• Title/Summary/Keyword: sodium dioctyl sulfosuccinate

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Synthesis on the Core-Shell Polymer of Silicone Dioxide/Styrene Using Sodium Dioctyl Sulfosuccinate (EU-DO133L) as a Surfactant (계면활성제 Sodium Dioctyl Sulfosuccinate (EU-DO133L)을 사용한 이산화규소/스티렌의 코어-셀 고분자의 합성)

  • Kim, Duck-Sool;Park, Keun-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.27 no.2
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    • pp.183-187
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    • 2010
  • Core-Shell polymers of silicone dioxide-styrene system were prepared by sequential emulsion polymerization. In inorganic/organic Core-Shell composite particle polymerization, silicone dioxide adsorbed by surfactant sodium dioctyl sulfosuccinate (EU-DO133L) was prepared initially and then core silicone dioxide was encapsulated emulsion by sequential emulsion polymerization using styrene at the addition of potassium persulfate (KPS) as an initiator. We found that $SiO_2$ core shell of $SiO_2$/styrene structure was formed when polymerization of styrene was conducted on the surface of $SiO_2$ particles, and the concentration sodium dioctyl sulfosuccinate (EU-DO133L) was 0.5~2.0g. The structure of core-shell polymer were investigated by measuring to the thermal decomposition of polymer composite using thermogravimetric analyzer and morphology of latex by scanning electron microscope(SEM).

Dewaxing of Sunflower Seed Oil (해바라기 유(油)의 탈납)

  • Rhee, Joon-Shick
    • Korean Journal of Food Science and Technology
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    • v.11 no.2
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    • pp.112-117
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    • 1979
  • By using the existing caustic refining system with a minimum modification and by using a combination of various emulsifiers(0.2 % sodium hexametaphosphate. 0.05 % sodium lauryl sulfate and 0.001 % dioctyl sodium sulfosuccinate), a new economical dewaxing process for sunflower seed oil was developed in order to reduce the cost of the dewaxing process. The results indicate that the waxes can be removed satisfactorily from the sunflower seed oil by emulsifying. batchwise or continuously, the oil with the aqueous surfactant solution, followed by centrifugation at ambient temperatures $(16{\sim}27^{\circ}C)$. Dewaxing loss for the batch process was satisfactory for both low wax-and high wax-crude oil, whereas dewaxing loss for the continuous process needs to be improved. The results indicate that initial level of wax content (low wax vs. high wax) did not affect the loss for batch process (0.82 % vs. 0.62 %), but affected the loss for continuous processes, regardless of the type of mixing mode (2.28 % and 5.68 % for low wax-and high wax-oil, respectively). It was also noted that the type of mixing mode (centactor vs. static mixer) for the continuous process affected the loss, regardless of the wax content (5.2 % and 2.8 % for contactor and static mixer, respectively).

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Inhibitory Activity of Surfactants against Tobacco Mosaic Virus Infection (계면활성제의 TMV 감염저지 효과)

  • 박은경
    • Journal of the Korean Society of Tobacco Science
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    • v.11 no.1
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    • pp.11-17
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    • 1989
  • Inhibition of tobacco mosaic virus (TMV) infection by 4 surfactants, sodium salts of alpha olefin (AOS), linear alkylbenzene (LAS), dioctyl sulfosuccinate (OSS), and dodecyl benzene sulfonic acid (SAS), was examined on tobacco cv. Xanthi-nc and NC 82. Infection of virions or TMV RNA was inhibited over 98% by the surfactants (2500 rpm). However, symptom development and viral concentration in tobacco plants treated with the surfactants into the rhizosphere soil 3 days before inoculation with TMV on leaves were not different from those in untreated tobacco plants. This indicates no significant systemic effects of the surfactants on the inhibition of TMV infection. The surfactants, except LAS, had no effect on the inhibition of viral infection when purified virions mixed with each surfactant and ultracentrifuged were inoculated on the tobacco plants. The virus was almost inactivated by LAS, showing that the viral infection was reduced more than 96%. The virus particles treated with the surfactants were not distinguishable in size and dimension from untreated normal particles, suggesting that the inhibitory action of the surfactants to TMV infection may not involve disintergration or uncoating of the virus at the early stage of infection.

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In Vivo Antifungal Activities of Surfactants against Tomato Late Blight, Red Pepper Blight, and Cucumber Downy Mildew (계면활성제를 이용한 역병과 오이 노균병 방제)

  • Yu, Ju-Hyun;Jang, Kyoung-Soo;Kim, Heung-Tae;Kim, Jin-Cheol;Cho, Kwang-Yun;Choi, Gyung-Ja
    • Applied Biological Chemistry
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    • v.47 no.3
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    • pp.339-343
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    • 2004
  • Anionic surfactants such as sodium dioctyl sulfosuccinate (SDSS) and sodium dodecylbenzene sulfonate (NaDBS) and a nonionic surfactant, polyoxyethylene oleyl ether (OE-7) were tested for their protective, curative, and persistent activities on tomato late blight (TLB, Phytophthora infestans), red pepper blight (RPB, P. capsici), and cucumber downy mildew (CDM, Pseudoperonospora cubensis). They exhibited a strong protective activity on TLB, RPB, and CDM. Among them, $NaDBS\;(500\;{\mu}g/ml)$ showed the most in vivo antifungal activities(1-day protective activity) with control values of 99%, 100%, and 85% against TLB, RPB, and CDM, respectively. However, the three surfactants represented a weak disease controlling efficacy on TLB, RPD, and CDM in a 1-day curative application. SDSS and NaDBS exhibited a good persistent activities on TLB and RPB. Especially, NaDBS, at $500\;{\mu}g/ml$, showed control values of more than 88% on TLB and RPB in a 7-day protective application. The results indicate SDSS and NaDBS have a potential for the control of TLB, RPB, and CDM in the fields.

HPLC Study on the Determination of Active Ingredients in Cough-Cold Preparations (HPLC법에 의한 종합감기약중 구성성분의 동시 정량)

  • Lee, Chang-Hyun;Rhee, Gye-Ju
    • YAKHAK HOEJI
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    • v.32 no.4
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    • pp.251-257
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    • 1988
  • A simple and sensitive HPLC method was developed for the simultaneous determination of ten kinds of active ingredients formulated in commercial cough-cold mixtures. A group of Pseudoephedrine HCl, dl-Methylephedrine HCl, Noscapine, Chlorophenylamine maleate, Dextromethorphan HBr and Phenylpropanolamine HCl were determined at 254nm using a Novapak $C_{18}$ column with mobile phase consisting of a mixture of methanol-acetonitrile-1, 4dioxane-tetrahydrofuran-water(12 : 20 : 20 : 5 : 43, pH4.7) containing 0.013M-dioctyl sodium sulfosuccinate. The another group of Acetoaminophen, Caffeine, Guaifenesin and Ethenzamide were also determined at 254nm using a Novapak $C_{18}$ column as the stationary phase, and a mixture of methanol-1% aqueous acetic acid (3 : 7). The results indicate that these methods are accurate and precise with relative standard deviation of not more than 1% (n=5) for the above active ingredients.

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Preparation and Analysis of Alkaline Powder Cleaning Agents for Steel (철강용 알칼리 분말세정제의 제조 및 세정해석)

  • Lee, Ae-Ri;Chung, Dong-Jin;Park, Hong-Soo;Im, Wan-Bin
    • Journal of the Korean Applied Science and Technology
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    • v.20 no.4
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    • pp.283-288
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    • 2003
  • Alkaline powder cleaning agents (APCAs) were prepared by blending of $Na_2CO_3$ tetrasodium pyrophosphate (TSPP). sodium orthosilicate (Na-OSi), Na-dioctyl sulfosuccinate (303C), Demol C, and MJU-100A (100A). The physical properties of APCAs tested with steel specimen showed the following results. The cleaning powers of APCA-6 ($Na_2CO_3$ 250g/TSPP 70g/Na-OSi 40g/303C 60g/Demol C 50g/100A 30g mixture) for press-rust preventing oil was 97% and 98% degreasing at 2wt%, $70^{\circ}C$ and $90^{\circ}C$, respectively; for Quenching oil, the cleaning power of APCA-6 was 95% degreasing at 2wt% and $70^{\circ}C$. From the results, it was ascertained that APCA-6 exhibited a good cleaning power. Also low foaming power tests proved that the APCA-6 maintained good defoaming effect.

Preparation and Behavior of High Performance Alkaline Cleaning Agents for Steel (철강용 고성능 알칼리세정제의 제조 및 세정거동)

  • Park, Hong-Soo;Jo, Hye-Jin;Shim, Il-Woo;You, Hyuk-Jae;Kim, Myung-Soo;Hahm, Hyun-Sik
    • Journal of the Korean Applied Science and Technology
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    • v.22 no.1
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    • pp.15-20
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    • 2005
  • $Na_2CO_3$. Sodium orthosilicate (Na-OSi), Tetronix T-701 (T-701), Na-dioctyl sulfosuccinate (303C), Newpol PE-68 (PE-68), MJU-100A, and tetrasodium pyrophosphate were blended to prepare high performance alkaline cleaning agents (ACASs). The results of cleaning test with steel specimen showed that ACAS-6 ($Na_2CO_3$ 50g/Na-OSi 35g/T-701 20g/303C 18g/PE-68 17g/MJU-100A 10g/TSPP 20g/ water 180g mixture) had a good cleaning power. The cleaning power for press-rust preventing oil was 98% and 99% degreasing at 4wt%, $70^{\circ}C$ and $90^{\circ}C$, respectively ; for quenching oil, the cleaning power of ACAS-6 was 91% degreasing at 4wt% and $70^{\circ}C$. The foam heights measured immediately after foaming by Ross & Miles method and Ross & Clark method at 6wt%, $60^{\circ}C$ were 18mm and 65mm, respectively. It was concluded that ACAS-6 had a good low foaming cleaning agent.

Encapsulation of ZnSe Quantum Dots within Silica by Water-in-oil Microemulsions (마이크로에멀전을 이용한 실리카에 담지된 ZnSe 양자점 제조)

  • Lee, Areum;Kim, Ji Hyeon;Yoo, In Sang;Park, Sang Joon
    • Applied Chemistry for Engineering
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    • v.22 no.3
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    • pp.328-331
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    • 2011
  • ZnSe quantum dots (QDs) were prepared by employing water-containing Dioctyl sodium sulfosuccinate (AOT) reversed micelles (microemulsions) and the silica-encapsulated ZnSe QDs were obtained by a direct injection of tetraethyl orthosilicate (TEOS) into the microemulsion system. When the QDs were coated by silica, well-defined spherical shapes were formed and the average size of the QDs was near 7 nm. In addition, the photoluminescence (PL) efficiency of the QDs was reduced from 8.0 to 1.1% as they were encapsulated by silica. However, the solid layers of the silica-encapsulated ZnSe QDs on gold surfaces showed the excellent photostability. In particular, they are cadmium free and thus, less toxic. Moreover, the present method does not require a hot reaction temperature or extremely toxic H2Se gas as a Se precursor. Accordingly, the method can be a safer and more economical process for producing silica-encapsulated ZnSe QDs, which may be a potential media for biosensors.