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A review on Separation Technologies for Lithium Recovery from Waste Solutions in Recycling Process of Waste Battery (폐배터리 재활용 공정 폐액 중 리튬 회수를 위한 분리 기술 고찰)

  • Song, Daesung;Kim, Eunkyu;Vu, Thang-Toan
    • Korean Chemical Engineering Research
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    • v.60 no.4
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    • pp.473-477
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    • 2022
  • In this study, candidate technologies for lithium recovery from the process waste liquid generated in the waste battery recycling process were reviewed, and technologies applicable to the process from the commercialization point of view were reviewed from a qualitative point of view. The evaporation method is difficult to apply because it requires a large-scale land and shows a low recovery rate due to the loss of Li during the concentration process. In the case of precipitation, a commercially available technology shows a high recovery rate due to the high Li/Na selectivity of phosphoric acid, but there are disadvantages in that the process is complicated due to the use of expensive phosphoric acid, requiring a recovery step, and continuous operation is impossible because solids are handled in the Li concentration process. In the case of solvent extraction, if we find an inexpensive extractant with high Li/Na selectivity, continuous operation is possible with the method used in extraction of other metals in the previous step, and when Li is concentrated, continuous operation is possible because it is in a liquid state. If it shows a similar recovery rate compared to precipitation technology, commercialization will be the most likely.

Characteristics of Heat Absorption by Gas in a Directly-irradiated Fluidized Bed Particle Receiver (태양열 유동층 흡열기의 기체 열흡수 특성)

  • Park, Sae Han;Kim, Sung Won
    • Korean Chemical Engineering Research
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    • v.59 no.2
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    • pp.239-246
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    • 2021
  • Characteristics of hydrodynamics and heat absorption by gas in a directly-irradiated fluidized bed particle receiver (50 mm-ID X 150 mm high) of SiC particles have been determined. Solid holdups of SiC particles show almost constant values with increasing gas velocity. Fine SiC particles (SiC II; dp=52 ㎛, ρs=2992 kg/㎥) showed low values of relative standard deviation of pressure drop across bed but high solids holdups in the freeboard region compared to coarse SiC particles (SiC I; dp=123 ㎛, ρs=3015 kg/㎥). The SiC II exhibited higher values of temperature difference normalized by irradiance due to the effect of additional solar heat absorption and heat transfer to the gas by the particles entrained in the freeboard region in addition to the efficient thermal diffusion of the solar heat received at bed surface. Heat absorption rate and efficiency increased with increasing the gas velocity and fluidization number. The SiC II showed maximum heat absorption rate of 17.8 W and thermal efficiency of 14.8%, which are about 33% higher than those of SiC I within the experimental gas velocity range.

Quality Properties Depending on Aging of Deabong Persimmon-fermented Liquor (매실 첨가 대봉감 발효 숙성주의 이화학적 특성)

  • Kwang Keun, Cho;Sang Won, Gal;Sang-Won, Lee
    • Journal of Life Science
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    • v.32 no.11
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    • pp.847-854
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    • 2022
  • The purpose of this study was to prepare Daebong persimmon-fermented liquor supplemented with Prunus mume fruit to promote the consumption of Daebong persimmon and to develop local specialties. As fermentation progressed, the alcohol content rapidly increased, whereas the sugar content decreased. With the production of CO2 from the second day of fermentation, the epidermis and flesh solids of the Daebong persimmons began mixing together and rose to the surface of the fermentation container. This phenomenon continued until the fourth and fifth days of fermentation; on the fifth day, the ethanol and sugar contents were 11.4% and 9.8°Brix, respectively. A concentration of 6 to 9% (w/w) P. mume fruit was found to be the optimal amount during Daebong persimmon fermentation. When the fermented liquor was stored for 60 days at 5℃, the pH and ethanol content showed no significant change during the aging period. As aging progressed, the content of sugar slowly decreased in both the control sample and in the one to which P. mume was added, showing 9.8 and 10.4 mg/ml at the eighth week post-aging, respectively. The total acid content was 0.79~0.81% at the beginning of aging but slightly increased to 0.84~0.86% in the second week of aging. As a result of the sensory test, the sour taste, sweetness, and flavor were slightly stronger in the P. mume fruit group than in the control group.

Effect of crop load on the yield, fruit quality, and fruit mineral contents of 'RubyS' apples

  • Nay Myo, Win;Dongyong, Lee;Yang-Yik, Song;Juhyeon, Park;Young Sik, Cho;Moo-Yong, Park;Youngsuk, Lee;Hun Joong, Kweon;Jingi, Yoo;In-Kyu, Kang;Jong-Chul, Nam
    • Korean Journal of Agricultural Science
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    • v.49 no.3
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    • pp.421-430
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    • 2022
  • Crop load management in apple trees is important for achieving optimum productivity and crop value. Hence, we investigated the influence of different crop loads on the fruit quality, mineral content, and yield of the 'RubyS' apple variety. After 4 weeks of full bloom, the crop load was adjusted by hand thinning to different (5, 10, and 15 fruits·cm-2) trunk cross-sectional areas (TCSA), representing low, medium, and high crop loads. The low crop load increased the fruit size and weight, the development of the red-blushed area, and the peel color a* at harvest; however, it reduced the total number of fruits·tree-1 and yield compared with that of the other crop loads. The medium crop load improved the fruit weight, flesh firmness, and soluble solids content and reduced the fruits·tree-1 but did not affect the fruit size and yield. However, there were no significant differences in the titratable acidity and starch index among the crop loads. The fruit mineral content (phosphorus and potassium) was higher in the low and medium crop loads compared to the high crop load. However, the nitrogen, calcium, and magnesium contents in the fruits were not affected by the crop loads. Overall, this study suggests that a low crop load improves the fruit size and weight, but its effect on the quality and fruit mineral content is similar to that of a medium crop load. Therefore, the optimum crop load level for the 'RubyS' apple trees was approximately 10 fruits·cm-2 TCSA.

Comparison of Characteristics of Acid-catalyzed Hydrothermal Fractionation for Production of Hemicellulose Hydrolyzate from Agricultural Residues (농경잔류물로부터 헤미셀룰로오스 가수분해물 생산을 위한 산촉매 열수 분별공정의 특성 비교)

  • Hwang, Jong Seo;Oh, Kyeong Keun;Yoo, Kyung Seun
    • Korean Chemical Engineering Research
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    • v.60 no.3
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    • pp.414-422
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    • 2022
  • The objective of this work was to investigate the feasibility of acid-catalyzed hydrothermal fractionation for maximum solubilization of the hemicellulosic portion of two typical agricultural residues. The fractionation conditions converted into combined reaction severity (CS) in the range of 1.2-2.9 was used to establish a simple reaction criteria at glance. The hemicellulosic sugar yield of 56.6% was shown when rice straw was fractionated at the conditions at the conditions; 160 ℃ of temperature 0.75% (w/v) of H2SO4, 20 min of reaction time, 1:15 solid/liquid ratio. The hemicellulosic sugar yield of 83.0%, however, was achieved when barley straw was fractionated at the conditions at the conditions; 150 ℃ of temperature 0.75% (w/v) of H2SO4, and 15 min of reaction time, 1:10 solid/liquid ratio. For barley straw, acid-catalyzed hydrothermal fractionation could be effectively performed. After the fractionation process, the remaining fractionated solids were 48.5% and 57.5% from raw rice and barley straws, respectively. The XMG contents in the solid residues decreased from 17.3% and 17.6% to 6.0% and 2.6%, which corresponded to 16.7% and 8.5% on the basis of the raw straws, respectively. In another way, only 5.6% of cellulose and 8.5% of XMG were lost due to excessive decomposition during the acid-catalyzed hydrothermal fractionation of barley straw, compared to cellulose and XMG losses of 6.4% and 26.6% in rice straw. Hemicellulosic sugars from the rice straw were considered more over-decomposed due to the somewhat higher reaction severity at the acid-catalyzed hydrothermal fractionation.

Somatic cell score: gene polymorphisms and other effects in Holstein and Simmental cows

  • Citek, Jindrich;Brzakova, Michaela;Hanusova, Lenka;Hanus, Oto;Vecerek, Libor;Samkova, Eva;Jozova, Eva;Hostickova, Irena;Travnicek, Jan;Klojda, Martin;Hasonova, Lucie
    • Animal Bioscience
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    • v.35 no.1
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    • pp.13-21
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    • 2022
  • Objective: The aim of the study was to evaluate the influence of gene polymorphisms and nongenetic factors on the somatic cell score (SCS) in the milk of Holstein (n = 148) and Simmental (n = 73) cows and their crosses (n = 6). Methods: The SCS was calculated by the formula SCS = log2(SCC/100,000)+3, where SCC is the somatic cell count. Polymorphisms in the casein alpha S1 (CSN1S1), beta-casein (CSN2), kappa-casein (CSN3), beta-lactoglobulin (LGB), acyl-CoA diacylglycerol transferase 1 (DGAT1), leptin (LEP), fatty acid synthase (FASN), stearoyl CoA desaturase 1 (SCD1), and 1-acylglycerol-3-phosphate O-acyltransferase 6 (AGPAT6) genes were genotyped, and association analysis to the SCS in the cow's milk was performed. Further, the impact of breed, farm, year, month of the year, lactation stage and parity on the SCS were analysed. Phenotype correlations among SCS and milk constituents were computed by Pearson correlation coefficients. Results: Only CSN2 genotypes A1/A2 were found to have significant association with the SCS (p<0.05), and alleles of CSN1S1 and DGAT1 genes (p<0.05). Other polymorphisms were not found to be significant. SCS had significant association with the combined effect of farm and year, lactation stage and month of the year. Lactation parity and breed had not significant association with SCS. The phenotypic correlation of SCS to lactose content was negative and significant, while the correlation to protein content was positive and significant. The correlations of SCS to fat, casein, nonfat solids, urea, citric acid, acetone and ketones contents were very low and not significant. Conclusion: Only CSN2 genotypes, CSN1S1 and DGAT1 alleles did show an obvious association to the SCS. The results confirmed the importance of general quality management of farms on the microbial milk quality, and effects of lactation stage and month of the year. The lactose content in milk reflects the health status of the udder.

Effects of Water Microspraying, Foliar Application of Calcium Carbonate and Kaolin Solution on Sunburn and Quality of Fruits in Satusma Mandarin (미세살수와 탄산칼슘 및 카올린 엽면살포가 온주밀감의 일소 발생과 과실 품질에 미치는 영향)

  • Joa, Jae-Ho;Kang, Seok-Beom;Park, Yo-Sup;Kim, Mi-Sun;Kim, Ha-Neul;Oh, Bok-Shim
    • Journal of Bio-Environment Control
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    • v.31 no.4
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    • pp.261-269
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    • 2022
  • This study was carried out to predict fruit surface temperature (FST) causing sunburn symptoms and assess the correlation between solar radiation and FST in satusma mandarin (Citrus unshiu Marc. 'Iwasaki'). And to reduce sunburn when ambient temperature was at 31℃, sprinkler system was repeated spraying every at 5 minutes of 30 minutes intervals and 1% calcium carbonate and 4% kaolin solution applied on citrus tree three times to investigate quality and sunburn of fruits. It showed highly significant positive correlation between FST and solar radiation (R = 0.788, p < 0.01), The FST increased up to 16℃ than ambient temperature at daytime. To estimate FST, a linear model y = 0.099 × (air temperature) + 0.018 × (solar radiation) + 20.779 (R = 0.687, p < 0.01) was derived. The canopy temperature of citrus trees was 5.1℃ lower in sprinkler system than in control. The incidence of sunburn showed at 2.1% in sprinkler system twice lower than in control and there was different significance. Fruit quality was similar between treatments. In conclusion, sunburn can be reduced by reflecting sunlight or downing of FST through sprinkler system.

A study on the introduction of organic waste-to-energy incentive system(II): material and energy balance of biogasification (유기성폐자원에너지 인센티브제도 도입방안 연구(II): 바이오가스화 물질·에너지수지)

  • Moon, Hee-Sung;Kwon, Jun-Hwa;Lee, Won-Seok;Lee, Dong-Jin
    • Journal of the Korea Organic Resources Recycling Association
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    • v.29 no.4
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    • pp.77-86
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    • 2021
  • In this study, to use as basic data for the organic waste resource energy incentive system, the energy efficiency is evaluated through the mass balance and energy balance calculation results of the anaerobic digester where food waste, food waste leachate and various organic wastes are treated. As a result of the mass balance analysis for 11 biogasification facilities, it was confirmed that 21.1% of process water and 25.7% of tap water were input in large amounts, excluding organic waste. Accordingly, it accounted for 87.6% of the total effluent of linked treated water. In addition, considering that 15.7% of the total input volume is converted to biogas and the average total solids (TS) is 22%, an average material conversion rate of 75% was confirmed. As a result of the energy balance analysis, the energy conversion rate was confirmed to be 78.5% on average by analyzing the biogas calorific value compared to the potential energy of the influent. The average biogas production efficiency including external energy sources for biogas production was 69.4%, and the biogas plant efficiency to which unused effluent energy was applied was 58.9% on average.

Elementary School Students' Understanding of Matter and its Examples (물질의 개념과 예에 대한 초등학생들의 이해)

  • Lim, Heejun
    • Journal of Korean Elementary Science Education
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    • v.41 no.1
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    • pp.150-161
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    • 2022
  • Matter is a basic concept that students should understand during their science classes. However, many difficulties are associated with understanding the concepts of matter due to its abstraction. In this study, the elementary school students' understanding of the concept of matter and the examples of matter and non-matter are investigated and analyzed by grade. The subjects of this study were 418 students from third grade to sixth grade. The survey was conducted using a free-response questionnaire comprising three questions. The results are as follows. First, the elementary school students' conceptions of matter were "materials that make up objects," "what can be seen and touched," and "solid, liquid, and gas." As the grade increased, the explanations for a material decreased and the explanations for the state of matter increased. Furthermore, only few students explained matter in terms of mass and volume. Second, solids were the most common examples of matter presented by the students, and liquids and gases were included in the upper grades. However, there were many cases in the upper grades where students were unable to distinguish between objects and matter. Third, non-matter was properly presented by the 6th graders as compared to the other graders, and in many cases, objects, liquids, and gases were mentioned as non-matter. Fourth, it was found that the students' conceptions of matter influenced the examples of matter and non-matter that they presented.

Effects of Freeze Drying, Room-temperature Drying, and Room-temperature Drying after Roasting on Volatile Compounds Sugar Content, Flavonoids, and Antioxidant Activity of Hallabong (Citrus sphaerocarpa Tanka nom. nud.) Peel Tea (동결건조, 상온 건조, 볶음 후 상온 건조가 한라봉(Citrus sphaerocarpa Tanka nom. nud.) 과피차의 향기 성분과 당도 및 플라보노이드, 항산화 활성에 미치는 영향)

  • Kim, Min-Gyeong;Kwon, Min-Ju;Ku, Kang-Mo
    • Korean Journal of Plant Resources
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    • v.35 no.4
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    • pp.455-463
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    • 2022
  • The effects of freeze-drying (FD), room-temperature drying (RD), and room-temperature drying after roasting (RDAR) on the volatile organic compounds (VOCs), sugar content, flavonoids, and antioxidant activity of Hallabong peel tea were tested. This experiment was conducted to collect a basic information for developing of peel tea. FD samples showed lower total soluble solids and VOCs than other drying treatments. RDAR samples showed a significant difference in VOCs and visual color of FD samples. The reduced VOCs in FD samples was caused by freeze drying treatment; identical VOCs composition of hallabong peel was detected from condensed ice of freeze-drying machine. Metabolomics analysis showed no difference among three drying treatments. In addition, antioxidant activity and total phenolic compounds were not significantly different from three different drying treatments. Thus, RD or RDAR is a suitable drying method for hallabong peel tea rather than FD method in terms of VOCs and economical reasons.