• Title/Summary/Keyword: solubility

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LCD Color Filter용 Cy3 염료의 제조 및 특성 연구 (Preparation and Characterization of Cy3 Dye for LCD Color Filter)

  • 이상동;현동균;정연태
    • 한국전기전자재료학회논문지
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    • 제29권1호
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    • pp.35-39
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    • 2016
  • In this research, we focused on the improvement of cy3 dye's characteristics for LCD color filter. Solubility and thermal stability are main characteristics of dyes for LCD color filter. We performed experiment to change counter cation of cy3 dyes with alkoxy substituent for these purposes. These cy3 dyes (1b~5b) were prepared through the synthetic procedure of three steps. The synthesized new cy3 dyes were charaterized by using NMR, FT-IR, UV/Vis spectroscopy, and TGA. These cy3 dyes showed purple color and maximum absorption wavelength (${\lambda}_{max}$) in the range of 578~590 nm in UV/Vis spectrum. We confirmed that solubility and thermal stability of cy3 dyes were dependent on the structure of counter cation. Cy3 dyes with alkoxy substituent have good solubility in organic solvents such as dichloromethane, methanol, and acetone. Especially, Cy3 dye with 4-nitrobenzyl counter cation (5b) gave excellent solubility characteristics.

탄소 포화 Mn 합금 용액내 C, Si 및 Fe 사이의 열역학적 상호작용 (Thermodynamic Interactions Among Carbon, Silicon and Iron in Carbon Saturated Manganese Melts)

  • 백민규;이원규;김길남;장정목;박종진
    • 대한금속재료학회지
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    • 제50권1호
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    • pp.45-51
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    • 2012
  • Thermodynamics of carbon in manganese alloy melts is important in manufacturing low carbon ferromanganese and silico-manganese alloys. In order to predict the carbon solubility in liquid $Mn-Si-Fe-C_{sat}$ alloys as a function of melt composition and temperature, thermodynamic interactions among carbon, silicon and iron in carbon saturated liquid manganese should be known. In the present study, the effects of silicon and iron on the carbon solubility in Mn-Si, Mn-Fe and Mn-Si-Fe melts were measured in the temperature range from 1673 to 1773 K. The carbon solubility decreases significantly as silicon and iron contents increase in liquid manganese alloy. The interaction parameters among carbon, silicon and iron in carbon saturated liquid manganese were determined from the carbon solubility data and the Lupis' relation for the interaction coefficient at constant activity.

Solubility of TiO2 in NaF-CaF2-BaF2 Melts

  • Yoo, Jeong-Hyun;Cho, Sung-Wook
    • Metals and materials international
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    • 제24권6호
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    • pp.1386-1393
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    • 2018
  • The solubility of $TiO_2$ in $NaF-CaF_2-BaF_2$ ternary eutectic melts was investigated at the temperature range of $1025-1150^{\circ}C$. The least-squares equation was obtained from the relationship between the reciprocal temperature and the natural logarithm of the titanium concentration in the melts saturated with $TiO_2$. The corresponding partial molar enthalpy of dissolution of $TiO_2$ was found to be 188 kJ/mol. The titanium saturation concentration was 3.73 wt% at $1100^{\circ}C$. From the titanium concentration change with the added amount of $TiO_2$ at different holding time after a final stirring, it was found that not only complete dissolution of $TiO_2$ but also enough sedimentation of excessive $TiO_2$ should be guaranteed to obtain more reliable solubility data. The holding time of 10 h was found to be enough for the excessive $TiO_2$ particles to settle down in our experimental conditions. It is noteworthy that in case of adding $TiO_2$ in excess of its solubility, the $Ba_{1.12}(Ti_8O_{16})$ phase was observed at the lower and bottom of the solidified salt ingots.

Effect of Solubility Parameter Mismatch in Holographic PDLCs

  • Jung, Ju-Ai;Kim, Eun-Hee;Kim, Byung-Kyu
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2004년도 Asia Display / IMID 04
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    • pp.1216-1219
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    • 2004
  • LC and polymer miscibility in HPDLC has been studied in terms of solubility parameter. It was found that better grating formation and diffraction efficiency were obtained when the difference in solubility parameters between polymer and LC is greater.

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초임계 이산화탄소에서 히노키치올의 용해도 측정과 예측 (Measurement and Correlation of Hinokitiol Solubility in Supercritical Carbon dioxide)

  • 신문삼
    • 한국산학기술학회:학술대회논문집
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    • 한국산학기술학회 2011년도 춘계학술논문집 1부
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    • pp.489-492
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    • 2011
  • Supercritical fluid technology has been an alternative for purification and separation of biological compounds in cosmetic, food, and pharmaceutical products. Solubility information of biological compounds in supercritical fluids is essential for choosing a supercritical fluid processes. The equilibrium solubility of hinokitiol was measured in supercritical carbon dioxide with a static method in the pressure range from 8 to 40 MPa and at temperatures equal to 313.2, 323.2 and 333.2 K. The experimental data were correlated well by Peng.Robinson equation of state and quasi-chemical nonrandom lattice fluid model.

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방부제 용해도의 교차점에 대하여

  • 정교민
    • 대한화장품학회지
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    • 제10권1호
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    • pp.8-12
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    • 1984
  • Increasing the oil volume in the oil : water mixtures using isopropyl myristate, oleic acid as oils, the solubilities of methyl, propyl and butyl parabens and the MICs (minimum hibitory concentrations) to E. coli were increased. But in liquid paraffin, the solubility was reversed. The relation between MIC and solubility of parabens had constant factor of 0.7 as saturation fraction percent. The solubility of methyl paraben was crossed over in those of propyl and butyl parabens, when the oil volume was increased. When the oil was used over the cross-over point, methyl paraven was useful to preserve the systems, and below the cross-over point the more lipophilic propyl and/or butyl parabens were effective.

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인도메타신의 용해도에 미치는 계면 활성제의 영향 (Effect of Surfactants on the Solubility Properties of Indomethacin)

  • 김경순;최영혜
    • 약학회지
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    • 제28권3호
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    • pp.161-167
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    • 1984
  • To improve the solubility properties of indomethacin, a poorly water-soluble drug, some attempts were made with surfactants, such as sodium deoxycholate, sodium laurylsulfate and polysorbate-80. The enhancement effect in solubility was found to be due to the micellar solubilization and dependent on the concentration of surfactants, pH and temperature. The mechanism of interaction was suggested to be attributed to the formation of mixed micelles between the drug and solubilizers.

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M\ulcorner를 첨가한 Cr2O3의 전기전도도 (Electrical Conductivity of MgO-doped Cr2O3)

  • 박진성;김호기
    • 한국세라믹학회지
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    • 제24권2호
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    • pp.179-185
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    • 1987
  • The microstructure and the electrical conductivity of MgO-doped Cr2O3 were investigated as a function of oxygen partial presure, temperature, and MgO content. The grain size was estimated about 1.0$\mu\textrm{m}$. The solubility limit is increased with oxygen partial pressure. Above the solubility limit of MgO in Cr2O3, the spinel phase(MgCr2O4) is formed by the reaction of MgO and Cr2O3. The electrical conductivity of MgO-doped Cr2O3 within the solubility limit is increased with MgO content. Above the solubility limit, however, it is decreased with increasing MgO content because of the formation of the spinel phase.

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오골계에서 추출한 Actomyosin 의 ATPase 활성 및 용해도 (ATPase Activity and Solubility of Actomyosin Extracted from Muscle of Silky Fowl)

  • 정인철;문윤희
    • 한국식품영양과학회지
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    • 제23권5호
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    • pp.827-831
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    • 1994
  • Investigation on the extractability, Mg2+-, Ca2+ , EDTA-ATPase activity and solubility of actomyosin prepared from leg and breast muscle of silky fowol were as follows. The extractability of actomyosin in leg and breast muscle was 779mg/100g and 1, 318mg/100g respectively, breast muscle was higher than leg muscle . Mg2+-ATPase activity of actomyosin was high inionic strength 0.02-0.10 and Mg2+ATPase activity of low ionic strength was higher than high ionic strength not related to the part. Ca2+ ATPase activity was high in ionic strength 0.05-0.13, the activity of leg muscle was higher that breast muscle. And EDTA-ATPase activity showed low in low ionic strength and showed high in high ionic strength, and increased greatly depend ionic strength up to 0.4. The solubility of actomyosin was not different in leg and breast muscle , the solution started in KCI concentration of 0.3M and ended in DCI concentration of 0.4M.

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담석 치료에 사용되는 단방요법에 대한 담석성분의 용해 실험 (The Study on the Solubility of the Ingredients of the Bilestone In the Solution of the Traditional Oriental Medicines)

  • 최성모
    • 동의생리병리학회지
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    • 제18권5호
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    • pp.1387-1390
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    • 2004
  • This study was carried out to investigate the solubility of the ingredients of the bilestone in the solution of the traditional oriental medicines. The cholesterol and the calcium carbonate(CaCO₃) were chosen as the ingredients of the bilestone. Coicis Semen, Polygonum aviculare L, Maydis Stigmata, Allium tuberosum Rottler, and Raphanus sativa var. hortensis for. acanthiformis Makino were studied as the oriental medicines for the bilestone. The cholesterol had showed no solubility in all solutions of the traditional oriental medicines, but the calcium carbonate had showed the good solubility in all solutions of the traditional oriental medicines except Coicis Semen.