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Preparation and Characteristics of Soda Lime for Carbon Dioxide Absorption

이산화탄소 흡수를 위한 소다라임 제조 및 특성

  • Young-Jin Kim (Department of Research and Development, Korea Institute of Limestone and Advanced Materials) ;
  • Seok-Je Kwon (Department of Research and Development, Korea Institute of Limestone and Advanced Materials) ;
  • Jun-Hyung Seo (Department of Research and Development, Korea Institute of Limestone and Advanced Materials) ;
  • Yang-Soo Kim (Department of Research and Development, Korea Institute of Limestone and Advanced Materials) ;
  • Kye-Hong Cho (Department of Research and Development, Korea Institute of Limestone and Advanced Materials) ;
  • Jin-Sang Cho (Department of Research and Development, Korea Institute of Limestone and Advanced Materials)
  • 김영진 (한국석회석신소재연구소 연구개발부) ;
  • 권석제 (한국석회석신소재연구소 연구개발부) ;
  • 서준형 (한국석회석신소재연구소 연구개발부) ;
  • 김양수 (한국석회석신소재연구소 연구개발부) ;
  • 조계홍 (한국석회석신소재연구소 연구개발부) ;
  • 조진상 (한국석회석신소재연구소 연구개발부)
  • Received : 2023.03.14
  • Accepted : 2023.03.23
  • Published : 2023.04.30

Abstract

In this study, soda lime was prepared from slaked lime to expand the scope of limestone use. To evaluate carbon dioxide absorption, an extruder-type and disc-type pelletizers were used to make the soda lime using bentonite as an additive. Regardless of the pelletizing process, the peak of CaCO3 was confirmed in soda lime due to its reaction with carbon dioxide. Furthermore, it was confirmed that both calcite and aragonite were present together. The soda lime prepared using the disc-type pelletizer showed a larger specific surface area than that prepared using the extruder-type pelletizer did, and the specific surface area improved on adding bentonite. The carbon dioxide absorption rate increased under the sample condition with an enhanced specific surface area.

본 연구에서는 석회석 활용분야 확대를 위해 소석회를 이용한 소다라임 제조 기초 실험을 실시하였다. 소다라임 제조를 위해 압출식 방식과 디스크 방식의 펠렛타이져를 이용하였으며, 첨가제로 벤토나이트를 투입하여 제조한 소다라임의 이산화탄소 흡수 특성을 평가하였다. 실험결과, 제조 방식에 관계없이 이산화탄소와의 반응에 따라 소다라임에서 CaCO3의 peak가 확인되었으며, 방해석과 아라고나이트가 함께 생성된 것을 확인하였다. 디스크 방식으로 제조한 소다라임이 압출방식에 비해 더 큰 비표면적을 나타내었고, 벤토나이트를 첨가한 조건에서도 비표면적이 향상되었다. 비표면적이 향상된 시료 조건에서 이산화탄소 흡수율이 증가되는 것으로 확인되었다.

Keywords

Acknowledgement

본 과제(결과물)는 2022년도 교육부의 재원으로 한국연구재단의 지원을 받아 수행된 지자체-대학 협력기반 지역혁신 사업의 결과입니다.(2021RIS-001)

References

  1. Kim, H. S., 2011 : Necessity of refining domestic limestone, Korean Inst. of Resources Recycling, 20(4), pp.3-22. https://doi.org/10.7844/kirr.2011.20.4.003
  2. Moropoulou, A., Bakolas, A., Aggelakopoulou, E., 2001 : The effect on limestone characteristics and calcination temperature to the reactivity of the quicklime, Cement and concrete research, 31(4), pp.633-639. https://doi.org/10.1016/S0008-8846(00)00490-7
  3. Yoshizawa Lime Industry. https://www.yoshizawa.co.jp/class/class08, March 3, 2023.
  4. Kim, K. E., 2004, KR. 10-2004-0013047.
  5. Jin, S. H., 2001, KR, 20-2000-0008641.
  6. Seung, E. S., Kim, D. W., Shim, J. C., 2002 : Clinical study of the duration of CO2 absorption of ROK-and USA-produced soda lime and their re-use time after being exhausted, Korean Journal of Anesthesiology, 40(4), pp. 455-459. https://doi.org/10.4097/kjae.2001.40.4.455
  7. Aitkenhead, A. R., Thompson, J., Rowbotham, D. J., et al., 2013 : Smith and Aitkenhead's texbook of anaesthesia, pp.280-281, 6th Edition, Elsevier Health Sciences, Beijing.
  8. Loeb, R. G., Gravenstein, N., 2018 : Simultaneous color change at opposite ends carbon dioxide absorbent canister, Anesthesiology, 129(6), pp.1170-1170. https://doi.org/10.1097/ALN.0000000000002415
  9. Shin, Y. J., Han, H. K., 2019 : Phase change of calcium carbonate by temperature and RPM in continuous crystallizer, Korean Chem. Eng. Res., 57(5), pp.666-671.
  10. Gang, S. G., Jung, J. W., 2021 : Swelling characteristics of clay minerals according to the ionic strength in pore water, J. Korean Soc. Hazard Mitig, 21(6), pp.201-207.  https://doi.org/10.9798/KOSHAM.2021.21.6.201