• 한국세라믹학회지
• /
• 제51권3호
• /
• pp.170-176
• /
• 2014

Effective glass frit compositions enabled to absorb laser energy, and to seal a commercial dye-sensitized solar-cell-panel substrate were developed by using $V_2O_5$-based glasses with various amounts of $TeO_2$ substitution. The latter was intended to increase the lifetime of the solar cells. Substitution of $V_2O_5$ by $TeO_2$ provided a strong network structure for the glasses via the formation of tetrahedral pyramids in the glass, and changed the various glass properties, such as glass transition temperature ($T_g$), dilatometric softening point ($T_d$), crystallization temperature, coefficient of thermal expansion (CTE), and glass flowage without any detrimental effect on the laser absorption property of the glasses. The thermal expansion mismatch (${\Delta}{\alpha}$) between the glass frit and the substrate could be controlled within less than ${\pm}5%$ by addition of 10 wt% of ${\beta}$-eucryptite. An 810 nm diode laser was used for the sealing test. The laser sealing test revealed that the VZBT20 glass frit with 10 wt% ${\beta}$-eucryptite was successfully sealed the substrates without interfacial cracks and pores. The optimum sealing conditions were provided by a beam size of 3 mm, laser power of 40 watt, scan speed of 300 mm/s, and 200 irradiation cycles.

• 한국세라믹학회지
• /
• 제50권3호
• /
• pp.238-243
• /
• 2013

We investigated the effect of Pb-metal filler added to a hybrid paste(PbO-$Bi_2O_3-B_2O_3$-ZnO glass frit and Pb-powder), for joining flip-chip sat lower temperatures than normal. The glass transition temperature was detected at $250^{\circ}C$ and the softening point occurred at $330^{\circ}C$. As the temperature increased, the specific density decreased due to the volatility of the Pb-metal and boron component in the glass. When the glass was heat-treated at $350^{\circ}C$ for 5 min, XRD results revealed a crystalline $Pb_4Bi_3B_7O_{19}$ phase that had been initiated by the addition of Pb-filler in the hybrid paste. The addition of the Pb-metal filler caused are action between the Pb-metal and glass that accelerated the formation of the liquid phase. The liquid phase that formed, promoted bonding between the flip-chip substrate sat lower temperature.

• Earthquakes and Structures
• /
• 제14권3호
• /
• pp.273-283
• /
• 2018

Previous experimental researches indicate that reinforced concrete beam-column joints play an important role in the mechanical properties of moment resisting frame structures, so as to require proper design. In order to get better understanding of the beam-column joint performance, a rational model needs to be developed. Based on the former considerations, two typical models for calculating the shear carrying capacity of the beam-column joint including the inelastic reinforced concrete joint model and the softened strut-and-tie model are selected to be introduced and analyzed. After examining the applicability of two typical models mentioned earlier to interior beam-column joints, several adjustments are made to get better predicting of the test results. For the softened strut-and-tie model, four adjustments including modifications of the depth of the diagonal strut, the inclination angle of diagonal compression strut, the smeared stress of mild steel bars embedded in concrete, as well as the softening coefficient are made. While two adjustments for the inelastic reinforced concrete joint model including modifications of the confinement effect due to the column axial load and the correction coefficient for high concrete are made. It has been proved by test data that predicted results by the improved softened strut-and-tie model or the modified inelastic reinforced concrete joint model are consistent with the test data and conservative. Based on the test results, it is also not difficult to find that the improved beam-column joint model can be used to predict the joint carrying capacity and cracks development with sufficient accuracy.

• 대한기계학회논문집A
• /
• 제24권7호
• /
• pp.1817-1825
• /
• 2000

The purpose of this study is to examine the fracture toughness of the welded pipe from the viewpoint of FATT for the S38 and S42 steels used widely as the pipe material. Post weld heat treatment(PW HT) was carried out like following conditions: temperature of 67$0^{\circ}C$, I hour of holding time and cooling in furnace. Fracture toughness was obtained by measuring the crack opening displacement(COD) of the notched specimens over the range of temperature from -14$0^{\circ}C$ to -$25^{\circ}C$. Hardness values at fusion line near around were the highest and the microstructures at welded zone were coarsened. Regardless of the pipe materials, COD and temperature curves of the as-welds were moved toward higher temperature compared with those of the parents. However, COD and temperature curves of the PWHT specimens were positioned at lower temperature compared with those of the as-welds. The more heat input causes to decrease the COD values at the constant temperature. It was verified through the recrystallization treatment that PWHT was attributed to move toward lower temperature region considerably due to the improved plastic deformation at the same applied COD value of 0.3mm and softening effect. In case of the weldment of S38 steel, cleavage fracture was observed at -105$^{\circ}C$ unlike the structural steels, in which brittle fracture mode was generally shown at - 196$^{\circ}C$.

• 한국소성가공학회:학술대회논문집
• /
• 한국소성가공학회 2004년도 추계학술대회논문집
• /
• pp.211-214
• /
• 2004

적절한 가공조건을 통하여, 중 탄소강에서 SIDT를 적용하여 페라이트-시멘타이트 미세조직이 압연 직후에 얻어졌다. 또한 이와 같은 조건은 압하온도 $690^{\circ}C$, 높이 감소율 $70\%$ (변형량 1.2) 및 변형율 속도 1/s에서 가공하였을 때 얻어졌으며, 가공 직후 $730^{\circ}C$로 승온하여 약 30분간 유지 후 서냉한 조건에서 매우 연한 미세조직이 얻어짐을 알 수 있었다. 이는 기존 20 시간 이상의 구상화 열처리에 비해 매우 짧은 시간이며, 구상화 열처리를 통한 경험한 미세조직과 유사한 특성을 나타낼 것으로 예상된다.

• 열처리공학회지
• /
• 제23권4호
• /
• pp.198-204
• /
• 2010

Modified 9Cr-1Mo steels possess excellent high-temperature mechanical properties and are widely used in energy conversion industries. However, in-service materials degradation, such as softening, carbide-induced embrittlement, temper embrittlement, etc., can take place during long-term operation. Evolution of microstructure due to service exposure to high temperature has a strong effect on the performance of heat resistant steels. In case of modified 9Cr-1Mo steels, precipitation of $Fe_2Mo$-type laves phases and coarsening of $M_{23}C_6$-type carbides are the primary cause of degradation of mechanical properties such as toughness, hardness, tensile strength and creep resistance. This study was aimed at finding reliable parameter for assessing the integrity of modified 9Cr-1Mo steels. Characteristic parameters were attained between mechanical and ultrasonic properties.

• 한국구조물진단유지관리공학회 논문집
• /
• 제16권5호
• /
• pp.121-128
• /
• 2012

이 논문에서는 대표적 수치해석에의 균열처리 방법으로 손상모델 기반의 분산균열모델을 체택하여 구조내력을 산정하였다. 또한 전력구 구조물의 실구조 모델링을 위해 3차원 해석방법을 택하였으며 3차원 콘크리트 구성모델로는 현재 3차원 모델중 콘크리트의 다축압축, 인장균열을 효과적으로 모사하는 미소면 모델(Microplane model)을 재료모델로 사용하여 비선형 유한요소해석을 수행하였다. SFRC의 인장연화곡선을 얻기 위해 역해석법을 사용하였으며, 역해석으로 구한 인장연화곡선이 실험결과와 아주 잘 일치함을 보였다. 하중-균열폭 관계를 입력값으로 사용한 역해석 결과와 하중-CMOD 관계를 사용한 역해석 결과는 서로 잘 일치하는 경향을 나타냈다. 이 논문에서는 실험으로부터 측정된 균열폭 데이터와 수치해석시의 손상지수와의 관계를 도출하여으며, 이와 같은 결과는 향후 균열탐사를 통한 구조물의 잔존 구조내력 산정에 적용할 수 있으리라 판단된다.

• 생물환경조절학회지
• /
• 제15권1호
• /
• pp.91-99
• /
• 2006

This study was conducted to determine the influence of postharvest dipping treatment with aminoethoxyvinylglycine (AVG) on ethylene production and composition of non-cellulosic neutral sugars in cell walls of 'Tsugaru' apple fruits during storage. Fruits were harvested on August 20, soaked in AVG 50 and 75 $mg L^{-1}$ solution for 5 minutes, and stored in cold storage chamber at $0{\pm}1^{\circ}C$ for 60 days. Fruit quality factor, ethylene productions, and cell wall component changes were investigated at 20 days interval. As a result, the fruit firmness and acid content were much higher in AVG treated fruits than those of untreated one during 60 days of cold storage. Ethylene production of AVG treated fruits was reduced to the level of 1/10 compared with untreated one. As to the change of non-cellulosic neutral sugars in the cell walls of 'Tsu- garu' fruits, the major sugar was arabinose and galactose in water, CDTA and $Na_2CO_3$ soluble fractions. The content of arabinose and galactose in untreated fruits increased as the softening of fruits was in progress, but the fruits treated with AVG showed a little change during storage, so it is predicted that these two cell wall compositional sugars were not solubilized by the treatment of AVG. Accordingly, the marketability of 'Tsu- garu' fruits could remarkably increase when soaking the fruits in AVG solution after harvest.

• Korean Chemical Engineering Research
• /
• 제50권1호
• /
• pp.6-10
• /
• 2012

본 연구의 목적은 styrene-butadiene-styrene(SBS) 블록공중합체와 폐타이어 고무분말(crumb rubber, CR)로 개질한 아스팔트의 저온접착특성에 대해 파라핀오일 가소제의 영향에 대한 것이다. SBS/CR로 개질한 아스팔트 블렌드와 파라핀오일/SBS/CR 아스팔트 블렌드의 온도 민감성을 침입도와 연화점으로 측정하였다. 형광현미경으로 파라핀오일/SBS/CR 아스팔트 블렌드에 대한 개질제들의 분산 상태와 만능시험기로 저온에서 접착성질을 각각 측정하였다. 저온접착시험에서 SBS 함량의 증가와 파라핀오일 함량 5 wt % 및 10 wt %에서 접착강도와 변형률이 증가하였다. $-20^{\circ}C$에서 측정한 접착강도와 강인성은 파라핀오일이 10 wt %와 SBS 공중합체의 양이 6 wt %인 조성에서 최대값을 얻었다. SBS/CR/아스팔트 블렌드에서 파라핀오일의 첨가는 유연성을 부여하는 효과를 나타내고, 저온에서 강인성의 증가를 가져오는 것을 확인하였다.

• 자연과학논문집
• /
• 제8권2호
• /
• pp.111-118
• /
• 1996

$Na_2O$-CaO-$SiO_2$ 계 유리의 화학적 내구성을 향상시키면서 작업점도의 변화를 최소화 하기 위하여, 기본 조성 유리를 선정한 후, 이 조성에 $B_2O_3$, ZnO 성분의 첨가량을 변화시키고 $Na_2O$, $Al_2O_3$, $Li_2O$ 성분을 변화시켜가면서 각 성분이 물성에 미치는 영향을 조사하여 최적 조성비를 얻는 것을 목적으로 하였다. 본 실험결과 $Na_2O$-CaO-$SiO_2$계 유리에서 연화점 변화를 최소화하고 화학적내구성을 극대화 시키는 최적조성(wt%)은 다음과 같았다.$B_2O_3$:3.36%, ZnO:2.88%, $Na_2O$:9.93%, $Al_2O_3$, $Li_2O$:0.19%, $SiO_2$:70.56%, CaO:11.22%, $K_2O$:0.14%