• Title/Summary/Keyword: sodium ions

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Ion Transport and High Frequency Dielectric of the Hollandite Nax$(Ti_{8-x}Cr_x)O_{16}$ (Hollandite Nax$(Ti_{8-x}Cr_x)O_{16}$의 이온 전송과 고유전율 특성)

  • Yun, Ju-Ho;Li, Ying;Choi, Yong-Sung;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.241-242
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    • 2008
  • The Velocity Autocorrelation Function (VAF) of the sodium ions is calculated for a range of temperature from 250K to 1000K and converted into the linear ac-conductivity and ac-susceptibility response via Fourier transformation. A peak is found in the conductivity around $6\times10^{12}$ Hz that has some of the character of a Poley absorption. Here it is shown to be due to an harmonically coupled site vibrations of the sodium atoms, which extend only over a limited range. At frequencies below the peak the conductivity tends towards a constant i.e. dc value corresponding to a constant flow of ions through the simulation cell. At high temperatures the conductivity due to this ion transport process behaves like a metal with an insulator to metal transition occurring around a specific temperature.

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Simple Formation of Poly(sodium 4-styrenesulfonate) Pattern on the Hydrophobic Substrate for the Control of Cell Adhesion via a Selective Ion Irradiation

  • Kim, Soo-Jung;Hwang, In-Tae;Jung, Jin-Mook;Jung, Chan-Hee
    • Journal of Radiation Industry
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    • v.7 no.2_3
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    • pp.149-154
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    • 2013
  • In this study, the simple preparation of poly(sodium 4-styrenesulfonate) (PSS)-patterned substrate via a selective ion irradiation was investigated to manipulate cell adhesion. PSS thin films spin-coated onto the hydrophobic polystyrene (PS) was patterned through masked 150 keV proton irradiation followed by developing with deionized water. The characteristics of the resulting PSS-patterned surfaces were investigated by using microscope, surface profiler, FT-IR, XPS, and contact angle analyzer. These analytical results revealed that the resolved $100{\mu}m$ PSS patterns were formed on the hydrophobic PS surface above the fluence of $1{\times}10^{15}ions\;cm^{-2}$ and the chemical structure, composition, and wettability of the PSS patterns were dependant on a fluence. Moreover, the results of the in-vitro cell culture and proliferation assay exhibited that H1299 cells preferentially adhered and proliferated onto the more hydrophilic PSS part of the PSS-patterned PS and the well-aligned cell patterns was formed on the PSS-patterned PS particularly at the fluence of $1{\times}10^{15}ions\;cm^{-2}$.

Proton Effect on the Degradation of Phenolic Compound by Activated Sludge and Nocardia asteroides (활성슬러지 혼합미생물과 Nocardia asteroides에 의한 페놀화합물 분해시 양성자이온의 영향)

  • 조관형;조영태;우달식
    • Journal of Environmental Science International
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    • v.11 no.6
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    • pp.561-567
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    • 2002
  • This study was investigated to evaluate the effect of the sodium ion and pH on toxicity of dinitrophenol at high concentrations (0.41 to 0.54 mM), over a sodium concentration range of 0.1 mM to 107 mM and over a pH range of 5 to 9. The concentration of sodium ions in the activated sludge mixed liquor seemed to have very little effect on dinitrophenol toxicity. However, lack of sodium in the growth media resulted in a reduction of the dinitrophenol degradation rate by bacterial isolate from the activated sludge culture, which has been identified as Nocardia asteroides. Dinitrophenol inhibition was found to be strongly dependent on mixed liquor pH. The dinitrophenol degradation rate was highest in the pH range of 6.95 to 7.84; at pH 5.94 degradation of 75 mg/L dinitrophenol was significantly inhibited; at pH < 5.77, dinitrophenol degradation was completely inhibited after approximately 30% of the dinitrophenol was degraded.

Assessment of Groundwater Quality for Irrigation and Agro-based Industrial Usage in Selected Aquifers of Bangladesh

  • Rahman, Md. Mokhlesur;Hoque, Syed Munerul;Jesmin, Sabina;Rahman, Md. Siddiqur;Kim, Jang-Eok
    • Korean Journal of Environmental Agriculture
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    • v.24 no.2
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    • pp.98-105
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    • 2005
  • Groundwater sampled from 24 tube wells of three districts namely Sherpur, Gaibandha and Naogaon in Bangladesh was appraised for their water quality for irrigation and agro-based industrial usage. All waters under test were slightly alkaline to alkaline (pH = 7.2 to 8.4) in nature and were not problematic for crop production. As total dissolved solid (TDS), all groundwater samples were classified as fresh water (TDS<1,000 mg/L) in quality. Electrical conductivity (EC) and sodium adsorption ratio (SAR) values reflected that waters under test were under medium salinity (C2), high salinity (C3) and also low alkalinity (S1) hazard classes expressed as C2S1 and C3S1. As regards to EC and soluble sodium percentage (SSP), groundwater samples were graded as good and permissible in category based on soil properties and crop growth. All water samples were free from residual sodium carbonate (RSC) and belonged to suitable in category. Water samples were under soft moderately hard, hard and very hard classes. Manganese, bicarbonate and nitrate ions were considered as major pollutants in some water samples and might pose threat in soil ecosystem for long-term irrigation. For most of the agro-based industrial usage, Fe and Cl were considered as troublesome ions. On the basis of TDS and hardness, groundwater samples were not suitable for specific industry. Some water samples were found suitable for specific industry but none of these waters were suitable for all industries. The relationship between water quality parameters and major ions was established. The correlation between major ionic constituents like Ca, Mg, K, Na, $HCO_3$ and Cl differed significantly. Dominant synergistic relationships were observed between EC-TDS, SAR-SSP, EC-Hardness, TDS-Hardness and RSC-Hardness.

Precipitation Characteristics of Heavy Metal Ions in Coal Mine Drainage (석탄광산배수에 함유된 중금속 이온의 침전 특성)

  • Jo, Young-Do;Ahn, Ji-Whan;Kim, Hyung-Seok
    • Journal of the Mineralogical Society of Korea
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    • v.20 no.2 s.52
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    • pp.125-134
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    • 2007
  • This study has been carried out in order to examine the precipitation characteristics of Fe, Mn and Al ions in coal mine drainage before removing heavy metals by using the froth flotation method. The removal rate of Fe(III), Mn(II) and Al(III) within 1 h accounted for over 99% in pH 5.0, 10.0, and $6.0{\sim}9.0$ respectively, and residual concentrations of which were under $1mgL^{-1}$. When sodium oleate as a collector was added to the solution of Fe, Mn, and Al ions, insoluble salts was not formed by the reaction of heavy metal and sodium oleate. So, we must remove the metals from coal mine drainage by using not the ion flotation method, but the precipitation flotation method

Research Trend on Conversion Reaction Anodes for Sodium-ion Batteries (나트륨이차전지용 전환반응 음극 소재 기술 동향)

  • Kim, Suji;Kim, You Jin;Ryu, Won-Hee
    • Journal of the Korean Electrochemical Society
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    • v.22 no.1
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    • pp.22-35
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    • 2019
  • Development of low cost rechargeable batteries has been considered as a significant task for future large-scale energy storage units (i.e. electric vehicles, smart grids). Sodium-ion batteries (SIBs) have been recognized as a promising alternative to replace conventional lithium-ion batteries (LIBs) because of their abundancy and economic benign. Nevertheless, Na ions have larger ionic radius than that of Li ions, resulting in sluggish transport of Na ions in electrodes for cell operation. There have been efforts to seek suitable anode materials for the past years operated based on three different kinds of reaction mechanism (intercalation, alloy reaction, and conversion reaction). In this review, we introduce a class of conversion reaction anode materials for Na-ion batteries, which have been reported.

SEPARATION BEHAVIOR OF WATER-ALCOHOL SOLUTION BY PARTIALLY DITHIOCARBAMATED POLY(VINYL CHLORIDE) MEMBRANE

  • Yamada, Sumio;Nakagawa, Tsutomu
    • Proceedings of the Membrane Society of Korea Conference
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    • 1993.10a
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    • pp.46-51
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    • 1993
  • Poly(vinyl chloride) was modified by reacting with sodium N-methyldithiocarbamate or N-methyl-N-carboxymethyldithiocarbamate to obtain crosslinked dithiocarbamated PVC(PMD, PSDC). In addition PSDC were substituted with metal ions of $Ma^+, Li^+$ and $Cs^+$. PLMD and PSDC were reacted with copper ions in alcohol or aqueous solution to produce chelate complexes of dithiocarbanated PVC, respectively(PMD-$Cu^{2+}$, PSDC-$Cu^{2+}$). PSDC was irradiated by ultraviolet light to enhance crosslinking(PSDC-UV).

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THE EFFECTS OF IONS AND BUFFER SOLUTIONS ON THE MRNA EXPRESSION OF gtfD GENE OF Streptococcus mutans (Streptococcus mutans의 gtfD 유전자 발현에 대한 이온 및 완충액의 영향)

  • Kim, Bo-Young;Kim, Shin;Chung, Jin
    • Journal of the korean academy of Pediatric Dentistry
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    • v.31 no.2
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    • pp.314-322
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    • 2004
  • The production of a glucan was affected by the concentration of ions and buffer solutions, and nutrients in an oral cavity. In this study, the effects of ions and buffer solutions on the mRNA expression of gtfD gene in Streptococcus mutans, an important causative agent of dental caries, were investigated by Fluorescent in situ hybridization(FISH). At first, ions and buffer solutions had little effect on the multiplication of Streptococcus mutans. The green fluorescence according to the mRNA expression of gtfD gene was detected in the BHI broth containing 1% sucrose. The intensities of the green fluorescence were strong at 0.25mM of $CaCl_2$. Little fluorescence was detected by the addition of KCl, except far 10mM KCl at which fluorescence intensities were similar to those of the control. Fluorescence intensities were weak at each concentration of $MgCl_2$ when compared to the control. As for buffer solutions, fluorescence intensities were similar to those of the control at each concentration of buffer solutions, except that they were little detected at 100mM of potassium phosphate.

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Novel Tm(III) Membrane Sensor Based on 2,2'-Dianiline Disulfide and Its Application for the Fluoride Monitoring of Mouth Wash Preparations

  • Ganjali, Mohammad Reza;Norouzi, Parviz;Tamaddon, Atefeh;Husain, Syed Waqif
    • Bulletin of the Korean Chemical Society
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    • v.27 no.9
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    • pp.1418-1422
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    • 2006
  • In this work the construction of a novel poly(vinyl chloride) membrane sensor based on 2,2'-dianiline disulfide (DADS) as a neutral carrier, o-nitrophenyloctyl ether (NPOE) as a plasticizer and sodium tetraphenyl borate (NaTPB) as an anionic site with unique selectivity towards Tm(III) ions is reported. The electrode has a linear dynamic range between $1.0\;{\times}\;10^{-6}$ and $1.0\;{\times}\;10^{-2}$ M, with a nice Nernstian slope of 19.5 ${\pm}$ 0.3 mV per decade and a detection limit of $4.0\;{\times}\;10^{-7}$ M at the pH range of 4.8-8.5. It has a very fast response time (<15 s) in the whole concentration range, and can be used for at least 4 weeks without any considerable divergence in the electrode potentials. The proposed sensor revealed comparatively good selectivity with respect to most common metal ions, and especially lanthanide ions. It was used as an indicator electrode in the potentiometric titration of Tm(III) ions with EDTA and in direct determination of concentration of Tm(III) ions in binary mixtures. It was also applied in determination of fluoride ions in mouth wash preparations.

Selectivity of cations in electrodialysis and its desalination efficiency on brackish water (전기투석 막여과의 이온제거 특성 및 지하염수의 담수화효율)

  • Choi, Su Young;Kweon, Ji Hyang
    • Journal of Korean Society of Water and Wastewater
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    • v.27 no.4
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    • pp.445-456
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    • 2013
  • In this study, desalination by electrodialysis with ion exchange membranes was applied to synthetic waters with various ion concentrations and also for ground waters from coastal areas in Korea. Electrodialysis performance on the synthetic solutions showed the similar tendency in operation time and current curves, i.e., shorter operation time and higher maximum current with increasing applied voltages. The ED results of synthetic waters with different ion compositions, i.e., $Na_2SO_4$, $MgSO_4$, $CaSO_4$, at the similar conductivity condition, i.e., $1,250{\mu}s/cm$ revealed that effects of mono- and divalent ions on water quality and performance in electrodialysis were different. The divalent ions had less efficiency in the ED compared to monovalent sodium ions and also divalent calcium ions showed better performance than Mg ions. The electrodialysis on the ground waters produced high quality of drinking water. The groundwater from SungRoe however showed a buildup of membrane resistance. Organic matter concentrations and great portions of divalent ions in the groundwater were possible causes of the deteriorated performance.