• Title/Summary/Keyword: slurry materials

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Effect of Bio-Sulfur Modified by Slaked Lime on Cement Hydration Properties (소석회에 의해 개질된 바이오 황이 시멘트 수화 특성에 미치는 영향)

  • Woong-Geol Lee;Lae-Bong Han;Sung-Hyun Cho;Pyeong-Su Lee;Myong-Shin Song
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.4
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    • pp.509-516
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    • 2023
  • The use of sulfur(S) in concrete has been variously studied as a way to improve salt resistance in concrete. However, sulfur is a solid material and is difficult to powder, which has disadvantages in its usability as an admixture or mixture for cement and concrete. For these problem, polymers such as dicyclopentadiene have been used to modify sulfur, but this also exists in a sticky state after modifying and does not improve the fundamental problem. So, reforming sulfur with slaked lime and the effect on cement hydration was examined by reforming sulfur with slaked lime, and the following conclusions were obtained. Depending on the reaction conditions, slaked lime modified bio-sulfur exists in a slurry state containing unreacted sulfur, unreacted slaked lime, calcium-sulfur(Ca-S) compounds and water. When slaked lime modified bio-sulfur is used as a cement mixture, salt resistance of concrete with slaked lime modified bio-sulfur is to be superior to that of plain concrete. This is believed to be because structure of cement hydrates with slaked lime modified bio-sulfur is to be more dense to that of plain cement hydrates by the continued presence of ettringite and can be used as a cement mixture in concrete.

Optimization for Ammonia Decomposition over Ruthenium Alumina Catalyst Coated on Metallic Monolith Using Response Surface Methodology (반응표면분석법을 이용한 루테늄 알루미나 메탈모노리스 코팅촉매의 암모니아 분해 최적화)

  • Choi, Jae Hyung;Lee, Sung-Chan;Lee, Junhyeok;Kim, Gyeong-Min;Lim, Dong-Ha
    • Clean Technology
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    • v.28 no.3
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    • pp.218-226
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    • 2022
  • As a result of the recent social transformation towards a hydrogen economy and carbon-neutrality, the demands for hydrogen energy have been increasing rapidly worldwide. As such, eco-friendly hydrogen production technologies that do not produce carbon dioxide (CO2) emissions are being focused on. Among them, ammonia (NH3) is an economical hydrogen carrier that can easily produce hydrogen (H2). In this study, Ru/Al2O3 catalyst coated onmetallic monolith for hydrogen production from ammonia was prepared by a dip-coating method using a catalyst slurry mixture composed of Ru/Al2O3 catalyst, inorganic binder (alumina sol) and organic binder (methyl cellulose). At the optimized 1:1:0.1 weight ratio of catalyst/inorganic binder/organic binder, the amount of catalyst coated on the metallic monolith after one cycle coating was about 61.6 g L-1. The uniform thickness (about 42 ㎛) and crystal structure of the catalyst coated on the metallic monolith surface were confirmed through scanning electron microscopy (SEM) and X-ray diffraction (XRD) analysis. Also, a numerical optimization regression equation for NH3 conversion according to the independent variables of reaction temperature (400-600 ℃) and gas hourly space velocity (1,000-5,000 h-1) was calculated by response surface methodology (RSM). This model indicated a determination coefficient (R2) of 0.991 and had statistically significant predictors. This regression model could contribute to the commercial process design of hydrogen production by ammonia decomposition.

Field Survey on the Structure and Manure Treatment of Two-Storey and Sawdust Pig Houses in Korea (국내 2층 돈사와 톱밥돈사의 구조 및 분뇨처리 실태조사)

  • Jeong J. W.;Yoo Y. H.;Song J. I.;Kim T. I.;Jeon B. S.;Yang C. B.
    • Journal of Animal Environmental Science
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    • v.11 no.3
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    • pp.169-176
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    • 2005
  • The farm house structure, ventilation system and manure treatment of two-storey buildings and sawdust pig houses were surveyed and analyzed. Based on the data for ten selected farms in five provinces during eight months, the goal is to eventually establish a standard two-storey pig house. Manure treatments were composting, slurry and activated sludge in two-storey pig houses, while fermentation method was done in sawdust pig house. The depth of sawdust as a litter material were 10 to 60cm, with a duration of 1/2, 1, 3 and 6 months, respectively. The ventilation systems were the mechanical type in two-storey pig houses and natural system in the sawdust pig house. Side wall in the two-storey pig house was enclosed with insulation materials such as block, colored metal sheet and sandwich panels. The minimum ceiling height in the first floor of the two-storey pig house was 2.0m and the maximum was 3.0m. On the second floor, ceiling height ranged from 2.0 to 2.7m. The construction cost in the two-storey systems were $700\~140$, and sidewall curtain systems were $30\~40$ thousand Won/pyung.

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Engineering Properties of Sound Absorbing Foamed Concrete Using Bottom Ash Depending on Mix Factors (배합요인에 따른 바텀애시 미분말을 사용한 흡음형 기포콘크리트의 공학적 특성)

  • Kim, Jin-Man;Kang, Cheol
    • Journal of the Korea Institute of Building Construction
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    • v.9 no.5
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    • pp.63-70
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    • 2009
  • This study is part of an ongoing research project on the development of a sound-absorbing lightweight foamed concrete manufactured by a hydro-thermal reaction between silica and calcium. As the silica source, pulverized bottom ash was used, and as several cementitious powders of ordinary portland cement, alumina cement and calcium hydroxide were used. Manufacture of foamed concrete was accomplished using the pre-foaming method to make a continuous pore system, which is the method of making the foam by using a foaming agent, then making the slurry by mixing the foam, water, and powders. The experiment factors are W/B, foam agent dilution ratio, and foam ratio, and test items are compressive strength, dry density, void ratio, and absorption rate, as evaluated by NRC. The experiment results showed that the sound absorption of lightweight foamed concrete satisfied NRC requirements for the absorbing materials in most of the experiments. It is thus concluded that foam ratio was the most dominant factor, and significantly affected all properties of lightweight foamed concrete in this study. W/B rarely affected total void ratio and continuous void ratio as well as compressive strength, and dry density and foam agent dilution ratio also had little effect onalmost all properties. The analysis of the correlation between NRC, absorption time, continuous void ratio, and absorption time showed that the interrelationship of the continuous void ratio was high.

An Experimental Study on the Optimum Mix Design and Site Application Case of Soil Mixing Wall for Trench Stability (구벽안정성을 위한 SMW 최적배합비 및 현장적용 사례에 관한 연구)

  • Kwon, Yeong-Ho
    • Journal of the Korea Concrete Institute
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    • v.27 no.4
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    • pp.419-426
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    • 2015
  • The purpose of this study is to investigate experimentally the optimum mix design and site application case of soil mixing wall (SMW) method which is cost-effective technique for construction of walls for cutoff wall and excavation support as well as for ground improvement before constructing LNG storage tank typed under-ground. Considering native soil condition in site, main materials are selected ordinary portland cement, bentonite as a binder slurry and also it is applied $1,833kg/m^3$ as an unit volume weight of native soil, Variations for soil mixing wall are as followings ; (1) water-cement ratio 4cases (2) mixing velocity (rpm) 3levels (3) bleeding capacity and ratio, compressive strength in laboratory and site application test. As test results, bleeding capacity and ratio are decreased in case of decreasing water-cement ratio and increasing mixing velocity. Required compressive strength (1.5 MPa) considering safety factors in site is satisfied with the range of water-cement ratio 150% below, and test results of core strength are higher than those of specimen strength in the range of 8~23% by actual application of element members including outside and inside in site construction work. Therefore, optimum mix design of soil mixing wall is proposed in the range of unit cement $280kg/m^3$, unit bentonite $10kg/m^3$, water-cement ratio 150% and mixing velocity 90rpm and test results of site application case are satisfied with the required properties.

Joint Displacement Resistance Evaluation of Waterproofing Material in Railroad Bridge Deck (철도교량상판 방수재료 선정을 위한 균열거동저항 성능평가)

  • Bae, Young-Min;Oh, Dong-Cheon;Park, Yong-Gul
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.11
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    • pp.683-692
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    • 2020
  • A joint displacement resistance evaluation method for selecting waterproofing materials in railway bridge decks is proposed. The displacement range for an evaluation is determined by finite element method (FEM) analysis of a load case based on an existing high-speed PSC Girder Box railroad bridge structure. The FEM analysis results were used to calculate the minimum joint displacement range to be applied during testing (approximately 1.5 mm). For the evaluation, four commonly used waterproofing membrane types, cementitious slurry coating (CSC), polyurethane coating system (PCS), self-adhesive asphalt sheet (SAS), and composite asphalt sheet (CAS), were tested, with five specimens of each membrane type. The joint displacement width range conditions, including the minimum displacement range obtained from FEM analysis, were set to be the incrementing interval, from 1.5, 3.0, 4.5, and 6.0 mm. The proposal for the evaluation criteria and the specimen test results demonstrated how the evaluation method is important for the sustainability of high-speed railway bridges.

Evaluation of Adhesion Characteristics of Crack Sealants Used in Asphalt Concrete Pavement (아스팔트 콘크리트 포장용 균열실링재의 부착특성 평가)

  • Lee, Jae-Jun;Kim, Seung-Hoon;Baek, Jong-Eun;Lim, Jae-Kyu;Kim, Yong-Joo
    • International Journal of Highway Engineering
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    • v.17 no.2
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    • pp.55-62
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    • 2015
  • Cracking is an inevitable fact of asphalt concrete pavements and plays a major role in pavement deterioration. Pavement cracking is one of the main factors determining the frequency and method of repair. Cracks can be treated with a number of preventative maintenance actions, including overlay surface treatments such as slurry sealing, crack sealing, or crack filling. Pavement cracks can show up as one or all of the following types: transverse, longitudinal, fatigue, block, reflective, edge, and slippage. Crack sealing is a frequently used pavement maintenance treatment because it significantly extends the pavement service life. However, crack sealant often fails prematurely due to a loss of adhesion. Because current test methods are mostly empirical and only provide a qualitative measure of the bond strength, they cannot accurately predict the adhesive failure of the sealant. This study introduces a laboratory test aimed at assessing the bonding of hot-poured crack sealant to the walls of pavement cracks. A pneumatic adhesion tensile testing instrument (PATTI) was adopted to measure the bonding strength of the hot-poured crack sealant as a function of the curing time and temperature. Based on a limited number of test results, the hot-poured crack sealants have very different bonding performances. Therefore, this test method can be proposed as part of a newly developed performance-based standard specification for hot-poured crack sealants for use in the future. PURPOSES : The purpose of this study was to evaluate both the adhesion and failure performance of a crack sealant as a function of its curing time and curing temperature. METHODS: A pneumatic adhesion tensile testing instrument (PATTI) was adopted to measure the adhesion performance of a crack sealant as a function of the curing time and curing temperature. RESULTS: With changes in the curing time, curing temperature, and sealant type, the bond strengths were found to be significantly different. Also, higher bond strengths were measured at lower temperatures. Different sealant types produced completely different bond strengths and failure behaviors. CONCLUSIONS: The bonding strength of an evaluated crack sealant was shown to differ depending on various factors. Two sealant types, which were composed of different raw materials, were shown to perform differently. The newly proposed test offers the possibility of evaluating and differentiating between different crack sealants. Based on alimited number of test results, this test method can be proposed as part of a newly developed performance-based standard specification for crack sealants or as part of a guideline for the selection of hot-poured crack sealant in the future.

Simulation of the flue gas treatment processes of an industrial-waste incinerator using Aspen plus (Aspen plus를 이용한 산업폐기물 소각로의 배가스 처리 공정 모사)

  • Lee, Ju-Ho;Jung, Moon-Hun;Kwon, Young-Hyun;Lee, Gang-Woo;Shon, Byung-Hyun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.10 no.11
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    • pp.3246-3252
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    • 2009
  • The interest on the recovery of thermal energy using the waste has been rising to solve the problems of continuous increase of waste generation and the depletion of the fossil fuel recently. The incineration has been used most popularly as a treatment process of the waste for the energy recovery. However, it is expected that incineration and design cost will increase in the treatment of air contaminant emitted from incinerator. This research has simulated the actual incinerator and the flue gas treatment system using the Aspen plus which is the software to simulate the chemical process. The incineration process is composed of the 1st and 2nd combustor to burn the waste, SNCR process to reduce the $NO_x$ using the urea, and the steam generation process to save the energy during incineration. The $Ca(OH)_2$ slurry was used as an acid gas (HCl, $SO_2$) treatment materials and the removal efficiency for the products from the neutralization of acid gas in SDA and combustion ash was simulated at the bag filter. The simulation result has been corresponded with the treatment efficiency of emitted gas from the actual industrial waste incinerator and it is presumed to be used to forecast the efficiencies of flue gas treatment system in the future.

Preparation of Flavor-enhancing Yeast Extract Using a Saccharomyces cerevisiae Strain with High RNA Content (고핵산 함유 Saccharomyces cerevisiae 균주를 이용한 정미성 효모 추출물의 제조)

  • Kim, Jae-Sik;Kim, Jin-Wook;Shim, Won;Kim, Jung-Wan;Park, Kwan-Hwa;Pek, Un-Hua
    • Korean Journal of Food Science and Technology
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    • v.31 no.2
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    • pp.475-481
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    • 1999
  • Yeast extracts were prepared using either autolysis or enzymatic digestion methods for industrial application of the Saccharomyces cerevisiae B24 strain developed previously to have high RNA content. Extraction ratio of yeast extract from yeast cell reached 65% when autolysis of yeast slurry having 10% solid content was induced at $50^{\circ}C$ and pH 5.0 by agitating with 100 rpm. However, neither 5'-IMP nor 5'-GMP was detected from the autolyzate. In another attempt to prepare a yeast extract S. cerevisiae B24 culture was treated at $90^{\circ}C$ and then treated by various enzymes including ${\beta}-1,3-glucanase$, phosphodiesterase (nuclease P1), adenylic deaminase, and a protease. The yeast extract prepared by the enzymatic digestion method contained 3.2g of 5'-IMP and 5'-GMP/100g dry yeast extract.

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Behavior of Geotextile Tube Composite Structure by 2-D Limit Equilibrium and Plane Strain Analysis (2차원 한계평형 및 평면변형해석을 통한 지오텍스타일 튜브 복합구조물의 거동분석)

  • Shin, Eunchul
    • Journal of the Korean GEO-environmental Society
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    • v.7 no.6
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    • pp.13-22
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    • 2006
  • The geotextile have been used in filtration and drainage for over 30 years in many applications of civil and environmental projects. Geotextile tube is compound technology of filtration and drainage property of geotextile. Geotextile have been used for various types of containers, such as small hand-filled sandbags, 3-dimensional fabric forms for concrete paste, large soil and aggregate filled geotextile gabion, prefabricated hydraulically filled containers, and other innovative systems involving containment of soils using geotextile. They are hydraulically filled with dredged materials. It have been applied in coastal protection and scour protection, dewatering method of slurry, and isolation of contaminated material. Recently, geotextile tube technology is no longer alternative construction technique but suitable desired solution. This paper presents the behavior of geotextile tube composite structure by 2-D limit equilibrium and plane strain analysis. 2-D limit equilibrium analysis was performed to evaluate the stability of geotextile tube composite structure for the lateral load and also the plane strain analysis was conducted to determine the design and construction factors. Based on the results of this paper, the three types of geotextile tube composite structure is stable. And the optimum tensile strength of geotextile is 151kN/m and maximum pumping pressure is 22.7kN/m.

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