• Title/Summary/Keyword: soil sediment

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Prediction of Pathway and Toxicity on Dechlorination of PCDDs by Linear Free Energy Relationship (다이옥신의 환원적 탈염화 분해 경로와 독성 변화예측을 위한 LFER 모델)

  • Kim, Ji-Hun;Chang, Yoon-Seok
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.2
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    • pp.125-131
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    • 2009
  • Reductive dechlorination of polychlorinated dibenzo-p-dioxins (PCDDs) and its toxicity change were predicted by the linear free energy relationship (LFER) model to assess the zero-valent iron (ZVI) and anaerobic dechlorinating bacteria (ADB) as electron donors in PCDDs dechlorination. Reductive dechlorination of PCDDs involves 256 reactions linking 76 congeners with highly variable toxicities, so is challenging to assess the overall effect of this process on the environmental impact of PCDD contamination. The Gibbs free energies of PCDDs in aqueous solution were updated to density functional theory (DFT) calculation level from thermodynamic results of literatures. All of dechlorination kinetics of PCDDs was evaluated from the linear correlation between the experimental dechlorination kinetics of PCDDs and the calculated thermodynamics of PCDDs. As a result, it was predicted that over 100 years would be taken for the complete dechlorination of octachlorinated dibenzo-p-dioxin (OCDD) to non-chlorinated compound (dibenzo-p-dioxin, DD), and the toxic equivalent quantity (TEQ) of PCDDs could increase to 10 times larger from initial TEQ with the dechlorination process. The results imply that the single reductive dechlorination using ZVI or ADB is not suitable for the treatment strategy of PCDDs contaminated soil, sediment and fly ash. This LFER approach is applicable for the prediction of dechlorination process for organohalogen compounds and for the assessment of electron donating system for treatment strategies.

Heavy Metal Concentrations in the Mollusc Gastropod, Cipangopaludina chinensis malleata from Upo Wetland Reflect the Level of Heavy Metals in the Sediments

  • Kim, Heung-Tae;Kim, Jae-Geun
    • Journal of Ecology and Environment
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    • v.29 no.5
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    • pp.453-460
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    • 2006
  • Upo wetland is the largest inland wetland in Korea as Ramsar Convention Area. The purposes of the study were to investigate the levels of heavy metals (Cd, Cr, Cu, Ni, Pb and Zn) in the sediment and Cipangopaludina chinensis malleata from three sites of the wetland and to assess the potential of the gastropod as a bioindicator for heavy metal levels. The gastropods were dissected into shell and soft tissue without the digestive and excretive organs. The levels of Cd, Cu and Pb were below the guideline of Soil Environment Conservation Act and the heavy metals except Cr were slightly different among the sites. Cd was higher in Upo site ($0.32{\mu}g/g$) than Sajipo site ($0.28{\mu}g/g$). Cu and Zn showed the highest value in Sajipo as $43.5{\mu}g/g\;and\;39.8{\mu}g/g$, respectively while the concentrations of Pb and Zn were the highest in Upstream as $58.8{\mu}g/g\;and\;138{\mu}g/g$, respectively. In the soft tissues and shells of the gastropod, the overall common trend in the concentrations of the heavy metals was revealed with the following order: Zn > Cu > Cr > Ni > Pb > Cd and Ni > Zn > Cr > Cu > Pb > Cd, respectively. Although the soft tissues exhibited higher concentrations of the heavy metals except Ni than the shell in the gastropod, the levels of Cd and Pb in the gastropod were generally below the restrictive values set up by Korea Food & Drug Administration. From Duncan's Multiple Range Test (DMRT) results, the concentrations of Pb and Zn in the sediments among the sites were reflected on the soft tissue (Pb) and the shell (Pb and Zn) of the gastropod in the same order. The lower value of coefficient of variation (CV) in Pb concentration of the shell than in that of the soft tissue supports the usefulness of the shell as a bioindicator for Pb pollution. Although the CV value in the shell was a little higher than in the soft tissue, DMRT results and the stability of incorporated Zn into the shell support the use of the shell of the gastropod as a potential bioindicator for long-term contamination of Zn.

Analysis of debris flow simulation parameters with entrainment effect: a case study in the Mt. Umyeon (연행작용을 고려한 우면산 토석류 모의 매개변수 특성분석)

  • Lee, Seungjun;An, Hyunuk;Kim, Minseok;Lim, Hyuntaek
    • Journal of Korea Water Resources Association
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    • v.53 no.9
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    • pp.637-646
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    • 2020
  • The shallow landslide-trigerred debris flow in hillslope catchments is the primary geological phenomenon that drives landscape changes and therefore imposes risks as a natural hazard. In particular, debris flows occurring in urban areas can result to substantial damages to properties and human injuries during the flow and sediment transport process. To alleviate the damages as a result of these debris flow, analytical models for flow and damage prediction are of significant importance. However, the analysis of debris flow model parameters is not yet sufficient, and the analysis of the entrainment, which has a significant influence on the flow process and the damage extent, is still incomplete. In this study, the effects of erosion and erosion process on the flow and the impact area due to the change in the soil parameters are analyzed using Deb2D model, a flow analysis model of debris developed in Korea. The research is conducted for the case of the Mt. Umyeon landslide in 2011. The resulting impacted area, total debris-flow volume, maximum velocity and inundated depth from the Erosion model are compared to the field survey data. Also, the effect of the entrainment changing parameters is analyzed through the erosion shape and depth. The debris flow simulation for the Raemian and Shindong apartment catchment with the consideration of entrainment effect and erosion has been successful. Each parameter sensitivity could be analyzed through sensitivity analysis for the two basins based on the change in parameters, which indicates the necessity of parameter estimation.

Characteristics of Shear Strength and Consolidation Behavior of Soft Ground according to Stage Fill (단계성토에 따른 연약지반의 전단강도 및 압밀거동 특성)

  • Bang, Seongtaek
    • Journal of the Korean GEO-environmental Society
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    • v.21 no.7
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    • pp.17-26
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    • 2020
  • The soft ground in the southwest coastal area composed of marine clay is greatly influenced by sediment composition, particle size distribution, particle shape, adsorption ions and pore water characteristics, tide and temperature. In addition, the geotechnical properties are very complex due to stress history, change in pore water, dissolution process and gas formation. In this study, the physical and mechanical properties of the soft ground were evaluated through field tests and laboratory tests to investigate the strength increase characteristics according to consolidation on the soft ground in the southwest coast. In addition, in order to understand the consolidation behavior of soft ground such as subsidence, pore water pressure, horizontal displacement of soil by embankment load, measuring instruments such as pore water pressuremeter, settlement gauge, inclinometer and differential settlement gauge was installed, and a piezocon penetration test was carried out step by step to confirm the increase in shear strength of the ground. Through this, it was confirmed that the shear strength of the ground is increased according to the stages of filling. In addition, by evaluating the properties of consolidation behavior, strength increase and consolidation prediction by empirical methods and theories were compared to analyze the characteristics of strength increase rate and consolidation behavior in consideration of regional characteristics.

Analysis of the Sea Condition on the Patrol Ship Cheonan Sinking Waters (천안호 침몰해역의 해상조건 분석)

  • Kim, Kang-Min;Lee, Joong-Woo;Kim, Kyu-Kwang;Kwon, So-Hyung;Lee, Hyung-Ha
    • Journal of Navigation and Port Research
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    • v.34 no.5
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    • pp.349-354
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    • 2010
  • Cheonan, Republic of Korea Navy patrol ship sank had happened by an unknown incident in the vicinity of Baekryeongdo southwest 1.6km(1 mile) sea at 21:45 on March 26, 2010. In terms of coastal researcher's point of view, it is meaningful to provide the sea condition of basic data necessary for search and rescue, more detailed predictions and inference data through the numerical simulations. Thus, in this study, we investigated the weather, wave, tide, tidal current, bottom soil conditions, and suspended sediment are investigated at the coast of Baekryeong-Daechung islands. And based on these data, the characteristics of sea conditions were analyzed. The tidal period at the time of incident corresponds between neap tide to mean tide. Until April 3-4 after March 26, the date of incident, the strongest velocity was progressed towards the spring tide. Thus, it was considered to be difficult to search and rescue operations. Also, because the ebb tide was in progress during 21:00 to 22:00, mass transport seems to be prevailed to the southeast. In particular, as the sudden turbulence due to the irregular topography existed was anticipated, we had carried out particle tracking experiment. From this experiment, depending on the situation of flow, the initial movement of the particles were directed to the southeast but it turned out moving towards the offshore based on the long term prediction. Through this result, it is considered that the scope of the search operation should be expanded towards the open sea.

Characteristics of Heavy Rainfall for Landslide-triggering in 2011 (2011년 집중호우로 인한 산사태 발생특성 분석)

  • Kim, Suk-Woo;Chun, Kun-Woo;Kim, Jin-Hak;Kim, Min-Sik;Kim, Min-Seok
    • Journal of Korean Society of Forest Science
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    • v.101 no.1
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    • pp.28-35
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    • 2012
  • Rainfall is widely recognized as a major landslide-triggering factor. Most of the latest landslides that occurred in South Korea were caused by short-duration heavy rainfall. However, the relationship between rainfall characteristics and landslide occurrence is poorly understood. To examine the effect of rainfall on landslide occurrence, cumulative rainfall(mm) and rainfall intensity(mm/hr) of serial rain and antecedent rainfall(mm) were analyzed for 18 landslide events that occurred in the southern and central regions of South Korea in June and July 2011. It was found that all of these landslides occurred by heavy rainfall for one or three days, with the rainfall intensity exceeding 30 mm/hr or with a cumulative rainfall of 200 mm. These plotted data are beyond the landslide warning criteria of Korea Forest Service and the critical line of landslide occurrence for Gyeongnam Province. It was also found that the time to landslide occurrence after rainfall start(T) was shortened with the increasing average rainfall intensity(ARI), showing an exponential-decay curve, and this relation can be expressed as "T = $94.569{\cdot}exp$($-0.068{\cdot}ARI$)($R^2$=0.64, p<0.001)". The findings in this study may provide important evidences for the landslide forecasting guidance service of Korea Forest Service as well as essential data for the establishment of non-structural measures such as a warning and evacuation system in the face of sediment disasters.

Calibration and Validation of SWAT Model for Long Term Simulation of Runoff and Sediment Transport at the Nakdong River Basin (낙동강유역의 장기 유역 유출 및 유사 모의를 위한 SWAT 모형의 검보정)

  • Lee, Eun-Jung;Jang, Eun-Kyung;Kim, Tae-Keun;Hwang, Man-Ha;Kwon, Yong-Sung
    • Proceedings of the Korea Water Resources Association Conference
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    • 2012.05a
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    • pp.881-881
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    • 2012
  • 낙동강유역에는 4대강 사업으로 8개의 보가 낙동강 본류에 새롭게 설치되었으며, 따라서 상류로부터 유입되는 유사가 보상류에 퇴적되어 하천제방이나 하천구조물의 안전을 위협할 수 있다. 또한 홍수시에는 농경지의 매몰과 저수지의 퇴적현상이 발생하는 등 유역유사에 의한 다양한 문제가 발생할 수 있으며, 강우로부터 유출되는 유사는 강우사상에 따라 빠르게 변할 수 있으나 수체에 즉각적인 영향을 유발하지 않을 경우 만성적인 특성으로 인해 침전물을 계속 이동시키며 축적되는 문제가 발생한다. 따라서 이러한 문제를 사전에 예측하고 낙동강유역에 대한 유역유사관리 대책마련을 마련하기 위해 유역유출과 유사의 이송 및 퇴적양상을 분석하여 유역관리를 위한 자료를 구축할 필요가 있다. 이러한 기초자료 분석을 위해 활용되는 유역모형 중 SWAT(Soil and Water Assessment Tool) 모형은 장기간 유역 유출로 인한 유사 모의를 수행하는데 가장 많이 활용되는 모형이며, 미국 농무성 농업연구소(USDA Agricultural Research Service, ARS)의 Jeff Amold 등에 의해 개발된 모형이다. SWAT 모형은 장기유출 및 유사 발생에 대한 시 공간적 변화를 모의하는 모형으로 넓은 범위의 유역에 대해 일단위 모의 간격으로 최대 100년까지 모의가 가능한 장기유역 모의에 최적화된 모형이다. 본 논문에서는 SWAT 모형을 이용하여 낙동강유역의 장기 유역 유출 및 유사 모의를 수행하기위해 2004년에서 2009년까지의 유출량 자료와 유량-유사량관계곡선 등을 이용하여 본류 및 지류 유출구 주요지점에 대해 검보정을 수행하고자 한다. 모의의 정확도 향상을 위해 안동댐, 임하댐, 영천댐, 합천댐, 남강댐, 밀양댐 및 낙동강 본류 등 총 7개 유역으로 구분하여 SWAT 모형을 구축하였으며, 각 유역별로 유출량과 유사량에 대하여 각각 보정 및 검증을 수행하였다. 낙동강 본류유역 총 7개의 댐 방류량자료와 20개의 대형하수종말처리장 방류량자료를 이용한 낙동강유역의 유출량 보정 및 검증 결과, 모의치가 실측치를 잘 반영하고 있는 것으로 나타났다. 또한 총 11개 지점의 수위관측소에 대해 유사량 측정 성과를 이용한 유사량 보정 및 검증 결과, 강우시 유사량 모의값은 유출량-유사량관계곡선 식을 잘 반영하였으나, 비강우시에는 모의값이 관계곡선 식의 결과값보다 대체적으로 높게 나타났다.

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Effects of Floating and Submerged Plants on Important Water Environments of Wetland (부유식물과 침수식물이 습지의 주요 수 환경에 미치는 영향)

  • Lee, Geun-Joo;Sung, Kijune
    • Journal of Wetlands Research
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    • v.15 no.3
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    • pp.289-300
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    • 2013
  • In this study, two types of wetland plants, Eichhornia crassipes (a floating plant) and Ceratophyllum demersum (a submerged plant) were introduced to wetland mesocosms to understand how the water properties of wetlands such as pH, dissolved oxygen content, water temperature, oxidation reduction potential, and nutrient concentrations are affected by different types of wetland plant. The floating plant lives on the water surface and can block light penetration; it exhibited the lowest water temperature and temperature difference between lower and upper layers. After the addition of contaminants, the dissolved oxygen (DO) concentration decreased abruptly but recovered continuously in all mesocosms; especially the submerged plants, which photosynthesize in water, showed the largest increases in DO and diel periodicity DO, as well as in pH value. The oxidation-reduction potential in both water and sediment were affected by the presence of wetland plants and plant type and the results suggest that various aspects of wetland biogeochemistry are affected by the presence and type of wetland plants. The total nitrogen and phosphorous concentrations in water decreased in the following order: Water only < Water + Soil < Floating Plants < Submerged Plants. Although both floating and submerged plants can control algal concentrations, the effect was more prominent for floating plants.

Constant Rate of Strain Consolidation Test with Rowe Cell on the Clay with Sand Seam (샌드심이 존재하는 점토에 Rowe Cell를 이용한 일정변형률 압밀시험)

  • Kim, Jae-Hong;Kim, Chan-Kee;Kim, Tae-Hyung
    • Journal of the Korean Geotechnical Society
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    • v.33 no.5
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    • pp.5-13
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    • 2017
  • The sand layer deposited in clay is called a sand seam, which is formed by inflow of sands due to river flooding or slope failure in the middle of sinking and sediment of clay. When the sand seam exists in clay layer, the drainage direction changes from one way to both ways, and the time of consolidation may be reduced. However, it is not clearly proved due to lack of studies of sand seam and currently is not reflected in the design of soft soil improvement. As a fundamental study about sand seam, the oedometer tests and constant rate of strain tests with Rowe cell were conducted on clay specimens with sand seam. For tests, a frozen method was specially designed for making the sand seam. It was concluded that the test results showed the sand seam affects the coefficient of consolidation of clay. If the thickness of sand seam exceeds 0.05 times of specimen height, the sand seam works as drainage layer of pore water horizontally as well as vertically, and consequently the consolidation is accelerated.

A Study on Detection and Monitoring in land creeping area by Using the UAV (무인기를 활용한 산지 땅밀림 피해지점 탐지 및 모니터링 방안 연구)

  • Seo, Jun-Pyo;Woo, Choong-Shik;Lee, Chang-Woo;Kim, Dong-Yeob
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.11
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    • pp.481-487
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    • 2018
  • This paper proposes a method to detect and monitor the land creeping area using a UAV to analyze the damaged area efficiently. Using a UAV, it was possible to secure the safety of the investigators before the field survey and effectively utilize it to establish an investigation plan because an orthophoto can be used to detect and scale the cracks in a land creeping area. In addition, it was possible to analyze the scale of the crack quantitatively by extracting the topographic information from the orthophoto. The study sites were found to have a total crack area of 1.01 ha, a length of 1.07 km, an average width of 10 m, and a step distance of 1 to 10 m. Periodic UAV measurements can be used to detect displacements on the land creeping area and monitor the direction and scale of crack spread. Therefore, it is expected to be used effectively during recovery planning. Applying the UAV to the land creeping area resulted in the qualitative and quantitative results quickly and easily in dangerous mountainous watersheds. Therefore, it is expected that it will contribute to the development of related industries because of the high availability of a UAV in forest soil sediment disasters, such as landslides, debris flow, and land creeping area.