• Title/Summary/Keyword: solvent-resistance

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An Electrochemical Evaluation on the Corrosion Resistance of Heavy Anticorrosive Paint(II) (중방식 도료의 내식성에 관한 전기 화학적 평가(II))

  • Sung, Ho-Jin;Kim, Jin-Kyung;Lee, Myung-Hoon;Kim, Ki-Joon;Moon, Kyung-Man
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2005.06a
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    • pp.382-387
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    • 2005
  • An electrochemical evaluation on the corrosion resistance for heavy anticorrosive paint was carried out for 5 kinds of heavy anticorrosive paints such as High solid epoxy(HE), Solvent epoxy(SE), Tar epoxy(TE), Phenol epoxy(PE), and Ceramic epoxy(CE) as parameters of DFT(Dry Film Thickness, 25${\mu}m$50${\mu}m$, solution condition(Flow of Nonflow). Corrosion current density of HE(DFT 50${\mu}m$ in case of flow condition was larger than that of nonflow condition. However, their values of the other anticorrosive paints were decreased compared to the nonflow condition. The values of AC impedance were increased with increasing of DFT regardless of kinds of anticorrosive paints. And the polarization resistance of cyclic voltammogram showed a good tendency to correspond with well the values of AC impedance measurement. HE and CE had a relatively good corrosion resistance than other heavy anticorrosive paint.

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Study on the Solvent Effect in the Coating of Conductive Polythiophene Derivative (용매에 따른 폴리싸이오펜 치환체의 전기전도성에 미치는 영향)

  • Pak, Na-Young;Lee, Seong-Min;Chung, Dae-Won
    • Elastomers and Composites
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    • v.46 no.4
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    • pp.290-294
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    • 2011
  • The surface resistance of poly(3,4-ethylenedioxythiophene)-polystyrene sulfonate (PEDOT/PSS), which has appeared to be one of the most successful conductive polymers, is affected by the solvent. In this paper, pellet-type PEDOT/PSS was suspended in $H_2O$, ethanol (EtOH), ethylene glycol (EG) or dimethylsulfoxide (DMSO), and coated on PET film. The surface resistances of the films made from EG or DMSO suspension were observed to be lower, nearly by 2 orders of magnitude, than that made from $H_2O$ suspension. No significant difference among four kinds of films was observed when the thermal properties and chemical structures were investigated by TGA and XPS, respectively. However, particle size of PEDOT/PSS was in the range of $1-3{\mu}m$ in EG or DMSO, on the other hand, less than $0.1{\mu}m$ in $H_2O$. It is considered that the particle size of PEDOT/PSS in the suspension plays an important role for the surface resistance.

Toughening of Epoxy Resin with PES-CTBN-PES Triblock Copolymers (PES-CTBN-PES 공중합체를 이용한 에폭시 수지의 강인성 향상 연구)

  • 김형륜;명범영;송경헌;육종일;윤태호
    • Polymer(Korea)
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    • v.25 no.2
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    • pp.246-253
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    • 2001
  • Amino terminated PES-CTBN-PES triblock copolymer was synthesized from PES oligomer and commercial CTBN rubber (CTBN1300$\times$13), and molecular weight of the copolymer was controlled to be 15000 g/mole. The copolymer was utilized to toughen diglycidyl ether of bisphenol-A (DGEBA) epoxy resin which was cured with 4,4'-diaminodi-phenylsulfone (DDS) and subjected to the measurement of thermal properties, fracture toughness ( $K_{IC}$), flexural properties and solvent resistance. The properties were compared with those from the samples modified by CTBN/PES blends. The maximum loading of copolymer into the epoxy resin was 40 wt% without utilizing solvent, at which $K_{IC}$ fracture toughness of 2.21 MPa${\cdot}m^{0.5}$ was obtained without sacrificing flexural properties and chemical resistance. However, the epoxy resin modified with PES/CTBN blend exhibited much lower $K_{IC}$ and flexural properties compared to the epoxy resins toughened by PES-CTBN-PES copolymers.

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Application Properties of Ultra Light Weight Silica Aerogel to Polyurethane Membrane (극초경량 실리카 에어로겔의 폴리우레탄 멤브레인 적용 특성)

  • Min, Munhong;Jeong, Cheonhee;Yoon, Seokhan;Yang, Junghan;Kim, Taekyeong
    • Textile Coloration and Finishing
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    • v.25 no.4
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    • pp.279-286
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    • 2013
  • Application properties of ultra light weight silica aerogel toward polyurethane membranes were investigated. From the results of pre-milling process of the silica aerogel, the solvent for dispersion of the aerogel was determined for methyl ethyl ketone and its content in the solvent was determined by 30%. Using this aerogel dispersion, the polyurethane membranes were prepared according to the mixing amount of silica aerogel and various properties of the membranes were investigated. As results, the optimum mixing amount of silica aerogel inside polyurethane membranes was decided at 11%, because the improvement of light weight property, air permeability, and moisture vapor permeability were improved upto 11% of silica aerogel content, maintaining the water penetration resistance almost unchanged.

Aging and Recovery of HTV Silicone Rubber Used for Outdoor Insulator (옥외용 HTV 실리콘고무 절연재료의 열화 및 회복특성)

  • Yeon, Bok-Hui;Heo, Chang-Su;Jo, Han-Gu
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.51 no.10
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    • pp.465-472
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    • 2002
  • This paper presents a study on the aging and recovery of HTV (high temperature vulcanized) silicone rubber used for outdoor insulators. UV irradiation, corona discharge and water immersion were employed as factors of the artificial aging. The effects of changes derived from these stresses on the tracking and arc resistance of silicone rubber were examined. We have investigated the aging phenomena of HTV silicone rubber by the above stresses using the surface energy calculation with contact angle measurement, solvent-extraction, and surface/volume resistivity and so on. These results showed that UV irradiation and corona discharge lead to nearly the same surface oxidation, but the percentage change of mobile low molecular weight by these stresses was different. Furthermore, the oxidized layer induced under UV irradiation restricted the recovery of hydrophobic surface. Water immersion little lowered hydrophobicity level and leaded to a loss of tracking and arc resistance. The degradation mechanism based on our results was discussed.

An Investigation of Welding Variables on Resistance Upset Welding for End Capping of HWR Fuel Elements (중수로 핵연료 봉단마개의 저항업셋 용접을 위한 용접변수)

  • 이정원;박춘호;고진현;정성훈;정문규
    • Journal of Welding and Joining
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    • v.7 no.2
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    • pp.60-69
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    • 1989
  • The present study was aimed at investigating the effect of welding parameters such as welding current, electrode force(or squeeze force) and parts cleaning on the sound weld, and establishing the most reliable weld conditions for HWP(Heavy Water Reactor) fuel end capping with the resistance upset butt welding. Major results obtained are as follows. 1. The amount of sound weld was increased with increasing weld current(5.0-11KA) because the activated diffusion with increasing heat generation played an important role in eliminating the porosity and weld line in the weld interface. 2. It was found that weld current was not significantly influenced by the electrode force although the increase of it caused a slight increase of weld current and upset deformation. 3. Acetone rinsing before drying for the Zircaloy-4 end cap cleaning produced the reliable sound weld because it would remove the remaining solvent and surface films, and provided the uniform contact between the end cap and the tube. 4. The optimum welding conditions for fuel end capping by a resistance upset hytt welding are obtained as follows. weld current: 10-11KA, electrode force: 62-90KPa parts cleaning: vapor degreasing.rarw.water, acetone rinsing.rarw.drying.

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Application Evaluation of Asphalt mixtures using SDAR (Solvent DeAsphaltene Residue) (SDAR을 이용한 아스팔트 혼합물의 적용성 평가)

  • Yang, Sung Lin;Im, Jeong Hyuk;Hwang, Sung Do;Baek, Cheolmin
    • International Journal of Highway Engineering
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    • v.17 no.4
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    • pp.53-61
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    • 2015
  • PURPOSES : The objective of this study is to evaluate the SDAR (solvent deasphaltene residue), which is obtained from the solvent deasphalting (SDA) process, as a pavement material. METHODS : The physical properties of the SDAR were evaluated based on its chemical composition, and asphalt mixtures with the SDAR were fabricated and used for the evaluation of mechanical properties. Firstly, the chemical composition of SARA (saturate, aromatic, resin and asphaltene) was analyzed using the TLC-FID (thin-layer chromatography-flame ionization detector). Moreover, the basic material properties of the asphalt binder with the SDAR were evaluated by the penetration test, softening point test, ductility test, and PG (performance grade) grade test. The rheological properties of the asphalt binder with the SDAR were evaluated by the dynamic shear modulus ($G^*$) obtained using the time-temperature superposition (TTS) principle. Secondly, the mechanical properties of the asphalt mixtures with the SDAR were evaluated. The compactibility was evaluated using the gyratory compacter. Moreover, the tensile strength ratio (TSR) was used for evaluating the moisture susceptibility of the asphalt mixtures (i.e., susceptibility to pothole damage). The dynamic modulus $E^*$, which is a fundamental property of the asphalt mixture, obtained at different temperatures and loading cycles, was used to evaluate the mechanical properties of the asphalt mixtures. RESULTS AND CONCLUSION : The SDAR shows stiffer and more brittle behavior than the conventional asphalt binder. As the application of the SDAR directly in the field may cause early failures, such as cracks on pavements, it should be applied with modifiers that can favorably modify the brittleness property of the SDAR. Therefore, if appropriate additives are applied on the SDAR, it can be used as a pavement material because of its low cost and strong resistance to rutting.

Investigation on Size Distribution of Tungsten-based Alloy Particles with Solvent Viscosity During Ultrasonic Ball Milling Process (초음파 볼밀링 공정에 의한 용매 점도 특성에 따른 텅스텐계 합금 분쇄 거동)

  • Ryu, KeunHyuk;So, HyeongSub;Yun, JiSeok;Kim, InHo;Lee, Kun-Jae
    • Journal of Powder Materials
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    • v.26 no.3
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    • pp.201-207
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    • 2019
  • Tungsten heavy alloys (W-Ni-Fe) play an important role in various industries because of their excellent mechanical properties, such as the excellent hardness of tungsten, low thermal expansion, corrosion resistance of nickel, and ductility of iron. In tungsten heavy alloys, tungsten nanoparticles allow the relatively low-temperature molding of high-melting-point tungsten and can improve densification. In this study, to improve the densification of tungsten heavy alloy, nanoparticles are manufactured by ultrasonic milling of metal oxide. The physical properties of the metal oxide and the solvent viscosity are selected as the main parameters. When the density is low and the Mohs hardness is high, the particle size distribution is relatively high. When the density is high and the Mohs hardness is low, the particle size distribution is relatively low. Additionally, the average particle size tends to decrease with increasing viscosity. Metal oxides prepared by ultrasonic milling in high-viscosity solvent show an average particle size of less than 300 nm based on the dynamic light scattering and scanning electron microscopy analysis. The effects of the physical properties of the metal oxide and the solvent viscosity on the pulverization are analyzed experimentally.

Fabrication of Organic Solvent Resistant Polyketone Hollow Fiber Membranes (유기용매 저항성 Polyketone 중공사 분리막의 제조)

  • Park, Yeji;Jang, Wongi;Choi, Jinwon;Woo, Yunha;Hou, Jian;Jeon, Sungil;Byun, Hongsik
    • Membrane Journal
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    • v.31 no.5
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    • pp.363-370
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    • 2021
  • Organic solvent resistant hollow fiber membranes were fabricated via a thermally induced phase separation (TIPS) method using Polyketone polymer, a material with excellent resistance to organic solvents. The PEG300, DMSO2 and Glycerine called the "green solvents" were used as diluents for TIPS method. The spherulite structure was formed with DMSO2 by S-L phase separation behavior whereas the bicontinuous structures were formed with PEG300 and Glycerine, respectively. The morphology of the PK hollow fiber membranes was investigated using SEM. The pure water permeability and the durability test were conducted to understand the permeation properties of PK hollow fiber membranes. The tensile strength test was conducted for the property of mechanical strength. In this study, the fabrication of PK hollow fiber membranes with various diluents was discussed to understand the correlation between diluent and polymer in detail.

Addictive Effects of Ecklonia cava Methanol and its Solvent-soluble Extract Against Antibiotic-resistant Cutibacterium acnes Causing Acne Vulgaris (항생제 내성 Cutibacterium acnes에 대한 감태(Ecklonia cava) 추출물의 항균 시너지 효과)

  • Eun-Song Kim;Ju-Won Ryu;Hyo-Bin Kim;Ho-Su Song;Na-Young Yoon;Kil Bo Shim;Hye Jin Hwang;Young-Mog Kim;Sung-Hwan Eom
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.56 no.3
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    • pp.293-299
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    • 2023
  • Acne vulgaris is often associated with acne-related bacteria such as Cutibacterium acnes. In this study, we investigated the antibacterial effects of the methanol extract of the algae Ecklonia cava and its solvent-soluble extract against C. acnes. Among five solvent fractions, the ethyl acetate (EtOAc) fraction exhibited the strongest antibacterial activity against C. acnes. Furthermore, the EtOAc-soluble extract exhibited the highest total phenolic contents among the five solvent fractions tested. The EtOAc subfraction 07 (Fr. 07) extract showed the highest antibacterial effect against C. acnes and isolated C. acnes along with minimum inhibitory concentration (MIC) ranging from 32 to 64 ㎍/mL. Additionally, MICs of antibiotics against antibiotic-resistant C. acnes strains were substantially reduced when antibiotics were combined with Fr. 07, suggesting that Fr. 07 restore the antibacterial activity of the antibiotics. The fractional inhibitory concentration indices clearly revealed an additive synergistic effect of Fr. 07 with antibiotics. The results of the present study suggest a potential role for E. cava in the control of infections related to acne vulgaris.