• Title/Summary/Keyword: soil chemistry

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Competitive Adsorption and Subsequent Desorption of Sulfate in the Presence of Various Anions in Soils

  • Hong, Byeong-Deok;Lee, Kyo-seok;Lee, Dong-Sung;Rhie, Ja-Hyun;Bae, Hui-Su;Seo, IL-Hwan;Song, Seung-Geun;Chung, Doug-Young
    • Korean Journal of Soil Science and Fertilizer
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    • v.49 no.5
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    • pp.541-547
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    • 2016
  • In this experiment we investigated the influence of various anions including oxalic acid encountered as solution phase in soil on the adsorption and desorption of sulfate in Chungwon Bt soil. The effect of chloride and nitrate on the adsorption of sulfate was not significant, suggesting that sulfate was better able to compete for adsorption sites at concentrations studied, in contrast to the large reduction in the amount of chloride adsorbed in the presence of sulfate. The results of competition for sorption sites between sulfate and anion showed that the simultaneous presence of two anions in solution was effective in reduction of competing anion at a maximum value of adsorption, due to the similar adsorption mechanism for anion competition. Therefore, the variation in the buffer power of the acids will produce a change in the strength and amount of adsorption and the competitive ability.

Effect of Chemical Amendments on Soil Biological Quality in Heavy Metal Contaminated Agricultural Field

  • Kim, Yoo Chul;Hong, Young Kyu;Oh, Se Jin;Oh, Seung Min;Ji, Won Hyun;Yang, Jae E.;Kim, Sung Chul
    • Korean Journal of Soil Science and Fertilizer
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    • v.48 no.2
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    • pp.146-152
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    • 2015
  • Heavy metal pollution has been a critical problem in agricultural field near at the abandoned metal mines and chemical amendments are applied for remediation purpose. However, biological activity can be changed depending on chemical amendments affecting crop productivity. Main purpose of this research was to evaluate biological parameters after applying chemical amendments in heavy metal polluted agricultural field. Result showed that soil respiration (SR) and microbial biomass carbon (MBC) were changed after chemical amendments were applied. Among three different amendments, lime stone (LS), steel slag (SS), and acid mine drainage sludge(AMDS), AMDS had an effect to increase SR in paddy soil. Comparing to control ($93.98-170.33mg\;kg^{-1}day^{-1}$), average of 30% increased SR was observed. In terms of MBC, SS had an increased effect in paddy soil. However, no significant difference of SR and MBC was observed in upland soil after chemical amendment application. Overall, SR can be used as an indicator of heavy metal remediation in paddy soil.

Effect of Saline Soil and Crop Growth with Bottom Ash from Biomass Power Plant Based Wood Pellet (우드펠릿 기반 바이오매스 발전소로부터 배출된 저회를 활용한 염류토양 및 작물성장에 미치는 영향)

  • So-Hui Kim;Seung-Gyu Lee;Jin-Ju Yun;Jae-Hyuk Park;Se-Won Kang;Ju-Sik Cho
    • Korean Journal of Environmental Agriculture
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    • v.41 no.4
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    • pp.310-317
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    • 2022
  • BACKGROUND: The salt in soil interrupts crop growth. Therefore, water resources are used to remove any salt found in the soil. However, water resources have been reduced by global warming; thus, a new study is required into reducing the salt in soil. Recently, the bottom ash (BA) of a biomass power plant was found to be similar to biochar. Hence, it can be used to remove heavy metals and wastewater through the adsorption characteristics of BA. The objective of this study was to evaluate the improvement effects on crop growth in saline soil containing the BA from biomass power plants. METHODS AND RESULTS: The effect on crop growth in the saline soil supplemented with BA was studied with the crop-planted pots, which were packed by reclaimed greenhouse soils collected from Byolyang, Suncheon. The BA application level was 25, 50, 100, 200, and 400 kg/10a (referred as BA25, BA50, BA100, BA200, and BA400, respectively). The BA increased the fresh weights of the leaf and root, while nitrogen uptake increased by approximately 24-102% and 54-77%, respectively for the lead and root. The phosphorous uptake increased by 38%, although only in the leaf of the lettuce. In the case of soil, BA increased water content, pH, EC, CEC, and NH4+ and the SAR of the soil decreased by 5-15%. The bottom ash increased the contents of Ca2+ and Mg2+, and fixed the amount of Na+. CONCLUSION(S): It was confirmed the bottom ash of a biomass power plant, based on wood pellets, improved crop growth, and increased the nutrient uptake of crops in saline soil. In addition, bottom ash, which has a wide range of porosity and high values of pH and EC, improved properties of the saline soil. However, the BA has a large amount of B, As, and heavy metals. Finally, it may require a study on the safety and contamination of heavy metals contained in the bottom ash, which would be applied in soil for a long time.

Adsorption-Desorption, Leaching, and Degradation Pattern of Fungicide Fluazinam in the Soil Environment (살균제 Fluazinam의 토양환경 중 흡.탈착, 용탈 및 분해양상)

  • Hu, Won;Lee, Seog-June;Kim, Jang-Eok
    • Applied Biological Chemistry
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    • v.40 no.2
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    • pp.128-133
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    • 1997
  • This study was conducted to evaluate the adsorption, desorption, leaching and degradation pattern of fungicide fluazinam in the soil environment under the laboratory conditions. The mode of isothermal adsorption of fluazinam in soil was coincident with the Freundlich equation. The adsorption amount of fluazinam was much higher on soils containing organic matter than on soils oxidized with hydrogen peroxide. The presence of organic matter, humic acid or fulvic acid, increased the adsorption amount of fluazinam on soils. The Freundlich constant K was much higher in soil added with humic acid than in soil added with fulvic acid. The desorption ratio of fluazinam adsorbed to soil was increased by removal of organic matter. In leaching experiment using soil column, the fluazinam applied on the soil surface was not moved down to the bottom of soil and was not detected in leachate water. The degradation of fluazinam was faster in Soil I with rich organic matter than Soil II with poor organic matter, in non-sterilized soil than sterilized soil, and in flooded soil than unflooded soil.

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Evaluating Soil Respiration as Indicator of Heavy Metal Pollution in Agricultural Field

  • Choi, Won-Suk;Hong, Young-Kyu;Min, Kyung-Jun;Kim, Kwang-Jin;Kim, Sung-Chul
    • Korean Journal of Soil Science and Fertilizer
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    • v.50 no.5
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    • pp.472-481
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    • 2017
  • Agricultural field near at the abandoned metal mine and industrial area has a high possibility to be polluted by heavy metals. However, concern about chemical properties including heavy metal concentration has been increased and biological properties such as soil respiration has been minimal in heavy metal polluted field. Therefore, main objective of this research was to evaluate soil respiration as an indicator of heavy metal pollution in agricultural field. Total of 60 sampling sites including each 30 sites of abandoned metal mine and industrial area were selected and heavy metal concentration, soil respiration, and chemical properties were measured. Results showed that heavy metal concentration in metal mine area was ranged Cu: $6.21~85.23mg\;kg^{-1}$, Pb: $23.84{\sim}1,044.72mg\;kg^{-1}$, As: $1.88{\sim}691.44mg\;kg^{-1}$, Zn: $18.72{\sim}527.55mg\;kg^{-1}$, Cd: $0.58{\sim}4.27mg\;kg^{-1}$, and Cu: $0.29{\sim}30.62mg\;kg^{-1}$, Pb: $4.41{\sim}19.77mg\;kg^{-1}$, As: $2.23{\sim}11.76mg\;kg^{-1}$, Zn $39.98{\sim}109.59mg\;kg^{-1}$, Cd $0.29{\sim}0.57mg\;kg^{-1}$ for industrial area respectively. While no sampling site was exceed the threshold value of each heavy metals in industrial field, metal mine area was highly polluted with Pb, As, Zn, and Cd. Soil respiration in the metal mine and industrial area was ranged $12.05{\sim}299.80mg\;O_2\;kg^{-1}$ and $27.68{\sim}330.94mg\;O_2\;kg^{-1}$, respectively. Correlation analysis between heavy metal concentration in soil and soil respiration showed that negative correlation was observed in metal mine area while no correlation was observed in industrial area. This result might indicate that as heavy metal concentration was increased, microbial activity in soil was decreased resulting decrease of soil respiration rate. Overall, soil respiration can be used as indicator of heavy metal pollution in soil and more biological properties need to be evaluated to better understand heavy metal pollution in soil.

Infection Mechanism of Pathogenic Exduate by Soil-Borne Fungal Pathogens : A Review

  • Lim, You-Jin;Kim, Hye-Jin;Song, Jin-A;Chung, Doug-Young
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.4
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    • pp.622-627
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    • 2012
  • The processes to determine the composition, dynamics, and activity of infection mechanisms by the rhizosphere microflora have attracted the interest of scientists from multiple disciplines although considerable progress of the infection pathways and plant-pathogen interactions by soil borne fungal pathogens have been made. Soilborne pathogens are confined within a three-dimensional matrix of mineral soil particles, pores, organic matter in various stages of decomposition and a biological component. Among the physical and chemical properties of soils soil texture and matric water potential may be the two most important factors that determine spread exudates by soil borne fungal pathogens, based on the size of the soil pores. Pathogenic invasion of plant roots involves complex molecular mechanisms which occur in the diffuse interface between the root and the soil created by root exudates. The initial infection by soilborne pathogens can be caused by enzymes which breakdown cell wall layers to penetrate the plant cell wall for the fungus. However, the fate and mobility of the exudates are less well understood. Therefore, it needs to develop methods to control disease caused by enzymes produced by the soilborne pathogens by verifying many other possible pathways and mechanisms of infection processes occurring in soils.

Synergistic Effects of Arbuscular Mycorrhizal Fungi and Plant Growth Promoting Rhizobacteria for Sustainable Agricultural Production

  • Ramasamy, Krishnamoorthy;Joe, Manoharan Melvin;Kim, Ki-Yoon;Lee, Seon-Mi;Shagol, Charlotte;Rangasamy, Anandham;Chung, Jong-Bae;Islam, Md. Rashedul;Sa, Tong-Min
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.4
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    • pp.637-649
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    • 2011
  • Soil microorganisms play a major role in improving soil fertility and plant health. Symbiotic arbuscular mycorrhizal fungi (AMF) form a key component of the soil microbial populations. AMF form a mutualistic association with the host plant and exert a positive influence on its growth and nutrient uptake. The establishment of mycorrhizal symbioses with the host plant can positively be influenced by plant growth promoting rhizobacteria through various mechanisms such as increased spore germination and hyphal permeability in plant roots. Though there are evidences that combined interactions between AMF and PGPR can promote the plant growth however mechanisms of these interactions are poorly understood. Better understanding of the interactions between AMF and other microorganisms is necessary for maintaining soil fertility and enhancing crop production. This paper reviews current knowledge concerning the interactions between AMF and PGPR with plants and discusses on enhanced nutrient availability, biocontrol, abiotic stress tolerance and phytoremediation in sustainable agriculture.

Mathematical Models of Competitive Adsorption of Inorganic Anions in Soils

  • Lee, Kyo Suk;Lee, Dong Sung;Lee, Jae Bong;Joo, Rhee Na;Lee, Myong Yun;Chung, Doug Young
    • Korean Journal of Soil Science and Fertilizer
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    • v.48 no.6
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    • pp.666-670
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    • 2015
  • Competition among anion species in solution for same sorption sites and soil surface can be of major significance in determining the effective mobility of any potentially adsorbing species. Major soil anion species include $OH^-$, $F^-$, $Cl^-$, $HCO_3{^-}$, $CO_3{^-}$, $NO_3{^-}$, $SO_4{^{2-}}$, and $PO_4{^{3-}}$. And some micro nutrients such as boron and molybdenum exist as $H_2BO_3{^-}$ and $MoO_4{^{2-}}$, as do some heavy metals such as chrome and arsenic as $CrO_4{^{2-}}$ and $HAsO_4{^{2-}}$. Pesticides such as 2,4,5-T and 2,4-D also exist as anions. Many anion species are retained by more complex mechanisms than the simple electrostatic attractions involved in most cation adsorption reactions. In binary system composed of two anions, the adsorption of one anion is influenced by the other anion due to the competition for the available and limited binding sites in soil constituents. The specifically adsorbed anions may compete more effectively for sorption sites than that of nonspecifically adsorbed anion. In this study, we aim to evaluate the mathematical models to determine the magnitude of concentration variations in adsorption due to competitive interactions between anions introduced to a system in binary mixtures.

Water Chemistry Profiles under Korean White Pine (Pinus koraiensis S. et Z.) Stand (잣나무 임분에 있어서 강우수질의 이동 특성)

  • Jin Hyun-O;Chung Doug-Young;Lee Choong-Hwa
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.1 no.2
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    • pp.110-118
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    • 1999
  • This experiment was conducted to characterize the vertical transport trend of dissolved elements through throughfall, stemflow, effluent from Ao layer, and leachate out of soil profile on Pinus koraiensis stand in Experimental Forest of Kyunghee University, located in Kwangju, Kyunggi province for 12 months from July, 1998 to Jun, 1999. In addition, we investigated the content of dissolved elements and the factors influencing the water chemistry concentrations separately collected from the field. Water movement in the process of throughfall and stemflow from precipitation, and rainfall leached from Ao layer into soil water was governed by concentration of through fall, precipitation, rainfall intensity, seasonal variation, and other factors. Also, smaller changes of pH in soil water than that of dissolved elements in soil water could contribute buffer capacity, as well as balancing the concentration between cations and anions.

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Near Infrared Spectroscopy for Measuring Soil Properties

  • Ryu, Kwan-Shig;Kim, Bok-Jin;Park, Woo-Churl;Cho, Rae-Kwang
    • Near Infrared Analysis
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    • v.1 no.1
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    • pp.37-41
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    • 2000
  • The purpose of this research was to develop a the reflection technique with near infrared (NIR) radiation for estimating soil components. NIR reflectance was scanned at 2nm intervals from 1100 to 2500nm with an InfraAlyzer 500 (Bran & Luebbe Co.). Over 400 soil sample from fields of different crops and land-use over Youngnam and Honam regions were used to obtain mean diffuse reflection of the soil for the calibration and validation of the calibration set in estimating moisture, organic matter (OM) and total nitrogen (T-N) of the soils. Multiple linear regression (MLR) was used to evaluate the correlation of NIR spectroscopy method. Reflection pattern of NIR spectra for finely sized sample (<0.5mm) and coarsely sized soil(<2mm) did not show much difference. The results showed that NIR spectroscopy and coarsely sized soil (<2mm) did not show much difference. The results showed that NIR spectroscopy could be used as a routine soil testing method in estimating OM, moisture, T-N in soil samples simultaneously.