• Title/Summary/Keyword: softening stability

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Joining of Presureless Sintered SiC Ceramics using $MgO-Al_2O_3-SiO_2$ System ($MgO-Al_2O_3-SiO_2$계를이용한 상압소결 SiC의 접합)

  • 이홍림;남서우;한봉석;박병학;한동빈
    • Journal of the Korean Ceramic Society
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    • v.34 no.7
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    • pp.781-789
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    • 1997
  • Pressure sintered SiC specimens were joined using MgO-Al2O3-SiO2 (MAS) glass which has a thermal expansion coefficient similar to that of SiC. MAS melt showed excellent behavior of wetting on the SiC substrate over 148$0^{\circ}C$, and the wettability was much influenced by the joining atmosphere. The joining was conducted at 150$0^{\circ}C$ for 30 min in Ar atmosphere. The flexural strength of the joined specimen shows 342~380 MPa up to 80$0^{\circ}C$, which is almost the same as that of as-recieved SiC specimen. However, the flexural strength of the joined specimen decreased to about 80 MPa at 90$0^{\circ}C$ due to softening of the glass melt. The analyses od XRD and WDS show that the reaction between the SiC specimen and the MAS melt produces the oxycarbide glass, which had a high strength and a good stability at high temperatures.

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Evaluation of Characteristics of Simulated Radioactive Vitrified Form Using Cooling Methods (냉각 방법에 따른 모의 방사성폐기물 유리고화체의 특성평가)

  • Lee, Kang-Taek;Lee, Kyu-Ho;Yoon, Duk-Ki;Ryu, Bong-Ki;Kim, Cheon-Woo;Park, Jong-Kil;Hwang, Tae-Won
    • Journal of the Korean Ceramic Society
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    • v.43 no.12 s.295
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    • pp.865-871
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    • 2006
  • In order to examine and compare the characteristics of two vitrified forms (AG8W1 and DG2) simulated for the operation of a commercial vitrification facility being constructed in Ulchin nuclear power plant, the vitrified forms were cooled by the natural cooling and annealing methods respectively. And the Product Consistency Test (PCT), compressive strength, thermal conductivity, specific heat, phase stability, softening point and Coefficient of Thermal Expansion (CTE) of the vitrified farms were experimented. Consequently, it was shown that there were no significant differences on the physiochemical properties of the vitrified forms performed the natural cooling and annealing.

Incorporating uplift in the analysis of shallowly embedded pipelines

  • Tian, Yinghui;Cassidy, Mark J.
    • Structural Engineering and Mechanics
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    • v.40 no.1
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    • pp.29-48
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    • 2011
  • Under large storm loads sections of a long pipeline on the seabed can be uplifted. Numerically this loss of contact is extremely difficult to simulate, but accounting for uplift and any subsequent recontact behaviour is a critical component in pipeline on-bottom stability analysis. A simple method numerically accounting for this uplift and reattachment, while utilising efficient force-resultant models, is provided in this paper. While force-resultant models use a plasticity framework to directly relate the resultant forces on a segment of pipe to the corresponding displacement, their historical development has concentrated on precisely modelling increasing capacity with penetration. In this paper, the emphasis is placed on the description of loss of penetration during uplifting, modelled by 'strain-softening' of the force-resultant yield surface. The proposed method employs uplift and reattachment criteria to determine the pipe uplift and recontact. The pipe node is allowed to become free, and therefore, the resistance to the applied hydrodynamic loads to be redistributed along the pipeline. Without these criteria, a localised failure will be produced and the numerical program will terminate due to singular stiffness matrix. The proposed approach is verified with geotechnical centrifuge results. To further demonstrate the practicability of the proposed method, a computational example of a 1245 m long pipeline subjected to a large storm in conditions typical of offshore North-West Australia is discussed.

Effect of Fermented Rice Bran on Rheological Properties of White Bread Dough (발효쌀겨의 첨가에 따른 식빵 반죽의 물리적 특성)

  • Park, Hyun-Sil;Han, Gi-Dong
    • Journal of the Korean Society of Food Culture
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    • v.25 no.1
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    • pp.82-90
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    • 2010
  • In this study, the rheological properties of doughs blended with 5% to 20% fermented rice bran (FRB) were investigated using farinographs, amylographs, extensographs, and SEM. In the farinograph analysis, the water absorption decreased and the replacement ratio of FRB increased over the time of development of the dough. The stability time of the dough was shortened, and the degree of softening decreased with added volume of FRB. The amylograph analysis showed that the temperature at the beginning of gelatinization showed a tendency to increase with increasing replacement ratio of FRB, but the gelatinization temperature showed no significant difference between the FRB-added groups and control group. The extensograph analysis showed that when the replacement ratio of FRB was over 10%, the extension of the dough decreased while the resistance was increased. In the SEM analysis, the added dough with less than 10% FRB had similar characteristics in gluten matrix and gas bubbles to those of the control of wheat flour alone. It was concluded that an added FRB volume of below 10% is most suitable for bread making.

Evaluation of Limit Strength for Steel Cable-Stayed Bridgesusing Various Cable Elements (다양한 케이블 요소를 이용한 강사장교의 극한강도 평가)

  • Song, Weon-Keun;Rhee, Jong Woo
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.10 no.5
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    • pp.115-121
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    • 2006
  • This paper deals with the influence of behavior of a variety of cable elements on the limit strength of steel cable-stayed bridges. The softening plastic-hinge model, which is represented in this study for the limit strength evaluation of the example bridge, considers both geometric and material nonlinearites. Geometric nonlinearity of beam-column members are accounted by using stability function, and material nonlinearity - by using CRC tangent modulus and parabolic function. Cable sag effect is considered for cable members. The result of this study shows that the limit strength of the example bridge using the equivalent of elasticity for truss straight elements is smaller than those using the cable or the catenary elements.

Study on Softness of an EO Adducted Amine Oxide Zwitterionic Surfactant (EO가 부가된 아민 옥사이드 양쪽성 계면활성제의 유연력에 관한 연구)

  • Kim, JiSung;Mo, DaHee;Lee, JinSun;Park, JunSeok;Han, DongSung;Lim, JongChoo
    • Korean Chemical Engineering Research
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    • v.50 no.6
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    • pp.960-968
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    • 2012
  • In this study, the measurement of physical properties of 3 different ethylene oxide adducted zwitterionic surfactants were measured such as critical micelle concentration, surface tension, interfacial tension, contact angle, viscosity and foam stability. Also, the dual function characteristics of the zwitterionic surfactants were investigated by determining an isoelectric point, which were obtained using zeta potential measurement and QCM (quartz crystal microbalance) experiments. The isoelectric point of the synthesized zwitterionic surfactant determined by zeta potential measurement was close to that obtained by QCM experiment and both results have shown almost the same trend as that determined by the frictional property measured using an automated mildness tester. In particular, it has been observed that all three surfactants used during this study provide better softening effect at a pH of neutral condition than at an acidic or an alkaline condition. This result indicates that the synthesized surfactants act as a cationic surfactant at a pH of neutral condition and thus provide good softening effect during a rinsing cycle in the detergency process.

Interfacial Properties of Imidazoline Cationic Surfactant (Imidazoline 양이온 계면활성제의 계면 특성)

  • Kim, Ji Sung;Lim, Jong Choo
    • Korean Chemical Engineering Research
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    • v.47 no.1
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    • pp.38-45
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    • 2009
  • In this study, interfacial properties were measured for imidazoline type cationic surfactant system which has been widely used as a fabric softener, a dispersant, an anti-static agent, a bleach activator, and an emulsifier. The CMC of imidazoline surfactant was near $6{\times}10^{-5}mol/L$ and the surface tension at CMC was about 32 mN/m. It was found that surface tension was not affected by surfactant concentration but decreased with an increase in pH. The interfacial tension between 1 wt% aqueous solution and n-dodecane was shown to be about 0.01 mN/m and equilibration time was not affected by pH. Phase behavior experiment in a binary aqueous surfactant system showed that only micellar solution of $L_1$ phase was found under conditions of temperature and pH investigated during this study. Only a two-phase region consisting of lower-phase microemulsion in equilibrium with excess oil phase existed under the same conditions, when oil was added to the binary surfactant system. The foam stability measured with 1 wt% surfactant solution increased with pH, which is consistent with surface tension measurement result. QCM(quartz crystal microbalance) measurement showed that surfactant adsorption increased with surfactant concentration but decreased with pH. According to the friction measurement, best fabric softening effect by imidazoline surfactant system was found under alkali conditions.

Comparative Study on the Flexural Performance of Concrete Reinforced with Polypropylene and Steel Fibers (폴리프로필렌 및 강섬유 보강콘크리트의 휨 성능에 관한 비교 연구)

  • Cho, Baiksoon;Lee, Jong-Han;Back, Sung Yong
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.34 no.6
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    • pp.1677-1685
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    • 2014
  • Short discrete fibers compounded with concrete can enhance the tensile resistance and ductility of concrete. Recently, the effectiveness of the reinforcement has increased according to the increasing length of steel fiber. However, the lengthening of steel fiber requires reducing the ratio of the fiber content to remain the workability and quality of concrete. Thus, the present study evaluated the flexural performance of fiber reinforced concrete with less than l.0% fiber volume ratios of steel fiber, 30mm and 60mm long, and polypropylene fiber, being evaluated as a good reinforcing material with chemical stability, long-term durability, and cost effectiveness. Concrete with more than 0.25% steel and 0.5% polypropylene fibers improved the brittle failure of concrete after reaching cracking strength. Concrete reinforced with polypropylene exhibited deflection-softening behavior, but that with more than 0.5% polypropylene delayed stress reduction and recovered flexural strength by 60 to 80% after cracking strength. In conclusion, concrete reinforced with more than 0.75% polypropylene could improve structural flexural performance. In particular, energy absorption capacity of reinforced concrete with 1.0% polypropylene fiber was similar to that with 0.5% and 0.7% steel fibers.

Measurement of an Isoelectric Point and Softness of a EO-PO Adducted Zwitterionic Surfactant (EO-PO가 부가된 양쪽성 계면활성제의 등전점 및 유연력 측정에 관한 연구)

  • Lim, JongChoo;Mo, DaHee;Lee, JinSun;Park, JunSeok;Han, DongSung
    • Korean Chemical Engineering Research
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    • v.50 no.3
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    • pp.455-463
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    • 2012
  • In this study, the measurement of physical properties of ethylene oxide-propylene oxide adducted zwitterionic surfactants were measured such as critical micelle concentration, surface tension, interfacial tension, contact angle, viscosity and foam stability. Also, the dual function characteristics of a zwitterionic surfactant were investigated by determining an isoelectric point, which were obtained using zeta potential measurement and QCM (quartz crystal microbalance) experiments. The isoelectric point of DEP-OSA82-AO zwitterionic surfactant determined by zeta potential measurement was close to that obtained by QCM experiment and both results have shown almost the same trend as that determined by the frictional property measured using an automated mildness tester. In particular, it has been observed that DEP32-OSA82-AO and DEP34-OSA82-AO surfactants provide better softening effect at a pH of acidic or neutral condition than at an alkaline condition. This result indicates that both surfactants act as a cationic surfactant at a pH of acidic or neutral condition and thus provide good softening effect during a rinsing cycle in the detergency process.

A Study on the Microstructural, Thermal and Mechanical Properties of Silicon Nitride Ceramic

  • Kim, Jong-Do;Lee, Su-Jin;Lee, Jae-Hoon;Sano, Yuji
    • Journal of Advanced Marine Engineering and Technology
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    • v.33 no.7
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    • pp.1026-1033
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    • 2009
  • Fine ceramics have high strength, excellent wear resistance, chemical stability and high strength at high temperature and are receiving attention in various fields such as construction, engineering, aerospace and marine science. Finish machining process is required to obtain precise ceramics components because sintering process necessary for obtaining high strength and high quality ceramics reduces the dimensions of components and precision of shape. But high strength and brittleness of ceramics materials cause difficulty in processing. So a process for obtaining wanted dimensions is studying using high temperature which makes ceramics softened and thermal affected recently. Laser beam is a very useful optical device for these kinds of processes. Laser process such as laser cutting, laser machining, laser heat treatment and laser-assisted machining(LAM) is researching to manufacture practical ceramics components using intense laser source which can cause local softening and damage of workpiece. In this paper, microstructural and mechanical properties of silicon nitride heated are studied as a basic study for researching of ceramics process by laser beam. The surface variation of HIP and SSN-silicon nitride was analyzed with SEM and EDS. A processing at $1,300^{\circ}C$ or above causes N element to combine into $N_2$ gas and the gas busts from surface. These phenomena make bloat, craters and heat defects on the surface of silicon nitride. Also, oxygen content is largely increased to oxidize the surface and it causes changing of phases and reducing of hardness of surface.