• 펄프종이기술
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• 제29권3호
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• pp.34-42
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• 1997

This study was carried out to investigate the proper cooking conditions of soda-anthraquinone and alkaline sulfite-anthraquinone pulping of rice-straw, and get basic data f9r the use of rice-straw chemical pulp through the test of characteristics and physical properties of pulps made in the various cooking conditions From the experimental results , we can conclude as follows. In the soda-anthraquinone pulping of rice-straw, the optimum cooking conditions were 60 min. at $150^{\circ}C$ in the amount of caustic soda of 20% with the addition of anthraquinone(0.05%). And total yield, Kappa No. and brightness of pulp made in the condition above mentioned were 41.9%, 7.7 and 51.1 respectively. In the alkaline sulfite-anthraquinone pulping of rice-straw, the proper mixing ratio of cooking chemical(caustic soda : sodium sulfite) was 50:50. And the optimum cooking conditions were 60 min. at $150^{\circ}C$ in the amount of cooking chemical of 20% with the addition of anthraquinone(0.05%). At that time, the total yield, Kappa No, and brightness of pulp were 50.1%, 9.1 and 40.2 respectively. As a result, the alkaline sulfite-anthraquinone pulping was superior to the soda-anthraquinone pulping in the aspect of yield, but inferior in the viewpoints of Kappa No. and brightness. For the comparison of qualities of pulps made in the various cooking methods and conditions, the physical properties of four sorts of pulps were tested. As a result, soda-anthraquinone pulps were superior to alkaline sulfite-anthraquinone pulps in the various strengths excluding tear strength and brightness. On the other hand, pulps made in the condition of addition of cooking chemical of 20% were superior to pulps in the dosage of 15% in the aspects of all the strengths and brightness.

• 펄프종이기술
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• 제42권2호
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• pp.35-40
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• 2010

Variations in hexeneuronic acid content in hardwood alkaline pulps were investigated to evaluate their contribution to kappa number. Out of diverse chemical pulps the highest hexeneuronic acid content were measured in yellow poplar kraft pulping, which was assumed to enhance ca. 7.0 of kappa number determined by acid permanganate consumption. In yellow poplar soda-anthraquinone pulping, hexeneuornic acid was contributed to increment of 5.0-6.0 kappa number. In eucalyptus alkaline pulping, hexeneuronic acid content was not significantly different from soda-anthraquinone pulping. Increment of Kappa number by hexeneuronic acid was 4.5-5.6 depending on pulping method and pulping time at target temperature.

• 펄프종이기술
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• 제37권5호통권113호
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• pp.35-40
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• 2005

We tried to synthesize the 2-methyl anthraquinone (2-MAQ) with reaction between phthalic anhydride and toluene instead of using 2-methyl phthalic anhydride and benzene. This process didn't generate significant of amount of 1-methyl anthraquinone (l-MAQ) as byproduct. The other advantage of this pathway is using less toxic toluene instead of benzene known as carcinogen. 2-MAQ synthesized this pathway was as effective as reagent grade from commercial available based on soda-anthraquinone(AQ) pulping results.

• 펄프종이기술
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• 제48권2호
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• pp.13-19
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• 2016

Moso Bamboo was investigated as the a raw material for pulp and paper industry. Soda-Anthraquinone (Soda-AQ) pulping, elemental chlorine free bleaching was applied. Yield of soda or soda-AQ pulp was 29.3-31.7% with Kappa number 33.0-22.8 with different cooking time or anthraquinone addition at 20% active alkali. In soda or soda-AQ pulping, 81-86% of xylan was removed, which was the main reason for lower pulp yield than hardwood species. Average fiber length of Moso Bamboo soda-AQ pulp was 1.36 mm with $15.5{\mu}m$ fiber width. Soda-AQ pulp from Moso Bamboo (P-3, lowest Kappa pulp) was bleached with 5.5-6.5% of chlorine dioxide charge as D0ED1 bleaching sequence. In 3-stages ECF bleaching, final brightness of 85.3% ISO was achieved with total chlorine dioxide 6.5%.

• 펄프종이기술
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• 제42권3호
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• pp.22-27
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• 2010

Pulping properties of the imported mixed eucalyptus chips and the domestic yellow poplar chips were investigated for comparing two chips as the raw materials for the hardwood chemical pulp. Soda-AQ (anthraquinone) pulping was applied for this study. The pulp from yellow poplar showed higher pulp yield than pulp from mixed eucalyptus, which comes from the lower hot-water soluble extractives and the higher polysaccharides in yellow poplar chips than those of the mixed eucalyptus chips. The yellow poplar pulp had higher average fiber length and fiber width than those of the mixed eucalyptus pulp, which led to the better respond to beating and the higher tear strength than those of the pulp from the mixed eucalyptus chips.

• 펄프종이기술
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• 제42권3호
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• pp.14-21
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• 2010

Three different species of cattails (Typha orientalis, Typha angustata, Typha latifolia) cultivated in South Korea were examined as raw materials for the production of pulp and paper. Soda pulping with anthraquinone was used for the stems and the leaves of cattail, separately. Addition of anthraquinone in soda pulping improved the yield greatly. Chemical components between three cattail species and within each species (leaves and stem) gave little differences. Average fiber length of the bleached cattail fibers was a little shorter than that of the HwBKP of Eucalyptus. Average fiber width of the cattail fibers was a half of that of the HwBKP. Compared to the HwBKP, cattail pulp gave higher breaking length, higher opacity, and better smoothness at equivalent freeness.

• 펄프종이기술
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• 제45권1호
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• pp.6-12
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• 2013

TFormic acid-hydrogen peroxide (or performic acid) pulping process needs milder reaction condition than other chemical pulping process. Two-step formic acid-hydrogen peroxide pulping process can produce the chemical pulp with similar pulp yield and lignin content compared with soda-anthraquinone process. Formic acid-hydrogen peroxide pulp can be produced less xylan content than other alkaline pulps, which favor for dissolving pulp production. Formic acid-hydrogen peroxide pulp showed better response beating than soda-anthraquinone(AQ) pulps with reaching target freeness with less beating. Also, formic acid-hydrogen peroxide pulp had better tensile index at similar freeness level compared with soda-AQ pulps.

• 펄프종이기술
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• 제48권3호
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• pp.44-50
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• 2016

As a raw material for pulp and paper industry, Moso bamboo, Timber bamboo and Henon bamboo pulps were prepared by soda or soda-anthraquinone(Soda-AQ) pulping process. Soda-AQ pulp yields was higher in Henon bamboo (43.2%) than in Moso bamboo or Timber bamboo (32.7-39.2%), but quite lower than hardwood species. In Kappa number comparison, Henon bamboo pulp showed lower (16.6) with 50 min cooking to $170^{\circ}C$ than that of Moso bamboo (22.8) and Timber bamboo (18.9) with 90 min cooking to $170^{\circ}C$. Fiber length of Timber bamboo soda pulp had higher (1.46 mm) than that of Moso bamboo or Henon bamboo (1.18-1.36 mm). All three bamboo pulps showed longer average fiber length than commercial hardwood pulp. With higher pulp yield and lower Kappa number, Henon bamboo is better raw material for pulp than Moso bamboo and Timber bamboo.

• 한국펄프종이공학회:학술대회논문집
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• 한국펄프종이공학회 2006년도 PAN PACIFIC CONFERENCE vol.2
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• pp.291-294
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• 2006

Studies of the effectiveness of anthraquinone (AQ) in kraft-AQ pulping in terms of its mechanism of mass transfer have been conducted. Experiments performed have demonstrated an 'apparent solubility' of AQ in caustic solutions of wood lignin. The adsorption behavior of AQ species was also analyzed. Anthraquinone-2-sulfonic acid (AQ-S), a water-soluble derivative of AQ, showed selective adsorption on wood. A mechanism for the transport of AQ into wood chips during kraft pulping are proposed, and some explanations for previously unexplained observations are addressed.

• Journal of the Korean Wood Science and Technology
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• 제7권2호
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• pp.3-30
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• 1979

우리나라에서는 일본잎갈나무가 대량(大量) 조림(造林)되어 축적(蓄積)과 생장량(生長量)으로 보아 주요(主要)한 조림(造林) 수종(樹種)이나 각종(各種) 추출물(抽出物)과 활성(活性) phenol 성분(成分)이 많고 심재율(心材率)이 높아 펄프화(化)에서 수율저하(收率低下)와 표백곤란(漂白困難)이 초래(招來)되어 펄프원료(原料)로서의 이용(利用)이 기피(忌避)되고 있다. 따라서 일본잎갈나무의 화학(化學)펄프 원료화(原料化)의 제고(提高)로서 펄프수율(收率) 향상(向上)과 표백성(漂白性) 개선(改善)을 위하여 셀룰로오스보호제를 첨가(添加)한 소다펄프화(化) 특성(特性)을 구명(究明)하였다. 증해(蒸解)는 최고온도(最高溫度) 170$^{\circ}C$까지 90분간(分間) 가열(加熱)하고 90분간(分間) 유지(維持)하는 일정조건(一定條件)으로 황화도(黃化度) 25%, 활성(活性)알칼리 18%의 크라프트법(法)으로 일본잎갈나무의 수령별(樹齡別) 펄프화(化) 특성(特性)을 구명(究明)하고, 18%활성(活性) 알칼리의 소다증해(蒸解)에 첨가제로 2.5% $MgSO_4$, 2.5% $ZnSO_4$, 2.5% $Al_2(SO_4)_3$, 2.5% KI, 2.5% hydroquinone, 2.5% ethylene diamine 또는 0.1~1.0% anthraquinone를 가(加)하여 15년생(年生) 일본잎갈나무의 변재(邊材)와 심재별(心材別) 소다펄프화(化) 특성(特性)을 구명(究明)한 후(後), 0.5% anthraquinone과 18% 활성(活性)알칼리로 증해(蒸解)된 펄프를 3%, 6%, 9% NaOH를 투입(投入)한 30%의 고농도(高農度)펄프를 상압(常壓) 산소표백(酸素漂白)하고, 이산화염소(二酸化鹽素)의 DED로 계속표백(繼續漂白)한 결과(結果) 다음과 같은 결론(結論)을 얻었다. 1. 일본잎갈나무의 수령별(樹齡別) 크라프트펄프는 수령간(樹齡間)에 펄프의 정선수율(精選收率)은 차(差)가 없으나, 수령(樹齡)이 증가함에 따라 펄프의 총수율(總收率)은 감소(減少)하고 비인열도(比引裂度)는 증가하였으며, 목재(木材)의 심재율(心材率), 용적밀도(容積密度) 수(數), 섬유장(纖維長) 및 온수추출물(溫水抽出物)도 증가하는 경향(傾向)을 나타냈다. 2. 일본잎갈나무의 변재(邊材)와 심재별(心材別) 소다증해(蒸解)에 셀룰로오스 보호제로 첨가(添加)된 7종(種)의 첨가제들은 변재(邊材)와 심재(心材)펄프화(化)에 대한 영향(影響)이 대체로 소다법(法)보다 증가되었으나 크라프트법(法)에 미치지 못하고, 크라프트펄프법(法)에 가까운 첨가제는 펄프수율(收率)에서 KI $MgSO_4$, anthraquinone이며, 특(特)히 다른 첨가제의 25분(分) 1이 첨가(添加)된 anthraquinone은 펄프의 정선수율(精選收率)과 KappaNo. 및 비파열도(比破裂度)에서 다른 첨가제보다 효과적이었다. 3. anthraquinone첨가량(添加量)에 따른 변재(邊材)와 심재별(心材別) 소다펄프의 품질(品質)은 변재(邊材)와 심재(心材) 모두 첨가량(添加量)이 많을수록 탈(脫)리그닌도(度)와 펄프수율(收率)이 높으나 활성(活性)알칼리가 낮으면 정선수율(精選收率)도 낮았으며 활성(活性)알칼리 17%의 소다 증해액(蒸解液)에 0.5% anthraquinone을 첨가(添加)한 조건(條件)에서는 크라프트펄프보다 비교적(比較的) 양호(良好)한 펄프가 얻어졌다. 4. 일반화(一般化)된 CEDED표백중(漂白中) 염소화(鹽素化)와 알칼리 추출단계(抽出段階) 대신(代身)에 30%의 고농도(高濃度)펄프에 상압(常壓) 산소표백(酸素漂白)한 ODED표백(漂白)은 산소단계(酸素段階)에서 변재(邊材)와 심재(心材)펄프 모두 NaOH투입량(投入量)이 증가될수록 백색도(白色度)와 비인열도(比引裂度)가 향상(向上)되나 펄프수율(收率)과 Kapa No.는 감소(減少)되었으며, NaOH 투입량(投入量)이 높을수록 펄프품질(品質)은 CEDED 표백(漂白)과 유사(類似)하나 펄프수율(收率)이 떨어졌다. 5. 따라서 본(本) 실험(實驗)에서는 펄프수율(收率) 향상(向上)을 위해서는 원료(原料)에서 심재율(心材率)이 낮은 수령(樹齡)의 경우가 펄프재(材)로 적당(適當)하고, 0.5% anthraquinone을 첨가(添加)한 활성(活性)알카리 18%의 소다증해(蒸解)하는 것이 적당(適當)하며 폐수중(廢水中)의 염소화합물(鹽素化合物)을 감소(減少)시키기 위하여서는 펄프농도(濃度) 30%이상(以上)의 고농도(高濃度)에서 상압(常壓) 산소(酸素)로 표백후(漂白後) 이산화(二酸化) 염소(鹽素)로 DED 표백(漂白)하면 일본잎갈나무의 크라프트법(法)보다 비교적(比較的) 우수(優秀)한 펄프를 얻을 수 있다.