• Title/Summary/Keyword: solution resistivity

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On the Stannic Oxide Thin Film (산화 주석 박막에 대하여)

  • 박순자
    • Journal of the Korean Ceramic Society
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    • v.13 no.2
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    • pp.8-16
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    • 1976
  • The conductive transparent film is prepared by spraying thin salt solution. In stannic chloride solution as a base solution, various dopants such as Al, Co, Cu and Ni were dissolved respectively as a chloride state and then the films were made by spraying solutions on hot glass plates. The properties of them were compared with those of the stannic salt single component film. The films doped with copper oxide and nickle oxide were improved by decreasing their sheet resistivity and temperature coefficient of resistivity. In comparison with the sheet resistivity and temperature coefficient of resistivity of stannic oxide single component film, being 2.5 K ohm/$\textrm{cm}^2$ and -1650ppm/$^{\circ}C$ respectively, its values of the film containing 15 mol % of copper oxide and formed at 40$0^{\circ}C$ were 2.5K ohm/$\textrm{cm}^2$ and -920ppm/$^{\circ}C$ respectively. The film containing 15 mol % of nickel oxide and formed at 50$0^{\circ}C$ has shown its sheet resistivity and temperature coefficient 0.7 K ohm/$\textrm{cm}^2$ and -940ppm/$^{\circ}C$ respectively.

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Electrical Resistivity of Cylindrical Cement Core with Successive Substitution by Electrolyte of Different Conductivity (전도성이 다른 공극수로 순차 치환한 시멘트 시험편의 전기비저항)

  • Lee, Sang-Kyu;Lee, Tae-Jong
    • Geophysics and Geophysical Exploration
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    • v.12 no.4
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    • pp.328-337
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    • 2009
  • To investigate the relation between pore fluid conductivity and bulk resistivity of a rock sample it is assumed that electrolyte solution perfectly substitute the pore fluid that occupied the pore space within the sample in general. In this study, it is investigated that how much can the electrolyte solution substitute the pore fluid by repeating the same saturation process. Four kinds of NaCl solutions of 8, 160, 3200, 64000 ${\mu}S$/cm are used. The saturation process has repeated four times for each electrolyte in increasing conductivity order first then four times each in decreasing order. The more the saturation process repeated with the same electrolyte, the more electrolyte solution substitute the pore fluid. Geometric mean of bulk resistivity in increasing and decreasing orders with the same electrolyte solution is assumed to be mostly close to the bulk resistivity with perfect substitution. Bulk resistivity measurements for both increasing and decreasing order differs within 10% to the geometric mean when repeating the saturation process 4 times while maximum 40% difference is observed when single saturation process for each electrolyte solution with increasing order. The modified parallel resistant model can generally represent the relations between pore fluid resistivity and bulk resistivity in the experiment, but more experimental data with various rock samples with different porosity is needed to generalize the model.

Dispersibility, Electrical Property of Nano-Composite by Solution Mixing Method (용액혼합법에 따른 나노복합재료 분산성 및 전기적 특성)

  • Yang, Hoon;Park, Dae-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.04c
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    • pp.73-74
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    • 2008
  • In this paper, we have investigated dispersibility, volume resistivity of nano-composite by solution mixing method. Dispersibility measured by FE-SEM(Field Emission Scanning Electron Microscope. And volume resistivity measured by ASTM D991. To expect interaction used dual filler system. But, dual filler system had influence on polymer complex. So, polymer chain mobility doesn't resist.

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Properties of ZnO:Al Films Prepared by Spin Coating of Aged Precursor Solution

  • Shrestha, Shankar Prasad;Ghimire, Rishi;Nakarmi, Jeevan Jyoti;Kim, Young-Sung;Shrestha, Sabita;Park, Chong-Yun;Boo, Jin-Hyo
    • Bulletin of the Korean Chemical Society
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    • v.31 no.1
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    • pp.112-115
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    • 2010
  • Transparent conducting undoped and Al impurity doped ZnO films were deposited on glass substrate by spin coat technique using 24 days aged ZnO precursor solution with solution of ethanol and diethanolamine. The films were characterized by UV-Visible spectroscopy, X-ray diffraction (XRD), scanning electron microscope (SEM), electrical resistivity ($\rho$), carrier concentration (n), and hall mobility ($\mu$) measurements. XRD data show that the deposited film shows polycrystalline nature with hexagonal wurtzite structure with preferential orientation along (002) crystal plane. The SEM images show that surface morphology, porosity and grain sizes are affected by doping concentration. The Al doped samples show high transmittance and better resistivity. With increasing Al concentration only mild change in optical band gap is observed. Optical properties are not affected by aging of parent solution. A lowest resistivity ($8.5 \times 10^{-2}$ ohm cm) is observed at 2 atomic percent (at.%) Al. With further increase in Al concentration, the resistivity started to increase significantly. The decrease resistivity with increasing Al concentration can be attributed to increase in both carrier concentration and hall mobility.

Dissolution Behavior of Complex Carbonitrides in a Microalloyed Steel (Microalloyed 강에서 복합 탄질화물의 재용해 거동)

  • Jung, Jae-Gil;Park, June-Soo;Ha, Yang-Soo;Lee, Young-Kook;Bae, Jin-Ho;Kim, Kisoo
    • Journal of the Korean Society for Heat Treatment
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    • v.21 no.6
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    • pp.287-292
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    • 2008
  • Dissolution behavior of complex carbonitrides in a Nb-Ti-V microalloyed steel was quantitatively examined by electrical resistivity, transmission electron microscopy (TEM), and optical microscopy. The electrical resistivity increased with solution treatment temperature up to $1250^{\circ}C$ for a holding time of 15 min. But, an increasing rate of electrical resistivity with temperature was obviously decreased above $1150^{\circ}C$. As the solution treatment temperature increases, irregular shaped Nb-rich carbonitrides disappear and cuboidal Ti-rich carbonitrides are observed. Abnormal grain growth occurs above $1250^{\circ}C$ for a holding time of 15 min. The optimal solution treatment temperature of a Nb-Ti-V microalloyed steel was determined as $1200^{\circ}C$ for a holding time of 15 min.

The Effects of Process Parameters on Properties of CdS Thin Films Prepared by Solution Growth Method

  • Kim, Soo-Gil;Lee, Yong-Eui;Kim, Sang-Deok;Kim, Hyeong-Joon;Jinsoo Song;Yoon, Kyung-Hoon;Park, Byung-Ho
    • The Korean Journal of Ceramics
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    • v.3 no.1
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    • pp.57-61
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    • 1997
  • The effects of pH of solution on structural, electrical, and optical properties of CdS thin films prepared by solution growth method were investigated. With increasing pH of the solution, both crystallinity and transmittance of CdS thin film were deteriorated due to impurities and CdS particles, which were produced by homogeneous nucleation and adsorbed on the surface of CdS thin films. The films were strongly adherent to substrates and has low resistivity of 10~$10^2{\omega}cm$ regrardless of deposition conditions. After annealing at 30$0^{\circ}C$ in Ar atmosphere, the resistivity decreased due to desorption of impurity ions as well as the formation of S vacancies, but after annealing above 35$0^{\circ}C$ it increased by an agglomeration of S vacancies. After annealing in air atmosphere, the film resistivity increased because of the formation of oxide particle in grain boundaries.

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FE model of electrical resistivity survey for mixed ground prediction ahead of a TBM tunnel face

  • Kang, Minkyu;Kim, Soojin;Lee, JunHo;Choi, Hangseok
    • Geomechanics and Engineering
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    • v.29 no.3
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    • pp.301-310
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    • 2022
  • Accurate prediction of mixed ground conditions ahead of a tunnel face is of vital importance for safe excavation using tunnel boring machines (TBMs). Previous studies have primarily focused on electrical resistivity surveys from the ground surface for geotechnical investigation. In this study, an FE (finite element) numerical model was developed to simulate electrical resistivity surveys for the prediction of risky mixed ground conditions in front of a tunnel face. The proposed FE model is validated by comparing with the apparent electrical resistivity values obtained from the analytical solution corresponding to a vertical fault on the ground surface (i.e., a simplified model). A series of parametric studies was performed with the FE model to analyze the effect of geological and sensor geometric conditions on the electrical resistivity survey. The parametric study revealed that the interface slope between two different ground formations affects the electrical resistivity measurements during TBM excavation. In addition, a large difference in electrical resistivity between two different ground formations represented the dramatic effect of the mixed ground conditions on the electrical resistivity values. The parametric studies of the electrode array showed that the proper selection of the electrode spacing and the location of the electrode array on the tunnel face of TBM is very important. Thus, it is concluded that the developed FE numerical model can successfully predict the presence of a mixed ground zone, which enables optimal management of potential risks.

Evaluation of Microstructure and Ductile-Brittle Transition Temperature in Thermally aged 2.25Cr-1Mo Steel by Electrical Resistivity Measurement (전기비저항을 이용한 2.25Cr-1Mo 강 열화재의 미세조직 및 연성-취성천이온도 평가)

  • Byeon, Jai-Won;Kwun, S.I.
    • Journal of the Korean Society for Nondestructive Testing
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    • v.22 no.3
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    • pp.284-291
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    • 2002
  • An attempt was made to evaluate the degree of aging degradation in thermally aged 2.25Cr-1Mo steel by electrical resistivity measurement. Artificial aging was performed to simulate the microstructural degradation in 2.25Cr-1Mo steel arising from long time exposure at $540^{\circ}C$. Microstructural parameter (amount of solid solution element), mechanical property (ductile-brittle transition temperature) and electrical resistivity were measured to investigate the mutual relationship among these parameters. Depletion of solid solution element(Mo and Cr) in matrix was detected after aging. The ductile-brittle transition temperature(DBTT) increased rapidly in the initial stage of aging and then saturated afterward. On the other hand, the electrical resistivity decreased rapidly in the beginning and then saturated in the later stage of aging.

Resistivity and Calibration Error Estimations for Small-Loop Electromagnetic Method

  • Sasaki, Yutaka;Son, Jeong-Sul;Kim, Chang-Ryol;Kim, Jung-Ho
    • 한국지구물리탐사학회:학술대회논문집
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    • 2007.06a
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    • pp.167-172
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    • 2007
  • The frequency-domain small-loop electromagnetic (EM) instruments are increasingly used for shallow environmental and geotechnical surveys because of their portability and speed. However, it is well known that the data quality is generally so poor that quantitative interpretation of the data is not justified in many cases. We present an inversion method that allows the correction for the calibration errors and also constructs multidimensional resistivity models. The key point in this method is that the data are collected at least at two different heights. The forward modeling used in the inversion is based on an efficient 3-D finite-difference method, and its solution was checked against 2-D finite-element solution. The synthetic and real data examples demonstrate that the joint inversion recovers reliable resistivity models from multi-frequency data severely contaminated by the calibration errors.

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Analyses of Apparent Resistivity Responses from Near-Surface Cavities (지하천부의 공동에 의한 외견 비저항의 해석)

  • Kim, Hee Joon
    • Economic and Environmental Geology
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    • v.17 no.2
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    • pp.101-107
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    • 1984
  • This paper describes dipole-dipole apparent resistivity responses from near-surface cavities in otherwise homogeneous earth materials. In applying the dipole-dipole resistivity method to the problem of locating and delineating subsurface cavities, it is important to know apparent resistivity responses not only for conductive bodies but also for resistive ones. Dipole-dipole apparent resistivities for these bodies are calculated by the numerical modeling technique using an integral equation solution. The magnitude and pattern of apparent resistivity is highly dependent on the ratio of body resistivity to background resistivity. In conductive bodies, the largest anomaly of apparent resistivity appears at the outside of the body. In resistive bodies, however, the position of the largest anomaly coincides with the location of the body. The field results gathered at Okinawa, Japan in 1978 showed that peak anomalies occurred at the locations of air-filled cavities.

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