• Journal of Korean Society for Atmospheric Environment
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• 제21권E3호
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• pp.87-94
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• 2005

Wet scavenging by rain drops is a most important removal process of air pollutants. In order to study the scavenging mechanisms of aerosol particles, the characteristics of chemical components in the rain water were examined as a function of the amount of rainfall. Rain water were collected continuously and separated into the soluble and insoluble components. The elemental concentrations in both components were determined by a PIXE analysis. The physical and chemical characteristics of atmospheric aerosols during the rainfall events were measured simultaneously. The elemental concentrations in rain water decreased substantially just after rain started and then gradually declined in subsequential rain fall exceeding 1.0 mm. The large particles were scavenged more easily than the fine particles. Fe, Ti and Si in rain water were in high insoluble state. Contrarily, almost whole of S was dissolved in rain water.

• 한국대기환경학회지
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• 제18권4호
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• pp.317-325
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• 2002

An air pollution monitoring station has been operated at Tokchok Island since April 1999 to characterize the background atmosphere in the vicinity of the Yellow Sea. In this study, eight chemical species in PM$_{2.5}$ and three gaseous species were analyzed. A total of 53 samples were collected for the analysis of PM$_{2.5}$ and gaseous species from April, 1999 to April, 2001. The overall mean mass concentration of PM$_{2.5}$ was 20.8 $\mu\textrm{g}$/㎥ and the eight soluble ionic species accounted for about 46.8% of PM$_{2.5}$ mass. Approximately 80% of samples appeared to experience the chloride loss effect. Air pollutant sources of PM$_{2.5}$ measured at Tokchok Island were qualitatively identified by the principal component analysis. It was found that five principal components are secondary aerosol, soil, incineration, phase change of nitrate, and ocean.and ocean.

• 한국대기환경학회지
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• 제31권6호
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• pp.520-529
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• 2015

The ambient $PM_{2.5}$ samples were collected by $PM_{2.5}$ sampler from September 2010 to December 2012 at Daegu University, Gyeongsan. A total of 260 samples were collected and 27 species were analyzed by inductively coupled plasma, ion chromatography, and thermal optical reflectance methods. Factor analysis identified four sources such as biomass burning source/secondary aerosol source, soil source, industry source, and incinerator source/mobile source. Also, backward trajectories were calculated using HYSPLIT 4 (Hybrid single-particle lagrangian integrated trajectory) model and PSCF (Potential source contribution function) model was applied to identify the possible source locations of carbonaceous species and water soluble ions species. PSCF results showed that the possible source locations of most chemical constituents measured in Gyeongsan were the industrial areas in the eastern coast of China, northeast regions of China, the Gobi Desert, and east sea of Korea.

• 한국대기환경학회지
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• 제27권2호
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• pp.168-180
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• 2011

The variation of the physicochemical properties of atmospheric aerosols in coexistence of the heavy Asian Dust and Haze observed from $15^{th}$ to $17^{th}$ March 2009 in Seoul was scrutinized through the mass and ion concentration observations and synoptic weather analysis. Although the ratio of PM1.0/PM10 was constant at 0.3 (which is typical during Asian Dust period in Korea) during the measurement period, both PM10 and PM1.0 mass concentrations were 3~6 times and 2~4 times higher than that of clear days, respectively. Water-soluble ion components accounted for 30~50% of PM10 and 50~70% of PM1.0 mass concentration. One of the secondary pollutants, $NO_3^-$ was found to be associated with $Ca^{2+}$ and $Na^+$ in coarse mode indicating that the aerosol derived from natural source was affected by anthropogenic pollutants. While the acidity of the aerosols increased in fine mode when the stagnation of weather patterns was the strongest (March $16^{th}$), the alkalinity increased in coarse mode when new air masses arrived with a southwestern wind after ending a period of stagnation (March $17^{th}$). In the selected case, SOR (Sulfur Oxidation Ratio, $nSO_4^{2-}/[nSO_4^{2-}+nSO_2]$) and NOR (Nitrogen Oxidation Ratio, $nNO_3^-/[nNO_3^-+nNO_2]$) values of ion components were higher than the general values during Asian Dust period. These results imply that dust aerosols could be mixed with pollutants transported from China even in heavy Asian Dust cases in Korea.

• 한국환경과학회지
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• 제12권2호
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• pp.217-225
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• 2003

Samples of size-fractionated PM10 (airborne particulate matter with aerodynamic diameter less than $10\mu\textrm{m}$) were collected at an urban site in Jeju city from May to September 2002. The mass concentration and chemical composition of the samples were measured. The data sets were then applied to the CMB receptor model to estimate the source contribution of PM10 in Jeju area. The average PM10 mass concentration was 28.80$\mu\textrm{g}/m^3$ ($24.6~33.49\mu\textrm{g}/m^3$), and the FP (fine particle with aerodynamic diameter less than $2.l\mu\textrm{m}$ fraction in PM10 was approximately 8% higher than the CP (coarse particle with aerodynamic diameter greater than $2.l\mu\textrm{m}$ and less than $10\mu\textrm{m}$ fraction in PM10. The CP composition was obviously different from the FP composition, that is, the most abundant water soluble species was nitrate ion in the FP, but sulfate ion in the CP. Also sulfur was the most dominant element in the FP, however, sodium was that in the CP. From CMB receptor model results, it was found that road dust was the largest contributor to the CP mass concentration (45% of the CP) and ammonium nitrate, domestic boiler, and marine aerosol were major sources to the CP mass. However, the secondary aerosol was the most significant contributor to the FP mass concentration (45% of the FP). In this study, it was suggested that the contributions of soil dust and gasoline vehicle became very low due to collinearity with road dust and diesel vehicle, respectively.

• 한국대기환경학회지
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• 제11권2호
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• pp.179-184
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• 1995

This study was carried out to characterize sources of suspended particulate matter(SPM) in Mt. Soback area from January to Novembver in 1993. The collection and major water soluble ion analysis of SPM were conducted by using a High Volumn Air Sampler(HVAS; W&A Inc., PM-10) and ion chromatograph(DIONEX 4000i), respectively. The variations of SPM and major ion concentrations were found to be 9. sim. 156.mu.g/ $m^{3}$, $F^{-10}$ 0.00 .sim. 0.15.mu.g/ $m^{3}$, C $l^{-10}$ 0.06 .sim. 3.79.mu.g/ $m^{3}$, N $O_{3}$$^{-10}$ 0.90 .sim. 6.85.mu.g/ $m^{3}$, S $O_{4}$$^{2-}$ 1.99 .sim. 9.36.mu.g/ $m^{3}$ N $a^{+}$0.00 .sim. 0.27.mu.g/ $m^{3}$, N $H_{4}$ $^{+}$0.72 .sim. 5.77.mu.g/ $m^{3}$, $k^{+}$0.03 .sim. 0.88.mu.g/ $m^{3}$ and $Ca^{2+}$0.12 .sim. 2.76.mu.g/ $m^{3}$. Tree sources were identified by Principal Component Amalysis(PCA) using a SPSS/P $C^{+}$. The explanation ability of forst, second and third Principal Component were 60.8%, 13.6%, 8.2%, of total variance. The sources classfied by PCA were found to be secondary aerosol/fuel combustion, soil dust related cement production/yellow sand and aerosol related waste burning.related waste burning.g.

• 한국환경보건학회지
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• 제19권3호
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• pp.52-57
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• 1993

This study was carried out to investigate the air pollution in Hwasoon Nulitjae tunnel for two months, from August 1992 to September 1992. The total suspended particles were collected by high volume air sampler at inside and outside of Hwasoon Nulitjae tunnel, of which major water soluble component and heavy metalic element were analyzed. Size distribution and respirable mass fraction of aerosol at inside were measured by filters on nine stages Andersen air sampler. The average concentration of TSP at inside was 657.57 $\mu$g/m$^3$, which appeared about 9.2 times as high as that of 71.47 $\mu$g/m$^3$ at outside. The decrease effect caused by using new tunnel was 31.2%. As a result of correlation analysis between concentration of TSP at inside of Hwasoon Nulitjae tunnel and that at outside, correlation coefficient was 0.713. The average concentrations of SO$_4^{2-}$ , NO$_3^-$, CI$^-$ were 43.02 $\mu$g/m$^3$, 19.86 $\mu$g/m$^3$, 4.96 $\mu$g/m$^3$, those of NH$_4^+$, Na$^+$, K$^+$ 1.42 $\mu$g/m$^3$, 4.45 $\mu$g/m$^3$, 2.89 $\mu$g/m$^3$ and those of Ca$^{2+}$, Mg$^{2+}$, Pb$^{2+}$ 3.92 $\mu$g/m$^3$, 2.27 $\mu$g/m$^3$. 1.52 $\mu$g/m$^3$, respectively. It was estimated that mass fraction rate of respirable particle at inside was about 84.54% of aerosol. The average concentration of suspended particle to be collected by Andersen sampler was 478.90 $\mu$g/m$^3$, this was about 72.8% of that by high volume air sampler.

• 한국입자에어로졸학회지
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• 제7권4호
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• pp.131-138
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• 2011

우리나라의 대표적인 배경지역 측정소인 안면도의 지구배경관측소에서 20010년에 채취한 미세먼지(PM10) 시료에 대해 n-alkane과 수용성 유기성분(WSOC) 농도를 분석하였다. 우리나라의 또 다른 배경지역인 고산에 비해 봄철의 수용성 유기성분의 농도는 세배 정도 높았다. 안면관측소의 수용성 유기성분의 농도는 서울이나 아시아 다른 도시지역의 농도와 비슷한 수준이었다. 그러나 아시아 도시는 겨울에 농도가 높았으나, 안면관측소는 가을에 높아 배출원, 또는 생성원이 다른 것으로 보인다. 한편 n-alkane 성분의 농도는 안면관측소가 고산보다 약간 낮았고, 서울 등의 아시아 도시의 1/3-1/2 수준으로 낮았다. 그러나 고산은 자연적인 기원의 n-alkane 농도가 높은 반면에 안면관측소는 인위적인 n-alkane이 대부분이어서 대조를 보이고 있다. 따라서 안면관측소는 우리나라의 대표적인 배경지역임에도 불구하고 수용성 유기성분과 n-alkanes 농도측면에서는 배경지역과 도시지역의 특성을 갖고 있어, 인위적인 영향을 많이 받고 있는 것으로 보인다. 보다 상세한 배출원과 생성원 분석은 무기이온농도와 다른 유기성분 분석을 추가하여 이루어질 예정이다.

• 한국대기환경학회지
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• 제29권1호
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• pp.74-85
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• 2013

Since the underground transportation system is a closed environment, indoor air quality problems may seriously affect many passengers' health. The purpose of this study was to understand $PM_{10}$ characteristics in the underground air environment and further to quantitatively estimate $PM_{10}$ source contributions in a Seoul Metropolitan subway station. The $PM_{10}$ was intensively collected on various filters with $PM_{10}$ aerosol samplers to obtain sufficient samples for its chemical analysis. Sampling was carried out in the M station on the Line-4 from April 21 to 28, July 13 to 21, and October 11 to 19 in the year of 2010 and January 11 to 17 in the year of 2011. The aerosol filter samples were then analyzed for metals, water soluble ions, and carbon components. The 29 chemical species (OC1, OC2, OC3, OC4, CC, PC, EC, Ag, Al, Ba, Cd, Cr, Cu, Fe, Mn, Ni, Pb, Si, Ti, V, Zn, $Cl^-$, $NO_3{^-}$, $SO_4{^{2-}}$, $Na^+$, $NH_4{^+}$, $K^+$, $Mg^{2+}$, $Ca^{2+}$) were analyzed by using ICP-AES, IC, and TOR after proper pretreatments of each sample filter. Based on the chemical information, positive matrix factorization (PMF) model was applied to identify the $PM_{10}$ sources and then six sources such as biomass burning, outdoor, vehicle, soil and road dust, secondary aerosol, ferrous, and brakewear related source were classified. The contributions rate of their sources in tunnel are 4.0%, 5.8%, 1.6%, 17.9%, 13.8% and 56.9% in order.

• Asian Journal of Atmospheric Environment
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• 제6권4호
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• pp.281-287
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• 2012

Aerosol concentrations at the CC-Lag site in the Teshio Experimental Forest increased from winter to spring and sometimes showed extremely high values associated with Kosa and/or forest-fire events. The range and mean of the mass concentrations of aerosol chemical species were as follows: total particulate mass, 1.2-29, 5.0; elemental carbon, 0.061-2.2, 0.43; organic carbon, 0.059-3.5, 0.79; and sulfate, 0.12-6.2, 1.8 ${\mu}g/m^3$. The total masses of the deposited particles on hybrid larch and on bamboo leaves were approximately 35 and 30 ${\mu}g/cm^2$, respectively. The amounts of soil particles on the leaves were 6 ${\mu}g/cm^2$ for the upper part of hybrid larch, 2 ${\mu}g/cm^2$ for the lower part of hybrid larch, and 1 ${\mu}g/cm^2$ for Sasa bamboo leaves. The amounts of deposited black carbon were 2.3 ${\mu}g/cm^2$ for the upper part of hybrid larch, 0.6 ${\mu}g/cm^2$ for the lower part of hybrid larch, and 0.2 ${\mu}g/cm^2$ for Sasa bamboo leaves. Half of the total deposited particular mass was attached on the hybrid larch; however, most of the total deposited mass was adhered on the Sasa bamboo leaves. Regardless of the species, there tend to be more deposited particles on the leaves in the upper part than in the lower part, with only a few meters height difference. Comparing the composition of the deposited particles to that of the atmospheric aerosols without any size cut, the fractions of water-soluble material sulfate and sea salt in the deposited aerosols were about one tenth and one hundredth lower than that in the aerosols, respectively. On the basis of the measured concentration and the deposited amount on leaves, the deposition velocity of black carbon was estimated to be approximately 0.5 cm/s.