• 제목/요약/키워드: soil chemicals

검색결과 369건 처리시간 0.032초

Reduction of Fluorine, Boron and Heavy Metals Leaching from Coal Ash by Adding Fixation Chemicals

  • Iwasaki, Makoto;Inoue, Kaori;Ikeshima, Kazuya;Ishizuka, Tadashi
    • 한국펄프종이공학회:학술대회논문집
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    • 한국펄프종이공학회 2006년도 PAN PACIFIC CONFERENCE vol.1
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    • pp.105-110
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    • 2006
  • In order to utilize coal fly ash (hereafter : coal ash ) discharged from coal boiler as a material for civil engineering usage such as snow melter or soil improver, we have to prevent leaching hazardous elements such as fluorine boron and heavy metals from the coal ash because the leaching concentrations of some elements in the ash exceed the Japanese standards for environmental soil quality. Through the laboratory experiments and mill trials we confirmed that the leaching concentrations of fluorine, boron and heavy metals were maintained below their environmental standards by mixing with fixation chemicals and curing for a short time.

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폐금속광산 주변 오염 농경지에서 비소의 안정화 효율 평가 (Evaluation of Stabilization of Arsenic in Contaminated Soil Taken from Farmland Near Abandoned Metal Mine)

  • 한수호;정명채;김정욱;윤경욱;민선기;박소연;심기태
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제26권1호
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    • pp.8-16
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    • 2021
  • This study has evaluated the stabilization of As contaminated paddy and cultivated soils by pot experiments for rice and lettuce. Various ratios of limestone (L) and steel slag (S) were mixed with the soils in each pot. The soils were taken from before and after pot experiments, and analyzed for As extracted by sequentially (Wenzel method) and totally (aqua regia method).. Paddy soils amended with L (0.5%) and L (1.0%) + S (1.0%) showed increasing fraction 2 (specifically bound As) compared with control soil. Arsenic concentrations in rice grain grown on the amended soils decreased 14% and 12% compared with those on the control soil, respectively. According to sequential extraction of As in cultivated soils, the fractions 1~3 were decreased due to stabilization of As by the soil amendment, especially for S (1.0%), S (3.0%) and L (1.0%) + S (1.0%). In addition, relatively low As concentrations were found in lettuce grown on amended soils with L (0.5%) and L (1.0%) + S (1.0%). Therefore, it can be suggested that soil amendments with L (0.5%) or L (1.0%) + S (1.0%) were suitable for enhancing stabilization of As in the study area.

마이크로파 가열에 의한 토양 유기오염물질 탈착특성 (Desorption Characteristics of Volatile Organics Compounds in Soil by Microwave Heating)

  • 문경환;김덕찬
    • 환경위생공학
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    • 제11권2호
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    • pp.65-73
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    • 1996
  • The objective of this study is to investigate the removal efficiency of volitile organic compounds in soil, and the mechanism of desorption by bench scale microwave heating, Silt soil used for experiment and was impregnated with toluene, tetrachloroethylene, o-xylene and p-dichlorobenzene and the microwave treatment was conducted in a modified domestic microwave oven : 2450MHz, 700W. According to the results of the research the removal efficiency was improved with increasing water contents and the soil temperature appeared to plateau period extending to 2-3minutes corresponds to the temperature a which steam distillation was expected. The value of removal rate constant (k) were calculated on dry and moisty silt soil, respectively, which showed linear with increasing microwave heating time. Therefore, addition of a certain amount of water to the contaminated soil can efficiently enhance the ability of the soil to absorb microwave energy and promote the evaporation of the volitile contaminants.

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환경 추적자의 흡착 특성을 이용한 수리지화학적 활용 가능성 고찰 (Potential Application of Environmental Tracer in Hydrogeochemistry Using Sorption Properties)

  • 정성욱;장세은;김민경;김성표;엄우용
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제17권6호
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    • pp.59-68
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    • 2012
  • This study provided sorption properties of chlorofluorocarbons (CFCs), and elucidated potential application of CFC sorption data in hydrogeochemistry. Prior sorption studies were reviewed for hydrophobic organic compounds similar to the CFCs, because there were only few CFC sorption studies. The CFCs are regarded as relatively conservative chemicals in groundwater environments based on their moderate hydrophobicity. However, thermally altered carbonaceous matter (TACM) can significantly increase sorption capacity and nonlinearity for hydrophobic organic compounds such as CFCs, compared to general soil organic matter. CFC sorption behavior are close to the sorption for reviewed organic chemicals. Therefore, the CFC sorption data can be used for determining hydrogeochemical properties and predicting transport of organic contaminants in TACM-containing aquifer environments.

농업 생태계에 대한 잔류농약의 영향 평가 (Evaluation on the effects of pesticide residues to agroecosystem in Korea)

  • 이규승
    • 한국환경농학회지
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    • 제16권1호
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    • pp.80-93
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    • 1997
  • Pesticide residues in soil could be affected to the growth of micro organisms and the activity of enzymes directly, and successively to the soil properties as pH, Eh and nitrogen metabolism. However, residues are diminished by degradation of soil microorganisms, run-off, leaching, volatilization, photodecomposition and uptake through crops. In this paper research results published in Korea were summarized about translocation of soil residues into crops, fates of residues in soil, effects to the activity of soil microorganisms and metabolic pathways of some pesticides. Generally speaking, pesticide residues in soil were not much affected to the agro-ecosystem except few chemicals. So it should be needed more further researches in this field, continuously.

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올방개 방제용(防除用) 제초제(除草劑) Benfuresate와 Cinosulfuron의 생물적(生物的) 특성(特性) 비교(比較) (Biological Properties of Benfuresate and Cinosulfuron for Chemical Control of Eleocharis kuroguwai Ohwi)

  • 이한규;이인룡;유갑희;이정운;이은종
    • 한국잡초학회지
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    • 제14권4호
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    • pp.272-279
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    • 1994
  • 다년생잡초(多年生雜草) 올방개 방제용(防除用) 제초제(除草劑) benfuresate와 cinosulfuron의 생물적(生物的) 특성(特性)을 구명하기 위하여 1993년 온실(溫室) 및 포장시험(圃場試驗)을 하여 다음과 같은 결과를 얻었다. 1. 논토양중(土壤中)에서 benfuresate와 cinosulfuron는 각각 2cm와 6cm깊이까지 수직이동(垂直移動)됨으로써 올방개 생육(生育)을 억제(抑制)시켰다. 2. Benfuresate는 올방개의 뿌리에서 주로 흡수(吸收)되었고 cinosulfuron은 뿌리와 줄기는 물론 중경(中莖)에서도 흡수(吸收)되었다. 3. 토양처리(土壤處理)로서 발생(發生)이 억제(抑制)된 올방개의 재출현율(再出現率)은 benfuresate에 비하여 cinosulfuron 처리구(處理區)에서 훨씬 높았으나 재생후(再生後) 생장속도(生長速度)에 있어서는 반대로 benfuresate 처리구(處理區)에서 빨랐다. 4. Benfuresate는 고살형(枯殺型)으로서 눈의 고사율(枯死率)은 높은 반면 살아있는 측아(側芽)가 빠른 생장(生長)을 하였으나, cinosulfuron은 억제형(抑制型)으로서 눈의 고사율(枯死率)은 낮은 반면 살아있는 측아(側芽)가 기형적(畸形的)으로 빈약(貧弱)한 생장(生長)을 하였다. 5. 토양처리(土壤處理)를 할 경우(境遇) benfuresate는 올방개의 발생전(發生前)부터 발생직후(發生直後)(초장(草長) 2cm)까지 방제(防除)가 가능(可能)하였으나 cinosulfuron은 발생전(發生前)부터 생육중기(生育中期)(초장(草長) 15cm)까지 90% 이상(以上)의 방제효과(防除效果)를 보였다. 6. Cinosulfuron을 경엽(莖葉)에 산포(散布)할 경우(境遇) 올방개 방제효과(防除效果)는 양호(良好)하였으나 벼에 약해(藥害)가 우려(憂慮)되었다. 7. Benfuresate/bensulfuron 입제(粒劑)의 경우(境遇) 벼 생육후기(生育後期)로 갈수록 올방개 방제효과(防除效果)가 낮아졌으나 cinosulfuron/mefenacet/dymron 입제(粒劑)의 경우(境遇)에는 벼 이앙후(移秧後) 65일(日)까지 높은 방제효과(防除效果)를 보였다.

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Tensiometric법을 이용한 친수하 PET 섬유의 표면특성 분석 (The Analysis of Surface Characteristics of the Hydrophilic Chemicals Treated PET Fibers using Tensiometric Methods)

  • 정혜원
    • 한국의류학회지
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    • 제15권4호
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    • pp.431-435
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    • 1991
  • The dispersion and Poiar force components of the surface free energy of PET fibers untreated and treated with hydrophilic chemicals, such as nonionic-soil release polymer (SRP), anionic, nonionic and hydrophilic silicone, were determined using harmonic-mean and geometric-mean methods. Contact angles of water and methylene iodide on the fibers were determined from the adhesion tensions using tensiometric method. Fibers treated with hydrophilic chemicals have the increased polar force component and the decreased dispersion force component. The adhesion tensions of triolein for the hydrophilic treated fibers were smaller than that for untreated fiber.

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익산 제 1 공단 토양의 중금속 함량 분포 조사 (Distribution of Heavy metals in Soil at Iksan 1st Industrial Complex Area)

  • 김성조;백승화;문광현;장광호;김수진
    • 한국환경농학회지
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    • 제17권1호
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    • pp.48-53
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    • 1998
  • 1975년부터 산업활동이 시작된 익산 제1공단내 토양 중에 중금속함량을 비오염지 자연토양 중의 이들 함량과 비교하고 산업활동의 종류에 따른 토양 중 중금속 함량 변화와의 관계를 구명하기 위하여 주로 표층토를 중심으로 $0{\sim}3$$3{\sim}6cm$ 토양층에 있는 Cd, Cu, Ni, Pb 및 Zn의 함량을 조사 분석한 결과는 다음과 같다. 공단 내 토양 중 중금속별 함량변화는 Cd와 Cu는 시료의 $16{\sim}25%$, Pb와 Zn은 93% 이상이 비오염지 자연토양 중 이들 중금속함량 평균치 이상의 토양 중 축적현상을 보였고, Ni함량은 산업활동에 의한 토양 중 변화를 인정할 수 없었다. Cd의 분포는 $0{\sim}3cm$ 토양층은 섬유산업지역에서 5ppm이상의 최고치를 나타내었고, 그 다음이 화학약품 및 식품산업지역에서 높은 것으로 나타났다. $3{\sim}6cm$ 토양층에서는 금속가공지역에서 5ppm 이상의 최고치를 보였고, 다음이 섬유산업지역에서 높은 것으로 나타나 토양층위에 따라 Cd의 축적분포가 조금씩 달랐다. Cu함량은 $0{\sim}3cm$의 토양층에서는 전선류를 제조하는 지역에서 400ppm 이상의 최고치를 나타냈으며, $3{\sim}6cm$ 토양층에서는 전기 저항기, 기계제작 및 전선류 제조지역에서 400ppm이상의 토양축적현상을 보였다. Ni은 도금 및 금속가공지역에서 시료채취 토양층과 관계없이 35ppm이상의 함량을 보였고, 그 다음으로 석재 및 반도체 산업지역에서 25ppm이상의 토양 중 함량을 나타냈다. Pb는 화학약품 및 견직물공장에서 시료채취 토층과 관계없이 $400{\sim}1000ppm$이상의 토양 중 함량을 보였다. Zn은 화학약품과 견직물공장지역에서 토양 깊이와 관계없이 1200ppm이상의 가장 높은 함량분포를 보이는 곳도 있었으며, 그 다음이 도금 및 금속가공, 그리고 피혁공장순으로 Zn함량이 많은 것으로 나타났다. 결과적으로 산업활동의 형태 및 종류는 토양 중의 중금속의 종류 및 함량변화의 원인이 되고 있었고 이 지역에서는 Pb 및 Zn 토양중 함량변화가 뚜렷하였다.

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친환경 토양 관리 방법과 기준에 대한 평가 (Review of Management Methods and Criteria for Environmentally-Sound Soil)

  • 유진희;이교석;정덕영
    • 농업과학연구
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    • 제35권1호
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    • pp.53-67
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    • 2008
  • The principle goal of environmentally-friendly agriculture is to maintain and conserve water and agriculture environment including drinking water resources by properly using agricultural materials such as agricultural chemicals, chemical fertilizers, and other agricultural materials according to act 19 of foster law of environmentally-friendly agriculture. To achieve these goals, we have to establish Integrated Nutrient Management(INM) and Integrated Pesticide Management(IPM) which are most important core technologies for environmentally-friendly rice cultivation. However, there are lack of criteria and technology for evaluation category according to soil management and its soil classes to practice an environmentally-friendly agriculture. Therefore, we should eatablish the standards to produce the safe agricultural products based on the soil physical and chemical characteristics which are basic properties of soil to accomplish the principle aims of environmentally-friendly agriculture.

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