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Systematic Study of Paper Breaks in Papermaking Process Using Fracture Mechanics - (1) Evaluation of Fracture Toughness in Wet State

  • Yung B. Seo;Roh, You-Sun
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2002.05a
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    • pp.76-84
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    • 2002
  • Fracture toughness was considered as one of the good estimates of the paper break tendency of paper web in the press room. Paper break on the paper machine is caused by many factors such as paper machine irregular vibrations, impurities in the fiber furnish, shives, and so on. On the paper machine, the solid content of paper web is changing very rapidly from less than 1% to over 95%. We tried to measure the fracture toughness of paper web at different solid contents for providing the fundamental knowledge of paper break. Stretches of wet web were also measured and compared to the fracture toughness changes. Four different fiber furnishes (SwBKP, HwBKP, ONP, and OCC) were refined to different degrees, and at different solid contents (40%, 60%, 80%, and 95%), their fracture toughnesses were measured. Two fracture toughness measurement methods (essential work of fracture and Tryding's load-widening method) were used, and we found they gave identical results. The stretch curves of the wet webs against the axis of solid contents were very similar to the fracture toughness curves of those.

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Esterification of the Soybean Oil and Waste Vegetable Oil by Solid Catalysts (고체 촉매를 이용한 대두유와 폐식용유의 에스테르화)

  • Sin, Yong Seop
    • Journal of Environmental Science International
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    • v.13 no.1
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    • pp.79-87
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    • 2004
  • Esterification of soybean oil with methanol was investigated. First of all, liquid-liquid equilibriums for systems of soybean oil and methanol were measured at temperatures ranging from 40 to 65$^{\circ}C$. Profiles of conversion of soybean oil with time were determined from the glycerine content in reaction mixtures for the different kinds of catalysts, such as NaOH, CaO, Ca(OH)$_2$, MgO, Mg(OH)$_2$, and Ba(OH)$_2$. The effects of dose of catalyst, cosolvent and reaction temperature on final conversion were examined. Esterification of waste vegetable oil with methanol was investigated and compared to the case of soybean oil. Solubility of methanol in soybean oil was substantially greater than that of soybean oil in methanol. When the esterification reaction of soybean oil was catalyzed by solid catalyst, final conversion was strongly dependent on the alkalinity of the solid catalyst, and increased with the alkalinity of the metal. Hydroxides from the alkali metals were more effective than oxides. When Ca(OH)$_2$ was used for the esterification catalyst, maximum value of final conversion was measured at dose of 4%. When CHCl$_3$ as a cosolvent, was added into the reaction mixture of soybean oil which catalyzed by Ba(OH)$_2$, maximum value of final conversion was appeared at dose of 3%. When waste vegetable oil was catalyzed by NaOH and solid catalysts, high final conversion, over 90%, and fast reaction rate were obtained.

Anticancer Activity of Acacia nilotica (L.) Wild. Ex. Delile Subsp. indica Against Dalton's Ascitic Lymphoma Induced Solid and Ascitic Tumor Model

  • Sakthive, K.M.;Kannan, N.;Angeline, A.;Guruvayoorappan, C.
    • Asian Pacific Journal of Cancer Prevention
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    • v.13 no.8
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    • pp.3989-3995
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    • 2012
  • The aim of the present investigation was to evaluate the effect of A.nilotica extract against Dalton's ascitic lymphoma (DAL) induced solid and ascitic tumors in BALB/c mice. Experimental animals received A.nilotica extract (10 mg/kg.bw) intraperitoneally for 10 and 14 consecutive days before induction of solid and ascitic tumors, respectively. Treatment with A.nilotica extract significantly decreased the development of tumor and percentage increase in body weight when compared to DAL induced solid tumor control group, also increasing the life span, restoring the total white blood cell count and hemoglobin content and significantly decreasing the levels of serum aspartate transaminase (SGPT), alanine transaminase (SGOT), alkaline phosphatase (ALP), gamma glutamyl transferase (GGT) and nitric oxide (NO) when compared to DAL induced ascitic tumor controls. The treatment also reduced significantly the cellular glutathione (GSH) and nitric oxide levels in treated animals. Histopathological studies also confirmed protective influence. The outcome of the present work indicates that A.nilotica extract could be used as natural anticancer agent for human health.

Sorption Equilibria and Transport of Gaseous Chlorinated Organic Solvent in Wet Solid Waste Layer (도시고형폐기물(都市固形廢棄物) 및 토양층(土壤層)에 있어서 비(非)이온성(性) 유해유기화학물질(有害有機化學物質)의 거동(擧動)에 관한 연구(硏究) (습윤고형물폐기물층(濕潤固形物廢棄物層)에 있어서 기체상(氣體相) 유해유기염소화물질(有害有機鹽素化物質)을 주대상(主對象)으로))

  • Lee, Donghoon;Tanaka, Nobutoshi
    • Journal of Korean Society of Water and Wastewater
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    • v.7 no.2
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    • pp.9-23
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    • 1993
  • Emission of hazardous and volatile organic chemicals from solid waste landfill site was become to important issue because of environmental pollution and health risk by such chemicals. Laboratory batch and continuous experiments were conducted respectively to elucidate isothermal sorption behaviors and transport phenomena(by gas through unsaturated solid waste layer) in wet solid waste-gas system. Source separated and size reduced refuse(bulky waste) and incinerated ash were used after controlling water content, and trichloroethylene(TCE) was chosen among many such chemicals because of it's generality among those man-created pollutants. Isothermal TCE sorption equilibria wet solid waste-gas system can be described in linear equation and partition coefficient in this system can be estimated approximately by the simple equation derived from schematic structure of the system. Transport equation modified by instantaneous equilibrium sorption fraction and kinetic sorption rate(overall mass transfer capacity coefficient) simulated well the column experiment results.

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Hydrothermal carbonization of sewage sludge for solid recovered fuel and energy recovery (수열탄화를 이용한 하수 슬러지의 고형연료화 및 에너지 회수 효율)

  • Kim, Daegi;Lee, Kwanyong;Park, Kiyoung
    • Journal of Korean Society of Water and Wastewater
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    • v.29 no.1
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    • pp.57-63
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    • 2015
  • Recently, Korea's municipal wastewater treatment plants generated amount of wastewater sludge per day. However, ocean dumping of sewage sludge has been prohibited since 2012 by the London dumping convention and protocol and thus removal or treatment of wastewater sludge from field sites is an important issue on the ground site. The hydrothermal carbonization is one of attractive thermo-chemical method to upgrade sewage sludge to produce solid fuel with benefit method from the use of no chemical catalytic. Hydrothermal carbonization improved that the upgrading fuel properties and increased materials and energy recovery, which is conducted at temperatures ranging from 200 to $350^{\circ}C$ with a reaction time of 30 min. Hydrothermal carbonization increased the heating value though the increase of the carbon and fixed carbon content of solid fuel due to dehydration and decarboxylation reaction. Therefore, after the hydrothermal carbonization, the H/C and O/C ratios decreased because of the chemical conversion. Energy retention efficiency suggest that the optimum temperature of hydrothermal carbonization to produce more energy-rich solid fuel is approximately $200^{\circ}C$.

Prediction of Soluble Solid and Firmness in Apple by Visible/Near-Infrared Spectroscopy (가시광선/근적외선 분광분석법을 이용한 사과의 당도 및 경도 측정)

  • 최창현;이강진;박보순
    • Journal of Biosystems Engineering
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    • v.22 no.2
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    • pp.256-265
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    • 1997
  • The objectives of this study were to examine the ability to predict soluble solid and firmness in intact apples based on the visible/near-infrared spectroscopic technique. Two cultivars of apples, Delicious and Gala, were handled, tested and analyzed separately. Reflectance spectra, Magness-Tayor (MT) firmness, and soluble solids in apples were measured sequentially. Maximum and minimum diameters, height, and weight of apples were recorded before the MT firmness tests. A spectrophotometer was used to collect reflectance spectra of intact apples over a wavelength range of 400 to 2, 498 nm. The W firmness tests were conducted using a standard 11.1mm (7/16 in.) MT probe mounted in an Instron universal testing machine. A digital refractormeter was used to measure soluble solid contents in the apples. Apple samples were divided into a calibration set and a prediction set. The calibration set was used during model development, and the prediction set was used to predict soluble solids and firmness from unknown spectra. The method of partial least square (PLS) analysis was used. An unique set of PLS loading vectors (factors) was developed for soluble solid content and firmness. The PLS model showed good correlations between predicted and measured soluble solids of intact apples in 860~1078 nm of the wavelengths. However, the PLS analysis was not good enough to predict the apple firmness.

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Development of FK506-hyperproducing strain and optimization of culture conditions in solid-state fermentation for the hyper-production of FK506

  • Mo, SangJoon;Yang, Hyeong Seok
    • Journal of Applied Biological Chemistry
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    • v.59 no.4
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    • pp.289-298
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    • 2016
  • FK506 hyper-yielding mutant, called the TCM8594 strain, was made from Streptomyces tsukubaensis NRRL 18488 by mutagenesis using N-methyl-N'-nitro-N-nitrosoguanidine, ultraviolet irradiation, and FK506 sequential resistance selection. FK506 production by the TCM8594 strain improved 45.1-fold ($505.4{\mu}g/mL$) compared to that of S. tsukubaensis NRRL 18488 ($11.2{\mu}g/mL$). Among the five substrates, wheat bran was selected as the best solid substrate to produce optimum quantities of FK506 ($382.7{\mu}g/g$ substrate) under solid-state fermentation, and the process parameters affecting FK506 production were optimized. Maximum FK506 yield ($897.4{\mu}g/g$ substrate) was achieved by optimizing process parameters, such as wheat bran with 5 % (w/w) dextrin and yeast extract as additional nutrients, 70 % (v/w) initial solid substrate moisture content, initial medium pH of 7.2, $30^{\circ}C$ incubation temperature, inoculum level that was 10 % (v/w) of the cell mass equivalent, and a 10 day incubation. The results showed an overall 234 % increase in FK506 production after optimizing the process parameters.

Systematic Study of Paper Breaks in Papermaking Process Using Fracture Mechanics - (1) Evaluation of fracture Toughness in Wet State

  • Seo, Yung-B;Roh, You-Sun
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.33 no.5
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    • pp.37-44
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    • 2001
  • Fracture toughness was considered as one of the good estimates of the paper break tendency of paper web in the press room. Paper break on the paper machine is caused by many factors such as paper machine irregular vibrations, impurities in the fiber furnish, shives, and so on. On the paper machine, the solid content of paper web is changing very rapidly from less than 1% to over 95%. We tried to measure the fracture toughness of paper web at different solid contents for providing the fundamental knowledge of paper break. Stretches of wet web were also measured and compared to the fracture toughness changes. Four different fiber furnishes (SwBKP, HwBKP, ONP, and OCC) were refined to different degrees, and at different solid contents (40%, 60%, 80% and 95%), their fracture toughnesses were measured. Two fracture toughness measurement methods (essential work of fracture and Tryding's load-widening method) were used, and we found they gave identical results. The stretch curves of the wet webs against the axis of solid contents were very similar to the fracture toughness curves of those.

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Synthesis and Electrochemical Properties of Solid Polymer Electrolytes Using BF3LiMA as Monomer (BF3LiMA를 단량체로 하는 고체 고분자전해질 합성과 전기화학적 특성)

  • Kim, Kyung-Chan;Ryu, Sang-Woog
    • Journal of the Korean Electrochemical Society
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    • v.14 no.4
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    • pp.208-213
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    • 2011
  • Solid polymer electrolytes using $BF_3LiMA$ as monomer were synthesized by usual one step radical polymerization in THF solvent. The effect of $BF_3LiMA$ concentration on ionic conductivity and electrochemical stability was investigated by AC impedance measurement and linear sweep voltammetry. As a result, the highest ionic conductivity reached $7.71{\times}10^{-6}S\;cm^{-1}$ at $25^{\circ}C$ was obtained in 12.9 wt% of $BF_3LiMA$ content. Further increase or decrease of $BF_3LiMA$ content result to decrease the ionic conductivity due to the brittle matrix properties in former case and the insufficient number of charge carrier in the latter case. Furthermore, since the counter-anion was immobilized in the self-doped solid polymer electrolytes, high electrochemical stability up to 6.0 V was observed even in $60^{\circ}C$.

A Study on the Reduction of Gossypol Levels by Mixed Culture Solid Substrate Fermentation of Cottonseed Meal

  • Zhang, Wenju;Xu, Zirong;Sun, Jianyi;Yang, Xia
    • Asian-Australasian Journal of Animal Sciences
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    • v.19 no.9
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    • pp.1314-1321
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    • 2006
  • The objective of this work was to study the effect of mixed culture solid substrate fermentation of C. tropicalis ZD-3 with A. niger ZD-8 on detoxification of cottonseed meal (CSM), and to investigate the effect of fermentation period, proportion of CSM in substrate, sodium carbonate, minerals and heat treatment on the reduction of free gossypol levels during mixed culture solid substrate fermentation of CSM. Experiment 1: Three groups of disinfected CSM substrate were incubated for 48 h after inoculation with either of the fungi C. tropicalis ZD-3, A. niger ZD-8 or mixed culture (C. tropicalis ZD-3 with A. niger ZD-8). One non-inoculated group was used as the control. Levels of initial and final free gossypol (FG), CP and in vitro CP digestibility were assayed. The results indicated that mixed culture fermentation was far more effective than single strain fermentation, which not only had higher detoxification rate, but also had higher CP content and in vitro digestibility. Experiment 2: CSM substrates were treated according to experimental variables including fermentation period, proportion of CSM in substrate, sodium carbonate, minerals and heat treatment, Then, the treated CSM substrates were inoculated with mixed culture (C. tropicalis ZD-3 with A. niger ZD-8) and incubated at $30^{\circ}C$ for 36 h in a 95% relative humidity chamber. After fermentation ended, FG and CP content of fermented CSM substrate was assayed. The results showed that the appropriate fermentation period was 36 h, and the optimal proportion of CSM in substrate was 70%. Addition of sodium carbonate to CSM substrate was beneficial for fermentative detoxification. Heat treatment could facilitate fermentative detoxification, and supplementation with minerals was instrumental in reducing gossypol levels during mixed culture solid substrate fermentation of CSM.