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Characterization of the Effects of Relative Humidity and Bed-depth on $CO_2$ Capture for Maximizing the Utilization Rate of Soda Lime Sorbent

  • Cho, Il-Hoon;Park, Guen-Il;Kim, Joon-Hyung;Hwang, Taek-Sung;Lee, Mi-Kyoung
    • Carbon letters
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    • v.2 no.2
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    • pp.113-119
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    • 2001
  • The advanced method for $CO_2$capture is currently one of the most important environmental issues in worldwide and it is therefore necessary to have available technologies, which minimize the discharge of $CO_2$ including Carbon-14 from nuclear facilities into the atmosphere. A key aspect of this work is to provide the technically principal data required to improve a $CO_2$ removal system for the utilization of regenerative sorbent use, specifically include suggestions regarding its modified column design (parallel dual-bed assembly), stop-restart operation and the economic feasibility of sorbent use. The removal performance of soda lime and the effects of relative humidity (RH) and packing bed-depth (BD) on $CO_2$ removal were investigated. In a single-bed, it revealed that the utilization of soda lime for $CO_2$ removal at line velocity of 13 cm/sec and bed depth of 12 cm increased with the increased relative humidity up to 85%. However, in the parallel dual-bed assembly applied with the stop-restart operation, a maximum utilization rate of soda lime for $CO_2$ removal was obtained even at 55% of RH and 8 cm of BD, specifically the utilization rate of soda lime by using this $CO_2$ removal assembly was about two-fold superior to that in a single-bed.

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Preparation and Characteristics of Soda Lime for Carbon Dioxide Absorption (이산화탄소 흡수를 위한 소다라임 제조 및 특성)

  • Young-Jin Kim;Seok-Je Kwon;Jun-Hyung Seo;Yang-Soo Kim;Kye-Hong Cho;Jin-Sang Cho
    • Resources Recycling
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    • v.32 no.2
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    • pp.52-58
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    • 2023
  • In this study, soda lime was prepared from slaked lime to expand the scope of limestone use. To evaluate carbon dioxide absorption, an extruder-type and disc-type pelletizers were used to make the soda lime using bentonite as an additive. Regardless of the pelletizing process, the peak of CaCO3 was confirmed in soda lime due to its reaction with carbon dioxide. Furthermore, it was confirmed that both calcite and aragonite were present together. The soda lime prepared using the disc-type pelletizer showed a larger specific surface area than that prepared using the extruder-type pelletizer did, and the specific surface area improved on adding bentonite. The carbon dioxide absorption rate increased under the sample condition with an enhanced specific surface area.

Chemical Characteristic of Glass Beads Excavated from Bakjimeure Site in Asan, Korea (아산 명암리 밖지므레 유적 출토 유리구슬의 화학적 특성)

  • Kim, Na Young;Kim, Gyu Ho
    • Journal of Conservation Science
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    • v.28 no.3
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    • pp.205-216
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    • 2012
  • 65 samples of glass bead excavated from Mahan tombs of Asan Bakjimeure site consists of 13 of potash glass group and 52 of soda glass group and soda glass is superior in numbers. When classified according to color, purple blue glass bead is accompanied potash and soda glass group whereas purple glass bead is potash glass group and red, greenish blue, green and gold foil glass bead is soda glass group. Purple blue glass bead is classified as LCA type in which the content of the stabilizer is low. Of this, the soda glass categorized as LMK type with low content of MgO and $K_2O$ is determined that natron is used as the raw material. As to red glass, the homogeneous glass is LCA-B/HMK type and the heterogeneous glass is HCLA/LMK type. Thus, each of these two types are likely to be used plant ash and natron respectively. Greenish blue and green glass depends of the type that round glass is LCA-A/LMHK type and the segmented glass is LCA-B/HMK type. The gold foil glass bead is manufactured by the purity of 19.9~22.6K gold foil and the soda glass of HCLA/LMK type. In other words, the most of the glass bead of Asan Bakjimeure site is similar to the composition of the glass confirmed in other sites of the Baekche period. On the other hand, the greenish blue and green segmented bead and some red round bead is a different chemical composition is considered that the difference in raw materials. These characteristics is expected to be an important evidence for the understanding of the trade system of the ancient glass.

Bending strength of alumina coated with bioglass and soda lime glass and the precipitation on the surface of coated alumina in PBS (생체 유리와 소다 유리침투에 따른 알루미나 세라믹의 굴곡 강도 및 PBS에서의 표면 생성물 연구)

  • Yuu, Jae-Yang
    • Journal of Technologic Dentistry
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    • v.30 no.2
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    • pp.39-45
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    • 2008
  • Titanium and its alloys are widely used as dental implants materials because of their excellent mechanical properties. However, the alumina and zirconia ceramics are preferred to use as the substitute of Ti implants because there is a problems in esthetics and biocompatibility in Ti implant. The the glass infiltrated alumina ceramics are studied to increase the toughness and biocompatibility. The 45S5 and soda-lime glass powder was mixed with ethanol at ratio of 1:1 and brushed on the surface of alumina. Then it was heat treated in the electric furnace at $1400^{\circ}C$ from 30 min. to 5 hours. The glass powder was controlled from 200 to $350{\mu}m$ using ball milling. After heat treatment, the glass infiltrated specimen was tested in universal testing machine to measure the bending strength. The surface microstructure of each specimen was observed with SEM. The biocompatibility of 45S5 and soda-lime glass coated alumina was investigated using PBS at $36.5^{\circ}C$ incubator. The specimen was immersed in PBS for 3, 5, 7, 10 days. After that, the surface morphology was investigated with SEM. As the results of experiment, the 45S5 bioglass infiltrated alumina show the increase of bending strength according to the increasing of heat treatment time from 30 min. to 5 hours at $1400^{\circ}C$ Finally the 1370N bending strength of alumina increased to 1958N at 5 hours heat treatment, which shows 1.4 times higher. In contrast to this, the soda lime glass infiltrated alumina ceramics shows the convex curve according to heat treatment time. Thus it shows maximum bending strength of 1820N at 1 hour heat treatment of $1400^{\circ}C$ It gives 1.3 times higher. However, the bending strength of soda lime glass infiltrated alumina is decreasing with increasing heat treatment time after 1 hour. The precipitation on the surface of 45S5 glass infiltrated alumina was revealed as a sodium phosphate ($Na_{6}P_{6}O_{24}6H_{2}O$) and the amount of precipitation is increasing with increasing of immersion time in PBS. In contrast to this, there is no precipitation are observed on the surface of soda lime glass infiltrated alumina. This implies that 45S5 glass infiltrated alumina brings more biocompatible when it is implanted in human body.

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Quality Characteristics of Choco-Chip Cookies with Different Quantities of Baking Sodas and Flour Types (소맥분 및 베이킹 소다 함량을 달리한 초코칩 쿠키의 품질 특성)

  • Hwang, Seong-Yun;Kang, Kun-Og
    • Journal of the East Asian Society of Dietary Life
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    • v.23 no.3
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    • pp.357-364
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    • 2013
  • The purpose of this study is to investigate the quality characteristics of choco-chip when using the baking soda. Medium flours are more commonly used for choco-chip cookies than cake flours due to the higher pH levels. The L and b values of the flours decreased but the redness colors were increased with the increased percentage of baking sodas. The hardness, brittleness and gumminess of cake flours and increased baking sodas were lower than the medium flours. Micrographs of the choco-chip cookies showed that the baking sodas with the medium flours had better tendency to melt the proteins than cake flours. Sensory characteristics suggested that the additional 2% of baking soda generated good appearance, flavor, color, texture and over all acceptance. According to the results, we gained knowledge on the effects of adding baking soda to the quality of cookies. And, the most recommended percentages of baking sodas base as suggested by bakers are 2%.

Effect of Concentrations of Wheat Flour and Sugar on Sponge Fermentation of Soda Cracker (밀가루 및 당 농도가 소다크랙커의 스폰지 발효에 미치는 영향)

  • Kim, Sang-Yong;Lee, Byung-Don;Kim, Jung-Min;Oh, Deok-Kun
    • Korean Journal of Food Science and Technology
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    • v.29 no.2
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    • pp.387-389
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    • 1997
  • Effect of concentrations of wheat flour and glucose on the sponge fermentation of soda cracker by the mixed lactic acid bacteria of L. brevis, L. fermentum and L. plantarum was investigated. When glucose was added to the wheat flour solution, pH was higher and TTA (total titrable acid) was lower as compared with the medium without glucose. This results suggested that glucose in the solution stimulate cell growth but inhibit the production of organic acids. With increasing of wheat flour concentration, pH decreased and TTA increased during the sponge fermentation of soda cracker.

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Lead free, Low temperature sealing materials for soda lime glass substrates in Plasma Display Panel (PDP)

  • Lee, Heon-Seok;Hwang, Jong-Hee;Lim, Tae-Young;Kim, Yoon-Hee;Lee, Suk-Hwa;Kim, Il-Won;Lee, Jong-Koo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.373-376
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    • 2008
  • New glass compositions for lead free, low temperature sealing glass frit was examined in $ZnO-V_2O_5-P_2O_5$ glass system which can be used sealing material for PDP to be made of soda lime glass substrates. Among many glass compositions, KFS-C glass showed low glass transition point (Tg) and good fluidity and adhesion characteristics when it was tested by flow button method at low temperature of $420^{\circ}C$. Its Tg was $317^{\circ}C$ and thermal expansion coefficient (CTE) was $70{\times}10^{-7}/K$. The glass frit was mixed with an organic vehicle to make a paste and it was dispensed and sealed with soda lime glass substrates at $420^{\circ}C$ for 10min. Sealed glass panels also showed good adhesion strength even sealed at low temperature of $420^{\circ}C$.

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Chemical Treatment of Low-level Radioactive Liquid Waste (I)

  • Lee, Sang-Hoon;Choe, Jong-In;Kim, Yong-Eak
    • Nuclear Engineering and Technology
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    • v.8 no.2
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    • pp.69-76
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    • 1976
  • This experiment has been carried out for the removal of long-lived radioactive-nuclides (Sr-90, Ru-106, Cs-137 and Ce-144) contained in the low-level radioactive effluents from the spent fuel reprocessing plant and nuclear power plant, in order to determine the decontaminability of various chemical coagulants and domestic clay mineral (montmorillonite). Phosphate process showed prominent efficiency for the removal of Ce-144, and lime-soda process did good removal efficiency for Sr-90. About Cs-137 copper-ferrocyanide process is much desirable. In phosphate or lime-soda process, most favorable removal efficiency was obtained at more than pH 11. The montmorillonite treated with sodium chloride showed a considerable improvement in the removal of the radioactive-nuclides. By a combined chemicals-montmorillionite process, the radioactive-nuclides could be more effectively removed than by the only chemicals process.

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Soda Pulp Properties from Corn Stalk as Raw Material (옥수수 줄기를 원료로 제조한 소다 펄프의 특성)

  • Song, Woo-Yong;Lee, Kyu-seong;Lee, Jai-Sung;Shin, Soo-Jeong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.6
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    • pp.73-80
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    • 2015
  • Corn stalk is the lignocellulosic biomass, which remain as leftover after harvesting. To use the corn stalk as raw material for paper industry, soda pulping was applied. In chemical compositional analysis, extractive contents of corn stalk (45.1%) was higher than hardwood. With corn stalk pith, soda pulp yield was 25.3% at 10.6 Kappa number, but 39.5% yield with 14.8 Kappa number for corn stalk rind. Higher extractives content in pith is one of the reason for lower pulp yield than rind. Pith pulp fibers had higher fines content than rind pulp. Pith parenchyma cell was removed as fines during pulping or washing process, which caused the lower yield. To use the corn stalks as a raw material for paper making, de-pith process is essential for higher pulp yield and longer pulp length.

Use and Evaluation of Lignin as Ion Exchangers (이온교환체로서 리그닌의 이용과 평가)

  • Ads, Essam.N.;Nada, A.M.A.;El-Masry, A.M.
    • Journal of the Korean Chemical Society
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    • v.55 no.1
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    • pp.86-91
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    • 2011
  • Modified lignins were prepared. Soda and peroxy lignins were precipitated from black liquor produced from bagasse pulping with soda and peroxyacid pulping process. The precipitated lignins were hydrolyzed using 10% HCl. Different functional groups were also incorporated into lignin by carboxylation and phosphorylation reactions. Moreover crosslinking of these lignins were carried out using epichlorohydrin. Characterization of the modified lignins and lignins derivative were carried out using Infrared spectroscopy. Thermal analysis of these compounds were also carried out using TGA and DTA techniques. Efficiency of sorption of metal ions by the modified lignin was also investigated. It was found that, the peroxylignin and its derivatives show higher efficiency toward metal ions uptake than the soda lignin.