• Title/Summary/Keyword: soda-anthraquinone (Soda-AQ) pulp

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Soda-Anthraquinone Pulping and Chlorine Dioxide Bleaching Properties from Moso Bamboo (Phyllostachys pubescens) (맹종죽(Phyllostachys pubescens)의 소다 안트라퀴논 펄핑 특성 및 이산화염소 표백 특성)

  • Lee, Kyu-seong;Song, Woo-Yong;Shin, Soo-Jeong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.48 no.2
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    • pp.13-19
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    • 2016
  • Moso Bamboo was investigated as the a raw material for pulp and paper industry. Soda-Anthraquinone (Soda-AQ) pulping, elemental chlorine free bleaching was applied. Yield of soda or soda-AQ pulp was 29.3-31.7% with Kappa number 33.0-22.8 with different cooking time or anthraquinone addition at 20% active alkali. In soda or soda-AQ pulping, 81-86% of xylan was removed, which was the main reason for lower pulp yield than hardwood species. Average fiber length of Moso Bamboo soda-AQ pulp was 1.36 mm with $15.5{\mu}m$ fiber width. Soda-AQ pulp from Moso Bamboo (P-3, lowest Kappa pulp) was bleached with 5.5-6.5% of chlorine dioxide charge as D0ED1 bleaching sequence. In 3-stages ECF bleaching, final brightness of 85.3% ISO was achieved with total chlorine dioxide 6.5%.

Elucidating soda and soda-anthraquinone pulping characteristics of Korean bamboo species (국내산 주요 죽종의 소다 및 소다-안트라퀴논 펄핑 특성 비교)

  • Lee, Kyu-Seong;Song, Woo-Yong;Shin, Soo-Jeong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.48 no.3
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    • pp.44-50
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    • 2016
  • As a raw material for pulp and paper industry, Moso bamboo, Timber bamboo and Henon bamboo pulps were prepared by soda or soda-anthraquinone(Soda-AQ) pulping process. Soda-AQ pulp yields was higher in Henon bamboo (43.2%) than in Moso bamboo or Timber bamboo (32.7-39.2%), but quite lower than hardwood species. In Kappa number comparison, Henon bamboo pulp showed lower (16.6) with 50 min cooking to $170^{\circ}C$ than that of Moso bamboo (22.8) and Timber bamboo (18.9) with 90 min cooking to $170^{\circ}C$. Fiber length of Timber bamboo soda pulp had higher (1.46 mm) than that of Moso bamboo or Henon bamboo (1.18-1.36 mm). All three bamboo pulps showed longer average fiber length than commercial hardwood pulp. With higher pulp yield and lower Kappa number, Henon bamboo is better raw material for pulp than Moso bamboo and Timber bamboo.

Comparison of the soda-anthraquinone pulping properties between imported Eucalyptus mixture chips and domestic yellow poplar (Liriodendron tulipifera)chips (수입산 혼합 유칼립투스 칩과 국내산 백합 나무 (Liriodendron tulipifera) 칩의 소다-안트라퀴논 (soda-anthraquinone) 펄핑 특성 비교)

  • Sung, Yong-Joo;Lee, Joon-Woo;Kim, Se-Bin;Shin, Soo-Jeong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.42 no.3
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    • pp.22-27
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    • 2010
  • Pulping properties of the imported mixed eucalyptus chips and the domestic yellow poplar chips were investigated for comparing two chips as the raw materials for the hardwood chemical pulp. Soda-AQ (anthraquinone) pulping was applied for this study. The pulp from yellow poplar showed higher pulp yield than pulp from mixed eucalyptus, which comes from the lower hot-water soluble extractives and the higher polysaccharides in yellow poplar chips than those of the mixed eucalyptus chips. The yellow poplar pulp had higher average fiber length and fiber width than those of the mixed eucalyptus pulp, which led to the better respond to beating and the higher tear strength than those of the pulp from the mixed eucalyptus chips.

New 2-methyl Anthraquinone Synthesis Approach and Application in Soda-anthraquinone (AQ) Pulping

  • Shin Soo-Jeong;Francis Raymond C.;Omori Shigetoshi
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.37 no.5 s.113
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    • pp.35-40
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    • 2005
  • We tried to synthesize the 2-methyl anthraquinone (2-MAQ) with reaction between phthalic anhydride and toluene instead of using 2-methyl phthalic anhydride and benzene. This process didn't generate significant of amount of 1-methyl anthraquinone (l-MAQ) as byproduct. The other advantage of this pathway is using less toxic toluene instead of benzene known as carcinogen. 2-MAQ synthesized this pathway was as effective as reagent grade from commercial available based on soda-anthraquinone(AQ) pulping results.

Impact of hexeneuronic acid on kappa number determination in 3 different bamboo soda-anthraquinone(AQ) pulps (대나무류 3종 소다-안트라퀴논 펄프 내 존재하는 hexeneuronic acid가 카파 값에 미치는 영향)

  • Song, Woo-Yong;Lee, Kyu-Seong;Lee, Suk-Gyeong;Shin, Soo-Jeong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.48 no.3
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    • pp.73-79
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    • 2016
  • Hexeneuronic acid in soda-anthraquinone(AQ) pulps from Moso bamboo(Phyllostachys pubescebs), Timber bamboo(Phyllostachys bambusoides) and Henon bamboo(Phyllostachys nigra var. henonis) was investigated with mercuric chloride hydrolysis and UV spectroscopic quantification. Concentration of hexeneuronic acid in bamboo pulps was $36.6-45.4{\mu}mol/g$, which contributed to 3.1-3.9 value increase of kappa number. Lower concentration of 4-O-methylglucuronic acid in bamboo xylan contributed to lower hexeneruonic acid content in bamboo pulps than those of hardwood(yellow poplar or eucalyptus) but higher than softwood(red pine).

Chemical and Mechanical Properties of Yellow Poplar Pulp Produced by Formic Acid- Hydrogen Peroxide Pulping (개미산-과산화수소 펄핑에 의하여 생산된 백합나무 펄프의 화학적 및 역학적 특성 분석)

  • Sim, Jaehoon;Kim, Jeong-Ho;Park, Jong-Moon;Shin, Soo-Jeong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.45 no.1
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    • pp.6-12
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    • 2013
  • TFormic acid-hydrogen peroxide (or performic acid) pulping process needs milder reaction condition than other chemical pulping process. Two-step formic acid-hydrogen peroxide pulping process can produce the chemical pulp with similar pulp yield and lignin content compared with soda-anthraquinone process. Formic acid-hydrogen peroxide pulp can be produced less xylan content than other alkaline pulps, which favor for dissolving pulp production. Formic acid-hydrogen peroxide pulp showed better response beating than soda-anthraquinone(AQ) pulps with reaching target freeness with less beating. Also, formic acid-hydrogen peroxide pulp had better tensile index at similar freeness level compared with soda-AQ pulps.

Study on the Mass Transfer Behavior of AQ and Its Effectiveness during AQ-Kraft Pulping Process

  • Huang, Xiannan;Song, Hainong;Qin, Chengrong;Yoon, Sung-Hoon;Chai, Xin-Sheng
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2006.06b
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    • pp.291-294
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    • 2006
  • Studies of the effectiveness of anthraquinone (AQ) in kraft-AQ pulping in terms of its mechanism of mass transfer have been conducted. Experiments performed have demonstrated an 'apparent solubility' of AQ in caustic solutions of wood lignin. The adsorption behavior of AQ species was also analyzed. Anthraquinone-2-sulfonic acid (AQ-S), a water-soluble derivative of AQ, showed selective adsorption on wood. A mechanism for the transport of AQ into wood chips during kraft pulping are proposed, and some explanations for previously unexplained observations are addressed.

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Studies on the Pulping Characteristics of Larchwood (Larix leptolepis Gordon) by Alkaline Process with Additives (첨가제(添加劑) 알칼리 법(法)에 의한 일본 잎갈 나무의 펄프화(化) 특성(特性)에 관(關)한 연구(硏究))

  • Lim, Kie-Pyo;Shin, Dong-Sho
    • Journal of the Korean Wood Science and Technology
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    • v.7 no.2
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    • pp.3-30
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    • 1979
  • Larch ($\underline{Larix}$ $\underline{leptolepis}$ GORDON), one of the major afforestation species in Korea in view of its growing stock and rate of growth, is not favored as a raw material for pulp due to its low yield of pulp and difficulties with bleaching arising from the high content of extractives in wood, and the high heartwood ratio and the active phenolics, respectively. The purpose of this study is to investigate the characteristics of firstly pulping with various additives of cellulose protector for the yield of pulp, and secondly bleaching with oxygen for chlotination-alkali extraction of five stage-sequence to reduce chlorine compounds in bleaching effluents. The kraft cooking liquor for five age groups of larchwood was 18 percent active alkali with 25 percent sulfidity and 5 : 1 liquor-to-wood ratio, and each soda liquor for sap-and heart-wood of the 15-year-old larchwood was 18 percent alkali having one of the following cellulose protectors as the additive; magnesium sulfate ($MgSO_4$, 2.5%), zinc sulfate ($ZnSO_4$, 2.5%), aluminium sulfate ($Al_2(SO_4)_3$, 2.5%), potasium iodide (KI, 2.5%), hydroquinone (HQ, 2.5%), anthraquinone (AQ, 0.1%) and ethylene diamine (EDA, 2.5%). Then each anthraquinone-soda liquor for the determination of suitable cooking condition was the active alkali level of 15, 17 and 19 percent with 1.0, 0.5 and 0.1 percent anthraquinone, respectively. The cooking procedure for the pulps was scheduled to heat to 170$^{\circ}C$ in 90 minutes and to cook 90 minutes at the maximum temperature. The anthraquinone-soda pulps from both heartwood and sapwood of 15-year-old larchwood prepared with 0.5 percent anthraquinone and 18 percent active alkali were bleached in a four-stage sequency of OCED. (O: oxygen bleaching, D: chlorine dioxide bleaching and E: alkali extraction). In the first stage oxygen in atmospheric pressure was applied to a 30 percent consistency of pulp with 0.1 percent magnesium oxide (MgO) and 3, 6, and 9 percent sodium hydroxide on oven dry base, and the bleached results were compared pulps bleached under the conventional CEDED (C: chlorination). The results in the study were summarized as follows: 1. The screened yield of larch kraft pulp did not differ from particular ages to age group, but heartwood ratio, basic density, fiber length and water-extractives contents of wood and the tear factor of the pulp increased with increasing the tree age. The total yield of the pulp decreased. 2. The yield of soda pulp with various chemicals for cellulose protection of the 15-year-old larchwood increased slightly more than that of pure soda pulp and was slightly lower than that of kraft pulp. The influence of cellulose protectors was similar to the yield of pulps from both sapwood and heartwood. The effective protectors among seven additives were KI, $MgSO_4$ and AQ, for which the yields of screened pulp was as high as that of kraft pulp. Considering the additive level of protector, the AQ was the most effective in improving the yield and the quality of pulp. 3. When the amount of AQ increased in soda cooking, the yield and the quality of the pulp increased but rejects in total yield increased with decreasing the amount of active alkali from 19 to 15 percent. The best proportion of the AQ seemed to be 0.5 percent at 17 percent active alkali in anthraquinone-soda pulping. 4. On the bleaching of the AQ-soda pulp at 30 percent consistency with oxygen of atomospheric pressure in the first stage of the ODED sequence, the more caustic soda added, the brighter bleached pulp was obtained, but more lignin-selective bleaching reagent in proportion to the oxygen was necessary to maintain the increased yield with the addition of anthraquinone. 5. In conclusion, the suitable pulping condition for larchwood to improve the yield and quality of the chemical pulp to the level for kraft pulp from conventional process seemed to be. A) the selection of young larchwood to prevent decreasing in yield and quality due to the accumulation extractives in old wood, B) the application of 0.5 percent anthraquinone to the conventional soda cooking of 18 percent active alkali, and followed, C) the bleaching of oxygen in atmospheric pressure on high consistency (30%) with 0.1 percent magnesium oxide in the first stage of the ODED sequence to reduce the content of chlorine compounds in effluent.

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On Possible Application of Microorganism for Chemical Pulping (화학(化學)펄프 제조(製造)에 미생물(微生物)의 응용(應用) 가능성(可能性))

  • Lee, Seon-Ho;Yoon, Byong-Ho;Lee, Won-Yong
    • Journal of Forest and Environmental Science
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    • v.13 no.1
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    • pp.143-152
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    • 1997
  • The decayed wood by Fomes pini (Thore) Lloyd required a smaller H factor than the sound wood for pulping to permanganate number 20. The H factors for the decayed wood pulping by the kraft and soda processes were reduced by 15% and 17%, respectively, in the presence of 1% anthraquinone. The wood components degraded by fungi are normally more readily solubilized in alkali than the corresponding components in sound wood. The nonphenolic ${\beta}$-O-4 type lignin model compound, veratrylglycerol-${\beta}$-guaiacyl ether(I), and phenolic model compound, syringylglycerol-${\beta}$-syringyl ether(III), were degraded by the white-rot fungi to yield ${\alpha}$-guaiacoxy-${\beta}$-hydroxypropioveratrone(II) from the former and ${\alpha}$-syringyloxy-${\beta}$-hydroxypropiosyringone(IV) from the latter. Structures of the degradation products indicated that C ${\alpha}$-oxidation could occur with white-rot fungi. It has been shown that the alkaline cleavage of ${\beta}$-aryl ether bonds in the lignin units is accelerated by the presence of ${\alpha}$-carbonyl groups.

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