• Title/Summary/Keyword: solution resistivity

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Influence of Chloride Content of on Electrical Resistivity in Concrete (콘크리트내 염소이온량이 전기저항에 미치는 영향)

  • Yoon, In-Seok;Nam, Jin-Won
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.18 no.6
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    • pp.90-96
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    • 2014
  • The electrical resistivity of concrete can be related to two processes involved in corrosion of reinforcement: initiation (chloride penetration) and propagation (corrosion rate). The resisistivity of concrete structure exposed to chloride indicates the risk of early corrosion damage, because a low resistivity is related to rapid chloride penetration and to high corrosion rate. Concrete resistivity is a geometry-independent material property that describes the electrical resistance, which is the ratio between applied voltage and resulting current in a unit cell. In previous study, it was realized that the resistivity of concrete depended on the moisture content in the concrete, microstructural properties, and environmental attack such as carbonation. The current is carried by ions dissolved in the pore liquid. While some data exist on the relationship between moisture content on electrical resistivity of concrete, very little research has been conducted to evaluate the effect of chloride on the conduction of electricity through concrete. The purpose of this study is to examine and quantify the effect of chloride content on surface electrical resistivity measurement of concrete. It was obvious that chloride content had influenced the resistivity of concrete and the relationship showed a linear function. That is, concrete with chloride ions had a comparatively lower resistivity. Decreasing rate of resistivity of concrete was clear at early time, however, after 50 days resistivity was constant irrespective of chloride concentration. Conclusively, this paper suggested the quantitive solution to depict the electrical resistivity of concrete with chloride content.

Three-Dimensional Resistivity Modeling by Serendipity Element (Serendipity 요소법에 의한 전기비저항 3차원 모델링)

  • Lee, Keun-Soo;Cho, In-Ky;Kang, Hye-Jin
    • Geophysics and Geophysical Exploration
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    • v.15 no.1
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    • pp.33-38
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    • 2012
  • A resistivity method has been applied to wide range of engineering and environmental problems with the help of automatic and precise data acquisition. Thus, more accurate modeling and inversion of time-lapse monitoring data are required since resistivity monitoring has been introduced to quantitatively find out subsurface changes With respect to time. Here, we used the finite element method (FEM) for 3D resistivity modeling since the method is easy to realize complex topography and arbitrary shaped anomalous bodies. In the FEM, the linear elements, also referred to as first order elements, have certain advantages of simple formulation and narrow bandwidth of system equation. However, the linear elements show the poor accuracy and slow convergence of the solution with respect to the number of elements or nodes. To achieve the higher accuracy of finite element solution, high order elements are generally used. In this study, we developed a 3D resistivity modeling program using high order Serendipity elements. Comparing the Serendipity element solutions for a cube model with the linear element solutions, we assured that the Serendipity element solutions are more accurate than the linear element solutions in the 3D resistivity modeling.

Resistivity Survey Using Long Electrodes (긴 전극을 사용하는 전기비저항 탐사)

  • Cho, In-Ky;Lee, Keun-Soo;Kim, Yeon-Jung;Kim, Rae-Young
    • Geophysics and Geophysical Exploration
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    • v.19 no.1
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    • pp.45-50
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    • 2016
  • Generally, a point source has been routinely used in the electrical resistivity measurements because of easy installation. If steel-cased wells are used as long electrodes, we can expect the better depth of investigation. However, the resistivity data with long electrodes can not be processed with a conventional inversion algorithm because a long electrode produces the different primary potential distribution compared with the point source. In this study, we proposed a new technique to process the electrical resistivity data with long electrodes by replacing the long electrode with a sequence of point electrodes. Comparing the potentials obtained from the technique with the analytic/numerical solution, we ensure that the proposed technique can be used for the numerical resistivity modeling based on the finite difference or finite element method.

Effect of Reductants and their Properties of Electric Resistivity on the Preparation of Ag coated Cu Powders by Chemical Reduction Method (화학환원법을 이용한 은 코팅 구리 분말 제조 시 환원제의 영향 및 전기비저항 특성)

  • Ahn, Jong-Gwan;Yoon, Chi-Ho;Kim, Dong-Jin;Cho, Sung-Wook;Park, Je-Shin
    • Korean Journal of Metals and Materials
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    • v.48 no.12
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    • pp.1097-1102
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    • 2010
  • Silver coated copper powders were prepared by a chemical reduction method with controlling the deposition process variables such as the feeding rate of the silver ionic solution and concentration of the reductants at room temperature. The characteristics of the products were evaluated by scanning electron microscope (SEM), X-ray diffractometer (XRD), atomic absorption spectrophotometer (AA) and a 4 probe resistivity measurement system. The optimum condition of the preparation of Ag coated Cu powders was at 0.05 M of potassium sodium tartrate and 2 ml/min of the feeding rate of the silver ionic solution. Our method successfully produced dense, uniform, and well-dispersed Ag coated Cu powder of $2{\sim}2.5{\mu}m$ witha silver layer of 100~200 nm. Additionally, we found that thespecific resistivity of the 30 wt.% Ag coated Cu powder was similar to that of pure silver, so that the composite powder could be used as an alternative electromagnetic shielding material for silver.

A Study on the Characteristics of $TiO_2$ Thin Films by Sol-Gel Process (졸-겔법에 의한 $TiO_2$ 박막의 특성에 관한 연구)

  • 황규석;김병훈
    • Journal of the Korean Ceramic Society
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    • v.32 no.3
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    • pp.281-288
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    • 1995
  • to prepare the TiO2 thin films, acetyl-acetone(2.4-pentanedione)(1 : 1 molar ratio) was dissolved in the propanol solution of titanium(IV)isopropoxide(Ti[OCH(CH3)2]4). Al, Cr and Sb in the form of soluble salt and niobium ethoxide were added s dopants, respectively. Thin films were coated by the dip-coating method and characteristics were investigated by XRD, SEM and conductance meter. As a result, viscosity of sol was maintained below 4 centi Poise more than 20 days, and crystal growth and diminution of resistivity occurred as the heat treatment temperature increased. The grains grew over 1${\mu}{\textrm}{m}$ and the lowest resistivity was obtained when Nb was added at 130$0^{\circ}C$.

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Electrical Properties of Ultrafine $(CeO_2)_{0.9}(Gd_2O_3)_{0.1}$ Powders Prepared by Glycine Nitrate Process for the High Efficient Solid Oxide Fuel Cell Applications

  • Lee, Kang-Ryeol;Park, Sung
    • The Korean Journal of Ceramics
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    • v.7 no.1
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    • pp.6-10
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    • 2001
  • Ultrafine $(CeO_2)_{0.9}(Gd_2O_3)_{0.1}$ solid solution powders synthesized by the glycine-nitrate process, with specific surface areas of $19-23\;\textrm{m}^2$/g were sintered at $1500^{\circ}C$ for various sintering times and then their electrical characteristics were investigated using AC impedance and four-point probe measurements. The electrical resistivity of the sintered $(CeO_2)_{0.9}(Gd_2O_3)_{0.1}$ bodies showed the minimum value at the sintering time of 10 hrs. The minimum total resistivity of the $(CeO_2)_{0.9}(Gd_2O_3)_{0.1}$ bodies sintered at $1500^{\circ}C$ for 10 hrs seems to result from the lowest activation energy for the electrical resistivity by the combination between the activation energies for the resistivities at the grain interior and grain boundary.

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Monitoring Cathodic Shielding and Corrosion under Disbonded Coatings

  • Varela, F.;Tan, M. YJ;Hinton, B.;Forsyth, M.
    • Corrosion Science and Technology
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    • v.16 no.3
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    • pp.109-114
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    • 2017
  • Monitoring of corrosion is in most cases based on simulation of environmental conditions on a large and complex structure such as a buried pipeline using a small probe, and the measurement of thermodynamics and kinetics of corrosion processes occurring on the probe surface. This paper presents a hybrid corrosion monitoring probe designed for simulating deteriorating conditions wrought by disbonded coatings and for measuring current densities and distribution of such densities on a simulated pipeline surface. The concept of the probe was experimentally evaluated using immersion tests under cathodic protection (CP) in high resistivity aqueous solution. Underneath the disbonded area, anodic currents and cathodic currents were carefully measured. Anodic current densities were used to calculate metal loss according to Faraday's law. Calculated corrosion patterns were compared with corrosion damage observed at the surface of the probe after a series of stringent tests. The capability of the probe to measure anodic current densities under CP, without requiring interruption, was demonstrated in high resistivity aqueous solution. The pattern of calculated metal loss correlated well with corrosion products distribution observed at the array surface. Working principles of the probe are explained in terms of electrochemistry.

Electrochemical Characteristics of AIZr Thin Film for TFT-LCD Bus Line (TFT-LCD 버스선을 위한 AIZr 합금 박막의 전기 .화학적 특성에 관한 연구)

  • 김장권;김동식;이종호;정관수
    • Proceedings of the IEEK Conference
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    • 2001.06b
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    • pp.49-52
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    • 2001
  • The electrochemical characteristics of Alalloy thin film with low impurity concentrations AIZr deposited by using do magnetron co-sputtering deposition are investigated for the applications as gate bus line in the TFT-LCD panel. AlZr thin films were deposited various atomic percent of Zr. For increasing Zr atomic percent the hillock density was decreased and the resistivity was increased. The deposited thin films show the decrease of resistivity and the increase of grain size after the RTA at 300 $^{\circ}C$for 20 min.. Moreover, the resistivity of AIZr does not show appreciable grain size dependence after RTA. It is concluded that the decrease of resistivity after RTA is due to the increase of grain size. The annealed AIZr(at.0.9%) is found to be hillock free. The electrode potentials of AIZr were less than ITO's (-1.4V) and the etching rate of AIZr(at.0.9%) was 3.8587ng/sec. in KOH(10%) solution. Caculation results reveal that the AIZr(at.0.9%) thin film can be applicable to gate line of 25" UXGA class TFT-LCD panels and can not be applicable to data line.line.

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Effects of Sputtering Power and Oxygen Flow Rate on the Electrical Properties of ATO Thin Films Made by DC Magnetron Sputtering (DC Magnetron Sputtering 법에 의해 ATO 박막 제조시 스퍼터전력 및 산소유량이 전기적 성질에 미치는 영향)

  • Lee, Hwan-Soo;Lee, Hae-Yong;Yoon, Cheon
    • Korean Journal of Materials Research
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    • v.9 no.5
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    • pp.533-537
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    • 1999
  • ATO(Sb doped $SnO_2$) thin films whose thicknesses were 600, 1100 and $2100\AA$ were prepared by DC magnetron sputtering method. They showed the lowest resistivity at DC sputtering power 0.24kW and had lower resistivity with increasing thickness. The power dependence of resistivity among ATO thin films was also different with thickness. The increase of carrier concentration in ATO thin films was responsible for the decrease of resistivity with thickness increase. ATO thin films which were prepared at 30sccm oxygen flow rate showed a great change of sheet resistance under 1M HCl solution. The investigation of SAM(Scanning Auger Microprobe) revealed that oxygen atomic percentage on the surface of ATO thin films was changed. The decrease of sheet resistance also occurred when ATO thin films, prepared at 30sccm oxygen flow rate, were exposed to air for a long period of time. For this reason, it was considered that the desorption of oxygen on ATO surface was accelerated by HCl.

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Utilization of Kota stone slurry powder and accelerators in concrete

  • Devi, Kiran;Saini, Babita;Aggarwal, Paratibha
    • Computers and Concrete
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    • v.23 no.3
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    • pp.189-201
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    • 2019
  • Recent advances in the concrete technology are aiding in minimizing the use of conventional materials by substituting by-products of various industries and energy sources. A large amount of stone waste i.e., dust and slurry form both are being originated during natural stone processing and causing deadily effects on the environment. The disposal problem of stone waste can be resolved effectively by using waste in construction industries. In present work, Kota stone slurry powder, as a substitution of cement was used along with accelerators namely calcium nitrate and triethanolamine as additives, to study their impact on various properties of the concrete mixtures. Kota stone slurry powder (7.5%), calcium nitrate (1%) and triethanolamine (0.05%) were used separately as well in combination in different concrete mixtures. Mechanical Strength, modulus of elasticity and electrical resistivity of concrete specimens of different mix proportions under water curing were studied experimentally. The durability properties in terms of strength and electrical resistivity against sulphate and chloride solution attack at various curing ages were also studied experimentally. Results showed that accelerators and Kota stone slurry powder separately enhanced the mechanical strength and electrical resistivity; but, their combination decreased strength at all curing ages. The durability of concrete specimens was also affected under the exposure to chemical attack too. Kota stone slurry powder found to be the most effective material among all materials. Material characterization was also done to study the microstructural properties.