• Title/Summary/Keyword: solid density

Search Result 1,199, Processing Time 0.027 seconds

Effect of Overlayer Thickness of Hole Transport Material on Photovoltaic Performance in Solid-Sate Dye-Sensitized Solar Cell

  • Kim, Hui-Seon;Lee, Chang-Ryul;Jang, In-Hyuk;Kang, Wee-Kyung;Park, Nam-Gyu
    • Bulletin of the Korean Chemical Society
    • /
    • v.33 no.2
    • /
    • pp.670-674
    • /
    • 2012
  • The photovoltaic performance of solid-state dye-sensitized solar cells employing hole transport material (HTM), 2,2',7,7'-tetrakis-(N,N-di-p-methoxyphenyl-amine)-9,9'-spirobifluorene (spiro-MeOTAD), has been investigated in terms of HTM overlayer thickness. Two important parameters, soak time and spin-coating rate, are varied to control the HTM thickness. Decrease in the period of loading the spiro-MeOTAD solution on $TiO_2$ layer (soak time) leads to decrease in the HTM overlayer thickness, whereas decrease in spin-coating rate increases the HTM overlayer thickness. Photocurrent density and fill factor increase with decreasing the overlayer thickness, whereas open-circuit voltage remains almost unchanged. The improved photocurrent density is mainly ascribed to the enhanced charge transport rate, associated with the improved charge collection efficiency. Among the studied HTM overlayer thicknesses, ca. 230 nm-thick HTM overlayer demonstrates best efficiency of 4.5% at AM 1.5G one sun light intensity.

The Surface Modification of Electrode with Solid Electrolyte Interphase for Hybrid Supercapacitor

  • Choi, Min-Geun;Kang, Soo-Bin;Yoon, Jung Rag;Lee, Byung Gwan;Jeong, Dae-Yong
    • Journal of Electrical Engineering and Technology
    • /
    • v.10 no.3
    • /
    • pp.1102-1106
    • /
    • 2015
  • A hybrid supercapacitor (HS) is an energy storage device used to enhance the low weight energy density (Wh/kg) of a supercapacitor. On the other hand, a sudden decrease in capacity has been pointed out as a reliability problem after many charge/discharge cycles. The reliability problem of a HS affects the early aging process. In this study, the capacity performance of a HS was observed after charge/discharge. For detailed analysis of the initial charge/discharge cycles, the charge and discharge curve was measured at a low current density. In addition, a solid electrolyte interphase (SEI) layer was confirmed after the charge/discharge. A HC composed of a lithium titanate (LTO) anode and active carbon cathode was used. The charge/discharge efficiency of the first cycle was lower than the late cycles and the charge/discharge rate was also lower. This behavior was induced by SEI layer formation, which consumed Li ions in the LTO lattice. The formation of a SEI layer after the charge/discharge cycles was confirmed using a range of analysis techniques.

Performance Predictions of the Planar-type Solid Oxide Fuel Cell with Computational Flow Analysis (II) - Non-isothermal Model - (유동 해석을 이용한 평판형 고체 산화물 연료전지의 성능 특성 분석 (II) - 비등온 모델 -)

  • Hyun, Hee-Chul;Sohn, Jeong L.;Lee, Joon-Sik;Ro, Sung-Tack
    • Transactions of the Korean Society of Mechanical Engineers B
    • /
    • v.27 no.7
    • /
    • pp.963-972
    • /
    • 2003
  • Performance characteristics of the planar-type solid oxide fuel cell (SOFC) are investigated by the analysis of flow fields coupled with heat and mass transfer phenomena in anode and cathode channels. For these purposes, performance analysis of the SOFC is conducted based on electrochemical reaction phenomena in electrodes and electrolyte coupled with flow fields in anode and cathode channels. In the present study, the isothermal model adopted in the previous paper prepared by the same authors is extended to the non-isothermal model by solving energy equation additionally with momentum and mass transfer equations using CFD technique. It is found that the difference between isothermal and non-isothermal models come from non-uniform temperature distribution along anode and cathode electrodes by solving energy equation in non-isothermal model. Non-uniform temperature distribution in non-isothermal model contributes to the increase of average temperature of the fuel cell and influences its performance characteristics.

Physical Properties of the Factors Affecting the Evaporation Process of Fruit Juices (과일쥬스의 농축공정에 영향을 미치는 인자의 물리적 특성)

  • Eun, Duc-Woo;Choi, Yong-Hee
    • Korean Journal of Food Science and Technology
    • /
    • v.23 no.5
    • /
    • pp.605-609
    • /
    • 1991
  • The physical properties which must be considered as engineering factors affecting on the evaporation process of fruit juices are boiling point rise, density, viscosity, thermal conductivity and specific heat. These factors are varied with food ingredients, soluble solids, pressure and temperature. In the reserch, it has been worked to obtain the data and to develop prediction model for the boiling point rise as a faction of soluble solid and pressure by the regression of SPSS package program. For the prediction model of density, it was developed as a fuction of soluble solid content on apple and pear juices. For the viscosity model, it was establised by the factors of temperature and content of soluble solid through the optimization program.

  • PDF

Microstructure and Tensile Property of Rapidly Solidified Al-Be alloy (급속응고한 Al-Be합금의 미세조직 및 인장특성)

  • Lee, In-Woo;Park, Hyun-Ho;Kim, Myung-Ho
    • Journal of Korea Foundry Society
    • /
    • v.15 no.5
    • /
    • pp.459-468
    • /
    • 1995
  • For high performance aerospace structures, the properties of highest priority are low density, high strength, and high stiffness(modulus of elasticity). Addition of beryllium decrease the density of the aluminum alloy and increase the strength and the stiffness of the alloy. However it is very difficult to produce the Al-Be alloy having useful engineering properties by conventional ingot casting, because of the extremely limited solid solubility of beryllium in aluminum. So, rapid solidification processing is necessary to obtain extended solid solubility. In this study, rapidly solidified Al-6 at% Be alloy were prepared by twin roll melt spinning process and single roll melt spinning process. Twin roll melt spun ribbons were extruded at $450^{\circ}C$ with reduction in area of 25 : 1 after vacuum hot pressing at $550^{\circ}C and 375^{\circ}C$. The microstructure of melt spun ribbon exhibited a refined cellular microstructure with dispersed Be particles. As advance velocity of liquid/solid interface increase, the morphology of Be particle vary from rod-like type to spherical type and the crystal structure of Be particle from HCP to BCC. These microstructural characteristics of rapidly solidified Al-6at.%Be alloy were described on the basis of metastable phase diagram proposed by Perepezko and Boettinger. The extruded ribbon consisted of recrystallized grains dispersed with Be particles and exhibited improved tensile property compared with that of extruded ingot.

  • PDF

Ballistic impact analyses of triangular corrugated plates filled with foam core

  • Panigrahi, S.K.;Das, Kallola
    • Advances in Computational Design
    • /
    • v.1 no.2
    • /
    • pp.139-154
    • /
    • 2016
  • The usage of sandwich structure is extensively increasing in lightweight protective structures due to its low density and other useful properties. Sandwich panels made of metal sheets with unfilled cellular cores are found to exhibit lower deflections by comparing to an equivalent monolithic plate of same metal and similar mass per unit density. However, the process of localized impact on solid structures involving plastic deformation, high strain rates, temperature effect, material erosion, etc. does not hold effectively as that of monolithic plate. In present work, the applications of the sandwich plate with corrugated core have been extended to develop optimized lightweight armour using foam as medium of its core by explicit finite element analysis (FEA). The mechanisms of hardened steel projectile penetration of aluminum corrugated sandwich panels filled with foams have been numerically investigated by finite element analysis (FEA). A comparative study is done for the triangular corrugated sandwich plate filled with polymeric foam and metallic foam with different densities in order to achieve the optimum penetration resistance to ballistic impact. Corrugated sandwich plates filled with metallic foams are found to be superior when compared to the polymeric one. The optimized results are then compared with that of equivalent solid and unfilled cores structure to observe the effectiveness of foam-filled corrugated sandwich plate which provides an effective resistance to ballistic response. The novel structure can be the alternative to solid aluminum plate in the applications of light weight protection system.

Natural vibration of the three-layered solid sphere with middle layer made of FGM: three-dimensional approach

  • Akbarov, Surkay D.;Guliyev, Hatam H.;Yahnioglu, Nazmiye
    • Structural Engineering and Mechanics
    • /
    • v.57 no.2
    • /
    • pp.239-263
    • /
    • 2016
  • The paper studies the natural oscillation of the three-layered solid sphere with a middle layer made of Functionally Graded Material (FGM). It is assumed that the materials of the core and outer layer of the sphere are homogeneous and isotropic elastic. The three-dimensional exact equations and relations of linear elastodynamics are employed for the investigations. The discrete-analytical method proposed by the first author in his earlier works is applied for solution of the corresponding eigenvalue problem. It is assumed that the modulus of elasticity, Poisson's ratio and density of the middle-layer material vary continuously through the inward radial direction according to power law distribution. Numerical results on the natural frequencies related to the torsional and spheroidal oscillation modes are presented and discussed. In particular, it is established that the increase of the modulus of elasticity (mass density) in the inward radial direction causes an increase (a decrease) in the values of the natural frequencies.

Numerical study on motion characteristics of a free falling two-dimensional circular cylinder in a channel using an Immersed Boundary - Lattice Boltzmann Method (가상경계 격자 볼츠만 법을 이용한 채널 내 자유 낙하하는 2차원 원형 실린더의 운동 특성)

  • Jeong, Hae-Kwon;Ha, Man-Yeong;Yoon, Hyun-Sik;Kim, Sung-Jool
    • Proceedings of the KSME Conference
    • /
    • 2008.11b
    • /
    • pp.2489-2494
    • /
    • 2008
  • The two-dimensional circular cylinder freely falling in a channel has been simulated by using Immersed boundary - lattice Boltzmann method in order to analyze the characteristics of motion originated by the interaction between the fluid and the solid. The wide range of the solid/fluid density ratio has been considered to identify the effect of the solid/fluid density ratio on the motion characteristics such as the falling time, the terminal velocity and the trajectory in the vertical and horizontal directions. In addition, the effect of the gap between the cylinder and the wall on the motion of two-dimensional circular cylinder freely falling has been revealed by taking into account a various range of the gap size. The Reynolds number in terms of the terminal velocity is diminished as the cylinder becomes close to the wall at the initial dropping position, since the repulsive force induced between the cylinder and wall constrains the vertical motion. Quantitative information about the flow variables such as the pressure coefficient and vorticity on the cylinders is highlighted.

  • PDF

Comparison of Three Different Helmet Bolus Device for Total Scalp Irradiation (Total Scalp의 방사선 치료 시 Helmet Bolus 제작방법에 관한 연구)

  • Song, Yong-Min;Kim, Jong-Sik;Hong, Chae-Seon;Ju, Sang-Gyu;Park, Ju-Young;Park, Su-Yeon
    • The Journal of Korean Society for Radiation Therapy
    • /
    • v.24 no.1
    • /
    • pp.31-37
    • /
    • 2012
  • Purpose: This study evaluated the usefulness of Helmet bolus device using Bolx-II, paraffin wax, solid thermoplastic material in total scalp irradiation. Materials and Methods: Using Rando phantom, we applied Bolx-II (Action Products, USA), paraffin wax (Densply, USA), solid thermoplastic material (Med-Tec, USA) on the whole scalp to make helmet bolus device. Computed tomography (GE, Ultra Light Speed16) images were acquired at 5 mm thickness. Then, we set up the optimum treatment plan and analyzed the variation in density of each bolus (Philips, Pinnacle). To evaluate the dose distribution, Dose-homogeneity index (DHI, $D_{90}/D_{10}$) and Conformity index (CI, $V_{95}/TV$) of Clinical Target Volume (CTV) using Dose-Volume Histogram (DVH) and $V_{20}$, $V_{30}$ of normal brain tissues. we assessed the efficiency of production process by measuring total time taken to produce. Thermoluminescent dosimeters (TLD) were used to verify the accuracy. Results: Density variation value of Bolx-II, paraffin wax, solid thermoplastic material turned out to be $0.952{\pm}0.13g/cm^3$, $0.842{\pm}0.17g/cm^3$, $0.908{\pm}0.24g/cm^3$, respectively. The DHI and CI of each helmet bolus device which used Bolx-II, paraffin wax, solid thermoplastic material were 0.89, 0.85, 0.77 and 0.86, 0.78, 0.74, respectively. The result of Bolx-II was the best. $V_{20}$ and $V_{30}$ of brain tissues were 11.50%, 10.80%, 10.07% and 7.62%, 7.40%, 7.31%, respectively. It took 30, 120, 90 minutes to produce. The measured TLD results were within ${\pm}7%$ of the planned values. Conclusion: The application of helmet bolus which used Bolx-II during total scalp irradiation not only improves homogeneity and conformity of Clinical Target Volume but also takes short time and the production method is simple. Thus, the helmet bolus which used Bolx-II is considered to be useful for the clinical trials.

  • PDF

Performance Study of Nozzleless Booster Casted to the High Density Solid Propellant with Zr as a Metal Fuel (고밀도 지르코늄(Zr) 금속연료 조성의 추진제를 이용한 무노즐 부스터 성능 연구)

  • Khil, Taeock;Jung, Eunhee;Lee, Kiyeon;Ryu, Taeha
    • Journal of the Korean Society of Propulsion Engineers
    • /
    • v.22 no.2
    • /
    • pp.38-51
    • /
    • 2018
  • This study was carried out to improve the performance characteristics of nozzleless boosters that are used in ramjet boosters. A propellant using Zr as the metal fuel was developed, which provided a higher density than the propellant using Al as the metal fuel. The developed propellant was cast using the nozzleless booster and a ground test was carried out by varying the length-to-diameter ratio (L/D ratio) of the propellant. From a comparison between the performance characteristics of propellants using Zr and Al, it was proved that the performance of the propellant using Zr is higher than that of propellant using Al, except for the specific impulse, under all tested conditions. As the length-to-diameter ratio was increased, the specific impulse of the propellant using Zr was decreased by 88% compared with that of the propellant with Al. However, because of the density difference between the propellants, the impulse density of the propellant with Zr was higher than that of the propellant with Al under all tested conditions.