• Title/Summary/Keyword: solid solution formation

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Laser Microfabrication for Silicon Restrictor

  • Kim, Kwang-Ryul;Jeong, Young-Keun
    • Journal of Powder Materials
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    • v.15 no.1
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    • pp.46-52
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    • 2008
  • The restrictor, which is a fluid channel from a reservoir to a chamber inside a thermal micro actuator, has been fabricated using ArF and KrF excimer lasers, Diode-Pumped Solid State Lasers (DPSSL) and femtosecond lasers for a feasibility study. A numerical model of fluid dynamics for the actuator chamber and restrictor is presented. The model includes bubble formation and growth, droplet ejection through nozzle, and dynamics of fluid refill through the restrictor from a reservoir. Since an optimized and well-fabricated restrictor is important for a high frequency actuator, some special beam delivery setups and post processing techniques have been researched and developed. The effects of variations of the restrictor length, diameter, and tapered shapes are simulated and the results are analyzed to determine the optimal design. The numerical results of droplet velocity and volume are compared with the experimental results of a cylindrical-shaped actuator. It is found that the micro actuators having tapered restrictors show better high frequency characteristics than those having a cylindrical shape without any notable decrease of droplet volume. The laser-fabricated restrictors demonstrate initial feasibility for the laser direct ablation technique although more development is required.

Hydrothermal Solution-Rhyolite Reaction and Origin of Sericitite in the Yukwang Mine (유문암-열수 반응과 유광 견운모 광상의 성인)

  • Park, Maeng-Eon;Choi, In-Sik;Kim, Jin-Sup
    • Economic and Environmental Geology
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    • v.25 no.3
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    • pp.225-232
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    • 1992
  • The hydrothermal alteration is evaluated using multicomponent equilibrium calculations with the program CHILLER for the reactions between hydrothermal water and rhyolite at the temperature of $300^{\circ}C$ and pressure of 500 bars. The chemical-reaction model on the depositional processes of the sericitite confirms that the hydrothermal water-rock interaction(hydrothermal alteration) is the main mechanism of the sericitite formation. The principal change in the aqueous phase during the reaction is the pH increase. Overall trends for the major species are the increase in total molalities of K, Ca, $SiO_2$, Al, Mg, Fe, Na, and sulfide in solid phase with hydrothermal water-rhyolite reaction and the decrease of them in aqeous solution by precipitation of hydrothermal products. Quartz and sericite are the first minerals to form. The sequence of minerals to precipitate following them is chlorite, epidote, pyrite and microcline as water/rock ratio decreases. Although calculated results cannot duplicate the complexities of natural hydrothermal alteration, the calculation provides thermodynamic constraints on the natural process. The calculation results resemble those of experimental studies. Sericitite forms where pH decreases and water/rock ratio increases.

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A Study on the Precipitation Behavior of Disordered ${\gamma}$ Phase in an $L1_2$ Ordered ${\gamma}^{\prime}-Ni_3(Al,Ti)$ Phase ($L1_2$${\gamma}^{\prime}-Ni_3(Al,Ti)$ 규칙상 중에 불규칙 ${\gamma}$상의 석출거동에 관한 연구)

  • Han, Chang-Suk
    • Journal of the Korean Society for Heat Treatment
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    • v.19 no.5
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    • pp.249-256
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    • 2006
  • Structural studies have been performed on precipitation hardening found in $L1_2$ ordered ${\gamma}^{\prime}-Ni_3(Al,Ti)$ alloys using transmission electron microscopy. A uniform solid solution of ${\gamma}^{\prime}-L1_2$ ordered phase supersaturated with Ni can be obtained by solution annealing in a suitable temperature range. The ${\gamma}^{\prime}$ phase hardens appreciably by the fine precipitation of disordered ${\gamma}$. The shape of ${\gamma}$ precipitates formed during aging is initially spherical or round-cubic and grow into platelets as aging proceeds. High resolution electron microscopy revealed that the ${\gamma}$ precipitates are perfectly coherent with the matrix ${\gamma}^{\prime}$ as long as the ${\gamma}$-precipitates are plates. The loss of coherency initiates by the introduction of dislocations at the ${\gamma}/{\gamma}^{\prime}$ interface followed by the step formation at the dislocations. The ${\gamma}$ precipitates become globular after the loss of coherency. The strength of ${\gamma}^{\prime}-Ni_3(Al,Ti)$ increases over the temperature range of experiment by the precipitation of fine ${\gamma}$ particles. The peak temperature where a maximum strength was obtained shifted to higher temperature.

Numerical Analysis for Cooling and Freezing Processes with Subcooling (과냉각을 동반한 동결과정의 수치해석)

  • Yoon, J.I.;Kim, J.D.;Kim, S.G.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.8 no.4
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    • pp.451-462
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    • 1996
  • In this study, which focuses on ice storage, a fundamental study in cooling and solidification was performed, including the interesting phenomena of density inversion, supercooling and dendritic ice. A numerical study was performed for natural convection and ice formation considering existence of subcooling and dendritic ice were analyzed numerically by using finite difference method and boundary fixing method. In the mesh, the solid fraction was introduced with adding as a term to the energy conservation equation. A flow in the dendrite was modelled as a flow in a porous medium, and the momentum conservation equation was modified to incorporate resistance forces involved in flows through porous media. A numerical solution of the time dependencies of dendrite area and dense ice front was successfully obtained, and the numerical results were good agreement with experimental results. Based on this methodology, a discussion was made of phenomena and characteristics of cooling and freezing processes under various conditions.

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A study on the depositional wear between different metals (이종 금속간의 용착마모에 관한 연구)

  • 신문교;이우환
    • Journal of Advanced Marine Engineering and Technology
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    • v.9 no.1
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    • pp.74-88
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    • 1985
  • The wear becomes the most complicated cause of making various machineries short lives. In the studies by many scholors so far, the accurate and perfect methods to eliminate it completely are not found yet owing to many affected factors. On this view point of Depositional Wear, the wear test with seven different specimens from the part of frequent usage of which are carbon steel, nickel, copper, aluminum, zinc, lead and tin was attempted to make clear the relation between the wear of different metals and their melting point, crystal structure, sliding speed, load and lattice factors. The results of this study are summerized as follows; 1) Worn amount of each metal is maximum when each metal is same quality. 2) The easier becomes the the formation of solid solution in the course of friction proceeding, the more it results in worn amount of each metal. 3) The samer is each metal in crystal structure as well as lattice factor, the more it results in worn amount of each metal. These results might be of use in designing machineries, selecting materials and operating machineries.

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High-Temperature Oxidation Behavior of Commercial Pure Titanium in Mixed Gases (혼합가스 분위기 중에서 공업용 순 타이타늄의 고온산화 거동)

  • Park, S.H.;Ahn, Y.S.
    • Journal of Power System Engineering
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    • v.11 no.2
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    • pp.44-50
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    • 2007
  • The oxidation behavior of commercial pure titanium is investigated in the temperature range of $727^{\circ}C{\sim}950^{\circ}C$ in mixed gases. The weight change is measured by TGA during oxidation in mixed gases. The oxidation behavior indicated by weight gain or the growth of oxide layer is based on the linear rate law at high temperatures. The structure of the oxide scale formed during oxidation is analysed by optical microscopy, electron probe microanalyzer, scanning electron microscope and x-ray diffraction. Oxide scales have a $TiO_2$ structure, and are constituted with multi-layered or two layered porous external one and a dense internal one. Ti-O solid solution region is formed at the interface of metal and scale layer. The formation of oxide scale is influenced by the oxidation temperature, time, crystal structure and the condition of atmosphere.

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New Methods in the Technology of Electroluminescent Phosphors

  • Sychov, M.M.;Bahmet'ev, V.V.;Khavanova, L.V.;Kuznetsov, A.I.;Smimov, A.;Vasil'eva, I.V.;Mjakin, S.V.;Nakanishi, Y.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.1065-1070
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    • 2003
  • Controlling synthesis conditions of ZnS:Cu,Al and ZnS:Cu electroluminescent phosphors we optimized particle size, color properties and efficiency. Surface properties were studied by new method and showed correlation with luminescence as shown by the analysis of EL spectra with Fok-Alentsev method. Luminance and maintenance improvement was achieved by the electron-beam annealing due to additional decomposition of $ZnS-Cu_{2}S$ solid solution and formation of centers of blue luminescence.

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Excimer laser micromachining of silicon in liquid phase (액상에서의 엑시머 레이저 실리콘 미세가공)

  • Jang, Deok-Suk;Kim, Dong-Sik
    • Laser Solutions
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    • v.11 no.1
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    • pp.12-18
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    • 2008
  • Laser micromachining is a promising technique to fabricate the micro-scale devices. However, there remains important challenges to reducethe redeposition of ablated materials around the laser irradiated zone and to get a smooth surface, especially for metal and semiconductor materials. To achieve the high-quality micromachined devices, various methods have been developed. Liquid-assisted micromachining can be a good solution to overcome the previously mentioned problems. During the laser ablation process, the liquid around the solid sample dramatically changes the ablation characteristics, such as ablation rate, surface profile, formation of debris, and so on. In this investigation, we conducted the laser micromachining of Si in various liquid environmental conditions, such as liquid types, liquid thickness. In addition, using nanoscale time-resolved shadowgraphy technique, we observed the ablation process in liquid environments to understand the mechanism of liquid-assisted laser micromachining.

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A Study on the Phase Equilibrium Conditions of Mixture Gas Hydrates using CSMHYD (CSMHYD를 이용한 혼합가스 하이드레이트의 상평형에 대한 연구)

  • Seo, Hyang-Min;Park, Yun-Beom;Chun, Won-Gee;Kim, Nam-Jin
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.585-589
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    • 2007
  • Gas hydrate is a special kind of inclusion compound that can be formed by capturing gas molecules to water lattice in high pressure and low temperature conditions. When referred to standard conditions, $1m^3$ solid hydrates contain up to $172Nm^3$ of methane gas, depending on the pressure and temperature of production, Such large volumes make natural gas hydrates can be used to store and transport natural gas. In this study, three-phase equilibrium conditions for forming methane hydrate were theoretically obtained in aqueous single electrolyte solution containing 3wt% Nacl. The results show that Nacl acts as a inhibitor, but help gases such as ethan, propane, i-butane, and n-butane reduce the hydrate formation pressure at the same temperature.

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Age-Hardening Behavior and Structural Changes in a Commercial Dental Au-Ag-Cu-Pd Alloy

  • Kim, Hyung-Il;Park, Seok-Kyu
    • Journal of Biomedical Engineering Research
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    • v.15 no.4
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    • pp.389-394
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    • 1994
  • The age-hardening behavior and the structural changes in a commercial dental Au-Ag-Cu-Pd alloy were investigated by means of hardness test, optical and scanning electron microscopic observation, energy dispersive spectroscopy and X-ray diffraction study. The drastic reduction in hardness by prolonged aging occurred after a rapid increase in hardness at the initial stage by the isothermal aging at $350^{\circ}C$. This softening was due to the broad precipitates formation of the lamellar structure which was composed of the f.c.t. AuCu I ordered f.c.t. phase containing Pd and the f.c.c. Ag-rich $\alpha$1 solid solution f.c.c.phase containing Au.

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