착부분이 존재하였으며 습지 토양의 경우 흡착된 chlorobenzene의 25.4-263%가 phenanthrene의 경우 흡착된 양의 1.4-1.9%(phenanthrene)가 각각 느린 흡착 부분에 해당하였으며, PPI 토양과 BM토양의 경우 흡착된 chlorobenzene의 40.0-55.93%와 흡착된 phenanthrene의 2.9-3.19%가 각각 느린 흡착 부분에 해당하였다. 느린 흡착 부분은 상층부 < 하층부 < PPI < BM 토양의 순으로 증가하였는데 이것은 토양 유기물질의 나이가 증가할수록 느린 흡착부분의 크기가 증가함을 나타낸다.