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Competitive Adsorption and Subsequent Desorption of Sulfate in the Presence of Various Anions in Soils

  • Hong, Byeong-Deok (National Institute of Crop Science, RDA) ;
  • Lee, Kyo-seok (Department of Bio-Environmental Chemistry, Chungnam National University) ;
  • Lee, Dong-Sung (Department of Bio-Environmental Chemistry, Chungnam National University) ;
  • Rhie, Ja-Hyun (Department of Bio-Environmental Chemistry, Chungnam National University) ;
  • Bae, Hui-Su (Technical Review and Quality Management Institute, Korea Rural Community) ;
  • Seo, IL-Hwan (Department of Bio-Environmental Chemistry, Chungnam National University) ;
  • Song, Seung-Geun (Department of Bio-Environmental Chemistry, Chungnam National University) ;
  • Chung, Doug-Young (Department of Bio-Environmental Chemistry, Chungnam National University)
  • Received : 2016.10.06
  • Accepted : 2016.10.25
  • Published : 2016.10.31

Abstract

In this experiment we investigated the influence of various anions including oxalic acid encountered as solution phase in soil on the adsorption and desorption of sulfate in Chungwon Bt soil. The effect of chloride and nitrate on the adsorption of sulfate was not significant, suggesting that sulfate was better able to compete for adsorption sites at concentrations studied, in contrast to the large reduction in the amount of chloride adsorbed in the presence of sulfate. The results of competition for sorption sites between sulfate and anion showed that the simultaneous presence of two anions in solution was effective in reduction of competing anion at a maximum value of adsorption, due to the similar adsorption mechanism for anion competition. Therefore, the variation in the buffer power of the acids will produce a change in the strength and amount of adsorption and the competitive ability.

Keywords

References

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